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    PRESSURE SENSITIVE ADHESIVE COMPOSITIONS AND METHOD OF MAKING THE SAME
    22.
    发明申请
    PRESSURE SENSITIVE ADHESIVE COMPOSITIONS AND METHOD OF MAKING THE SAME 审中-公开
    压敏粘合剂组合物及其制备方法

    公开(公告)号：US20150094415A1

    公开(公告)日：2015-04-02

    申请号：US14567657

    申请日：2014-12-11

    Applicant: Dow Global Technologies LLC

    Inventor： Bedri Erdem ,  Debkumar Bhattacharjee ,  Keith J. Andes

    IPC: C09J175/08

    Abstract: The instant invention is a pressure sensitive adhesive composition comprising an ultra-high solid polyurethane dispersion. The ultra-high solid polyurethane dispersion comprises (1) a first component comprising a first polyurethane prepolymer comprising the reaction product of a polyol and polyisocyanate, (2) a second component comprising a media phase selected from the group consisting of a second polyurethane prepolymer emulsion, a low solid content polyurethane dispersion, a seed latex, and combinations thereof; and (3) optionally a chain extender. The ultra-high solid polyurethane dispersion has at least a solid content of at least 60 percent by weight of solid content, based on the total weight of the ultra-high solid polyurethane dispersion, and a viscosity of less than 5000 cps at 20 rpm at 21° C. using spindle #4 with Brookfield viscometer.

    Abstract translation: 本发明是包含超高固含量聚氨酯分散体的压敏粘合剂组合物。 超高固体聚氨酯分散体包括（1）包含第一聚氨酯预聚物的第一组分，所述第一聚氨酯预聚物包含多元醇和多异氰酸酯的反应产物，（2）第二组分，其包含介质相，其选自第二聚氨酯预聚物乳液 ，低固含量聚氨酯分散体，种子胶乳及其组合; 和（3）任选的扩链剂。 基于超高固体聚氨酯分散体的总重量，超高固含量聚氨酯分散体至少具有至少60重量％固体含量的固体含量，并且在20rpm时粘度小于5000cps 21°C，使用纺锤＃4与布鲁克菲尔德粘度计。

    AQUEOUS LEATHER COATING COMPOSITION AND METHOD FOR COATING LEATHER
    23.
    发明申请
    AQUEOUS LEATHER COATING COMPOSITION AND METHOD FOR COATING LEATHER 有权
    水性皮革涂料组合物和涂层方法

    公开(公告)号：US20140162073A1

    公开(公告)日：2014-06-12

    申请号：US14064296

    申请日：2013-10-28

    Applicant: Rohm and Haas Company ,  Dow Global Technologies LLC

    Inventor： Adam L. Grzesiak ,  Joseph M. Hoefler ,  Debkumar Bhattacharjee ,  Bradley K. Hageman

    IPC: C09D175/04 ,  D06N3/14 ,  C14C11/00

    CPC classification number: D06N3/147 ,  C08G18/283 ,  C08G18/6216 ,  C08G18/706 ,  C08G18/792 ,  C08G2105/02 ,  C09D175/04 ,  C14C11/006 ,  Y10T428/31547

    Abstract: An aqueous leather coating composition having improved storage stability includes 1 to 40 weight percent of an emulsifiable polyisocyanate comprising the reaction product of an isocyanurate and an emulsifier, wherein the average isocyanate functionality of the emulsifiable polyisocyanate is 2 to 4.5; and 60 to 99 weight percent of an aqueous polymer dispersion having a Tg of −70 to 40° C. and selected from a (meth)acrylic polymer dispersion, a polyurethane dispersion, a (meth)acrylic polymer/polyurethane hybrid dispersion and a combination comprising one or more of the foregoing aqueous polymer dispersions, wherein all weight percents are on a dry basis, and based on the total dry amount of the emulsifiable polyisocyanate and the aqueous polymer dispersion. The aqueous polymer dispersion can be free of hydroxyl groups. Also disclosed are a method of coating leather with the composition, and a coated leather article.

