公开(公告)号：US5573872A

公开(公告)日：1996-11-12

申请号：US561724

申请日：1995-11-22

申请人： Dale R. Shackle

发明人： Dale R. Shackle

IPC分类号： H01M10/052 ,  H01M10/0565 ,  H01M10/0568 ,  H01M6/18

CPC分类号： H01M10/0568 ,  H01M10/052 ,  H01M10/0565

摘要： Solid electrolytes containing a novel electrolyte salt which has the combined functions of both inorganic salt and electrolytic solvent are provided. The novel electrolyte has the structure: ##STR1## where A is either ##STR2## where Z is oxygen, --O--, sulfide --SH.sub.2 --, or amine ##STR3## is 1 to about 10; where R' is selected from the group consisting of an alkyl group having 1 to about 5 carbon atoms, and an unsubstituted or substituted aromatic group having from 6 to about carbon atoms, and wherein n is independently an integer from 1 to about 5 and R is independently selected from the group consisting of hydrogen, an alkyl group having 1 to about 5 carbon atoms, and an unsubstituted or substituted aromatic group having from 6 to about 11 carbon atoms.

摘要翻译： 提供了含有具有无机盐和电解溶剂两者的组合功能的新型电解质盐的固体电解质。 该新型电解质具有以下结构：，-O-，硫化物-SH2-或胺为1至约10; 其中R'选自具有1至约5个碳原子的烷基和具有6至约碳原子的未取代或取代的芳族基团，并且其中n独立地为1至约5的整数，并且R 独立地选自氢，具有1至约5个碳原子的烷基和具有6至约11个碳原子的未取代或取代的芳族基团。

公开(公告)号：US5455127A

公开(公告)日：1995-10-03

申请号：US220797

申请日：1994-03-31

申请人： Ib I. Olsen ,  Dale R. Shackle

发明人： Ib I. Olsen ,  Dale R. Shackle

IPC分类号： H01M6/18 ,  H01M10/052 ,  H01M10/0565 ,  G01N27/26

CPC分类号： H01M10/052 ,  H01M10/0565 ,  H01M6/181

摘要： This invention is directed to a solid electrolyte containing a polymeric matrix, a salt, a solvent, a viscosifying agent, and a flame retardant, as well as electrolytic cells prepared from such solid electrolytes.

摘要翻译： 本发明涉及含有聚合物基质，盐，溶剂，增粘剂和阻燃剂的固体电解质，以及由这种固体电解质制备的电解槽。

公开(公告)号：US5238758A

公开(公告)日：1993-08-24

申请号：US776722

申请日：1991-10-15

申请人： Mei-Tsu Lee ,  Dale R. Shackle ,  Gerhart Schwab

发明人： Mei-Tsu Lee ,  Dale R. Shackle ,  Gerhart Schwab

IPC分类号： H01M6/18

CPC分类号： H01M6/181

摘要： A method for forming an interpenetrating polymeric network containing a liquid electrolyte for use in solid state electrochemical cells which comprises forming a mixture of a liquid monomeric or prepolymeric radiation polymerizable, compound, a radiation inert ionically conducting liquid, and an ionizable alkaline metal salt; subjecting said mixture to actinic radiation to thereby crosslink said radiation polymerizable ionically conducting material and form a solid matrix containing said ionically conducting liquid; and electrode half elements and electrochemical cells incorporating said network.

摘要翻译： 一种用于形成含有用于固态电化学电池的液体电解质的互穿聚合物网络的方法，其包括形成液体单体或预聚物可辐射聚合的化合物，辐射惰性离子导电液体和可电离的碱金属盐的混合物; 使所述混合物经受光化辐射从而使所述可辐射聚合的离子导电材料交联并形成含有所述离子导电液体的固体基质; 以及包含所述网络的电极半元件和电化学电池。

公开(公告)号：US5037712A

公开(公告)日：1991-08-06

申请号：US506408

申请日：1990-04-06

申请人： Dale R. Shackle ,  Mei-Tsu Lee

发明人： Dale R. Shackle ,  Mei-Tsu Lee

IPC分类号： C08F20/28 ,  C08F20/10 ,  C08F283/06 ,  C08F283/12 ,  C08F290/00 ,  C08F299/02 ,  C08K3/00 ,  C08L71/02 ,  C08L83/04 ,  H01B1/06 ,  H01M6/18 ,  H01M10/052 ,  H01M10/0565 ,  H01M10/36

