摘要:
A molecular system that is reversibly switchable between four states includes two or more ends. At least three rotors and at least two stators are located between the ends. Each of the rotors is capable of rotating when under the influence of an electric field having a predetermined strength. The predetermined strength of the electric field for rotating one of the rotors is different than that of the predetermined strength of the electric field for rotating each of the other rotors. One or more conjugated connecting units links at least one of the at least three rotors and at least one of the at least two stators. The rotation of at least one of the at least three rotors switches the molecular system to one of the four states.
摘要:
A method for forming a functionalized latex polymer includes polymerizing a heterogeneous dispersion of water insoluble monomers in water, thereby forming a latex polymer. An at least partially water soluble halogenated non-ionic group is reacted with the latex polymer, whereby a halogen is displaced from the non-ionic group, thereby forming an at least partially water soluble non-ionic group that attaches to the latex polymer.
摘要:
Classes of molecules are disclosed which can, for example, be used in molecular switches. The classes of molecules include at least three segments—an electronic donor (“D”), a switchable bridge (“B”), and an electronic acceptor (“A”)—chemically connected and linearly arranged (e.g., D-B-A). The electronic donor can be an aromatic ring system with at least one electron donating group covalently attached; an aromatic ring system with an electron withdrawing group covalently attached is usually employed as the electronic acceptor; and the switchable bridge can be a pi system that can be switched on or off using an external electric field.
摘要:
The invention described herein includes a molecular switch, comprising: a donor subunit; an acceptor subunit; and an aromatic bridging subunit comprising one or more bridging groups for bonding the donor subunit to the aromatic bridging subunit and for bonding the acceptor subunit to the aromatic bridging subunit wherein the aromatic bridging subunit is conformable in a manner effective for polarizing and de-polarizing the molecular switch at a low electric field voltage.
摘要:
A digital dye having an optical change resulting from an electrochemical oxidation/reduction reaction is provided for use in a molecular system. The molecular system provides two different colors based on two different oxidation states of at least one digital dye in the molecular system. Further, an optical switch comprising the molecular system configured within an electric field generated by a pair of electrodes is provided, employing the above-described digital dye. Still further, a display device including a transparent display electrode, a counter electrode, and the molecular system disposed therebetween is provided, where the molecular system comprises at least one digital dye.
摘要:
A compound is disclosed. The compound has the general structure: wherein Y is selected from the group consisting of hydrocarbons, hydrocarbons including nitrogen in the carbon backbone, and hydrocarbons including oxygen in the carbon backbone; wherein R1 and R2 are each independently selected from the group consisting of hydrogen, linear hydrocarbons, branched hydrocarbons, and cyclic hydrocarbons and wherein R1 and R2 are not both hydrogen; wherein X is selected from the group consisting of CH2, O, N—R3, S, and nothing and wherein R3 is selected from the group consisting of hydrogen, branched hydrocarbons, linear hydrocarbons, and cyclic hydrocarbons; wherein m is an integer between 1 and 50, inclusive; wherein n is an integer between 1 and 10,000, inclusive; and wherein p, q, and z are each independently an integer greater than 0.
摘要:
An alcohol-soluble organic coating including a hole transport material formed on a surface of organic photoconductor is provided. The coating comprises a cationic alternate fluorene-based copolymer with phosphonium salt terminal groups embedded in an in-situ cross-linked polymer.
摘要:
An organic photoconductor includes an inner charge generation layer for generating charges and an outer charge transport layer for facilitating charge transport. The charge transport layer comprises a semi-interpenetrating hole-transport polymer or oligomer network in which the polymer or oligomer is cross-linked. A process for forming a charge transport layer in an organic photoconductor is also provided.
摘要:
A pigment-based ink comprises: a non-polar carrier fluid; and pigment particles suspended in the non-polar carrier fluid. The pigment particles are coated with a metal oxide that is modified with at least one silane coupling agent to introduce functional groups, steric stabilizers or both. A combination of an electronic display and an electronic ink is provided, as is a method for modifying the pigment particles.
摘要:
A doped protective coating for extending a lifetime of an organic photoconductor is provided. The coating includes an in-situ cross-linked polymer matrix and a substantially uniformly distributed dopant therein. The dopant comprises a charge transport molecular species. A process for coating the organic photoconductor and a coated organic photoconductor are also disclosed.