公开(公告)号：US20100179272A1

公开(公告)日：2010-07-15

申请号：US12530871

申请日：2008-02-13

申请人： Christoph Balzarek ,  Martin Jakob

发明人： Christoph Balzarek ,  Martin Jakob

IPC分类号： C08L29/04 ,  C08L33/10 ,  C08L31/02 ,  C08L31/04 ,  C08L33/06 ,  C08L25/10 ,  C08L33/08 ,  C08L39/00 ,  C08L37/00

CPC分类号： C08K5/07 ,  C08L1/32 ,  C08L29/04 ,  C08L2312/00 ,  C09J131/04

摘要： Compositions containing an aqueous dispersion of selected polymers and selected polyaldehydes as crosslinking agents are described.Adhesives having very high resistance to boiling water can be produced from these formulations.

摘要翻译： 描述了包含所选聚合物的水性分散体和选择的聚醛作为交联剂的组合物。 可以从这些制剂制备具有非常高耐沸水性的粘合剂。

公开(公告)号：US20060047069A1

公开(公告)日：2006-03-02

申请号：US11213483

申请日：2005-08-26

申请人： Martin Jakob ,  Heinrich Harrer

发明人： Martin Jakob ,  Heinrich Harrer

IPC分类号： C08F116/06

CPC分类号： C08F218/08 ,  A23B4/10 ,  A23B7/16 ,  A23C19/11 ,  A23C19/163 ,  A23L3/34635 ,  C08L1/26 ,  C09D135/02 ,  C08L2666/26

摘要： A description is given of an aqueous polymer dispersion which is set to a pH range of 4 to 6 and comprises A) 100 parts by weight of a homopolymer or copolymer produced by emulsion polymerization, B) 0.1 to 15 parts by weight, based on the total amount of the monomers used, of at least one protective colloid, C) 0.1 to 10 parts by weight, based on the total amount of the monomers used, of at least one nonionic emulsifier, D) 10 to 990 ppm by weight, based on the mass of the total dispersion of at least one antioxidant, and E) at least one polyene fungicide. A second variant of the aqueous polymer dispersions is set to a pH range of 4.5 to 5.5 and has components A) to C) and E) but no antioxidant. The protective colloid of the aqueous polymer dispersions has no cellulose ether, or up to 0.45 part by weight of cellulose ether, based on the total amount of the monomers used. The polymer dispersions described are distinguished by excellent polyene-fungicide tolerance and may be used for coating foods.

摘要翻译： 给出了一种水性聚合物分散体的描述，该分散体的pH范围为4至6，并且包含A）100重量份的通过乳液聚合制备的均聚物或共聚物，B）0.1至15重量份，基于 所用单体的总量，至少一种保护胶体，C）基于所用单体总量的0.1至10重量份的至少一种非离子乳化剂，D）10至990重量ppm，基于 关于至少一种抗氧化剂的总分散体的质量，和E）至少一种多烯杀真菌剂。 水性聚合物分散体的第二变体设定为4.5至5.5的pH范围，并具有组分A）至C）和E），但不含抗氧化剂。 基于所用单体的总量，聚合物水分散体的保护胶体不含纤维素醚，或高达0.45重量份的纤维素醚。 所述的聚合物分散体的特征在于优良的多烯 - 杀真菌剂耐受性，可用于涂覆食品。

公开(公告)号：US20050032970A1

公开(公告)日：2005-02-10

申请号：US10899164

申请日：2004-07-26

申请人： Martin Jakob ,  Werner Prass

发明人： Martin Jakob ,  Werner Prass

IPC分类号： C08F8/30

CPC分类号： C08F8/30 ,  C08L29/04 ,  C09J131/04

摘要： Water-resistant adhesives, their preparation and use A description is given of an aqueous dispersion adhesive based on an aqueous polymer dispersion comprising at least one emulsion polymer with small amounts of crosslinkable N-methylol groups, at least one protective colloid, and at least one crosslinking agent containing N-methylol groups, of which at least one is etherified with an alkanol, said crosslinking agent being selected from the group consisting of hydroxymethylated cyclic ethyleneureas, hydroxymethylated cyclic propyleneureas, hydroxymethylated bicyclic glyoxal diureas, hydroxymethylated bicyclic malonaldehyde diureas or combinations thereof. The aqueous dispersion adhesive can be employed in particular for adhesively bonding porous and semiporous substrates.