CPC分类号： H01M10/0565 ,  C08F283/06 ,  C08F283/12 ,  C08L71/02 ,  H01M6/181 ,  H01M10/052

摘要： A method is described for forming a solid electrolyte comprising a polymeric network structure containing an ionically conducting liquid for use in solid state electrochemical cells which comprises forming a mixture of a crosslinkable polysiloxane or a crosslinkable polyethylene oxide, an ionically conducting liquid, and an ionizable ammonium or alkali metal salt, and subjecting said mixture to actinic radiation to thereby crosslink said crosslinkable polysiloxane or crosslinkable polyethylene oxide to form a solid matrix through which said ionically conducting liquid interpenetrates to provide continuous paths of high conductivity in all directions throughout said matrix.

摘要翻译： 描述了一种用于形成固体电解质的方法，该固体电解质包含含有用于固态电化学电池的离子导电液体的聚合物网络结构，其包括形成可交联聚硅氧烷或可交联聚环氧乙烷，离子导电液体和可离子化铵的混合物 或碱金属盐，并使所述混合物进行光化辐射，从而使所述可交联聚硅氧烷或可交联聚环氧乙烷交联以形成固体基质，通过所述固体基质，所述离子导电液体通过该固体基质互穿，从而在所有基体上沿所有方向提供高导电性的连续路径。

公开(公告)号：US4935317A

公开(公告)日：1990-06-19

申请号：US369376

申请日：1989-06-21

申请人： Denis G. Fauteux ,  Dale R. Shackle

发明人： Denis G. Fauteux ,  Dale R. Shackle

IPC分类号： H01M4/08 ,  H01M4/131 ,  H01M4/1391 ,  H01M6/18 ,  H01M10/052 ,  H01M10/0565 ,  H01M10/0585 ,  H01M10/36

CPC分类号： H01M10/052 ,  H01M10/0565 ,  H01M10/0585 ,  H01M4/131 ,  H01M4/1391 ,  Y02P70/54 ,  Y10T29/49115

摘要： A process for making a solid state alkali metal anode cell comprising the steps of:coating a radiation or thermally polymerizable cathode composition layer onto a current collector layer;rolling the external surface of said cathode composition to provide an external surface having minimal surface discontinuities;coating an ionically conductive, radiation or thermally polymerizable electrolyte composition layer onto said cathode composition layer;partially or totally curing said cathode composition and said electrolyte composition;applying a laminar anode onto said electrolyte composition layer to form a cell assembly and the cell produced thereby is disclosed.

摘要翻译： 将辐射或热可聚合阴极组合物层涂覆到集电器层上。 将阴极组合物的外表面卷起以提供具有最小表面不连续性的外表面。 将离子导电的，辐射的或热可聚合的电解质组合物层涂覆到阴极组合物层上。 阴极组合物和所述电解质组合物部分或完全固化。 将层状阳极施加到电解质组合物层上以形成电池组件。

公开(公告)号：US4365018A

公开(公告)日：1982-12-21

申请号：US262015

申请日：1981-05-11

申请人： E. Bryant Crutchfield ,  Richard F. Wright ,  Paul C. Adair ,  Seth O. Harris ,  Dale R. Shackle ,  Dennis L. Williams

发明人： E. Bryant Crutchfield ,  Richard F. Wright ,  Paul C. Adair ,  Seth O. Harris ,  Dale R. Shackle ,  Dennis L. Williams

IPC分类号： G03C5/08 ,  G03C1/765 ,  G03C5/04

CPC分类号： G03C5/04

摘要： A self-exposing imaging element is disclosed comprising a support member, a light sensitive layer, and a layer containing reagents which will chemically react in a chemiluminescent reaction to produce light which exposes the light sensitive layer when in contact with an original. Reagents in the light generating layer are physically or chemically segregated prior to exposure to prevent reaction, for example, by encapsulation of one of the reactants, the reaction solvent, or a catalyst. To copy the self-exposing imaging element is placed in contact with an original, the light generating layer is activated by causing the reactants to mix or introducing the reaction solvent or catalyst and the radiant energy generated produces an image of the original in the radiation sensitive layer by reflex imaging or direct transmission imaging.

