公开(公告)号：US06699939B2

公开(公告)日：2004-03-02

申请号：US10176723

申请日：2002-06-21

Applicant: James A. Schwindeman ,  Robert J. Letchford ,  Conrad W. Kamienski ,  Roderic P. Quirk

Inventor： James A. Schwindeman ,  Robert J. Letchford ,  Conrad W. Kamienski ,  Roderic P. Quirk

IPC: C08F29704

CPC classification number: C08F36/04 ,  C08C19/44 ,  C08F4/46 ,  C08F4/48 ,  C08F4/72 ,  C08F8/34 ,  C08F12/04 ,  C08F2810/40 ,  C08F112/08

Abstract: Hetero-telechelic polymers having the formula: FG—(Q)d—Z—J—[A(R1R2R3)]x  (I) wherein FG is a protected or non-protected functional group; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; d is an integer from 10 to 200; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R1R2R3)]x is a protecting group, wherein A is an element selected from Group IVa of the Periodic Table of Elements; R1, R2, and R3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and cycloalkyl and substituted cycloalkyl containing 5 to 12 carbon atoms; and x is dependent on the valence of J and varies from one when J is oxygen or sulfur to two when J is nitrogen, with the proviso J and FG are not the same, and processes for making the same.

公开(公告)号：US06221991B1

公开(公告)日：2001-04-24

申请号：US09109210

申请日：1998-06-30

Applicant: Robert J. Letchford ,  James A. Schwindeman ,  Conrad W. Kamienski ,  Roderic P. Quirk

Inventor： Robert J. Letchford ,  James A. Schwindeman ,  Conrad W. Kamienski ,  Roderic P. Quirk

IPC: C08F2054

CPC classification number: C08F20/56 ,  C08F4/46 ,  C08F4/72 ,  C08F8/00 ,  C08F20/14 ,  C08F20/18 ,  C08F20/42 ,  C08F2810/40 ,  C08G81/021 ,  C08F120/14

Abstract: Polar polymers having the following formula: FG-(Q)d-Rn-Z-J-[A(R1R2R3)]x   (I) wherein FG is H or a protected or non-protected functional group; Q is a polar hydrocarbyl group derived by incorporation of a polar compound selected from group consisting of esters, amides, and nitrites of acrylic and methacrylic acid, and mixtures thereof; d is an integer from 10 to 2000; R is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; n is an integer from 0 to 5; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R1R2R3)]x is a protecting group, in which A is an element selected from Group IVa of the Periodic Table of Elements; R1, R2, and R3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and cycloalkyl and substituted cycloalkyl containing 5 to 12 carbon atoms; and x is dependent on the valence of J and varies from one when J is oxygen or sulfur to two when J is nitrogen, and living anionic polymerization processes for preparing the same.

Abstract translation: 具有下式的极性聚合物：其中FG是H或被保护或未被保护的官能团; Q是通过掺入选自丙烯酸和甲基丙烯酸的酯，酰胺和亚硝酸盐的极性化合物及其混合物衍生的极性烃基; d为10〜2000的整数， R是通过引入选自共轭二烯烃，烯基取代的芳族烃及其混合物的化合物衍生的饱和或不饱和烃基; n为0〜5的整数， Z是含有3-25个碳原子的支链或直链烃基，任选含有芳基或取代的芳基; J是氧，硫或氮; [A（R 1 R 2 R 3）] x是保护基，其中A是选自元素周期表Ⅳa族的元素; R 1，R 2和R 3各自独立地选自氢，烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的取代烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的芳基或取代芳基 和含有5至12个碳原子的环烷基和取代的环烷基; 并且x取决于J的化合价，并且当J为氮时J为氧或硫时为2，并且当用于制备其的活性阴离子聚合方法时，其为不同的。

公开(公告)号：US06184309B2

公开(公告)日：2001-02-06

申请号：US09207226

申请日：1998-12-08

Applicant: James A. Schwindeman ,  John F. Engel ,  Eric J. Granger ,  Conrad W. Kamienski ,  Roderic P. Quirk

Inventor： James A. Schwindeman ,  John F. Engel ,  Eric J. Granger ,  Conrad W. Kamienski ,  Roderic P. Quirk

IPC: C08F800

CPC classification number: C08C19/00 ,  C08F8/00 ,  C08F2810/40 ,  C08F112/08 ,  C08F120/14

Abstract: A process for removing a protecting group from a polymer. Protected functional groups of a polymer may be deprotected by treating the polymer in the presence of an acid catalyst, including organic acids, mineral acids, heterogeneous acid systems, Lewis acids, and fluoride ion sources.