摘要翻译： 防水粘合剂及其制备和应用描述了基于包含至少一种具有少量可交联的N-羟甲基的至少一种乳液聚合物，至少一种保护胶体和至少一种保护胶体的水性分散体粘合剂 含有至少一个与链烷醇醚化的N-羟甲基的交联剂，所述交联剂选自羟甲基化环状亚乙基脲，羟甲基化环丙烯脲，羟甲基化双环乙二醛脲，羟甲基化双环丙二醛二脲或其组合。 水性分散粘合剂可以特别用于粘合多孔和半孔基材。

公开(公告)号：US07776938B2

公开(公告)日：2010-08-17

申请号：US11159785

申请日：2005-06-23

申请人： Martin Jakob ,  Heinrich Harrer ,  Ivan Cabrera

发明人： Martin Jakob ,  Heinrich Harrer ,  Ivan Cabrera

IPC分类号： A23C19/16 ,  A23B4/10 ,  A23B7/16 ,  C09D131/04 ,  C09D133/10

CPC分类号： A22C13/0013

摘要： A description is given of food coating compositions comprising a) a plastics dispersion or a mixture of plastics dispersions comprising at least one homo- or copolymer poly(meth)acrylate having at least 55% by weight (meth)acrylate monomer units and also 0.1 to 30% by weight of at least one protective colloid, and also b) aids and/or additives used for producing food coatings. The coatings are distinguished by sufficiently high water vapor transmission rates, low water absorption capacity and also low reemulsification capacity and have good mechanical properties in the moist state.

摘要翻译： 描述了食品涂料组合物，其包括a）塑料分散体或塑料分散体的混合物，其包含至少一种具有至少55重量％（甲基）丙烯酸酯单体单元的均聚物或共聚物聚（甲基）丙烯酸酯，并且还包含0.1至 30重量％的至少一种保护胶体，以及b）用于生产食品涂料的助剂和/或添加剂。 涂层的特征在于足够高的水蒸气透过率，低吸水能力和低再乳化能力，并且在潮湿状态下具有良好的机械性能。

公开(公告)号：US07491777B2

公开(公告)日：2009-02-17

申请号：US11000406

申请日：2004-11-30

申请人： Martin Jakob ,  Heinrich Harrer

发明人： Martin Jakob ,  Heinrich Harrer

IPC分类号： C08F218/08 ,  C08F222/14 ,  C09D131/04 ,  A23C19/16

CPC分类号： A23C19/16 ,  A22C13/0013 ,  A22C2013/004 ,  A23P20/19 ,  C08F218/04 ,  C08F222/14 ,  C08L29/04 ,  C08L33/04 ,  C08L71/02 ,  C09D131/04 ,  C08L2666/02

摘要： A decsription is given of an aqueous copolymer poly(vinyl ester) dispersion comprising A) 100 parts by weight of a copolymer derived from A1) from 34.9 to 95% by weight of vinyl esters of aliphatic, saturated carboxylic acids, A2) from 4.9 to 65% by weight of maleic esters and/or fumaric esters of monohydric aliphatic alcohols having a chain length of C1-C18 and/or alpha-olefins having from 2 to 8 carbon atoms, A3) from 0.1 to 10% of at least one comonomer having at least one stabilizing nonionic or ionic group, and also A4) if appropriate, other comonomers, the sum of components A1, A2 and A3 and if appropriate A4 giving 100% by weight, B) from 0.1 to 4.5 parts by weight, based on the total amount of the monomers used, preferably from 0.5 to 3.5 parts by weight of at least one protecting colloid, preferably poly(vinyl alcohol), C) from 0.1 to 10 parts by weight, based on the total amount of the monomers used, preferably from 0.5 to 5.0 parts by weight, of a nonionic emulsifier, and D) if appropriate, further additives suitable for coating foods. The dispersion is produced by free-radical emulsion polymerization and is suitable for coating foods. The films formed from these dispersions are distinguished by a low water-vapor transmission rate.

