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公开(公告)号：US20150307644A1
公开(公告)日：2015-10-29
申请号：US14794209
申请日：2015-07-08
Applicant: FINA TECHNOLOGY, INC.
Inventor： Carlos DeAnda , Graciela Morales , Jose M. Sosa , David Knoeppel
IPC: C08F279/02 , C08F299/02
CPC classification number: C08F279/02 , C08F285/00 , C08F297/044 , C08F299/02 , C08F212/08
Abstract: A process for producing rubber modified polymers having an increased rubber phase volume, including feeding a vinyl aromatic monomer and an elastomer to a polymerization reactor to form a reaction mixture, polymerizing the reaction mixture, combining a copolymer to the polymerized reaction mixture to form a combined mixture, subjecting the combined mixture to further polymerization, and obtaining a rubber modified polymer product from the further polymerization.
Abstract translation: 一种制备具有增加的橡胶相体积的橡胶改性聚合物的方法，包括将乙烯基芳族单体和弹性体加入到聚合反应器中以形成反应混合物，使反应混合物聚合，将共聚物与聚合的反应混合物结合形成 混合物，使组合的混合物进一步聚合，并从进一步的聚合中获得橡胶改性的聚合物产物。
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232.发明申请公开(公告)号：US20150267018A1
公开(公告)日：2015-09-24
申请号：US14729124
申请日：2015-06-03
Applicant: FINA TECHNOLOGY, INC.
Inventor： Mark Leland
CPC classification number: C08J5/18 , B29C45/0001 , B29K2021/00 , B29K2023/14 , B29L2007/002 , C08J2323/12 , C08J2323/14 , C08L23/12 , C08L23/14 , C08L23/142 , C08L23/16 , C08L2201/10 , C08L2203/16 , C08L2205/02 , C08L2205/03 , C08L2207/02 , C08L2308/00 , C08L2314/02
Abstract: Methods for preparing an impact copolymer by selecting a continuous phase polymer having a first melt flow rate and selecting a rubber phase polymeric material such that the final melt flow rate of the impact copolymer is within 2 g/10 min of the first melt flow rate. Impact copolymers made from such methods and films and molded articles produced from such impact copolymers are also included.
Abstract translation: 通过选择具有第一熔体流动速率的连续相聚合物和选择橡胶相聚合物材料使得冲击共聚物的最终熔体流动速率在第一熔体流动速率的2g / 10min内来制备抗冲共聚物的方法。 还包括由这种方法制成的抗冲共聚物和由这种抗冲共聚物制成的膜和模制品。
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公开(公告)号：US20150252134A1
公开(公告)日：2015-09-10
申请号：US14663648
申请日：2015-03-20
Applicant: FINA TECHNOLOGY, INC.
Inventor： John Tomlinson , Jose Sosa
IPC: C08F279/02 , C08L51/04
CPC classification number: C08F279/02 , C08F2/00 , C08F2/001 , C08F2/38 , C08L51/04 , C08F212/08
Abstract: A process for producing a high impact polystyrene having a high swell index may include feeding at least one vinyl aromatic monomer and at least one elastomer to at least one polymerization reactor to form a reaction mixture. The process may include polymerizing the reaction mixture, combining a chain transfer agent to the reaction mixture leaving the at least one polymerization reactor to form a combined mixture, and sending the combined mixture to a devolatilization zone. The process may include obtaining a HIPS product having a high swell index.
Abstract translation: 用于生产具有高膨胀指数的高抗冲聚苯乙烯的方法可包括将至少一种乙烯基芳族单体和至少一种弹性体进料至至少一个聚合反应器以形成反应混合物。 该方法可以包括使反应混合物聚合，将链转移剂与反应混合物结合，离开至少一个聚合反应器以形成混合的混合物，并将合并的混合物送至脱挥发分区。 该方法可以包括获得具有高溶胀指数的HIPS产品。
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公开(公告)号：US20150175783A1
公开(公告)日：2015-06-25
申请号：US14639323
申请日：2015-03-05
Applicant: FINA TECHNOLOGY, INC.
Inventor： Likuo Sun , Jose Sosa , Serge Eon , Carlos Corleto , Scott Cooper
IPC: C08L9/06
CPC classification number: C08F2/001 , C08F212/08 , C08F279/02 , C08L9/06 , C08L2555/84
Abstract: A process for producing high impact polystyrene including feeding at least one vinyl aromatic monomer, an elastomer, and a free radical initiator to a first linear flow reactor to form a reaction mixture. Polymerizing the reaction mixture in the first linear flow reactor to a point below the point at which phase inversion occurs to produce a first polymerization mixture and feeding the first polymerization mixture from the first linear flow reactor to a second linear flow reactor. Polymerizing the reaction mixture in the second linear flow reactor to at least a phase inversion point of the mixture to produce a second polymerization mixture and feeding the second polymerization mixture from the second linear flow reactor to at least a third linear flow reactor for post-inversion polymerization of the second polymerization mixture. The product stream can have an ESCR value of at least 10% toughness retained with less than 10 wt % rubber content.
