公开(公告)号：US4789656A

公开(公告)日：1988-12-06

申请号：US070170

申请日：1987-07-02

申请人： Nai Y. Chen ,  Sharon B. McCullen

发明人： Nai Y. Chen ,  Sharon B. McCullen

IPC分类号： B01J29/74 ,  C10G45/64 ,  B01J29/32

CPC分类号： C10G45/64 ,  B01J29/7415

摘要： A process is described for preparing a binder-free Zeolite Beta containing catalyst which has a highly dispersed noble metal incorporated into the framework. The process comprises steaming Zeolite Beta, followed by noble metal incorporation and calcination. The present invention is also directed to an improved calcination process.

摘要翻译： 描述了一种制备不含无粘结剂的含沸石沸石的催化剂的方法，该催化剂具有掺入框架中的高度分散的贵金属。 该方法包括蒸煮沸石β，然后进行贵金属掺入和煅烧。 本发明还涉及一种改进的煅烧方法。

公开(公告)号：US4756822A

公开(公告)日：1988-07-12

申请号：US31807

申请日：1987-03-30

申请人： Nai Y. Chen ,  Tracy J. Huang

发明人： Nai Y. Chen ,  Tracy J. Huang

IPC分类号： B01J29/86 ,  C10G47/16

CPC分类号： B01J29/86 ,  C10G47/16

摘要： This invention provides a novel hydrocracking catalyst composition that contains Zeolite Beta having a framework boron content, a solid source of alumina, and a hydrogenation component. It further provides a low-pressure hydrocracking process that uses such composition.

摘要翻译： 本发明提供一种新型加氢裂化催化剂组合物，其包含具有骨架硼含量的沸石β，氧化铝的固体源和氢化组分。 它还提供了使用这种组合物的低压加氢裂化方法。

公开(公告)号：US4749467A

公开(公告)日：1988-06-07

申请号：US054115

申请日：1987-05-22

申请人： Nai Y. Chen ,  Bruce P. Pelrine

发明人： Nai Y. Chen ,  Bruce P. Pelrine

IPC分类号： C10G45/64 ,  C10G73/38

CPC分类号： C10G45/64

摘要： An improved method which provides for an extended cycle length in catalytic lube dewaxing of residual lube oil feedstocks and easier catalyst regeneration. The method may incorporate catalytically dewaxing a feedstock in a fixed bed reactor with or without product recycle, or a series of reactors with interreactor separation of vapors from liquids. Improved performance is achieved by operating the reactor at a temperature between about 490.degree. and about 620.degree. F., employing a high activity crystalline zeolite catalyst having an alpha value between about 50 and about 900 based on the zeolite and a space velocity sufficiently low to produce a dewaxed effluent of desired pour point and to maintain an average catalyst aging rate of less than about 2.degree. F. per day. This relatively low temperature operation allows catalyst performance to be restored by simple hydrogen reactivation.

摘要翻译： 一种改进的方法，其提供了在残余润滑油原料的催化润滑油脱蜡中延长的循环长度并且更容易的催化剂再生。 该方法可以将原料催化脱蜡在具有或不具有产物再循环的固定床反应器中，或者一系列具有蒸发器与液体的反应器分离的反应器。 通过使用基于沸石的α值在约50至约900之间的高活性结晶沸石催化剂，在约490℃至约620℃的温度下操作反应器来实现改进的性能，空间速度足够低至 产生所需倾点的脱蜡流出物，并保持每天平均催化剂老化速率小于约2°F。 这种相对较低的温度操作允许通过简单的氢再活化来恢复催化剂性能。

公开(公告)号：US4711710A

公开(公告)日：1987-12-08

申请号：US938214

申请日：1986-12-05

申请人： Nai Y. Chen ,  Thomas F. Degnan, Jr. ,  Susan M. Leiby ,  Stephen M. Oleck ,  Bruce P. Pelrine

发明人： Nai Y. Chen ,  Thomas F. Degnan, Jr. ,  Susan M. Leiby ,  Stephen M. Oleck ,  Bruce P. Pelrine

IPC分类号： B01J29/46 ,  C10G11/05 ,  C10G45/64 ,  C10G11/10 ,  C10G47/16

CPC分类号： C10G45/64 ,  B01J29/46 ,  B01J2229/26 ,  B01J2229/42

摘要： There is disclosed an improved dewaxing process which will operate for longer periods of time involving contacting a feedstock having a 50 volume percent boiling point greater than 900.degree. F. with a crystalline aluminosilicate zeolite having a Constraint Index of from 1 to 12 and a silica-to-alumina ratio of at least 12. The crystalline aluminosilicate zeolite is composited with an inorganic oxide, such as alumina. The composite also containing a hydrogenation metal and the catalyst composite has a maximum diffusion distance of less than 0.025 inch.