摘要翻译： 给出了一种含水共聚物聚（乙烯基酯）分散体的分解物，其包含A）100重量份的衍生自A1）的共聚物，34.9-95重量％的脂肪族饱和羧酸的乙烯基酯，A2）为4.9〜 65重量％的链长为C1-C18和/或具有2至8个碳原子的α-烯烃的一元脂肪醇的马来酸酯和/或富马酸酯，A3）0.1至10％的至少一种共聚单体 具有至少一个稳定的非离子或离子基团，以及A4），如果合适的话，其它共聚单体，组分A1，A2和A3的总和，如果合适的话A4给出100重量％，B）0.1至4.5重量份 相对于使用的单体的总量，优选为0.5〜3.5重量份的至少一种保护胶体，优选聚（乙烯醇），C）为0.1〜10重量份，基于所用单体的总量 ，优选0.5-5.0重量份的非离子乳化剂，和D） 如果合适，还可以添加适合涂层食品的其他添加剂。 分散体是通过自由基乳液聚合生产的，适用于涂层食品。 由这些分散体形成的薄膜的特征在于低的水蒸气透过率。

公开(公告)号：US20080139650A1

公开(公告)日：2008-06-12

申请号：US11576124

申请日：2005-08-26

申请人： Martin Jakob ,  Heinrich Harrer

发明人： Martin Jakob ,  Heinrich Harrer

IPC分类号： A01N25/10 ,  C08K5/01 ,  C08K5/09 ,  A01N37/06 ,  A01P3/00 ,  C08K5/16 ,  C08K5/05

CPC分类号： A01N31/16 ,  A01N31/08 ,  A01N37/02 ,  A01N43/90 ,  A01N43/50 ,  A01N37/06 ,  A01N25/30 ,  A01N25/10 ,  A01N25/04 ,  A01N2300/00

摘要： A description is given of an aqueous polymer dispersion comprising A) a polymer dispersion produced by free-radical polymerization of ethylenically unsaturated monomers, B) stabilizers suitable for carrying out the free-radical polymerization, and also C) 0.01 to 20 000 ppm by weight, based on the mass of the total dispersion, of at least one compound of the formula Ia and/or Ib where R1, R2, R13 and R14 independently of one another are hydrogen, C1-C6-alkyl, C1-C6-alkoxy, carboxyl, nitrile, isonitrile, cyano or halogen, R3 to R12 and R15 to R24 independently of one another are hydrogen and selected organic radicals, and at least one of the substituents R3 to R12, or R15 to R24, being hydroxyl and/or alkoxy and/or alkanoyloxy. The aqueous polymer dispersion may be used for coating foods, as color, or as adhesive, and the resultant films are distinguished by high fungicidal resistance.

摘要翻译： 描述了一种含水聚合物分散体，其包括A）通过烯属不饱和单体的自由基聚合制备的聚合物分散体，B）适用于进行自由基聚合的稳定剂，以及C）0.01至20,000ppm重量 基于总分散体的质量，至少一种式Ia和/或Ib的化合物，其中R 1，R 2，R 13， R 1和R 2彼此独立地是氢，C 1 -C 6 - C 6 - 烷基，C 1〜 C 6 -C 6 - 烷氧基，羧基，腈，异腈，氰基或卤素，R 3至R 12和R 15， 彼此独立的R 24和R 24彼此是氢和选择的有机基团，并且至少一个取代基R 3至R 12的取代基 或R 15至R 24为羟基和/或烷氧基和/或烷酰氧基。 聚合物水分散体可以用于涂覆食品，如颜色或粘合剂，并且所得到的膜具有高的杀真菌性。

