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公开(公告)号:US20150337210A1
公开(公告)日:2015-11-26
申请号:US14716472
申请日:2015-05-19
Applicant: SCHLUMBERGER TECHNOLOGY CORPORATION
Inventor: Trevor Lloyd Hughes , Alexander D. Wilson
IPC: C10G1/04
CPC classification number: C10G1/045 , C10G2300/1033 , C10G2300/208 , E21B21/066
Abstract: Oil residues are removed from contaminated solids, in particular from cuttings produced from drilling a borehole using an oil-based drilling fluid, by contacting the solids with a washing fluid which comprises carbon dioxide and cosolvent under conditions at which carbon dioxide is a supercritical fluid and the cosolvent is in solution in the supercritical carbon dioxide and then separating washed solids from the washing fluid; wherein the washing fluid comprises at least 5% by volume of cosolvent which is one or more organic compounds with a Hildebrand solubility parameter in a range from 16 to 21 MPa1/2. The washing process may be applied to drilling cuttings produced offshore.
Abstract translation: 通过在二氧化碳是超临界流体的条件下使固体与包含二氧化碳和共溶剂的洗涤液接触,将油残留物从被污染的固体,特别是从使用油基钻井液钻孔的切屑中除去, 共溶剂处于超临界二氧化碳的溶液中,然后从洗涤液中分离洗涤的固体; 其中所述洗涤流体包含至少5体积%的共溶剂,所述共溶剂是一种或多种具有希尔德布兰德溶解度参数在16至21MPa1 / 2范围内的有机化合物。 洗涤过程可用于近海生产的钻屑。
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公开(公告)号:US20230018020A1
公开(公告)日:2023-01-19
申请号:US17756917
申请日:2020-11-18
Applicant: Schlumberger Technology Corporation
Inventor: Jill F. Geddes , Trevor Lloyd Hughes , Evgeny Borisovich Barmatov
IPC: G01N23/223 , G01B15/02
Abstract: A method for measuring average thickness of a metal or alloy coating on a metal or alloy substrate using an X-ray fluorescence (XRF) spectrometer is used when the coating has an uneven surface at different distances from a measurement window of the XRF spectrometer. The method includes measuring elemental composition of the coating or substrate using the XRF spectrometer and obtaining the average thickness of the coating using a calibration relationship between coating thickness and elemental composition of the coating or substrate. The metal or alloy coating may be a metal or alloy coating of a plurality of outer armor wires wrapped around a cable. The method may be used to analyze coating thickness changes over time or along the length of the cable, or to analyze a corrosive environment in order to choose optimal material for a metal or alloy coating.
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公开(公告)号:US20230003517A1
公开(公告)日:2023-01-05
申请号:US17757096
申请日:2020-12-08
Applicant: Schlumberger Technology Corporation
Inventor: Jill F. Geddes , Trevor Lloyd Hughes , Evgeny Borisovich Barmatov , Man Yi Ho , Paul Barnes
Abstract: A method for measuring a thickness of a deposit layer on a metal or alloy substrate using an X-ray fluorescence (XRF) spectrometer, where the deposit layer includes scale deposits or corrosion products. As part of the method, an elemental composition of the deposit layer or the metal or alloy substrate is measured using the XRF spectrometer. The thickness of the deposit layer is obtained from the elemental composition using a calibration relationship between deposit layer thicknesses and corresponding elemental compositions of the deposit layer or the metal/alloy substrate. The method can be applied to determine the rate of deposit layer formation and evaluate the effectiveness of a treatment.