摘要翻译： 公开了一种改进的脱蜡方法，该方法操作更长的时间段，包括使具有大于900°F的50体积％沸点的原料与约1至12的约束指数的结晶硅铝酸盐沸石接触， 氧化铝比至少为12.结晶硅铝酸盐沸石与无机氧化物如氧化铝复合。 还含有氢化金属和催化剂复合材料的复合材料具有小于0.025英寸的最大扩散距离。

公开(公告)号：US4500417A

公开(公告)日：1985-02-19

申请号：US453970

申请日：1982-12-28

申请人： Nai Y. Chen ,  Werner O. Haag ,  Tracy J. Huang ,  Stephen S. Wong

发明人： Nai Y. Chen ,  Werner O. Haag ,  Tracy J. Huang ,  Stephen S. Wong

IPC分类号： C10G45/64 ,  B01J29/00 ,  B01J29/74 ,  B01J29/78 ,  C07C1/00 ,  C07C1/04 ,  C07C9/00 ,  C07C67/00 ,  C10G47/16 ,  C10G49/08 ,  C10G47/20

CPC分类号： C10G47/16 ,  B01J2229/37 ,  B01J29/7415 ,  B01J29/7815 ,  Y10S208/95

摘要： The high boiling fraction of Fischer-Tropsch synthesis is upgraded by contact with a catalyst comprising a high-silica, large pore zeolite and a hydrogenation component. The products are a distillate fraction characterized by low sulfur and nitrogen content, high isoparaffin content and low pour point and a lube fraction characterized by its high viscosity index and low pour point.

摘要翻译： 通过与包含高二氧化硅，大孔沸石和氢化组分的催化剂接触来提高费 - 托合成的高沸点馏分。 该产品是以低硫和氮含量，高异链烷烃含量和低倾点为特征的馏出物部分，其特征在于其高粘度指数和低倾点。

公开(公告)号：US4443325A

公开(公告)日：1984-04-17

申请号：US452482

申请日：1982-12-23

申请人： Nai Y. Chen ,  Lillian A. Rankel

发明人： Nai Y. Chen ,  Lillian A. Rankel

IPC分类号： C10B55/00 ,  C10G51/04 ,  C10B55/10 ,  C10G65/18

CPC分类号： C10B55/00 ,  C10G51/04

摘要： A combined process for treating heavy hydrocarbon feedstocks, such as resids that minimizes coke production and maximizes naphtha production, comprising the steps of thermally treating the feedstocks, in the absence of an added catalyst and either with or without hydrogen and steam, at a temperature of at least about 750.degree. F. (399.degree. C.) and under a pressure greater than about 400 psig to create significant chemical transformations without causing phase separation and consequent formation of sludge or a coke deposit; topping the thermally treated product to produce a distillate fraction and a bottoms fraction; coking the bottom fraction to produce gas, liquid products, and coke; and finally catalytically cracking the combined distillate fraction and liquid products to recover gas, gasoline, and light distillate products.

摘要翻译： 用于处理重烃原料的组合方法，例如使焦炭生产最小化并使石脑油生产最大化的残渣，包括以下步骤：在不存在加入的催化剂的情况下热处理原料，以及在有或没有氢气和蒸汽的情况下，在 至少约750°F（399℃），并且在大于约400psig的压力下产生显着的化学转化，而不引起相分离，从而形成污泥或焦炭沉积物; 顶部热处理产物以产生馏出物馏分和塔底馏分; 焦化底部馏分产生气体，液体产物和焦炭; 并最终催化裂化组合的馏出物馏分和液体产物以回收气体，汽油和轻馏分产物。

公开(公告)号：US4396538A

公开(公告)日：1983-08-02

申请号：US187667

申请日：1980-09-16

申请人： Nai Y. Chen ,  David S. Shihabi

发明人： Nai Y. Chen ,  David S. Shihabi

IPC分类号： B01J23/85 ,  B01J29/40 ,  C10G11/05 ,  C10G47/16 ,  B01J29/28

CPC分类号： B01J35/0006 ,  B01J23/85 ,  B01J29/40 ,  B01J29/405 ,  C10G11/05 ,  C10G47/16 ,  B01J2229/26 ,  B01J2229/42

摘要： Conversion of hydrocarbons is conducted over low acidity zeolites such as the sodium form of zeolite ZSM-5 to yield products like those produced by hydrocracking but with substantially decreased proportion of light hydrocarbons having one to four carbon atoms. (Sulfiding of sodium zeolites activates such sodium zeolites for the present purpose.) The hydrocarbon conversion is conducted with mixed phase charge (Trickle mode) under hydrogen pressure or with liquid phase charge in a liquid-full reactor.A catalyst composition comprising a metallic hydrogenation catalyst on a refractory support and an alkali metal crystalline zeolite.

