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11.发明授权Method and composition for incorporating radiation-absorbing agents into polymers 有权将辐射吸收剂掺入聚合物中的方法和组合物
公开(公告)号：US6149692A
公开(公告)日：2000-11-21
申请号：US141128
申请日：1998-08-27
申请人： John Martin Lally , Deborah Jean Mulcahy , Achim Muller , Beat Muller , Bernhard Seiferling , Friedrich Stockinger
发明人： John Martin Lally , Deborah Jean Mulcahy , Achim Muller , Beat Muller , Bernhard Seiferling , Friedrich Stockinger
CPC分类号： G02B1/043 , C08F290/04 , D06P1/0064 , D06P3/58 , D06P5/2005
摘要： A method of incorporating dyes into polymeric materials. The method involved contacting a functionalized dye with a high molecular weight crosslinkable polymer precursor, dispensing the solution into a mold and applying radiation, thereby forming a molded article having dye covalently bonded to the polymer backbone. A preferred product is a visibility tinted disposable contact lens comprising poly(vinyl alcohol). Various embodiments of the innovative method offer advantages in reduced fabrication cycles, reduced extractables, elimination of post-polymerization activation steps, elimination of post-polymerization extraction steps and reduced scrap and costs associated with lens handling.
摘要翻译： 将染料掺入聚合物材料的方法。 该方法包括使官能化染料与高分子量可交联聚合物前体接触，将溶液分配到模具中并施加辐射，从而形成具有共价键合到聚合物主链上的染料的模制品。 优选的产品是包括聚（乙烯醇）的可见度着色的一次性隐形眼镜。 创新方法的各种实施方案在减少制造周期，减少的可萃取物，消除后聚合活化步骤，消除后聚合萃取步骤以及降低的废料以及与透镜处理相关的成本方面提供了优点。
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12.发明授权Curable composition of polyether sulfone or polyether ketone copolymer and unsaturated imide 失效聚醚砜或聚醚酮共聚物和不饱和酰亚胺的固化组合物
公开(公告)号：US4883845A
公开(公告)日：1989-11-28
申请号：US299294
申请日：1989-01-23
IPC分类号： C08K5/35 , C08G59/04 , C08G59/30 , C08G65/40 , C08G65/48 , C08G73/12 , C08G75/23 , C08L63/00 , C08L71/00 , C08L71/08 , C08L71/10 , C08L81/00 , C08L81/02 , C08L81/06
CPC分类号： C08L63/00 , C08G59/04 , C08G59/302 , C08G65/4012 , C08G65/48 , C08G73/12 , C08G75/23 , C08J5/24 , C08L71/00 , C08G2650/20 , C08J2379/08 , C08L2312/00
摘要： The invention relates to curable compositions comprising(a) a copolyether resin having end groups --OR.sup.1 linked direct to phenyl nuclei and containing 1 to 50 mol % of repeating structural units of formula I ##STR1## and 99 to 50 mol % of repeating structural units of formula II ##STR2## wherein R.sup.1 is hydrogen, a phenylene radical substituted by amino agroups or ethylenically unsaturated radicals or is a 2,3-epoxypropyl radical, R.sup.2 is a direct C--C bond or a group of formula --C.sub.r H.sub.2r --, --O--, --S--, --CO-- or --SO.sub.2 --, r is 1 to 20, R.sup.3 is hydrogen or methyl, R.sup.4, R.sup.5 and R.sup.7 are inert substituents, m, n and o are each independently 0, 1 or 2, p is 1 or 2, R.sup.6 is a radical of a bisphenol, X and Y are --SO.sub.2 -- or --CO--, and(b) at least one compound of formula VIII, IX or X ##STR3## wherein A forms a maleimidyl, nadicimidyl, allylnadicimidyl or methallylnadicimidyl system, and R.sup.14 and R.sup.15 are mono- or divalent alipahtic, cycloaliphatic, aromatic or heterocyclic radicals, and R.sup.16 and an aromatic radical of valency t and t is an integer from 3 to 12.The compounds can be used as matrix resins for the preparation of fibrous composite structures.
