Isoparaffin-olefin alkylation with a catalyst complex of a cation exchange resin, BF{HD 3 {B and HF
    13.
    发明授权
    Isoparaffin-olefin alkylation with a catalyst complex of a cation exchange resin, BF{HD 3 {B and HF 失效
    异戊烷 - 烯烃与阳离子交换树脂BF {HD 3 {B和HF的催化剂络合物]烷基化

    公开(公告)号:US3879489A

    公开(公告)日:1975-04-22

    申请号:US45836274

    申请日:1974-04-05

    Applicant: MOBIL OIL CORP

    Abstract: This invention relates to a process for effecting alkylation of an isoparaffin with an olefin in the presence of a catalyst comprising a macroreticular acid cation exchange resin characterized by a surface acid concentration of less than about 0.5 milliequivalents of hydrogen ion per square meter surface area, boron trifluoride in an amount of at least about 0.1 equivalent per equivalent of resin acid groups but not in excess of that required to saturate said resin and hydrogen fluoride in an amount between about 0.1 equivalent and about 10 equivalents per equivalent of resin acid groups.

    Abstract translation: 本发明涉及一种在含有大网络酸阳离子交换树脂的催化剂存在下用烯烃进行烷烃化的方法,其特征在于表面酸浓度小于约0.5毫当量的每平方米表面积的氢离子,硼 三氟化硼的量为每当量树脂酸基团至少约0.1当量,但不超过将所述树脂和氟化氢饱和所需的量相当于每当量树脂酸基团约0.1当量至约10当量。

    Oxidative dehydrogenation of organic compounds
    14.
    发明授权
    Oxidative dehydrogenation of organic compounds 失效
    有机化合物的氧化脱氢

    公开(公告)号:US3875252A

    公开(公告)日:1975-04-01

    申请号:US42999474

    申请日:1974-01-02

    Applicant: MOBIL OIL CORP

    CPC classification number: C07C5/46 C07C15/40

    Abstract: Alkyl aromatic compounds, such as ethylbenzene, are dehydrogenated by reaction with carbonyl sulfide in the vapor phase in the presence of either silica or a supported heavy metal catalyst, e.g., iron on an oxide carrier.

    Abstract translation: 在二氧化硅或负载型重金属催化剂,例如氧化物载体上的铁的存在下,通过与气相中的羰基硫反应,烷基芳族化合物如乙苯脱氢。

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