    Abstract translation: 具有改进的储存稳定性的水性皮革涂料组合物包括1至40重量％的可乳化聚异氰酸酯，其包含异氰脲酸酯和乳化剂的反应产物，其中可乳化多异氰酸酯的平均异氰酸酯官能度为2至4.5; 和60〜99重量％的Tg为-70〜40℃的聚合物水分散体，选自（甲基）丙烯酸系聚合物分散液，聚氨酯分散液，（甲基）丙烯酸系聚合物/聚氨酯混合分散液和组合 包括一种或多种上述水性聚合物分散体，其中所有重量百分比均为干基，并且基于可乳化多异氰酸酯和聚合物水分散体的总干燥量。 聚合物水分散体可以不含羟基。 还公开了用该组合物涂覆皮革的方法和涂覆的皮革制品。

    Composite dispersion, method of producing the same, and articles made therefrom
    24.
    发明授权
    Composite dispersion, method of producing the same, and articles made therefrom 有权
    复合分散体，其制造方法以及由其制成的制品

    公开(公告)号：US08680198B2

    公开(公告)日：2014-03-25

    申请号：US13693437

    申请日：2012-12-04

    Applicant: Dow Global Technologies LLC

    Inventor： David L. Malotky ,  Sarah T. Eckersley ,  Bedri Erdem ,  Debkumar Bhattacharjee

    IPC: C08L83/07 ,  C08L67/00 ,  C08L71/02

    CPC classification number: C08L83/04 ,  C08J3/05 ,  C08L23/16 ,  C08L33/04 ,  C08L63/00

    Abstract: The instant invention is a composite dispersion, method of producing the same, and articles made therefrom. The composite dispersion according to the instant invention comprises (1) a first seed dispersion comprising (a) a first internal phase; and (b) an external phase, and (2) a second internal phase; wherein the composite dispersion comprises more than 60 percent by the combined weight of the first internal phase and the second internal phase, and the composite dispersion has a viscosity of less than 10,000 cP measured by RV4 spindle at 20 rpm at greater than 60 weight percent total internal phase, and wherein the composite dispersion has a bimodal particle size distribution and a particle size ratio (P2/P1) in the range of 2 to 200.

    Abstract translation: 本发明是一种复合分散体，其制备方法和由其制成的制品。 根据本发明的复合分散体包含（1）第一种子分散体，其包含（a）第一内相; 和（b）外部相，和（2）第二内部相; 其中所述复合分散体包含多于60％的第一内相和第二内相的组合重量，并且所述复合分散体具有通过RV4主轴在20rpm下以大于60重量％的总量测量的小于10,000cP的粘度 内相，并且其中所述复合分散体具有2至200的双峰粒度分布和粒径比（P2 / P1）。

    Layered structures and articles prepared therefrom
    27.
    发明授权
    Layered structures and articles prepared therefrom 有权
    由其制备的分层结构和制品

    公开(公告)号：US09487337B2

    公开(公告)日：2016-11-08

    申请号：US14344815

    申请日：2012-09-19

    Applicant: DOW GLOBAL TECHNOLOGIES LLC ,  ROHM AND HAAS COMPANY

    Inventor： Sekhar Sundaram ,  Debkumar Bhattacharjee ,  Jozef J. Van Dun ,  Bradley A. Jacobs ,  Rajen M. Patel ,  Alexander Williamson

    IPC: B65D65/40 ,  C09J7/02 ,  B32B27/40 ,  B32B27/08 ,  B32B27/32 ,  B32B7/12 ,  C09J175/04

    CPC classification number: B65D65/40 ,  B32B7/12 ,  B32B27/08 ,  B32B27/32 ,  B32B27/40 ,  B32B2439/70 ,  B32B2439/80 ,  C09J7/243 ,  C09J175/04 ,  C09J2423/006 ,  C09J2475/00 ,  Y10T428/2848 ,  Y10T428/2896

    Abstract: The invention provides a layered structure comprising at least two layers: A) a first layer A, formed from a composition A, comprising a polyurethane; and B) a second layer B, formed from a composition B, comprising at least one functionalized polymer B comprising the following: i) at least one polymerized monomeric unit comprising a functional group selected from the group consisting of the following: a) an acid group, b) an anhydride group, c) a primary or secondary amine group, and d) combinations thereof; or ii) at least one reacted functionalization agent comprising a functional group selected from the group consisting of the following: e) an acid group, f) an anhydride group, g) a primary or secondary amine group, and h) combinations thereof; or iii) combinations thereof; and wherein the functionalized polymer B has a number-average molecular weight greater than 1,000 g/mole, and/or a melt index (I2) less than, or equal to, 2500 g/10 min.