摘要翻译： 本发明涉及可固化组合物，其包含（a）具有端基-OR1的共聚醚树脂，直接与苯基核连接并含有1至50mol％的式I（I）的重复结构单元和99至50mol％的 重复式II的结构单元（II）其中R1是氢，被氨基或乙烯基不饱和基取代的亚苯基，或是2,3-环氧丙基，R2是直接的CC键或式 - R 2，R 2，R 3，R 3，R 3，R 3，R 5，R 5和R 7是惰性取代基，m，n和o各自独立地为0， 1或2，p为1或2，R6为双酚基团，X和Y为-SO 2 - 或-CO-，（b）至少一种式VIII，IX或X化合物（VIII （IX）其中A形成马来酰亚胺基，N-二亚氨基亚氨基，烯丙基壬二酰亚胺基或甲代烯丙基酰亚胺基系统，R 14和R 15是单或二价的Alipahtic，脂环族，芳族或杂环基， 并且R 16和价态t和t的芳族基团是3至12的整数。该化合物可以用作制备纤维复合结构体的基质树脂。
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公开(公告)号：US4611041A
公开(公告)日：1986-09-09
申请号：US725866
申请日：1985-04-22
IPC分类号： C08F26/00 , C07C67/00 , C07C239/00 , C07C261/04 , C08F12/26 , C08F26/02 , C08G59/00 , C08G59/40 , C08G59/44 , C09J163/00 , C08F20/42 , C08F120/42 , C08F220/42
CPC分类号： C08F12/26 , C08F26/02 , C08G59/4014 , C08G59/44
摘要： N-Cyanoacylamide compounds of the formula I ##STR1## wherein R.sub.1 is hydrogen, alkyl, cycloalkyl or aryl, R.sub.2 is hydrogen or alkyl and R.sub.3 is alkylene or arylenealkylene, are prepared by reacting 1 mol of an N-cyanocarboxylic acid amide salt with 1 mol of a halogen compound in a polar, aprotic solvent.The N-cyanoacylamide compounds of the formula I can be used for hardening epoxide resins, for the preparation of isomelamine or for the preparation of linear polymers which can be crosslinked by heat.
摘要翻译： 式I的N-氰基酰胺化合物其中R1是氢，烷基，环烷基或芳基，R2是氢或烷基，R3是亚烷基或亚芳基亚烷基，是通过使1摩尔N-氰基羧酸酰胺 在极性非质子溶剂中与1mol卤素化合物盐。 式I的N-氰基酰胺化合物可用于固化环氧树脂，用于制备异质凝胺或用于制备可通过加热交联的线性聚合物。
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公开(公告)号：US4518748A
公开(公告)日：1985-05-21
申请号：US568684
申请日：1984-01-06
CPC分类号： C08G59/623 , C08G14/06
摘要： Curable mixtures containing (a) epoxide compounds with on average more than one 1,2-epoxide group per molecule, (b) the condensates prepared from certain phenols, certain amines and aldehydes or ketones in an acid medium and, where relevant, (c) curing accelerators. The novel curable mixtures have a good storage stability and give shaped substances with outstanding resistance to chemicals.