公开(公告)号：US20050287257A1

公开(公告)日：2005-12-29

申请号：US11159785

申请日：2005-06-23

申请人： Martin Jakob ,  Heinrich Harrer ,  Ivan Cabrera

发明人： Martin Jakob ,  Heinrich Harrer ,  Ivan Cabrera

IPC分类号： A22C13/00 ,  A23L1/27

CPC分类号： A22C13/0013

摘要： Food coating composition comprising protective-colloid-stabilized polyacrylate dispersions, use thereof and coated foods produced therewith A description is given of food coating compositions comprising a) a plastics dispersion or a mixture of plastics dispersions comprising at least one homo- or copolymer poly(meth)acrylate having at least 55% by weight (meth)acrylate monomer units and also 0.1 to 30% by weight of at least one protective colloid, and also b) aids and/or additives used for producing food coatings. The coatings are distinguished by sufficiently high water vapor transmission rates, low water absorption capacity and also low reemulsification capacity and have good mechanical properties in the moist state.

摘要翻译： 包含保护胶体稳定的聚丙烯酸酯分散体的食品涂料组合物，其用途和由其生产的包衣食品给出了食品涂料组合物的描述，其包括a）塑料分散体或包含至少一种均聚物或共聚物的塑料分散体的混合物 ）丙烯酸酯，其具有至少55重量％（甲基）丙烯酸酯单体单元和0.1至30重量％的至少一种保护胶体，以及b）用于生产食品涂料的助剂和/或添加剂。 涂层的特征在于足够高的水蒸气透过率，低吸水能力和低再乳化能力，并且在潮湿状态下具有良好的机械性能。

公开(公告)号：US20050154123A1

公开(公告)日：2005-07-14

申请号：US11000406

申请日：2004-11-30

申请人： Martin Jakob ,  Heinrich Harrer

发明人： Martin Jakob ,  Heinrich Harrer

IPC分类号： A22C13/00 ,  A23C19/16 ,  A23L1/00 ,  C08F218/04 ,  C08F218/08 ,  C08F222/12 ,  C08F222/14 ,  C08L29/04 ,  C08L33/04 ,  C08L71/02 ,  C09D131/04 ,  C09D135/02 ,  C08K3/00

CPC分类号： A23C19/16 ,  A22C13/0013 ,  A22C2013/004 ,  A23P20/19 ,  C08F218/04 ,  C08F222/14 ,  C08L29/04 ,  C08L33/04 ,  C08L71/02 ,  C09D131/04 ,  C08L2666/02

摘要： A description is given of an aqueous copolymer poly(vinyl ester) dispersion comprising A) 100 parts by weight of a copolymer derived from A1) from 34.9 to 95% by weight of vinyl esters of aliphatic, saturated carboxylic acids, A2) from 4.9 to 65% by weight of maleic esters and/or fumaric esters of monohydric aliphatic alcohols having a chain length of C1-C18 and/or alpha-olefins having from 2 to 8 carbon atoms, A3) from 0.1 to 10% of at least one comonomer having at least one stabilizing nonionic or ionic group, and also A4) if appropriate, other comonomers, the sum of components A1, A2 and A3 and if appropriate A4 giving 100% by weight, B) from 0.1 to 4.5 parts by weight, based on the total amount of the monomers used, preferably from 0.5 to 3.5 parts by weight of at least one protecting colloid, preferably poly(vinyl alcohol), C) from 0.1 to 10 parts by weight, based on the total amount of the monomers used, preferably from 0.5 to 5.0 parts by weight, of a nonionic emulsifier, and D) if appropriate, further additives suitable for coating foods. The dispersion is produced by free-radical emulsion polymerization and is suitable for coating foods. The films formed from these dispersions are distinguished by a low water-vapor transmission rate.