Abstract translation: 一种生产高抗冲聚苯乙烯的方法，包括将至少一种乙烯基芳族单体，弹性体和自由基引发剂进料至第一线性流动反应器以形成反应混合物。 将第一线性流动反应器中的反应混合物聚合到低于发生相转移点的点以产生第一聚合混合物并将第一聚合混合物从第一线性流动反应器进料到第二线性流动反应器。 将第二线性流动反应器中的反应混合物聚合到混合物的至少相转变点，以产生第二聚合混合物，并将第二聚合混合物从第二线性流动反应器进料到至少第三线性流动反应器用于后反转 第二聚合混合物的聚合。 产品流的ESCR值可以保持至少10％的韧性，橡胶含量小于10wt％。
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公开(公告)号：US09012708B2
公开(公告)日：2015-04-21
申请号：US14299395
申请日：2014-06-09
Applicant: Fina Technology, Inc.
Inventor： James R. Butler , Joseph E. Pelati
CPC classification number: C07C2/867 , C07C1/2076 , C07C15/46 , C07C45/002 , C07C45/32 , C07C45/38 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/02 , C07C2523/04 , C07C2523/06 , C07C2523/10 , C07C2523/20 , C07C2523/22 , C07C2523/24 , C07C2523/34 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/72 , C07C2523/75 , C07C2523/755 , C07C2523/80 , C07C2523/86 , C07C2527/047 , C07C2527/049 , C07C2527/051 , C07C2529/06 , C07C2529/40 , Y02P30/42 , C07C47/04
Abstract: A process is disclosed for making styrene by converting methanol to formaldehyde in a reactor then reacting the formaldehyde with toluene to form styrene in a separate reactor.
Abstract translation: 公开了一种通过在反应器中将甲醇转化成甲醛来制造苯乙烯的方法，然后使甲醛与甲苯反应，在单独的反应器中形成苯乙烯。
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Patent Agency Ranking
公开(公告)号：US08889755B2
公开(公告)日：2014-11-18
申请号：US14103192
申请日：2013-12-11
Applicant: Fina Technology, Inc.
Inventor： John Gaustad , Juan Aguirre , Joe Shuler
IPC: C08F30/04 , C08J5/18 , C08K5/00 , C08J9/04 , C08J9/00 , C08L35/06 , C08F230/04 , C08F212/08 , C08F220/06
CPC classification number: C08F30/04 , C08F212/08 , C08F220/06 , C08F230/04 , C08J5/18 , C08J9/00 , C08J9/04 , C08J2325/14 , C08K5/0091 , C08L35/06 , C08L35/00 , C08F220/14 , C08F222/10
Abstract: Embodiments of the present invention include a branched aromatic ionomer, and a process of making it, by co-polymerizing a first monomer comprising an aromatic moiety and an unsaturated alkyl moiety and a second monomer represented by the general formula: [R-AZ]y-MX wherein R is a hydrocarbon chain having from 2 to 40 carbons and at least one polymerizable unsaturation; A is an anionic group; M is a cationic group; Z is −1 or −2; X is +1, +2, +3, +4, or +5; and y is an integer having a value of from 1 to 4. The branched aromatic ionomer has a melt flow index ranging from 1.0 g/10 min. to 13 g/10 min. Optionally the melt flow index ranges from 1.3 g/10 min. to 1.9 g/10 min.
Abstract translation: 本发明的实施方案包括支链芳族离聚物及其制备方法，通过共聚合包含芳族部分和不饱和烷基部分的第一单体和由通式[R-AZ] y表示的第二单体 -MX，其中R是具有2至40个碳的烃链和至少一个可聚合不饱和度; A是阴离子基团; M是阳离子基团; Z为-1或-2; X是+1，+2，+3，+4或+5; y为1〜4的整数。支链芳族离聚物的熔体流动指数为1.0g / 10min。 至13g / 10min。 任选地，熔体流动指数为1.3g / 10min。 至1.9g / 10分钟。
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公开(公告)号：US20140323654A1
公开(公告)日：2014-10-30
申请号：US14328342
申请日：2014-07-10
Applicant: FINA TECHNOLOGY, INC.
