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    Well-defined donor-acceptor rod-coil diblock copolymer based on P3HT containing C60
    21.
    发明授权
    Well-defined donor-acceptor rod-coil diblock copolymer based on P3HT containing C60 有权
    基于含有C60的P3HT的定义明确的供体 - 受体棒状线圈二嵌段共聚物

    公开(公告)号：US08211996B2

    公开(公告)日：2012-07-03

    申请号：US12592486

    申请日：2009-11-25

    申请人： Changduk Yang ,  Fred Wudl

    发明人： Changduk Yang ,  Fred Wudl

    IPC分类号： C08G75/00

    CPC分类号： H01L51/4253 ,  C08F293/005 ,  C08F2438/03 ,  C08G61/126 ,  C08G2261/126 ,  C08G2261/1642 ,  C08G2261/1644 ,  C08G2261/3223 ,  C08G2261/417 ,  H01L51/0043 ,  Y02E10/549

    摘要： A method for the synthesis of well-defined rod-coil block copolymers consisting of P3HT donor and C60 acceptor chromophores (P3HT-b-P(SxAy)-C60) in a molecular architecture is reported for use in bulk-heterojunction (BHJ) solar cells. In thin films of the resulting block copolymer, reproducible self-assembly into well-defined “nanofibrils” is observed. This is the first example of a block copolymer containing a C60 derivative that shows exclusively a nanofibrilar structure. A substantial improvement in device performance is achieved when the block copolymer is used as a “surfactant” for controlling the interface morphology of the P3HT:PCBM donor-acceptor phase domains within the composite.

    摘要翻译： 据报道，在分子结构中合成由P3HT供体和C60受体发色团（P3HT-b-P（SxAy）-C60）组成的良好定义的棒状线圈嵌段共聚物的方法用于体异质结（BHJ）太阳能电池。 在所得嵌段共聚物的薄膜中，观察到可重现的自组装成明确定义的“纳米原纤维”。 这是包含仅具有纳米纤丝结构的C60衍生物的嵌段共聚物的第一个实例。 当嵌段共聚物用作“表面活性剂”以控制复合材料中P3HT：PCBM供体 - 受体相域的界面形态时，可以实现器件性能的显着提高。

    Self-doped polymers
    24.
    发明授权
    Self-doped polymers 失效
    自掺杂聚合物

    公开(公告)号：US5569708A

    公开(公告)日：1996-10-29

    申请号：US297589

    申请日：1994-08-29

    申请人： Fred Wudl ,  Alan Heeger

    发明人： Fred Wudl ,  Alan Heeger

    IPC分类号： C08G61/12 ,  C08G73/00 ,  C08G83/00 ,  G02F1/15 ,  G02F1/155 ,  H01B1/12 ,  H01M4/60 ,  C08K3/00

    CPC分类号： C08G61/123 ,  C08G73/00 ,  C08G83/00 ,  G02F1/1525 ,  G02F1/155 ,  H01B1/127 ,  H01M4/60

    摘要： A self-doped conducting polymer having along its backbone a .pi.-electron conjugated system which comprises a plurality of monomer units, between about 0.01 and 100 mole % of the units having covalently linked thereto at least one Bronsted acid group. The conductive zwitterionic polymer is also provided, as are monomers useful in the preparation of the polymer and electrodes comprising the polymer.

    摘要翻译： 一种自掺杂的导电聚合物，其沿其主链具有π-电子共轭体系，其包含多个单体单元，在约0.01至100摩尔％的共价连接至少一个布朗斯台德酸基团的单元之间。 还提供导电两性离子聚合物，以及可用于制备聚合物的单体和包含聚合物的电极。

    Bridged cyclic arleneethylene polymers
    25.
    发明授权
    Bridged cyclic arleneethylene polymers 失效
    桥连环丙烯乙烯聚合物