摘要翻译： 含有（a）每分子平均具有多于一个1,2-环氧基的环氧化合物的可固化混合物，（b）在酸性介质中由某些酚，某些胺和醛或酮制备的缩合物， ）固化促进剂。 新型可固化混合物具有良好的储存稳定性，并具有出色的抗化学药品的成型物质。
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公开(公告)号：US4302573A
公开(公告)日：1981-11-24
申请号：US147682
申请日：1980-05-07
IPC分类号： C08G59/00 , C07C275/16 , C07D207/28 , C07D207/40 , C07D207/404 , C07D207/44 , C07D207/452 , C07F1/08 , C07F3/00 , C07F3/06 , C07F9/40 , C07F15/00 , C08G59/50 , C08G59/68 , C08G59/70
CPC分类号： C07D207/404 , C07C255/00 , C07C275/16 , C07D207/28 , C07D207/452 , C07F3/003 , C07F9/4006 , C08G59/5093 , C08G59/70
摘要： Novel carboxylic acid metal salt/amine complexes are prepared by reacting 1 mol of a carboxylic acid metal salt of the formula(A.sup..crclbar.).sub.2 ME.sup.2+in which A.sup..crclbar. is the anion of a carboxylic acid which contains polar substituents or radicals and in particular contains an amide or imide grouping, such as a halogenoacetic acid, nitrilo-, cyano- or ureido-acetic acid, monoamidosuccinic acid, succinimidyl- or maleimidyl-alkanecarboxylic acid, benzenesulphonic acid or pyrrolidone-5-carboxylic acid, and Me.sup.2+ is a divalent metal cation, with 1 mol of a diamine of the formulaR.sub.1 --NH--R--NH--R.sub.2in which R is an aliphatic radical having not more than 7 C atoms or is a cycloaliphatic radical and R.sub.1 and R.sub.2 are hydrogen, alkyl having 1 to 4 C atoms, cyclohexyl, benzyl, 2-aminoethyl or 3-aminopropyl, in a polar organic solvent and in the temperature range from 25.degree. to 200.degree. C., to give complex compounds. The novel complex compounds are suitable as catalytic curing agents for epoxide resins.
摘要翻译： 通过使1摩尔式（A（ - ））2ME2 +的羧酸金属盐与其中A（ - ）是含有极性取代基或基团的羧酸的阴离子反应制备新的羧酸金属盐/胺络合物，和 特别是含有酰胺或酰亚胺基，例如卤代乙酸，次氮基，氰基或脲基 - 乙酸，单酰氨基琥珀酸，琥珀酰亚胺基或马来酰亚胺基 - 链烷羧酸，苯磺酸或吡咯烷酮-5-羧酸，Me2 + 二价金属阳离子与1摩尔式R 1 -NH-R-NH-R 2的二胺，其中R是具有不超过7个C原子的脂族基团或者是脂环族基团，R 1和R 2是氢，烷基 在极性有机溶剂中，在25〜200℃的温度范围内具有1〜4个C原子，环己基，苄基，2-氨基乙基或3-氨基丙基，得到络合物。 新型复合化合物适用于环氧树脂的催化固化剂。
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公开(公告)号：US5270435A
公开(公告)日：1993-12-14
申请号：US816839
申请日：1992-01-09
CPC分类号： C08G75/23 , C08G65/4012 , C08L71/00
摘要： Polyarylene ethers which, based on the total amount of the structural units present in the polyether resin, contain 2-100 mol % of a recurring structural unit of formula I ##STR1## and 0-98 mol % of a recurring structural unit of formula II wherein each a is 1 or 2, 10 to 100% of X, based on the total number of the bonds X present in the structural units of formulae I and II, are --SO.sub.2 --, and 0 to 90% of X are --CO--, and A is a group of formula IIIa-IIIg: ##STR2## wherein Y is --CH.sub.2 --, --C(CH.sub.3).sub.2 --, --C(CF.sub.3).sub.2 --, --S--, --SO--, --SO.sub.2 --, --O-- or --CO--, and the aromatic rings in the structural units of formulae I and II are unsubstituted or substituted by one or more alkyl groups of 1 to 4 carbon atoms, have good solubility in organic solvents and are suitable preferably for modifying other plastics materials or for use as matrix resins for the production of fibrous composite structures.
