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    Copolymers of ethylene and/or α-olefins and vicinally disubstituted olefins
    13.
    发明授权
    Copolymers of ethylene and/or α-olefins and vicinally disubstituted olefins 失效
    乙烯和/或α-烯烃和邻近二取代烯烃的共聚物

    公开(公告)号：US07037989B2

    公开(公告)日：2006-05-02

    申请号：US10446325

    申请日：2003-05-27

    申请人： Smita Kacker ,  Enock Berluche ,  Timothy Daniel Shaffer ,  Jo Ann Marie Canich

    发明人： Smita Kacker ,  Enock Berluche ,  Timothy Daniel Shaffer ,  Jo Ann Marie Canich

    IPC分类号： C08F4/52

    CPC分类号： C08F210/02 ,  C08F210/08 ,  C08F210/16 ,  C08F2500/20 ,  C08F2500/03 ,  C08F210/06

    摘要： Substantially random ethylene and/or α-olefin copolymers containing units derived from vicinally disubstituted olefin monomers are described. The vicinally disubstituted olefin monomers may be represented by the generic formula (R1)CH═CH(R2), where R1 and R2 independently comprise hydrocarbyl or silyl-hydrocarbyl groups containing 1 or more carbon atoms, or may be linear, branched or cyclic substituted or unsubstituted hydrocarbyl groups having from 1-100 carbon atoms, or they may contain 30 or less carbon atoms. The copolymers may be prepared by coordination polymerization by means of contacting at least one vicinally disubstituted olefin monomer and ethylene and/or α-olefin, optionally with one or more other coordination polymerizable monomers, with a catalyst system comprising a monocyclopentadienyl heteroatom-containing Group 4 transition metal catalyst component.

    摘要翻译： 描述了含有衍生自邻近二取代的烯烃单体的单元的基本无规的乙烯和/或α-烯烃共聚物。 邻位二取代的烯烃单体可以由通式（R 1）CH-CH（R 2）表示，其中R 1和R 2 独立地包含含有1个或更多个碳原子的烃基或甲硅烷基 - 烃基，或者可以是具有1-100个碳原子的直链，支链或环状取代或未取代的烃基，或者它们可以含有30或 碳原子少。 共聚物可以通过使至少一个相邻二取代的烯烃单体和乙烯和/或α-烯烃（任选地与一种或多种其它配位可聚合单体）与含有单环戊二烯基杂原子的第4组的催化剂体系 过渡金属催化剂组分。

    Copolymers of ethylene and germinally disubstituted olefins
    16.
    发明授权
    Copolymers of ethylene and germinally disubstituted olefins 失效
    乙烯和二取代烯烃的共聚物

    公开(公告)号：US5866665A

    公开(公告)日：1999-02-02

    申请号：US959040

    申请日：1997-10-28

    申请人： Timothy Daniel Shaffer ,  Jo Ann Marie Canich ,  Kevin Richard Squire

    发明人： Timothy Daniel Shaffer ,  Jo Ann Marie Canich ,  Kevin Richard Squire

    IPC分类号： C08F4/64 ,  C08F4/645 ,  C08F4/659 ,  C08F4/6592 ,  C08F210/02 ,  C08F210/10

    CPC分类号： C08F210/02 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  Y10S526/916

    摘要： Substantially random ethylene copolymers containing at least 3.0 mole percent of geminally disubstituted olefin monomers are described. The geminally disubstituted olefin monomers can be represented by the generic formula R.sub.1 =R.sub.2 (R.sub.3)(R.sub.4), where R.sub.1 is CH.sub.2, R.sub.2 is C, and R.sub.3 and R.sub.4 are, independently, essentially linear hydrocarbyl groups having from 1 to 30 carbon atoms, or more, and containing one carbon atom bound directly to R.sub.2. The copolymers can be prepared by coordination polymerization by means of contacting at least one geminally disubstituted olefin monomer and ethylene, optionally with one or more other coordination polymerizable monomers, with a catalyst system comprising a monocyclopentadienyl, heteroatom-containing Group 4 transition metal catalyst component.

    摘要翻译： 描述了含有至少3.0摩尔％的双取代烯烃单体的基本上无规的乙烯共聚物。 氧化双取代的烯烃单体可以由通式R 1（R 2）（R 3）（R 4）表示，其中R 1是CH 2，R 2是C，R 3和R 4独立地是具有1至30个碳原子的直链烃基 或更多，并含有直接与R2结合的一个碳原子。 共聚物可以通过使至少一种双取代烯烃单体和任选与一种或多种其它配位聚合单体的乙烯与包含单环戊二烯基，含杂原子的第4族过渡金属催化剂组分的催化剂体系接触进行配位聚合制备。

    Multiple catalyst system for olefin polymerization and polymers produced therefrom
    18.
    发明申请
    Multiple catalyst system for olefin polymerization and polymers produced therefrom 有权

    公开(公告)号：US20090069475A1

    公开(公告)日：2009-03-12

    申请号：US11888870

    申请日：2007-08-02

    申请人： Peijun Jiang ,  Armenag Hagop Dekmezian ,  Jo Ann Marie Canich ,  Charles Lewis Sims ,  Ramin Abhari ,  Cesar Alberto Garcia-Franco ,  David Raymond Johnsrud

    发明人： Peijun Jiang ,  Armenag Hagop Dekmezian ,  Jo Ann Marie Canich ,  Charles Lewis Sims ,  Ramin Abhari ,  Cesar Alberto Garcia-Franco ,  David Raymond Johnsrud

