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    CATALYST SYSTEM FOR POLYMERISATION OF AN OLEFIN
    11.
    发明申请
    CATALYST SYSTEM FOR POLYMERISATION OF AN OLEFIN 有权
    用于聚合烯烃的催化剂体系

    公开(公告)号：US20160176998A1

    公开(公告)日：2016-06-23

    申请号：US14911028

    申请日：2014-08-11

    申请人： Martin Alexander ZUIDEVELD ,  Jaiprakash Brijlal SAINANI ,  Mahendrabhai Patel VIMALKUMAR ,  SAUDI BASIC INDUSTRIES CORPORATION ,  SABIC GLOBAL TECHNOLOGIES B.V.

    发明人： Martin Alexander Zuideveld ,  Jaiprakash Brijlal Sainani ,  Vimalkumar Mahendrabhai Patel

    IPC分类号： C08F210/16 ,  C07F7/02

    CPC分类号： C08F210/06 ,  C07F7/025 ,  C08F210/16 ,  C08F4/6465 ,  C08F4/6565 ,  C08F2500/12 ,  C08F2500/15

    摘要： The present invention relates to a catalyst system comprising a procatalyst, a co-catalyst and an external electron donor, wherein the external electron donor comprises a compound having the structure according to Formula I: Si(L)n(OR11)4-n (Formula I), wherein, Si is a silicon atom with valency 4+; O is an oxygen atom with valency 2− and O is bonded to Si via the silicon-oxygen bond; n is 1, 2, 3 or 4; R11 is a selected from the group consisting of linear, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; L is a group represented by (Formula II), wherein, L is bonded to the silicon atom via the nitrogen-silicon bond; L has a single substituent on the nitrogen atom, where this single substituent is an imine carbon atom; and X and Y are independently selected from the group consisting of a hydrogen atom; a heteroatom selected from group 13, 14, 15, 16 or 17 of the IUPAC Periodic Table of the Elements; a linear, branched and cyclic alkyl having at most 20 carbon atoms, optionally containing a heteroatom selected from group 13, 14, 15, 16 or 17 of the IUPAC Periodic Table of the Elements and an aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, optionally containing a heteroatom selected from group 13, 14, 15, 16 or 7 of the IUPAC Periodic Table of the Elements.

    摘要翻译： 本发明涉及包含前催化剂，助催化剂和外电子给体的催化剂体系，其中外电子给体包括具有式I结构的化合物：Si（L）n（OR 11）4-n（ 式I），其中Si是价态为4+的硅原子; O是具有2-价的氧原子，O经由硅 - 氧键与Si键合; n为1,2,3或4; R11选自具有至多20个碳原子的直链，支链和环状烷基和具有6至20个碳原子的芳族取代和未取代的烃基; L是由式（II）表示的基团，其中L通过氮 - 硅键与硅原子键合; L在氮原子上具有单个取代基，其中该单取代基是亚胺碳原子; X和Y独立地选自氢原子; 选自IUPAC元素周期表的第13,14,15,16或17族的杂原子; 含有至多20个碳原子的直链，支链和环状烷基，任选地含有选自元素周期表IUPAC元素周期表第13,14,15,16或17族的杂原子和具有6至20个碳原子的芳族取代和未取代的烃基 原子，任选地含有选自IUPAC元素周期表的第13,14,15,16或7族的杂原子。

    CATALYST SYSTEM FOR POLYMERISATION OF AN OLEFIN
    12.
    发明申请
    CATALYST SYSTEM FOR POLYMERISATION OF AN OLEFIN 审中-公开

    公开(公告)号：US20170283531A1

    公开(公告)日：2017-10-05

    申请号：US15625679

    申请日：2017-06-16

    申请人： SAUDI BASIC INDUSTRIES CORPORATION ,  SABIC GLOBAL TECHNOLOGIES B.V.

    发明人： Martin Alexander Zuideveld ,  Jaiprakash Brijlal Sainani ,  Vimalkumar Mahendrabhai Patel

    IPC分类号： C08F210/06 ,  C08F210/16 ,  C07F7/02

    CPC分类号： C08F210/06 ,  C07F7/025 ,  C08F210/16 ,  C08F4/6465 ,  C08F4/6565 ,  C08F2500/12 ,  C08F2500/15

    摘要： The present invention relates to a catalyst system comprising a procatalyst, a co-catalyst and an external electron donor, wherein the external electron donor comprises a compound having the structure according to Formula I: Si(L)n(OR11)4−n  (Formula I), wherein, Si is a silicon atom with valency 4+; O is an oxygen atom with valency 2− and O is bonded to Si via the silicon-oxygen bond; n is 1, 2, 3 or 4; R11 is a selected from the group consisting of linear, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; L is a group represented by Formula II wherein, L is bonded to the silicon atom via the nitrogen-silicon bond; L has a single substituent on the nitrogen atom, where this single substituent is an imine carbon atom; and X and Y are independently selected from the group consisting of a hydrogen atom; a heteroatom selected from group 13, 14, 15, 16 or 17 of the IUPAC Periodic Table of the Elements; a linear, branched and cyclic alkyl having at most 20 carbon atoms, optionally containing a heteroatom selected from group 13, 14, 15, 16 or 17 of the IUPAC Periodic Table of the Elements and an aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, optionally containing a heteroatom selected from group 13, 14, 15, 16 or 17 of the IUPAC Periodic Table of the Elements.