    公开(公告)号：US5510456A

    公开(公告)日：1996-04-23

    申请号：US261299

    申请日：1994-06-16

    申请人： Reiko Ichikawa ,  Yoshiaki Ikenoue ,  Fred Wudl

    发明人： Reiko Ichikawa ,  Yoshiaki Ikenoue ,  Fred Wudl

    IPC分类号： C08G61/10 ,  C08G61/12 ,  H01B1/12 ,  C08G75/00 ,  C08G73/06

    CPC分类号： H01B1/127 ,  C08G61/123

    摘要： A polymer represented by the following formula (III) ##STR1## wherein R.sub.1 and R.sub.2 each independently represents H, a straight or branched alkyl group or alkoxy group having 1 to 20 carbon atoms, X is S, O, or NR.sub.3, R.sub.3 represents a straight or branched akyl group having 1 to 6 carbon atoms or a phenyl group, Y represents R.sub.4 S.sup.+ R.sub.5 M.sup.- or OR.sub.6, R.sub.4 and R.sup.5 each independently represent a straight or branched alkyl group having 1 to 5 carbon atoms, or form a heterocyclic ring together with sulfur, and M.sup.- is an anion, R.sub.6 represents H or a straight or branched alkyl group having 1 to 10, m is 1 to 2, and n represents a degree of polymerization and is a value larger than 5.

    摘要翻译： （III）表示的聚合物其中R 1和R 2各自独立地表示H，具有1〜20个碳原子的直链或支链烷基或烷氧基 碳原子，X是S，O或NR 3，R 3表示具有1〜6个碳原子的直链或支链烷基或苯基，Y表示R4S + R5M-或OR6，R4和R5各自独立地表示直链或支链 具有1至5个碳原子的烷基，或与硫一起形成杂环，M-为阴离子，R6表示H或具有1-10个直链或支链烷基，m为1至2，n表示 聚合度为大于5的值。

    Polyisothianaphtene, a new conducting polymer
    26.
    发明授权
    Polyisothianaphtene, a new conducting polymer 失效
    Polyisothianaphtene，一种新的导电聚合物

    公开(公告)号：US4640748A

    公开(公告)日：1987-02-03

    申请号：US736984

    申请日：1985-05-22

    申请人： Fred Wudl ,  Masao Kobayashi ,  Alan Heeger

    发明人： Fred Wudl ,  Masao Kobayashi ,  Alan Heeger

    IPC分类号： C08G61/12 ,  C09K9/02 ,  G02F1/15 ,  H01B1/12 ,  H01M4/60 ,  C25C1/00

    CPC分类号： C08G61/123 ,  C09K9/02 ,  G02F1/15 ,  H01B1/127 ,  H01M4/60

    摘要： A polymer having an isothianaphthene structure represented by the formula (Ia) and/or Ib): ##STR1## wherein R.sup.1 and R.sup.2 each represents a hydrogen atom or a hydrocarbon residue having 1 to 5 carbon atoms such as methyl, methoxy and thiomethyl, with the proviso that R.sup.1 and R.sup.2 may link together to form, along with the benzene ring, a fused ring which is naphthalene; X is sulfur, selenium or tellurium; Y.sup.- represents an anion of an electrolyte; z represents a number from 0.01 to 1 showing a ratio of the anion per mol of a monomer; and n represents a number of from 5 to 500 showing a degree of polymerization.An electrochromic display wherein a high molecular weight conductive membrane formed on a conductive transparent base is used as a display base and an opposing electrode is arranged thereunder via a liquid electrolyte, which is characterized in that said high molecular weight conductive membrane is a polymer having an isothianaphthene structure and capable of being reversibly oxidized or reduced.

    摘要翻译： 具有由式（Ia）和/或Ib）表示的异硫茚结构的聚合物：其中R 1和R 2各自表示氢原子或具有1至5个碳原子的烃残基如甲基，甲氧基和硫代甲基， 条件是R1和R2可以连接在一起，与苯环一起形成为萘的稠环; X是硫，硒或碲; Y-表示电解质的阴离子; z表示0.01〜1的数，表示每摩尔单体的阴离子比; n表示聚合度为5〜500的数。 一种电致变色显示器，其中形成在导电透明基底上的高分子量导电膜用作显示基底，并且相对电极经由液体电解质布置在其下方，其特征在于所述高分子量导电膜是具有 异硫茚结构并能够被可逆地氧化或还原。

    ELECTRONIC SENSING OF BIOLOGICAL AND CHEMICAL AGENTS USING FUNCTIONALIZED NANOSTRUCTURES
    28.
    发明申请
    ELECTRONIC SENSING OF BIOLOGICAL AND CHEMICAL AGENTS USING FUNCTIONALIZED NANOSTRUCTURES 审中-公开
    使用功能化纳米结构的生物和化学试剂的电子感测