Inventor： Carlos DeAnda , Graciela Morales , Jose M. Sosa , David Knoeppel
IPC: C08F279/02
CPC classification number: C08F279/02 , C08F285/00 , C08F297/044 , C08F299/02 , C08F212/08
Abstract: A process for producing rubber modified polymers having an increased rubber phase volume, including feeding a vinyl aromatic monomer and an elastomer to a polymerization reactor to form a reaction mixture, polymerizing the reaction mixture, combining a copolymer to the polymerized reaction mixture to form a combined mixture, subjecting the combined mixture to further polymerization, and obtaining a rubber modified polymer product from the further polymerization.
Abstract translation: 一种制备具有增加的橡胶相体积的橡胶改性聚合物的方法，包括将乙烯基芳族单体和弹性体进料到聚合反应器中以形成反应混合物，使反应混合物聚合，将共聚物与聚合的反应混合物结合形成 混合物，使组合的混合物进一步聚合，并从进一步的聚合中获得橡胶改性的聚合物产物。
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公开(公告)号：US20140288343A1
公开(公告)日：2014-09-25
申请号：US14204527
申请日：2014-03-11
Applicant: FINA TECHNOLOGY, INC.
Inventor： Kenneth Paul Blackmon , Sivadinarayana Chinta , Jun Wang
IPC: C07C2/86
CPC classification number: C07C2/867 , C07C2521/12 , C07C2521/16 , C07C2529/08 , C07C2529/40 , C07C2529/44 , C07C2529/83 , C07C11/173
Abstract: A process is disclosed that includes reacting a C1 source with n-butene to form a C-5 diolefin.
Abstract translation: 公开了包括使C1源与正丁烯反应以形成C-5二烯烃的方法。
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公开(公告)号：US08841501B2
公开(公告)日：2014-09-23
申请号：US13964813
申请日：2013-08-12
Applicant: Fina Technology, Inc.
Inventor： James Butler , Olga Khabashesku , Darek Wachowicz , Callum Bailey
IPC: C07C15/12 , C07C6/12 , C07C15/04 , C07C15/08 , C07C5/22 , C07C5/52 , B01J29/26 , B01J29/076 , B01J37/02 , B01J38/12 , C07C6/06 , B01J38/14 , B01J38/10 , B01J29/90
CPC classification number: B01J29/85 , B01J29/076 , B01J29/16 , B01J29/26 , B01J29/83 , B01J29/90 , B01J37/0203 , B01J38/10 , B01J38/12 , B01J38/14 , B01J2229/20 , C07C6/06 , C07C6/12 , C07C2523/20 , C07C2523/36 , C07C2529/06 , C07C2529/08 , C07C2529/18 , Y02P20/52 , Y02P20/584 , Y02P20/588 , C07C15/04 , C07C15/08
Abstract: A group V metal/rhenium-modified molecular sieve catalyst can be used in hydrocarbon conversion reactions. Embodiments can provide a toluene conversion of at least 30 wt % with selectivity to benzene above 40 wt % and to xylenes above 40 wt % and non-aromatics selectivity of less than 2.0 wt %.
Abstract translation: V族金属/铼改性分子筛催化剂可用于烃转化反应。 实施方案可以提供至少30重量％的甲苯转化率，对苯高于40重量％的选择性和高于40重量％的二甲苯和小于2.0重量％的非芳族选择性。
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240.发明申请公开(公告)号：US20140235791A1
公开(公告)日：2014-08-21
申请号：US14220997
申请日：2014-03-20
Applicant: FINA TECHNOLOGY, INC.
Inventor： Fengkui Li , John Ashbaugh
CPC classification number: C08L23/26 , C08J5/18 , C08J2323/12 , C08L23/0884 , C08L23/10 , C08L33/068 , C08L51/003 , C08L51/06 , C08L67/04 , C08L2203/16 , C08L2666/02
Abstract: Films (or a cap layer of co-extruded films) and methods of forming the same are described herein. The films generally include a modified olefin based polymer including polypropylene and from 1 wt. % to 30 wt. % polylactic acid (PLA), wherein the modified olefin based polymer exhibits a seal initiation temperature (SIT) that is at least 5° C. less than a seal initiation temperature of the polypropylene absent the PLA and a hot tack range of at least 20° C.
Abstract translation: 本文描述了膜（或共挤出膜的盖层）及其形成方法。 膜通常包括改性烯烃基聚合物，包括聚丙烯和1重量％ ％〜30重量％ ％聚乳酸（PLA），其中改性烯烃基聚合物的密封起始温度（SIT）比不含PLA的聚丙烯的密封起始温度低至少5℃，热粘性范围为至少20 C。
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