摘要翻译： 基于存在于聚醚树脂中的结构单元的总量的聚亚芳基醚含有2-100摩尔％的式I的重复结构单元（I）和0-98摩尔％的重复结构单元 式II其中每个a为1或2,10至100％X，基于存在于式I和II的结构单元中的键X的总数为-SO 2 - ，且为 （IIIa）（IIIc）（IIIc）（IIIc）（IIId）图像（IIId）（图像）（IIId） （IIIf）（IIIg）其中Y是-CH 2 - ， - C（CH 3）2 - ， - C（CF 3）2 - ， - S - ， - SO - ， - SO 2 - O-或-CO-，并且式I和II的结构单元中的芳环是未取代的或被一个或多个具有1至4个碳原子的烷基取代，在有机溶剂中具有良好的溶解度，并且适合用于改性其它 塑料材料或用作生产纤维复合结构体的基质树脂。
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公开(公告)号：US5212278A
公开(公告)日：1993-05-18
申请号：US493058
申请日：1990-03-13
CPC分类号： C08G75/23 , C08G65/4012 , C08L63/00
摘要： The invention relates to polyarylene ethers which contain, based on the total amount of structural elements present in the polyether resin, 5-100 mol % of a recurring structural element of the formula I ##STR1## and 0-95 mol % of a recurring structural element of the formula II ##STR2## in which X and X' independently of one another are --SO--, --SO.sub.2 -- or --CO--, one of the radicals R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is phenyl or phenyl which is substituted by one to three (C.sub.1 -C.sub.4)alkyl groups and the remaining radicals R.sub.1, R.sub.2, R.sub.3 and R.sub.4 independently of one another are hydrogen, (C.sub.1 -C.sub.4)alkyl, phenyl or phenyl which is substituted by one to three (C.sub.1 -C.sub.4)alkyl groups, and A is an aromatic radical, at least 25% of the bonds X and/or Y and/or the bridge members contained in A being --SO.sub.2 --.These industrial materials are distinguished by very good mechanical properties and good solubility.
摘要翻译： 本发明涉及聚亚芳基醚，它包含基于存在于聚醚树脂中的结构元素的总量，5-100mol％的式I（I）的重复结构元素和0-95mol％的 其中X和X'彼此独立地是-SO - ， - SO 2 - 或-CO-的式II（II）的重复结构元件，基团R 1，R 2，R 3和R 4之一是苯基 或被一至三个（C 1 -C 4）烷基取代的苯基，其余基团R 1，R 2，R 3和R 4彼此独立地是氢，（C 1 -C 4）烷基，苯基或被一个至 三个（C 1 -C 4）烷基，A是芳族基团，A中包含的至少25％的键X和/或Y和/或桥连构成为-SO 2 - 。 这些工业材料的特征在于非常好的机械性能和良好的溶解性。
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公开(公告)号：US5126427A
公开(公告)日：1992-06-30
申请号：US665492
申请日：1991-03-06
IPC分类号： C08G75/00 , C08G75/23 , C08J5/18 , C08L63/00 , C09D181/00 , C09D181/06
摘要： Polyarylene ether sulfones which have a reduced viscosity of 0.1 to 2.0 dl/g, measured at 25.degree. C. in a 1% solution in N-methylpyrrolidone (NMP), and which contain, based on the total number of structural units present in the polyarylene ether sulfone resin, 99-1 mol % of a recurring structural unit of formula I ##STR1## and 1-99 mol % of a recurring structural unit of formula II--O--Ar.sub.2 --O--Ar.sub.1 -- (II)wherein the aromatic rings in the structural unit of formula I are unsubstituted or substituted by one or more C.sub.1 -C.sub.4 alkyl groups, C.sub.1 -C.sub.4 alkoxy groups or halogen atoms, Ar.sub.1 is a radical of formula IIIa-IIIc ##STR2## wherein a is 0 or 1, ##STR3## which radical is unsubstituted or substituted by one or more C.sub.1 -C.sub.4 alkyl groups, C.sub.1 -C.sub.4 alkoxy groups or halogen atoms, and Ar.sub.2 is a radical of formula IVa-IVe ##STR4## wherein b is 0 or 1 ##STR5## wherein c is 0 or 1 ##STR6## wherein Z is --CO--, --SO.sub.2 --, --SO--, --S--, --O--, ##STR7## wherein R is methyl or phenyl, which radical is unsubstituted or substituted by one or more C.sub.1 -C.sub.4 alkyl groups, C.sub.1 -C.sub.4 alkoxy groups or halogen atoms, are soluble in customary organic solvents and can be processed from the solution to films or incorporated in other matrix resins.