Abstract translation: 从聚合物中除去保护基团的方法。 通过在酸催化剂存在下处理聚合物，包括有机酸，无机酸，多相酸体系，路易斯酸和氟离子源，可以将保护的聚合物的官能团脱保护。

公开(公告)号：US5900464A

公开(公告)日：1999-05-04

申请号：US677793

申请日：1996-07-10

Applicant: Robert J. Letchford ,  James A. Schwindeman ,  Conrad W. Kamienski ,  Roderic P. Quirk

Inventor： Robert J. Letchford ,  James A. Schwindeman ,  Conrad W. Kamienski ,  Roderic P. Quirk

IPC: C08F4/46 ,  C08F4/72 ,  C08F8/00 ,  C08F20/14 ,  C08F20/18 ,  C08F20/42 ,  C08F20/56 ,  C08G81/02 ,  C08L31/02 ,  C08F297/02

CPC classification number: C08F20/56 ,  C08F20/14 ,  C08F20/18 ,  C08F20/42 ,  C08F4/46 ,  C08F4/72 ,  C08F8/00 ,  C08G81/021 ,  C08F2810/40

Abstract: Polar polymers having the following formula:FG--(Q).sub.d --R.sub.n --Z--J--�A(R.sup.1 R.sup.2 R.sup.3)!.sub.x(I)wherein FG is H or a protected or non-protected functional group; Q is a polar hydrocarbyl group derived by incorporation of a polar compound selected from group consisting of esters, amides, and nitriles of acrylic and methacrylic acid, and mixtures thereof; d is an integer from 10 to 2000; R is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; n is an integer from 0 to 5; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; �A(R.sup.1 R.sup.2 R.sup.3)!.sub.x is a protecting group, in which A is an element selected from Group IVa of the Periodic Table of Elements; R.sup.1, R.sup.2, and R.sup.3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and cycloalkyl and substituted cycloalkyl containing 5 to 12 carbon atoms; and x is dependent on the valence of J and varies from one when J is oxygen or sulfur to two when J is nitrogen, and living anionic polymerization processes for preparing the same.

Abstract translation: 具有下式的极性聚合物：FG-（Q）d-Rn-Z-J- [A（R1R2R3）] x（I）其中FG是H或被保护或未被保护的官能团; Q是通过掺入选自丙烯酸和甲基丙烯酸的酯，酰胺和腈的极性化合物及其混合物衍生的极性烃基; d为10〜2000的整数， R是通过引入选自共轭二烯烃，烯基取代的芳族烃及其混合物的化合物衍生的饱和或不饱和烃基; n为0〜5的整数， Z是含有3-25个碳原子的支链或直链烃基，任选含有芳基或取代的芳基; J是氧，硫或氮; [A（R 1 R 2 R 3）] x是保护基，其中A是选自元素周期表Ⅳa族的元素; R 1，R 2和R 3各自独立地选自氢，烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的取代烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的芳基或取代芳基 和含有5至12个碳原子的环烷基和取代的环烷基; 并且x取决于J的化合价，并且当J为氮时J为氧或硫时为2，并且当用于制备其的活性阴离子聚合方法时，其为不同的。

公开(公告)号：US5081191A

公开(公告)日：1992-01-14

申请号：US591572

申请日：1990-09-20

Applicant: Roderic P. Quirk

Inventor： Roderic P. Quirk

IPC: C08F297/02

CPC classification number: C08F297/02

Abstract: Novel polymers prepared by anionic polymerization techniques containing phenol, silyl ether, aminophenyl functionality or carboxylic acid or ester.