    公开(公告)号：US20110154648A1

    公开(公告)日：2011-06-30

    申请号：US13047593

    申请日：2011-03-14

    申请人： Jean Christophe Gabriel ,  George Gruner ,  Philip Collins ,  Basil Swanson ,  Fred Wudl

    发明人： Jean Christophe Gabriel ,  George Gruner ,  Philip Collins ,  Basil Swanson ,  Fred Wudl

    IPC分类号： H05K13/00 ,  B82Y99/00

    CPC分类号： B82Y30/00 ,  G01N33/5438 ,  G01N33/551 ,  G01N33/566 ,  G01N33/582 ,  Y10T29/49002

    摘要： This invention provides for an apparatus and a method for detecting the presence of pathogenic agents with sensors containing functionalized nanostructures integrated into circuits on silicon chips. The nanostructures are functionalized with molecular transducers that recognize and bind targeted analytes which are diagnostic of the pathogenic agent of interest. The molecular transducer includes a receptor portion, which binds the analyte, and an anchor portion that attaches to the nanostructure. Upon binding of the analyte, a change in molecular configuration represented by the newly formed receptor-analyte complex creates a force that is transmitted to the nanostructure via the anchor portion of the transducer. The effect of the force transmitted to the nanostructure is to alter its conductivity. The change in conductivity of the nanotube thus represents a signal that indicates the presence of the pathogenic agent of interest.

    摘要翻译： 本发明提供了一种用于检测病原体的存在的装置和方法，所述传感器包含集成在硅芯片上的电路中的功能化纳米结构。 纳米结构用识别和结合目标分析物的分子换能器进行功能化，这些目标分析物是目标病原体的诊断。 分子换能器包括结合分析物的受体部分和附着到纳米结构的锚定部分。 在分析物结合后，由新形成的受体 - 分析物复合物表示的分子构型的变化产生通过换能器的锚定部分传递到纳米结构的力。 传递到纳米结构的力的作用是改变其导电性。 因此，纳米管的电导率的变化表示表示感兴趣的病原体的存在的信号。

    ELECTRONIC SENSING OF BIOLOGICAL AND CHEMICAL AGENTS USING FUNCTIONALIZED NANOSTRUCTURES
    29.
    发明申请
    ELECTRONIC SENSING OF BIOLOGICAL AND CHEMICAL AGENTS USING FUNCTIONALIZED NANOSTRUCTURES 审中-公开
    使用功能化纳米结构的生物和化学试剂的电子感测

    公开(公告)号：US20100231242A1

    公开(公告)日：2010-09-16

    申请号：US12634525

    申请日：2009-12-09

    申请人： Jean Christophe Gabriel ,  George Gruner ,  Philip Collins ,  Basil Swanson ,  Fred Wudl

    发明人： Jean Christophe Gabriel ,  George Gruner ,  Philip Collins ,  Basil Swanson ,  Fred Wudl

    IPC分类号： G01R27/08

    CPC分类号： B82Y30/00 ,  G01N33/5438 ,  G01N33/551 ,  G01N33/566 ,  G01N33/582 ,  Y10T29/49002

    摘要： This invention provides for an apparatus and a method for detecting the presence of pathogenic agents with sensors containing functionalized nanostructures integrated into circuits on silicon chips. The nanostructures are functionalized with molecular transducers that recognize and bind targeted analytes which are diagnostic of the pathogenic agent of interest. The molecular transducer includes a receptor portion, which binds the analyte, and an anchor portion that attaches to the nanostructure. Upon binding of the analyte, a change in molecular configuration represented by the newly formed receptor-analyte complex creates a force that is transmitted to the nanostructure via the anchor portion of the transducer. The effect of the force transmitted to the nanostructure is to alter its conductivity. The change in conductivity of the nanotube thus represents a signal that indicates the presence of the pathogenic agent of interest.

    摘要翻译： 本发明提供了一种用于检测病原体的存在的装置和方法，所述传感器包含集成在硅芯片上的电路中的功能化纳米结构。 纳米结构用识别和结合目标分析物的分子换能器进行功能化，这些目标分析物是目标病原体的诊断。 分子换能器包括结合分析物的受体部分和附着到纳米结构的锚定部分。 在分析物结合后，由新形成的受体 - 分析物复合物表示的分子构型的变化产生通过换能器的锚定部分传递到纳米结构的力。 传递到纳米结构的力的作用是改变其导电性。 因此，纳米管的电导率的变化表示表示感兴趣的病原体的存在的信号。