    IPC分类号： C08F10/00 ,  C08F10/04 ,  C08F10/14 ,  C08L91/06

    CPC分类号： C09J123/12 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F4/65927 ,  C08F10/00 ,  C08F110/06 ,  C08F210/06 ,  C08L57/02 ,  C08L2666/02 ,  C09J5/00 ,  C09J7/20 ,  C09J123/10 ,  C09J2201/606 ,  C09J2201/622 ,  C09J2205/31 ,  C09J2401/006 ,  C09J2421/00 ,  C09J2423/006 ,  C09J2423/046 ,  C09J2423/106 ,  C09J2427/006 ,  C09J2433/00 ,  Y10S526/943 ,  C08F4/65904 ,  C08F2500/15 ,  C08F2500/05 ,  C08F2500/20 ,  C08F2500/17 ,  C08F2500/09 ,  C08F2500/12 ,  C08F236/20 ,  C08F2500/03 ,  C08F210/16 ,  C08F4/63904

    摘要： This invention relates to a polymer comprising one or more C3 to C40 olefins, optionally one or more diolefins, and less than 15 mole % of ethylene, where the polymer has: a) a Dot T-Peel of 1 Newton or more; and b) a branching index (g′) of 0.95 or less measured at the Mz of the polymer; c) an Mw of 100,000 or less. This invention also relates a polymer comprising one or more C3 to C40 olefins where the polymer has: a) a Dot T-Peel of 1 Newton or more on Kraft paper; b) a branching index (g′) of 0.95 or less measured at the Mz of the polymer; c) a Mw of 10,000 to 100,000; and d) a heat of fusion of 1 to 70 J/g. This invention also relates a polymer comprising one or more C3 to C40 olefins where the polymer has: a) a Dot T-Peel of 1 Newton or more on Kraft paper; b) a branching index (g′) of 0.98 or less measured at the Mz of the polymer; c) a Mw of 10,000 to 60,000; d) a heat of fusion of 1 to 50 J/g. This invention also relates to a homopolypropylene or a copolymer of propylene and up to 5 mole % ethylene having: a) an isotactic run length of 1 to 30 (isotactic run length “IRL” is defined to be the percent of mmmm pentad divided by 0.5×percent of mmmr pentad) as determined by Carbon 13 NMR, preferably 3 to 25, more preferably 4 to 20, b) a percent of r dyad of greater than 20%, preferably from 20 to 70% as determined by Carbon 13 NMR, and c) a heat of fusion of 70 J/g or less, preferably 60 J/g or less, more preferably between 1 and 55 J/g, more preferably between 4 and 50 J/g. This invention further relates to a process to produce an olefin polymer comprising: 1) selecting a first catalyst component capable of producing a polymer having an Mw of 100,000 or less and a crystallinity of 5% or less at selected polymerization conditions; 2) selecting a second catalyst component capable of producing polymer having an Mw of 100,000 or less and a crystallinity of 20% or more at the selected polymerization conditions; 3) contacting the catalyst components in the presence of one or more activators with one or more C3 to C40 olefins, at the selected polymerization conditions in a reaction zone; 4) obtaining the polymer. This invention further relates to a continuous process to produce a branched olefin polymer comprising: 1) selecting a first catalyst component capable of producing a polymer having an Mw of 100,000 or less and a crystallinity of 5% or less under selected polymerization conditions; 2) selecting a second catalyst component capable of producing polymer having an Mw of 100,000 or less and a crystallinity of 20% or more at the selected polymerization conditions; 3) contacting the catalyst components in the presence of one or more activators with one or more C3 to C40 olefins, and, optionally one or more diolefins; 4) at a temperature of greater than 100° C.; 5) at a residence time of 120 minutes or less; 6) wherein the ratio of the first catalyst to the second catalyst is from 1:1 to 50:1; 7) wherein the activity of the catalyst components is at least 100 kilograms of polymer per gram of the catalyst components; and wherein at least 20% of the olefins are converted to polymer.

    Soluble late transition metal catalysts for olefin oligomerizations III
    19.
    发明授权
    Soluble late transition metal catalysts for olefin oligomerizations III 失效
    用于烯烃低聚的可溶性后过渡金属催化剂III

    公开(公告)号：US07429548B2

    公开(公告)日：2008-09-30

    申请号：US11204828

    申请日：2005-08-16

    申请人： Baiyi Zhao ,  Enock Berluche ,  Smita Kacker ,  Jo Ann Marie Canich

    发明人： Baiyi Zhao ,  Enock Berluche ,  Smita Kacker ,  Jo Ann Marie Canich

    IPC分类号： B01J21/00 ,  B01J23/00 ,  B01J25/00 ,  B01J29/00 ,  B01J31/00

    CPC分类号： C07F15/0066 ,  C07F15/045

    摘要： A This invention relates to a composition comprising a catecholate ligand, palladium or nickel, and an ancillary ligand with the following structure: where Pn is a Group-15 element; H is hydrogen; R7 and R8 are independently hydrogen or C1-C30 hydrocarbyl radicals, or both are C1-C30 hydrocarbyl radicals that form a ring structure comprising one or more aromatic or non-aromatic rings; and R13-R18 are, independently, hydrogen or C1-C30 hydrocarbyl radicals. The composition can be used to oligomerize ethylene.

    摘要翻译： 本发明涉及包含儿茶酚酸配体，钯或镍的组合物和具有以下结构的辅助配体：其中Pn是15族元素; H是氢; R 7和R 8独立地是氢或C 1 -C 30烃基，或两者都是C 1 -C 6烷基， 形成包含一个或多个芳族或非芳族环的环结构的亚烷基-C 30亚烷基; R 13和R 12独立地是氢或C 1 -C 30烃基。 该组合物可用于使乙烯低聚。