Abstract translation: 通过含有苯酚，甲硅烷基醚，氨基苯基官能团或羧酸或酯的阴离子聚合技术制备的新型聚合物。

公开(公告)号：US09156696B2

公开(公告)日：2015-10-13

申请号：US13808406

申请日：2011-07-06

Applicant: Xuehui Dong ,  Wenbin Zhang ,  Stephen Z. D. Cheng ,  Roderic P. Quirk

Inventor： Xuehui Dong ,  Wenbin Zhang ,  Stephen Z. D. Cheng ,  Roderic P. Quirk

IPC: C07C69/52 ,  C01B31/02 ,  C07C17/16 ,  C07C23/18 ,  C07C29/42 ,  C07C29/68 ,  C07C35/44 ,  C07C69/606 ,  C07C69/63

CPC classification number: C01B31/0213 ,  C01B32/152 ,  C07C17/16 ,  C07C23/18 ,  C07C29/42 ,  C07C29/68 ,  C07C35/44 ,  C07C69/606 ,  C07C69/63 ,  C07C2604/00 ,  C07C35/46

Abstract: The preparation of novel fullerynes which are fullerenes (e.g. C60, C70, C80, etc.) that contain one or more alkyne functionalities and may contain additional functional groups such as hydroxyls, halogens, esters, haloesters, phenyl, oligo(ethylene glycol)s, perfluorinated alkyl chains, and the like. Two desired preparation routes are disclosed. The first one is the Fischer esterification in desired solvents using a special designed reactor in contrast to the heretofore initial Steglich reaction that results in side reactions and low yields. The second one uses acetylide Grignard reagents that have reduced nucleophilicity and higher stability in contrast to the use of heretofore initial lithium organyls or other Grignard reagents that would add to C60 with possible multi-additions in an uncontrollable manner.

Abstract translation: 含有一个或多个炔官能团并且可以含有另外的官能团例如羟基，卤素，酯，卤代酯，苯基，低聚（乙二醇）的富勒烯（例如C60，C70，C80等）的新型富勒烯的制备 ，全氟化烷基链等。 公开了两种期望的制备途径。 第一种是在所需溶剂中使用特殊设计的反应器进行费歇尔酯化，与迄今为止初始的Steglich反应相反，其导致副反应和低产率。 第二种使用与使用迄今初始的锂有机物或其他格利雅试剂相比，其具有降低的亲核性和更高的稳定性的乙炔化物格氏试剂，其将以不可控的方式以可能的多次添加添加到C60。

公开(公告)号：US07157549B2

公开(公告)日：2007-01-02

申请号：US10852980

申请日：2004-05-25

Applicant: Roderic P. Quirk ,  Robert T. Mathers

Inventor： Roderic P. Quirk ,  Robert T. Mathers

IPC: C08G65/10

CPC classification number: C08G65/105

Abstract: A method is provided for polymerizing oxiranes by employing a lithium-containing polymerization initiator in a liquid reaction medium devoid of polymerization additives. Linear and star polymers can be produced by practicing the subject method.

Abstract translation: 提供了在不含聚合添加剂的液体反应介质中使用含锂聚合引发剂使环氧烷聚合的方法。 线性和星形聚合物可以通过实践本发明的方法制备。

公开(公告)号：US06812295B2

公开(公告)日：2004-11-02

申请号：US10801367

申请日：2004-03-16

Applicant: James Anthony Schwindeman ,  Robert J. Letchford ,  Eric John Granger ,  Roderic P. Quirk

Inventor： James Anthony Schwindeman ,  Robert J. Letchford ,  Eric John Granger ,  Roderic P. Quirk

IPC: C08F818

CPC classification number: C08C19/44 ,  C07F1/02 ,  C08F36/04 ,  C08F4/48

Abstract: The present invention provides functionalized electrophiles, their analogous initiators, and processes for preparing these compounds. The present invention also relates to homotelechelic, heteroelechelic, and radial functional polydiene polymers, polyarylene polymers and polydiene/polyarylene copolymers, their optionally hydrogenated analogues, their optionally deprotected analogs, and process for preparing these functionalized polymers.