摘要翻译： 公开了一种自曝光成像元件，其包括支撑构件，光敏层和含有试剂的层，所述试剂将在化学发光反应中化学反应以产生当与原件接触时暴露光敏层的光。 在曝光之前，光产生层中的试剂物理或化学分离以防止反应，例如通过包封反应物之一，反应溶剂或催化剂。 将自曝光成像元件复制放置成与原件接触，通过使反应物混合或引入反应溶剂或催化剂来激活光产生层，并且产生的辐射能产生原始辐射敏感的图像 层反射成像或直接透射成像。

公开(公告)号：US4171981A

公开(公告)日：1979-10-23

申请号：US792323

申请日：1977-04-29

申请人： Robert A. Austin ,  Dale R. Shackle

发明人： Robert A. Austin ,  Dale R. Shackle

IPC分类号： B41M5/132 ,  B41M5/155 ,  C09D11/00 ,  C09D11/02 ,  C09D11/12 ,  B41M5/22

CPC分类号： C09D11/50 ,  B41M5/132 ,  C09D11/03 ,  Y10S428/914

摘要： A process for the production of a hot melt coating composition containing microcapsules. The process comprises the steps of preparing a dispersion of substantially discrete microcapsules in a volatile solvent continuous phase. A hot melt suspending medium is prepared, the hot melt suspending medium having a melting point of from about 50.degree. C. to about 140.degree. C. and a melting point range of less than about 15.degree. C., the hot melt suspending medium being in a fluid state. The dispersion of substantially discrete microcapsules in a volatile solvent is then mixed with the fluid hot melt suspending medium with turbulent agitation to form an intimate mixture of the dispersion of microcapsules and the hot melt suspending medium. Heat and a vacuum are applied to the mixture, while maintaining the agitation, until the volatile solvent is substantially removed from the mixture to form a dispersion of substantially discrete microcapsules in the liquid hot melt suspending medium. The heat is applied at a rate sufficient to maintain the mixture at a temperature above the melting point of the hot melt suspending medium, the temperature also being above the boiling point of water at the vacuum level.

摘要翻译： 一种制备含有微胶囊的热熔涂料组合物的方法。 该方法包括在挥发性溶剂连续相中制备基本上分散的微胶囊的分散体的步骤。 制备热熔悬浮介质，该熔融悬浮介质的熔点为约50℃至约140℃，熔点范围小于约15℃，热熔悬浮介质为 处于流体状态。 然后将基本上分散的微胶囊在挥发性溶剂中的分散体与流体热熔悬浮介质在湍流搅拌下混合以形成微胶囊分散体和热熔悬浮介质的紧密混合物。 在保持搅拌的同时，将热量和真空度施加到混合物，直到基本上从混合物中除去挥发性溶剂，以形成基本上分散的微胶囊在液体热熔悬浮介质中的分散体。 以足以将混合物保持在高于热熔悬浮介质的熔点的温度的速度施加热量，该温度也高于真空水平面上的水沸点。

公开(公告)号：US4143890A

公开(公告)日：1979-03-13

申请号：US747682

申请日：1976-12-06

申请人： Gerald T. Davis ,  Gerhart Schwab ,  Dale R. Shackle

发明人： Gerald T. Davis ,  Gerhart Schwab ,  Dale R. Shackle

IPC分类号： B41L1/36 ,  B41M5/132 ,  B41M5/155 ,  B41M5/165 ,  B41M5/22

CPC分类号： B41L1/36 ,  B41M5/132 ,  Y10S428/914 ,  Y10T428/264 ,  Y10T428/265 ,  Y10T428/277 ,  Y10T428/2984 ,  Y10T428/2987

