Abstract:
Provided is an aqueous composition comprising dispersed particles that comprise a polyurethane, wherein said polyurethane is a reaction product of a group of reactants (GR1), wherein GR1 comprises one or more aromatic polyisocyanates and, a polyol component, wherein said polyol component comprises (a) 50% to 99% by weight, based on the weight of said polyol component, one or more polyester polyols, (b) 0.1% to 10% by weight, based on the weight of said polyol component, one or more diols having a hydrophilic side chain, and (c) 0.9% to 40% by weight, based on the weight of said polyol component, one or more polyols different from (a) and (b). Also provided is a method of bonding a metal foil to a polymer film using such an aqueous composition.
Abstract:
The invention provides a layered structure comprising at least two layers: A) a first layer A, formed from a composition A, comprising a polyurethane; and B) a second layer B, formed from a composition B, comprising at least one functionalized polymer B comprising the following: i) at least one polymerized monomeric unit comprising a functional group selected from the group consisting of the following: a) an acid group, b) an anhydride group, c) a primary or secondary amine group, and d) combinations thereof; or ii) at least one reacted functionalization agent comprising a functional group selected from the group consisting of the following: e) an acid group, f) an anhydride group, g) a primary or secondary amine group, and h) combinations thereof; or iii) combinations thereof; and wherein the functionalized polymer B has a number-average molecular weight greater than 1,000 g/mole, and/or a melt index (I2) less than, or equal to, 2500 g/10 min.
Abstract:
A film comprising a) at least one base layer comprising a thermoplastic polymeric matrix material; and b) a skin layer comprising a thermoplastic polymeric matrix material and from 5 wt % to 80 wt % of polymeric particles having an average particle diameter from 0.5 μm to 15 μm, a refractive index from 1.46 to 1.7, and at least 60 mole % of acrylic monomer units wherein the film is stretched by a factor of 2 to 8 uniaxially or biaxially; and wherein after stretching, the skin layer has a thickness that is between 50% and 200% of the diameter of the polymeric particles, and a method of making the film, are disclosed.
Abstract:
An aqueous leather coating composition having improved storage stability includes 1 to 40 weight percent of an emulsifiable polyisocyanate comprising the reaction product of an isocyanurate and an emulsifier, wherein the average isocyanate functionality of the emulsifiable polyisocyanate is 2 to 4.5; and 60 to 99 weight percent of an aqueous polymer dispersion having a Tg of −70 to 40° C. and selected from a (meth)acrylic polymer dispersion, a polyurethane dispersion, a (meth)acrylic polymer/polyurethane hybrid dispersion and a combination comprising one or more of the foregoing aqueous polymer dispersions, wherein all weight percents are on a dry basis, and based on the total dry amount of the emulsifiable polyisocyanate and the aqueous polymer dispersion. The aqueous polymer dispersion can be free of hydroxyl groups. Also disclosed are a method of coating leather with the composition, and a coated leather article.
Abstract:
Provided is an aqueous composition comprising dispersed particles that comprise a polyurethane, wherein said polyurethane is a reaction product of a group of reactants (GR1), wherein GR1 comprises one or more aromatic polyisocyanates and, a polyol component, wherein said polyol component comprises (a) 50% to 99% by weight, based on the weight of said polyol component, one or more polyester polyols, (b) 0.1% to 10% by weight, based on the weight of said polyol component, one or more diols having a hydrophilic side chain, and (c) 0.9% to 40% by weight, based on the weight of said polyol component, one or more polyols different from (a) and (b). Also provided is a method of bonding a metal foil to a polymer film using such an aqueous composition.
Abstract:
The invention provides a layered structure comprising at least two layers: A) a first layer A, formed from a composition A, comprising a polyurethane; and B) a second layer B, formed from a composition B, comprising at least one functionalized polymer B comprising the following: i) at least one polymerized monomeric unit comprising a functional group selected from the group consisting of the following: a) an acid group, b) an anhydride group, c) a primary or secondary amine group, and d) combinations thereof; or ii) at least one reacted functionalization agent comprising a functional group selected from the group consisting of the following: e) an acid group, f) an anhydride group, g) a primary or secondary amine group, and h) combinations thereof; or iii) combinations thereof; and wherein the functionalized polymer B has a number-average molecular weight greater than 1,000 g/mole, and/or a melt index (I2) less than, or equal to, 2500 g/10 min.
Abstract:
The invention provides a layered structure comprising at least two layers: A) a first layer A formed from a composition A comprising a polyurethane; B) a second layer B formed from a composition B comprising at least one compound selected from the group consisting of the following compounds: a) a compound 1 comprising at least one acid group, b) a compound 2 comprising at least one anhydride group, c) a compound 3 comprising at least one primary amine group and/or at least one secondary amine group, and d) a combination thereof; and wherein the compound has a molecular weight or number average molecular weight, each less than 10,000 g/mole.
Abstract:
Provided is an aqueous composition comprising dispersed particles that comprise a polyurethane, wherein said polyurethane is a reaction product of a group of reactants (GR1), wherein GR1 comprises one or more aromatic polyisocyanates and, a polyol component, wherein said polyol component comprises (a) 50% to 99% by weight, based on the weight of said polyol component, one or more polyester polyols, (b) 0.1% to 10% by weight, based on the weight of said polyol component, one or more diols having a hydrophilic side chain, and (c) 0.9% to 40% by weight, based on the weight of said polyol component, one or more polyols different from (a) and (b). Also provided is a method of bonding a metal foil to a polymer film using such an aqueous composition.
Abstract:
An aqueous leather coating composition having improved storage stability includes 1 to 40 weight percent of an emulsifiable polyisocyanate comprising the reaction product of an isocyanurate and an emulsifier, wherein the average isocyanate functionality of the emulsifiable polyisocyanate is 2 to 4.5; and 60 to 99 weight percent of an aqueous polymer dispersion having a Tg of −70 to 40° C. and selected from a (meth)acrylic polymer dispersion, a polyurethane dispersion, a (meth)acrylic polymer/polyurethane hybrid dispersion and a combination comprising one or more of the foregoing aqueous polymer dispersions, wherein all weight percents are on a dry basis, and based on the total dry amount of the emulsifiable polyisocyanate and the aqueous polymer dispersion. The aqueous polymer dispersion can be free of hydroxyl groups. Also disclosed are a method of coating leather with the composition, and a coated leather article.
Abstract:
A multilayer film comprising (a) a biaxially-oriented polyethylene furanoate (BO-PEF) polymer layer, (b) an optional ink layer, (c) a bonding layer, and (d) a sealant layer, wherein the BO-PEF polymer has an O2 gas permeability of less than 0.25 cc-mil/100 in.2 24 hrs atm at 80% relative humidity, or a moisture permeability of less than 0.5 g-mil/100 in.2 24 hrs atm at 38° C., or both. The film may be formed from microlayers of BO-PEF-based polymer and polymer with a melting point of at least 5° C. greater than the melting point of the BO-PEF-based polymer.