Abstract translation: 本发明提供功能化的亲电子试剂，它们的类似的引发剂，以及制备这些化合物的方法。 本发明还涉及同基亚类，异亚烯基和径向功能性聚二烯聚合物，聚亚芳基聚合物和聚二烯/聚亚芳基共聚物，它们任选氢化的类似物，它们任选脱保护的类似物，以及制备这些官能化聚合物的方法。

公开(公告)号：US06235819B1

公开(公告)日：2001-05-22

申请号：US09002056

申请日：1997-12-31

Applicant: David F. Lawson ,  Ashley S. Hilton ,  John R. Schreffler ,  Roderic P. Quirk

Inventor： David F. Lawson ,  Ashley S. Hilton ,  John R. Schreffler ,  Roderic P. Quirk

IPC: C08K534

CPC classification number: C08K5/3492

Abstract: A method for scavenging amines within polymeric compositions of matter comprising the step of adding to a polymeric composition of matter at least one triazine compound, wherein said triazine compound is defined according to the formula: where X is selected from the group consisting of hydrogen, halides, amines, and organic groups having from 1 to about 20 carbon atoms, Y is selected from the group consisting of halides, alkoxy derivatives, amine derivatives, aryloxy derivatives, and urea derivatives, with the proviso that the substituent Y is displacable by a reaction with a secondary amine, and Z is selected from the group consisting of alkoxy derivatives, amino derivatives, aryloxy derivatives, and urea derivatives, with the proviso that the substituent Z is displacable by a reaction with a secondary amine.

Abstract translation: 一种用于清除物质的聚合物组合物中的胺的方法，其包括向物质的聚合物组合物中加入至少一种三嗪化合物的步骤，其中所述三嗪化合物根据下式定义：其中X选自氢，卤化物 ，具有1至约20个碳原子的胺和有机基团，Y选自卤化物，烷氧基衍生物，胺衍生物，芳氧基衍生物和脲衍生物，条件是取代基Y可通过反应置换 与仲胺，Z选自烷氧基衍生物，氨基衍生物，芳氧基衍生物和脲衍生物，条件是取代基Z可通过与仲胺的反应置换。

公开(公告)号：US6063873A

公开(公告)日：2000-05-16

申请号：US2054

申请日：1997-12-31

Applicant: David F. Lawson ,  Ashley S. Hilton ,  John R. Schreffler ,  Roderic P. Quirk

Inventor： David F. Lawson ,  Ashley S. Hilton ,  John R. Schreffler ,  Roderic P. Quirk

IPC: B60C1/00 ,  C07D251/34 ,  C07D251/50 ,  C08K5/29 ,  C08K5/3492 ,  C08L21/00 ,  C08C19/22

CPC classification number: C08K5/34922 ,  Y10T152/10495

Abstract: A rubber tread stock comprising a vulcanizable composition of matter, and a triazine, wherein said triazine is defined by the formula ##STR1## where X is selected from the group consisting of hydrogen, halides, amines, and organic groups having from 1 to about 20 carbon atoms, Y is selected from the group consisting of halides, alkoxy derivatives, amine derivatives, aryloxy derivatives, and urea derivatives, with the proviso that the substituent Y is displacable by a reaction with a secondary amine, and Z is selected from the group consisting of alkoxy derivatives, amino derivatives, aryloxy derivatives, and urea derivatives, with the proviso that the substituent Z is displacable by a reaction with a secondary amine.

Abstract translation: 一种橡胶胎面料，其包含可硫化的物质组合物和三嗪，其中所述三嗪由下式定义：其中X选自氢，卤化物，胺和具有1至约20个碳原子的有机基团， Y选自卤化物，烷氧基衍生物，胺衍生物，芳氧基衍生物和脲衍生物，条件是取代基Y可以通过与仲胺的反应置换，并且Z选自烷氧基 衍生物，氨基衍生物，芳氧基衍生物和脲衍生物，条件是取代基Z可通过与仲胺的反应置换。