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公开(公告)号:US20190055330A1
公开(公告)日:2019-02-21
申请号:US15759143
申请日:2016-08-30
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: FABRIZIO PIEMONTESI , GIANNI VITALE , DARIO LIGUORI , GIAMPIERO MORINI
IPC: C08F10/06
Abstract: A catalyst for the homopolymerization or copolymerization of CH2═CHR olefins, made from or containing the product obtained by contacting: (i) a solid catalyst component made from or containing Ti, Mg, Cl, and an internal electron donor compound, wherein the solid catalyst component contains from about 0.1 to about 50 wt % of Bi, based upon the total weight of the solid catalyst component; (ii) an alkyl aluminum compound and, (iii) an external electron donor compound having the formula: (R1)aSi(OR2)b wherein R1 and R2 are independently selected from the group consisting of alkyl radicals with 1-8 carbon atoms and a is 0 or 1 and a+b=4.
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公开(公告)号:US10208135B2
公开(公告)日:2019-02-19
申请号:US15516651
申请日:2015-09-28
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Simona Guidotti , Dario Liguori , Giampiero Morini
Abstract: A catalyst component comprising Ti, Mg, Cl, and an electron donor compound having porosity of at least 0.2 cm3/g and characterized by the fact that it further comprises Cu oxide, with the proviso that when the electron donor compound is selected from esters of phthalic acids, the porosity is of at least 0.45 cm3/g.
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公开(公告)号:US10155888B2
公开(公告)日:2018-12-18
申请号:US15400734
申请日:2017-01-06
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Massimo Covezzi , Gabriele Mei , Maria Di Diego , Piero Gessi , Pietro Baita , Roberta Pica
IPC: C09J151/06 , C08F10/00 , C08F110/02 , B32B7/12 , B32B15/085 , B32B27/06 , C08L23/06 , C08L23/20 , C08L51/06 , C09J5/02 , C09J123/06 , C09J123/20
Abstract: The present technology relates to a method of introducing a supported antistatic compound that does not comprise a transition-metal-based catalyst component for use in an olefin polymerization reactor. In some embodiments, the methods disclosed herein avoid the formation of polymer agglomerates in the reactor and minimize potentially negative effects on catalyst yield.
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公开(公告)号:US10113013B2
公开(公告)日:2018-10-30
申请号:US15128830
申请日:2015-03-24
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Alessandro Mignogna , Giampiero Morini
IPC: C08F4/642 , C08F4/02 , C08F4/659 , C08F110/06 , C08L57/00 , C07C271/44 , C08F10/14
Abstract: The present disclosure relates to a solid catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of the formula (I): where each Q is a group —COOR1, in which R1 is selected from C1-C15 hydrocarbon groups, optionally containing a heteroatom selected from the group consisting of halogens, P, S, N and O; or a group —CON(R2)2, in which R2 groups, equal to or different from each other, are hydrogen or R1 groups which can be fused together to form one or more cycles, and A is a bivalent bridging group with the proviso that the Q groups cannot be simultaneously a group —COOR1 or —CON(R2)2.
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公开(公告)号:US10077322B2
公开(公告)日:2018-09-18
申请号:US15533856
申请日:2015-12-01
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Pietro Baita , Tiziano Dall'Occo , Maria Di Diego , Dario Liguori , Lorella Marturano , Andreas Maus , Gabriele Mei , Gerhardus Meier , Giampiero Morini , Roberta Pica , Ulf Schueller
IPC: C08F4/649 , C08F4/654 , C08F110/02 , C08F210/02 , C08F2/34
CPC classification number: C08F2/34 , C08F4/6493 , C08F4/6494 , C08F110/02 , C08F2410/02 , C08F2500/12 , C08F2500/18 , C08F4/6543 , C08F210/02
Abstract: The present disclosure provides a gas-phase polymerization process for preparing polyethylene, wherein halogenated alcohols in combination with a Ti based catalyst component and aluminum alkyls as co-catalyst suppress ethane formation or increase polymerization activity.
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公开(公告)号:US20180215845A1
公开(公告)日:2018-08-02
申请号:US15750469
申请日:2016-08-03
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: GIAMPIERO MORINI , MASSIMO COVEZZI , TIZIANO DALL'OCCO , DARIO LIGUORI , FABRIZIO PIEMONTESI , GIANNI VITALE
IPC: C08F10/06
Abstract: A gas-phase process for the homopolymerization or copolymerization of propylene with other olefins, including carrying out the polymerization in the presence of a catalyst system made from or containing: (a) a solid catalyst component made from or containing Mg, Ti, halogen, an electron donor selected from 1.3-diethers and an olefin polymer in a specific amount; (b) an aluminum alkyl compound and (c) an external electron donor (ED) compound, wherein components (b) and (c) being employed in amounts such that the Al/(ED) molar ratio ranges from about 2 to about 200.