摘要翻译： 描述了一种含水共聚物聚（乙烯基酯）分散体，其包含A）100重量份的衍生自A1）的共聚物，34.9-95重量％的脂肪族，饱和羧酸的乙烯基酯，A2）为4.9〜 65重量％的链长为C 1 -C 18的一元脂肪醇的马来酸酯和/或富马酸酯和/或具有2〜 8个碳原子，A3）0.1至10％的至少一种具有至少一个稳定非离子或离子基团的共聚单体，以及A4）如果合适的话，其它共聚单体，组分A1，A2和A3的总和以及如果合适的话给予A4 100重量％，B）0.1至4.5重量份，基于所用单体的总量，优选0.5至3.5重量份的至少一种保护胶体，优选聚（乙烯醇），C） 基于所使用的单体的总量，0.1至10重量份，优选0.5至5.0重量份的非离子表面活性剂 nic乳化剂和D）如果合适，还可以添加适合涂层食品的其他添加剂。 分散体是通过自由基乳液聚合生产的，适用于涂层食品。 由这些分散体形成的薄膜的特征在于低的水蒸气透过率。

公开(公告)号：US20050107515A1

公开(公告)日：2005-05-19

申请号：US10499503

申请日：2002-12-23

申请人： Martin Jakob ,  Heinrich Harrer

发明人： Martin Jakob ,  Heinrich Harrer

IPC分类号： A23C19/16 ,  A23L1/00 ,  A23P20/00 ,  C08F218/04 ,  C08K5/06 ,  C08L29/04 ,  C09D131/04 ,  C08J3/00

CPC分类号： C08F218/04 ,  A23C19/163 ,  A23P20/19 ,  C08K5/06 ,  C08L29/04 ,  C08L2205/02 ,  C09D131/04 ,  C08L2666/04

摘要： A novel food coating substance comprising a plasticizer-free aqueous copolymer poly(vinyl ester) dispersion of emulsion polymer, emulsifier, protective colloid and optionally other stabilizers is outstandingly suitable for the surface treatment or surface coating of hard cheese or semi-hard cheese, but also of meat products, fruits, nuts or seed material.

摘要翻译： 包含不含增塑剂的水性共聚物乳液聚合物，乳化剂，保护胶体和任选的其它稳定剂的聚（乙烯基酯）分散体的新型食品包衣物质显着地适用于硬干酪或半硬质干酪的表面处理或表面涂层，但是 还有肉制品，水果，坚果或种子材料。

公开(公告)号：US06730718B1

公开(公告)日：2004-05-04

申请号：US10110406

申请日：2002-08-28

申请人： Martin Jakob

发明人： Martin Jakob

IPC分类号： C09J1104

CPC分类号： C09J131/02 ,  C08L2666/28

摘要： The present invention relates to water-resistant aqueous dispersion adhesives with prolonged pot life and good color constancy of their bonds, comprising homopolymeric and/or copolymers polyvinyl esters, polymeric protective colloids, water-soluble compounds which can be complexed with the polymeric protective colloids, and derivatives of glyoxal and polyaldehydes having at least 3 carbon atoms, from which aldehyde groups can be controllably released in acidic media. The inventive dispersion adhesives are suitable for adhesively bonding porous and semiporous substrates.

摘要翻译： 本发明涉及具有延长使用寿命和良好的颜色恒定性的耐水性水性分散粘合剂，其包含均聚聚合物和/或共聚物聚乙烯基酯，聚合物保护胶体，可与聚合物保护胶体络合的水溶性化合物， 以及具有至少3个碳原子的乙二醛和多醛的衍生物，醛基可以从其中酸性介质中可控地释放。 本发明的分散粘合剂适用于粘合多孔和半孔基材。