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公开(公告)号:US10808164B2
公开(公告)日:2020-10-20
申请号:US15508512
申请日:2015-08-26
Applicant: SCHLUMBERGER TECHNOLOGY CORPORATION
Inventor: Evgeny Borisovich Barmatov , Trevor Lloyd Hughes , Jill F. Geddes
Abstract: A method of inhibiting corrosion of duplex stainless steel by aqueous acidic solution, comprises carrying out a preliminary treatment which is passivation of the steel while exposing the steel to a first aqueous acidic solution containing at least one organic corrosion inhibitor able to adsorb to a steel surface, so as to deposit a passivating and corrosion inhibiting film on the steel surface; and thereafter during a second period of time exposing the steel to a second aqueous acidic solution different from the first aqueous acidic solution and also containing at least one organic corrosion inhibitor able to adsorb to a steel. The second aqueous acidic solution maintains the film on the steel surface, such that weight loss through corrosion in the second period of time is lower than the weight loss which would be observed with the same second aqueous acidic solution but without carrying out the preliminary treatment.
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公开(公告)号:US10787745B2
公开(公告)日:2020-09-29
申请号:US15533315
申请日:2015-10-19
Applicant: SCHLUMBERGER TECHNOLOGY CORPORATION
Inventor: Evgeny Borisovich Barmatov , Jill F. Geddes , Lynne Patricia Crawford , Trevor Lloyd Hughes , Michaela Nagl-Vogel
IPC: C23F11/00 , C23F11/08 , C23F11/10 , C23F11/12 , C23F11/16 , C23F11/173 , C23F11/04 , C09D7/63 , C09K8/54 , C23F11/14 , C09D5/08
Abstract: A corrosion inhibiting composition which is a liquid carrier in which is dissolved or dispersed a corrosion inhibitor compound comprising at least one moiety (A) which is an aliphatic, aromatic or mixed aliphatic/aromatic structure containing one or more hetero atoms which are nitrogen, oxygen, phosphorus or sulphur, and also at least one moiety (B) which contains one or more polymerisable groups containing double or triple bonded carbon, with the moieties (A) and (B) directly or indirectly covalently connected together.
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公开(公告)号:US20170240796A1
公开(公告)日:2017-08-24
申请号:US15508512
申请日:2015-08-26
Applicant: SCHLUMBERGER TECHNOLOGY CORPORATION
Inventor: Evgeny Borisovich Barmatov , Trevor Lloyd Hughes , Jill F. Geddes
Abstract: A method of inhibiting corrosion of duplex stainless steel by aqueous acidic solution, comprises carrying out a preliminary treatment which is passivation of the steel while exposing the steel to a first aqueous acidic solution containing at least one organic corrosion inhibitor able to adsorb to a steel surface, so as to deposit a passivating and corrosion inhibiting film on the steel surface; and thereafter during a second period of time exposing the steel to a second aqueous acidic solution different from the first aqueous acidic solution and also containing at least one organic corrosion inhibitor able to adsorb to a steel. The second aqueous acidic solution maintains the film on the steel surface, such that weight loss through corrosion in the second period of time is lower than the weight loss which would be observed with the same second aqueous acidic solution but without carrying out the preliminary treatment.
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公开(公告)号:US20150152321A1
公开(公告)日:2015-06-04
申请号:US14620979
申请日:2015-02-12
Applicant: Schlumberger Technology Corporation
Inventor: Zinaida Yurievna Usova , Anna Petrovna Dunaeva , Mohan K.R. Panga , Anatoly Vladimirovich Medvedev , Sergey Makarychev-Mikhailov , Evgeny Borisovich Barmatov , Trevor Lloyd Hughes
IPC: C09K8/80 , E21B43/24 , E21B43/267
CPC classification number: C09K8/80 , C09K2208/08 , E21B43/2405 , E21B43/267
Abstract: A method for forming proppant aggregates, for example downhole in an injection well, includes injecting a slurry including a thermo-responsive polymer with a low critical solution temperature and a proppant downhole, and heating the slurry above the low critical solution temperature of the polymer. The heating of the slurry above the low critical solution temperature of the polymer aggregates the proppant. A composition of the slurry includes a carrier fluid including a thermo-responsive polymer, a proppant, and optional additives.