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公开(公告)号:US20180201003A1
公开(公告)日:2018-07-19
申请号:US15750778
申请日:2016-07-19
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: PAOLA MASSARI , CAROLINE CATHELIN , CLAUDIO CAVALIERI , MARCO CIARAFONI , ANDREA FELISATI , ANGELO FERRARO , GIAMPIERO MORINI , FABRIZIO PIEMONTESI , GIANNI VITALE
IPC: B32B27/32 , B32B27/08 , C08J5/18 , C08F210/06 , C08F210/16
Abstract: A film made from or containing a polyolefin composition made from or containing: A) from about 19 wt % to about 50 wt %, based upon the total weight of the polyolefin composition, of a propylene ethylene copolymer having an ethylene derived units content ranging from about 1.5 wt % to about 6.0 wt %, based upon the total weight of the propylene ethylene copolymer; and B) from about 50 wt % to about 81 wt %, based upon the total weight of the polyolefin composition, of a propylene ethylene 1-butene terpolymer having an ethylene derived units content ranging from about 1.5 wt % to about 6.0 wt %, based upon the total weight of the propylene ethylene 1-butene terpolymer, and 1-butene derived units content of between about 4.8 wt % and about 12.4 wt %, based upon the total weight of the propylene ethylene 1-butene terpolymer; the sum of the amount of component A) and B) being 100.
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公开(公告)号:US20180194870A1
公开(公告)日:2018-07-12
申请号:US15128830
申请日:2015-03-24
Applicant: Basell Poliolefine Italia S.R.L.
Inventor: Alessandro MIGNOGNA , Giampiero MORINI
IPC: C08F4/642 , C08F4/02 , C08F4/659 , C08L57/00 , C08F110/06
CPC classification number: C08F4/6425 , C07C271/44 , C08F4/022 , C08F4/65912 , C08F10/14 , C08F110/06 , C08F2500/15 , C08L57/00 , C08L2207/10 , C08L2314/02 , C08F4/651 , C08F2500/12
Abstract: The present disclosure relates to a solid catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of the formula (I): where each Q is a group —COOR1, in which R1 is selected from C1-C15 hydrocarbon groups, optionally containing a heteroatom selected from the group consisting of halogens, P, S, N and O; or a group —CON(R2)2, in which R2 groups, equal to or different from each other, are hydrogen or R1 groups which can be fused together to form one or more cycles, and A is a bivalent bridging group with the proviso that the Q groups cannot be simultaneously a group —COOR1 or —CON(R2)2.
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公开(公告)号:US10005860B2
公开(公告)日:2018-06-26
申请号:US15428940
申请日:2017-02-09
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: Alessandro Mignogna , Reynald Chevalier , Igor Kashulin , Ilya Nifant'ev , Giampiero Morini , Martin Schneider
IPC: C08F110/06 , C07C327/26 , C07C327/28 , C07C329/10 , C07C333/04
CPC classification number: C08F110/06 , C07C327/26 , C07C327/28 , C07C329/10 , C07C333/04 , C08F4/651 , C08F2500/12 , C08F2500/15 , C08F4/6545
Abstract: Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of formula (I) In which X and Y are selected from, R1, and —OR1 and —NR2, B is oxygen or sulphur S is sulphur, R1 is selected from C1-C15 hydrocarbon groups, optionally contain a heteroatom selected from halogen, P, S, N, O and Si, which can be fused together to form one or more cycles, R is hydrogen or R1 and A is a bivalent bridging group with chain length between the two bridging bonds being 1-10 atoms.
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公开(公告)号:US09969870B2
公开(公告)日:2018-05-15
申请号:US15313456
申请日:2015-04-28
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Paola Massari , Marco Ciarafoni , Tiziana Caputo , Nicoletta Martini
CPC classification number: C08L23/142 , C08L23/16 , C08L2205/025 , C08L2207/02 , C08L2205/02
Abstract: A propylene polymer composition comprising: A) from 81 wt % to 91 wt % of a propylene ethylene copolymer containing from 1.0 wt % to 3.5 wt % of ethylene derived units having a fraction soluble in xylene at 25° C. comprised between 10 wt % and 3 wt %; and a melt flow rate ranging from 5 to 50 g/10 min; B) from 9 wt % to 19 wt %, of a copolymer of propylene and ethylene with from 21.0 wt % to 31.0 wt % of ethylene derived units; the sum A)+B) being 100; the composition having an melt flow rate ranging from 20 to 35 g/10 min; the xylene soluble fraction to 25° C. ranging from 13.0 wt % to 25.0 wt % and the intrinsic viscosity of the fraction soluble in xylene at 25° C. ranging from 0.7 dl/g to 1.9 dl/g.
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