摘要翻译： 碳氢化合物的转化是通过低沸点沸石如沸石ZSM-5的沸石进行的，以产生类似于通过加氢裂化产生的产物，但具有1-4个碳原子的轻质烃的比例实质上降低。 （为了本目的，钠沸石的硫化活化这种钠沸石。）在氢气压力下或在液体充满的反应器中用液相电荷在混合相电荷（涓流模式）下进行烃转化。 一种催化剂组合物，其包含耐火载体上的金属氢化催化剂和碱金属结晶沸石。

公开(公告)号：US4376036A

公开(公告)日：1983-03-08

申请号：US241319

申请日：1981-03-06

申请人： William E. Garwood ,  Paul G. Rodewald ,  Nai Y. Chen

发明人： William E. Garwood ,  Paul G. Rodewald ,  Nai Y. Chen

IPC分类号： B01J21/08 ,  B01J29/40 ,  B01J29/70 ,  C10G45/64 ,  C10G47/16

CPC分类号： B01J29/40 ,  B01J21/08 ,  B01J2229/26 ,  B01J2229/42 ,  B01J29/70 ,  C10G2400/10

摘要： A process for the manufacture of high quality lubricating oils having a high viscosity index and low pour point is disclosed which comprises catalytically dewaxing a lubricating oil stock by contacting the same in the presence of hydrogen over a zeolite such as ZSM-5 which has been silica-modified.

摘要翻译： 公开了一种用于制造具有高粘度指数和低倾点的高品质润滑油的方法，其包括通过在氢气存在下使其与沸石如ZSM-5（其已经是二氧化硅）接触来催化脱蜡润滑油原料 -改性。

公开(公告)号：US4229608A

公开(公告)日：1980-10-21

申请号：US970718

申请日：1978-12-18

申请人： Nai Y. Chen ,  Werner O. Haag ,  Rudolph M. Lago

发明人： Nai Y. Chen ,  Werner O. Haag ,  Rudolph M. Lago

IPC分类号： B01J8/38 ,  C07C1/20 ,  C07C1/00

CPC分类号： B01J8/388 ,  C07C1/20 ,  C07C2529/06 ,  C07C2529/50 ,  C07C2529/70 ,  Y02P20/584 ,  Y02P30/42

摘要： A catalytic heat balanced cyclic process is provided for converting a charge consisting essentially of methanol, dimethyl ether or mixtures thereof to a hydrocarbon product rich in ethylene and propylene by contact, under specified conditions of temperature and contact time, with a catalyst comprising a crystalline aluminosilicate zeolite characterized by pores, the major dimension of which is less than 6 Angstroms and the capability, under such conditions, of producing less than about 20 weight percent methane in said hydrocarbon product, regenerating the catalyst so employed at a temperature between about 1200.degree. and about 1400.degree. F. to remove accumulated carbonaceous deposit therefrom and provide a source of hot regenerated catalyst for further contact, under controlled temperature conditions, with said charge.

摘要翻译： 提供催化热平衡循环方法，用于在基本上由甲醇，二甲醚或其混合物组成的电荷下，在特定的温度和接触时间条件下，与包含结晶硅铝酸盐的催化剂接触，将富含乙烯和丙烯的烃产物 沸石的特征在于其主要尺寸小于6埃的孔，以及在这种条件下在所述烃产物中产生小于约20重量％的甲烷的能力，在约1200℃和 约1400°F以从其中除去积聚的碳质沉积物，并提供热再生催化剂源，在受控的温度条件下与所述电荷进一步接触。

公开(公告)号：US5110445A

公开(公告)日：1992-05-05

申请号：US545162

申请日：1990-06-28

申请人： Nai Y. Chen ,  Randall D. Partridge

发明人： Nai Y. Chen ,  Randall D. Partridge

IPC分类号： C10G67/04

CPC分类号： C10G67/0409 ,  C10G2400/10

摘要： Hydrocarbon lubricants having a high viscosity index (V.I.) and low pour point are produced by hydroisomerizing a waxy lube feed such as slack wax or a waxy gas oil over zeolite beta after which aromatic components are removed by extraction, e.g. with furfural. The raffinate is then dewaxed, preferably by solvent dewaxing to target pour point with a final hydrofinishing step. The hydroisomerization coupled with the aromatics extraction and dewaxing increases the range of crudes that can be processed into high V.I. lubes while maintaining equivalent product qualities. Hydrogen consumption in the process is relatively low.

摘要翻译： 具有高粘度指数（V.I.）和低倾点的烃类润滑剂通过将蜡状润滑油进料例如松散蜡或蜡状瓦斯油在沸石β上加氢异构化而生成，其后通过萃取除去芳族组分，例如， 与糠醛。 然后将脱蜡剂脱蜡，优选通过溶剂脱蜡至最终加氢精制步骤的目标倾点。 加氢异构化与芳烃萃取和脱蜡相结合，增加可加工成高V.I.的原油范围。 同时保持同等的产品质量。 过程中的氢消耗相对较低。