Abstract translation: 用于形成支撑剂聚集体的方法,例如在注入井中的井下,包括将包含具有低临界溶解温度的热响应聚合物和支撑剂的浆料注入井下,并将该浆料加热到聚合物的低临界溶解温度以上。 高于聚合物低临界溶液温度的浆料的加热使支撑剂聚集。 浆料的组合物包括载体流体,其包括热响应聚合物,支撑剂和任选的添加剂。
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公开(公告)号:US20130244912A1
公开(公告)日:2013-09-19
申请号:US13889470
申请日:2013-05-08
Applicant: SCHLUMBERGER TECHNOLOGY CORPORATION
Inventor: Trevor Lloyd Hughes , Evgeny Borisovich Barmatov , Jill F. Geddes , Michael J. Fuller , Bruno Drochon , Sergey Makarychev-Mikhailov
IPC: C09K8/66
CPC classification number: C09K8/665 , C09K8/70 , C09K8/92 , E21B43/267
Abstract: A wellbore fluid is an aqueous carrier liquid with first and second hydrophobic particulate materials suspended therein. The first hydrophobic particles have a higher specific gravity than the second hydrophobic particles and the fluid also comprises a gas to wet the surface of the particles and bind them together as agglomerates. The fluid may be a fracturing fluid or gravel packing fluid and the first particulate material may be proppant or gravel. The lighter second particulate material and the gas both reduce the density of the agglomerates which form so that they settle more slowly from the fluid, or are buoyant and do not settle. This facilitates transport and placement in a hydraulic fracture or gravel pack. One application of this is when fracturing a gas-shale with slickwater. The benefit of reduced settling is better placement of proppant so that a greater amount of the fracture is propped open.
Abstract translation: 井筒流体是其中悬浮有第一和第二疏水性颗粒材料的水性载体液体。 第一疏水性颗粒具有比第二疏水性颗粒更高的比重,并且流体还包括用于润湿颗粒表面的气体并将其作为附聚物结合在一起。 流体可以是压裂流体或砾石填充流体,并且第一颗粒材料可以是支撑剂或砾石。 较轻的第二颗粒材料和气体都降低了附聚物的密度,使得它们从流体更缓慢地沉降,或者浮力并且不沉降。 这有助于运输和放置在水力裂缝或砾石包装中。 这种情况的一个应用是用瓦斯页岩压裂瓦斯页岩。 减少沉降的好处是支撑剂的更好的放置,使得更大量的裂缝被支撑开放。
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公开(公告)号:US20240318068A1
公开(公告)日:2024-09-26
申请号:US18680934
申请日:2024-05-31
Applicant: Schlumberger Technology Corporation
Inventor: Evgeny Borisovich Barmatov , Jill F. Geddes , Man Yi Ho , Trevor Lloyd Hughes , Lynne Patricia Crawford
Abstract: An aqueous acid composition that may be used, for example, in a matrix acidizing treatment can include an acid, a polymeric acid corrosion inhibitor, and an acid corrosion inhibitor intensifier. The acid corrosion inhibitor can include iodide ions and metal ions, with the metal ions being one or more of copper, silver, bismuth, or antimony. The molar ratio of metal ions to iodide ions can be 1:X, where X is greater than or equal to 2. The polymer of the polymeric acid corrosion inhibitor can have a molecular weight less than 100,000 g/mol.
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公开(公告)号:US12007226B2
公开(公告)日:2024-06-11
申请号:US17757096
申请日:2020-12-08
Applicant: Schlumberger Technology Corporation
Inventor: Jill F. Geddes , Trevor Lloyd Hughes , Evgeny Borisovich Barmatov , Man Yi Ho , Paul Barnes
CPC classification number: G01B15/02 , G01N17/006
Abstract: A method for measuring a thickness of a deposit layer on a metal or alloy substrate using an X-ray fluorescence (XRF) spectrometer, where the deposit layer includes scale deposits or corrosion products. As part of the method, an elemental composition of the deposit layer or the metal or alloy substrate is measured using the XRF spectrometer. The thickness of the deposit layer is obtained from the elemental composition using a calibration relationship between deposit layer thicknesses and corresponding elemental compositions of the deposit layer or the metal/alloy substrate. The method can be applied to determine the rate of deposit layer formation and evaluate the effectiveness of a treatment.
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