摘要翻译： 在25℃下在1％N-甲基吡咯烷酮（NMP）溶液中测定的具有0.1至2.0dl / g的比浓粘度的聚亚芳基醚砜，并且基于存在于 聚亚芳基醚砜树脂，99-1摩尔％的式I的重复结构单元（I）和1-99mol％的式II-O-Ar-O-Ar1-（II）的重复结构单元， 其中式I的结构单元中的芳环是未取代的或被一个或多个C 1 -C 4烷基，C 1 -C 4烷氧基或卤素原子取代，Ar 1是式IIIa-IIIc（IIIa）的基团，其中a是 0或1，
（IIIb）或 （IIIc），该基团是未取代的或被一个或多个C 1 -C 4烷基，C 1 -C 4烷氧基或卤素原子取代，Ar 2是式IVa-IVe基团 （IVa）其中b为0或1（IVb）（IVc）（IVc）其中c为0或1（IVe）其中Z为-CO-， - SO2-，-SO-，-S-，-O-， 其中R是甲基或苯基，该基团是未被取代的或被一个或多个C 1 -C 4烷基，C 1 -C 4烷氧基或卤原子取代的，可溶于常规有机溶剂中，并且可以从溶液中加工成膜或并入 其他基体树脂。 -
19.发明授权Heat-curable epoxy resin mixtures containing imide compounds and condensation products of phenols, amines and aldehydes or ketones 失效含有酰亚胺化合物和酚类，胺类和醛类或酮类的缩合产物的热固性环氧树脂混合物
公开(公告)号：US4552935A
公开(公告)日：1985-11-12
申请号：US568845
申请日：1984-01-06
IPC分类号： C08G59/00 , C08G14/06 , C08G59/40 , C08G59/56 , C08G59/62 , C08L63/00 , C08L61/00 , C08G8/32
CPC分类号： C08G59/623 , C08G14/06 , C08G59/4042 , C08L63/00
摘要： Heat-curable mixtures containing (a) epoxy compounds having on average more than one 1,2-epoxy group per molecule, (b) monoimides or polyimides of specific unsaturated dicarboxylic acids of the formula I ##STR1## wherein A is an x-valent aromatic or aliphatic radical, R.sup.1 is hydrogen or methyl, and x is 1, 2 or 3, and (c) products of condensing specific phenols, specific amines and aldehydes or ketones in an acid medium.The novel curable mixtures have a long shelf life and give rise to moulded materials which are highly resistant to chemicals and resistant to boiling water.
摘要翻译： 包含（a）每分子平均具有多于一个1,2-环氧基的环氧化合物的热固化性混合物，（b）式I的特定不饱和二羧酸的单酰亚胺或聚酰亚胺其中A是 x价芳族或脂族基，R1是氢或甲基，x是1,2或3，和（c）在酸性介质中缩合特异性酚，特定胺和醛或酮的产物。 新型可固化混合物具有长的保存期限，并产生耐化学品和耐沸水的成型材料。
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20.发明授权Process for the preparation of pyrrolidonecarboxylic acid/metal/amine complexes 失效吡咯烷酮羧酸/金属/胺络合物的制备方法
公开(公告)号：US4219650A
公开(公告)日：1980-08-26
申请号：US956522
申请日：1978-10-31
IPC分类号： C07D207/28 , C07F1/08 , C07F3/06 , C07F3/08 , C07F15/04
CPC分类号： C07D207/28
摘要： A process for the preparation of pyrrolidone-5-carboxylic acid/metal salt/amine complexes by reacting 1 mol of a L-glutamic acid lower alkyl ester/metal salt complex with 1 mol of an aliphatic, cycloaliphatic or aromatic-aliphatic damine or 2 mols of an aliphatic or cycloaliphatic monoamine in a polar solvent, with the elimination of 2 mols of alcohol.The complex compounds prepared according to the invention are valuable curing agents for epoxide resins.
摘要翻译： 通过使1摩尔L-谷氨酸低级烷基酯/金属盐络合物与1摩尔脂肪族，脂环族或芳香族 - 脂肪族或2摩尔的脂肪族或二元醇的混合物制备吡咯烷酮-5-羧酸/金属盐/胺络合物的方法 脂肪族或脂环族单胺在极性溶剂中的摩尔数，同时消除2摩尔醇。 根据本发明制备的复合化合物是环氧树脂的有价值的固化剂。
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