摘要： A pressure-sensitive carbonless transfer sheet comprising a paper substrate having a front and back surface and a coating compositon adhered to at least one of the front and back surfaces of the paper substrate. The coating composition is set to a flexible, tack-free coat, and the coating composition includes a solvent free non-aqueous hot melt suspending medium which is characterized by being substantially water insoluble, being characterized by the presence of one or more functional groups selected from the group consisting of: carboxyl, carbonyl, hydroxyl, ester, amide, amine, heterocyclic groups and combinations thereof to impart polarity thereto and having a melting point of from about 60.degree. C. to about 140.degree. C. and a melting point range of less than about 15.degree. C. In addition the coating composition includes an encapsulated, chromogenic material which is substantially dispersed therein, the hot melt suspending medium being compatible with the color forming characteristics of the capsular chromogenic material. This invention further includes a liquid chromogenic coating compositon which comprises a hot melt suspending medium in combination with a microencapsulated chromogenic material. The chromogenic material is a color precursor of the electron donating type which is mixed with a carrier oil to form an oil solution of the chromogenic color precursor material which is then combined with one or more wall forming compounds.

摘要翻译： 一种压敏无碳转印片，其包含具有前表面和后表面的纸基材和粘合到纸基材的前表面和后表面中的至少一个上的涂料组合物。 该涂料组合物被设定为柔性，无粘性的涂层，并且该涂料组合物包括无溶剂的非水热熔悬浮介质，其特征在于基本上不溶于水，其特征在于存在一个或多个选自 由羧基，羰基，羟基，酯，酰胺，胺，杂环基及其组合构成的组中，赋予极性，熔点为约60℃至约140℃，熔点范围为 小于约15℃。此外，涂料组合物包括基本上分散在其中的包封的显色材料，热熔悬浮介质与荚膜发色材料的着色特性相容。 本发明还包括液体显色涂料组合物，其包含与微胶囊化显色材料组合的热熔悬浮介质。 显色材料是供电类型的彩色前体，其与载体油混合以形成显色前体材料的油溶液，然后将其与一种或多种形成壁的化合物组合。

公开(公告)号：US06242167B1

公开(公告)日：2001-06-05

申请号：US09290538

申请日：1999-04-12

申请人： Dale R. Shackle ,  Benjamin Chaloner-Gill

发明人： Dale R. Shackle ,  Benjamin Chaloner-Gill

IPC分类号： G03C500

CPC分类号： C01B13/14 ,  B41M5/3338

摘要： An electron accepting developer useful for producing visible images by reaction with an electron donor in carbonless paper and photo-imaging systems, the developer comprising an acid-treated, water insoluble alkali metal-modified, inorganic oxide or an acid-treated molecular sieve.

摘要翻译： 一种电子接受显影剂，其用于通过与无电子纸和光成像系统中的电子给体反应产生可视图像，所述显影剂包含酸处理的水不溶性碱金属改性的无机氧化物或酸处理的分子筛。

公开(公告)号：US5541020A

公开(公告)日：1996-07-30

申请号：US193047

申请日：1994-02-04

申请人： Milton N. Golovin ,  Russell D. Moulton ,  Dale R. Shackle ,  Bhuwon Pradhan

发明人： Milton N. Golovin ,  Russell D. Moulton ,  Dale R. Shackle ,  Bhuwon Pradhan

IPC分类号： H01M10/052 ,  H01M10/0565 ,  H01M10/0569 ,  H07M10/40

CPC分类号： H01M10/0569 ,  H01M10/052 ,  H01M10/0565

摘要： This invention is directed to solid electrolytes containing a solvent and, in particular, a solvent comprising a mixture of an organic carbonate and triglyme as well as electrolytic cells prepared from such solid electrolytes. The electrolyte also contains an inorganic ion salt, preferably an alkali metal salt, and most preferably LiPF.sub.6.

摘要翻译： PCT No.PCT / US93 / 06894 Sec。 371日期1994年2月4日 102（e）日期1994年2月4日PCT提交1993年7月22日PCT公布。 出版物WO94 / 02662 日本特开1994年2月3日本发明涉及含有溶剂，特别是包含有机碳酸酯和三甘醇二甲醚的混合物的溶剂以及由这种固体电解质制备的电解槽的固体电解质。 电解质还含有无机离子盐，优选碱金属盐，最优选LiPF 6。