    Catalyst system for polymerisation of an OLEFIN
    13.
    发明授权
    Catalyst system for polymerisation of an OLEFIN 有权

    公开(公告)号：US09701773B2

    公开(公告)日：2017-07-11

    申请号：US14911028

    申请日：2014-08-11

    申请人： SAUDI BASIC INDUSTRIES CORPORATION ,  SABIC GLOBAL TECHNOLOGIES B.V.

    发明人： Martin Alexander Zuideveld ,  Jaiprakash Brijlal Sainani ,  Vimalkumar Mahendrabhai Patel

    IPC分类号： C08F210/16 ,  C07F7/02

    CPC分类号： C08F210/06 ,  C07F7/025 ,  C08F210/16 ,  C08F4/6465 ,  C08F4/6565 ,  C08F2500/12 ,  C08F2500/15

    摘要： The present invention relates to a catalyst system comprising a procatalyst, a co-catalyst and an external electron donor, wherein the external electron donor comprises a compound having the structure according to Formula I: Si(L)n(OR11)4-n (Formula I), wherein, Si is a silicon atom with valency 4+; O is an oxygen atom with valency 2− and O is bonded to Si via the silicon-oxygen bond; n is 1, 2, 3 or 4; R11 is a selected from the group consisting of linear, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; L is a group represented by (Formula II), wherein, L is bonded to the silicon atom via the nitrogen-silicon bond; L has a single substituent on the nitrogen atom, where this single substituent is an imine carbon atom; and X and Y are independently selected from the group consisting of a hydrogen atom; a heteroatom selected from group 13, 14, 15, 16 or 17 of the IUPAC Periodic Table of the Elements; a linear, branched and cyclic alkyl having at most 20 carbon atoms, optionally containing a heteroatom selected from group 13, 14, 15, 16 or 17 of the IUPAC Periodic Table of the Elements and an aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, optionally containing a heteroatom selected from group 13, 14, 15, 16 or 7 of the IUPAC Periodic Table of the Elements.

    CATALYST SYSTEM FOR POLYMERIZATION OF AN OLEFIN
    15.
    发明申请
    CATALYST SYSTEM FOR POLYMERIZATION OF AN OLEFIN 有权
    用于烯烃聚合的催化剂体系

    公开(公告)号：US20160311950A1

    公开(公告)日：2016-10-27

    申请号：US15106061

    申请日：2014-12-19

    申请人： SAUDI BASIC INDUSTRIES CORPORATION ,  SABIC GLOBAL TECHNOLOGIES B.V.

    发明人： Aurora Alexandra Batinas-Geurts ,  Martin Alexander Zuideveld ,  Raymond Gerlofsma ,  Henrica Norberta Alberta Maria Steenbakkers-Menting ,  Peter Degenhart

    IPC分类号： C08F210/06 ,  C08F110/06

    CPC分类号： C08F210/06 ,  C08F110/06 ,  C08L23/12 ,  C08L2207/02 ,  C08F210/02 ,  C08F2500/12 ,  C08F4/651 ,  C08F2/001 ,  C08F4/6565 ,  C08F4/6465 ,  C08L23/16

    摘要： A process for the preparation of a catalyst system for olefin polymerization, including: A) providing said procatalyst obtainable via a process comprising: i) contacting a compound R4zMgX42-z with an alkoxy- or aryloxy-containing silane compound to give a first intermediate reaction product, ii) optionally contacting the solid product obtained in step i) with at least one activating compound selected from an activating electron donor or metal alkoxide compound; iii) contacting the first or second intermediate reaction product, with a halogen-containing Ti-compound and optionally an internal electron donor to obtain the procatalyst; and B) contacting the procatalyst with a co-catalyst and at least diethylaminotriethoxysilane as the external donor. Further disclosed is a catalyst system obtained by the process; a process for preparing a polyolefin by contacting at least one olefin with the catalyst system; a polyolefin obtained thereby; a composition comprising a propylene-ethylene copolymer; a shaped article thereof; and use of polyolefin.

    摘要翻译： 一种制备用于烯烃聚合的催化剂体系的方法，包括：A）提供可通过以下方法获得的所述主催化剂，所述方法包括：i）使化合物R4zMgX42-z与含烷氧基或芳氧基的硅烷化合物接触，得到第一中间反应 产品，ii）任选地使步骤i）中获得的固体产物与选自活化电子给体或金属醇盐化合物的至少一种活化化合物接触; iii）使第一或第二中间反应产物与含卤素的Ti化合物和任选的内部电子给体接触以获得前催化剂; 和B）使前催化剂与助催化剂和至少二乙基氨基三乙氧基硅烷作为外给体接触。 进一步公开了通过该方法获得的催化剂体系; 通过使至少一种烯烃与催化剂体系接触来制备聚烯烃的方法; 由此获得的聚烯烃; 包含丙烯 - 乙烯共聚物的组合物; 其成型制品; 并使用聚烯烃。