    Abstract translation: 本发明提供了包括至少两层的层状结构：A）由组合物A形成的包含聚氨酯的第一层A; 和B）由组合物B形成的第二层B，其包含至少一种官能化聚合物B，其包含以下物质：i）至少一种包含选自以下的官能团的聚合单体单元：a）酸 基团，b）酸酐基团，c）伯或仲胺基团，和d）其组合; 或ii）至少一种反应官能化剂，其包含选自以下的官能团：e）酸基，f）酸酐基，g）伯或仲胺基，和h）其组合; 或iii）其组合; 并且其中所述官能化聚合物B的数均分子量大于1,000g / mol，和/或小于或等于2500g / 10min的熔体指数（I 2）。

    BARRIER FILMS OF FDCA-BASED POLYESTERS
    28.
    发明申请
    BARRIER FILMS OF FDCA-BASED POLYESTERS 审中-公开
    基于FDCA的聚酯的阻隔膜

    公开(公告)号：US20150353692A1

    公开(公告)日：2015-12-10

    申请号：US14653563

    申请日：2013-12-18

    Applicant: DOW GLOBAL TECHNOLOGIES LLC

    Inventor： Debkumar Bhattacharjee ,  Steven R. Jenkins ,  Kalyan Sehanobish

    IPC: C08J5/18 ,  B32B27/08 ,  B65D65/38 ,  B32B27/36 ,  B65D81/24 ,  C08G63/66 ,  B32B27/32

    CPC classification number: C08J5/18 ,  B32B27/08 ,  B32B27/32 ,  B32B27/36 ,  B32B2250/02 ,  B32B2250/24 ,  B32B2307/7244 ,  B32B2307/7246 ,  B32B2439/70 ,  B65D65/38 ,  B65D81/24 ,  B65D2565/388 ,  C08G63/66 ,  C08J2367/00 ,  Y10T428/31678 ,  Y10T428/31797

    Abstract: A barrier film comprising a polyester-based polymer with (a) an O2 gas permeability of 0.25 cc-mil/100 in.2 24 hrs atm (5 cc 20 μm/m2 24 hrs atm) at 80% relative humidity (ASTM D-3985) or less, (b) a moisture permeability of 0.5 g-mil/100 in.2 24 hrs atm (9.8 g 20 μm/m2 24 hrs atm) at 38° C. (ASTM F-1249) or less, (c) haze of 1% or less (ASTM D1003), and (d) a glass transition temperature of 100° C. or higher. The polyester-based polymer may comprise reaction product of (a) one or more diacid or diester thereof, and (b) one or more polyol, wherein component (a) comprises 5 to 100 mole %, based on the total amount of component (a), of 2,5-furan dicarboxylic acid, or one or more C1 to C10 alkyl diester thereof, and component (b) comprises ethylene glycol, a mixture of 1,3-cyclohexanedimethanol and 1,4-cyclohexanedimethanol, or 2,2,4,4-tetramethyl-1,3-cyclobutanediol, or combinations thereof.

    Abstract translation: 包含聚酯基聚合物的隔离膜，其具有（a）在80％相对湿度下的氧气渗透率为0.25cc密尔/ 100in.2,24小时atm（5cc20μm/ m 2 24小时atm）（ASTM D- 3985）或更小，（b）在38℃下24小时大气压（9.8g20μm/ m 2 24小时atm）下的透湿度为0.5g密耳/ 100（ASTM F-1249）或更低，（ c）雾度为1％以下（ASTM D1003），（d）玻璃化转变温度为100℃以上。 基于聚酯的聚合物可以包含（a）一种或多种二酸或二酯的反应产物和（b）一种或多种多元醇，其中组分（a）占组分总量的5-100摩尔％ a），2,5-呋喃二羧酸或其一个或多个C1至C10烷基二酯，组分（b）包括乙二醇，1,3-环己烷二甲醇和1,4-环己烷二甲醇的混合物，或2， 2,4,4-四甲基-1,3-环丁二醇或其组合。

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