摘要:
A highly effective surfactant mixture which is liquid at room temperature comprising:(1) from 50 to 84.degree. C. by weight ether alcohol corresponding to the general formulaR.sub.1 --O--[PO].sub.0-3 [EO].sub.6-8 H,(2) from 10 to 40% by weight ether alcohol corresponding to the formulaR.sub.2 --O--[PO].sub.0-3 [EO].sub.3-6 H,(3) from 0 to 10% by weight ethoxylation products of polyols which may be obtained by reaction of C.sub.12 -C.sub.18 1,2-epoxides with ethylene glycol, glycerol, trimethylol propane or neopentyl glycol,(4) from 0.1 to 10% by weith of an amino alcohol selected from(A)R.sub.3 --[EO].sub.0-4 N(CH.sub.2 CH.sub.2 OH).sub.2,orR.sub.3 --[EO].sub.0-4 NH--CH.sub.2 CHOH(B) the reaction product of C.sub.12 -C.sub.18 1,2-epoxide with mono- or diethanolamine,(C) reaction product of epoxidized oleyl or linoleyl alcohol with mono- or diethanolamine or(D) reaction product of compound (A), (B) or (C) with from 2 to 12 times the molar quantity of ethylene oxide, and(5) lower carboxylic acids in the quantity required to adjust a 1% aqueous solution to a neutral pH-value; wherein R.sub.1 is a C.sub.9 -C.sub.11 alkyl group, R.sub.2 is a C.sub.12 -C.sub.15 alkyl group, R.sub.3 is a C.sub.12 -C.sub.18 alkyl or alkenyl group, (EO) are ring-opened ethylene oxide residues and (PO) are ring-opened propylene oxide residues.
摘要:
New oil components for cosmetic and pharmaceutical applications consist of reaction products of epoxidized triglyceride oils with monohydric alcohols containing from 1 to 4 carbon atoms. The oil components are produced by reacting an epoxidized triglyceride oil containing from about 4 to about 8% by weight of epoxide oxygen, preferably an epoxidized soya bean oil containing from about 6 to about 7% by weight of epoxide oxygen, in the presence of an acidic catalyst with a monohydric C.sub.1 -C.sub.4 -alcohol, preferably methanol, in excess at the boiling temperature of the alcohol until the oxirane rings have been completely opened, followed by neutralizing the catalyst and distilling off the excess alcohol. The new oil components are eminently suitable, inter alia, for the production of cosmetic stick preparations.
摘要:
Fatty alcohol mixtures R.sub.mix --OH of natural and, in particular, purely vegetable origin and ethoxylates thereof showing improved low-temperature behavior and corresponding to the general formula R.sub.mix --O--(CH.sub.2 CH.sub.2 O).sub.x --H, in which x is a number of 2 to 10 and R.sub.mix represents selected mixtures of saturated and olefinically unsaturated fatty alcohol hydrocarbon radicals in the C 6-20 or C 12-20 ranges correspond to specification I for the chain length range R.sub.mix --=6-20 and to specification II for the chain length range R.sub.mix --=C 12-20:______________________________________ Specification I II structurally analogous to % by weight ______________________________________ C 6 caproic acid 0.1-0.6 -- C 8 caprylic acid 2.5-10 -- C 10 capric acid 2.5-14 -- C 12 lauric acid 37-52 39-69 C 14 myristic acid 10-20 10-27 C 16 palmitic acid 6-10 6-14 C 18 stearic acid 1-5 1-7 C 18' oleic acid 5-23 6-31 C 18" linoleic acid 1-4 1-6 C 18"' linolenic acid 0.1-1 0.1-2 C 20 arachic acid 0.1-1 0.1-2 ______________________________________
摘要翻译:天然的,特别是纯植物来源的脂肪醇混合物Rmix-OH,其乙氧基化物显示出改进的低温行为,并且对应于通式Rmix-O-(CH2CH2O)xH,其中x为2至10的数 Rmix表示C 6-20或C 12-20范围内饱和和烯属不饱和脂肪醇烃基的选定混合物,对应于链长范围Rmix- = 6-20的规范I,链长范围为规范II Rmix- = C 12-20:-21规格30-21 I25 II-8结构类似于21重量%30 C 6己酸0.1-0.6 C 8辛酸2.5-10 C 10癸酸2.5-14 - -C 12月桂酸37-5239-69-C 14肉豆蔻酸10-2010-27-C 16棕榈酸6-10 6-14-C 18硬脂酸-51-7-C 18油酸5-23 6-31-C 18“ 亚油酸1-41-6-C 18“'亚麻酸0.1-1 0.1-2 -C 20arachic acid 0.1-1 0.1-2 -
摘要:
A process for the production of alkyl polyoxyethylenes showing improved low-temperature behavior, by reaction of alcohols with ethylene oxide at elevated temperature in the presence of basic alkali metal compounds as catalysts and subsequent neutralization of the alkaline catalyst with acids, which under prior art practice was impractical because of clogging of reaction vessels and equipment associated with precipitation of salts during neutralization, is made practical by adding a finely divided solid to serve as a precipitation control agent during neutralization. The finely divided solids used are, in particular, organic and/or inorganic materials known in the prior art as filter aids, such as kieselguhr and sawdust or other finely divided cellulose.
摘要:
Foam-depressing additives comprising polyethyleneglycol ethers of formula IR.sup.1 --O--(CH.sub.2 CH.sub.2 O).sub.n --R.sup.2 (I)in which R.sup.1 represents a straight-chain or branched alkyl radical with 6 to 13 carbon atoms, R.sup.2 represents an alkyl radical with 1 to 3 carbon atoms and n is a number from 2 to 6, for low-foam, preferably sprayable cleaning agents.
摘要:
A process for cleaning a soiled solid molded article in an aqueous detergent wash bath in the presence of ultrasound whereby pigmented and/or fatty soils are loosened from the soiled article. The wash bath is contacted with a soil-collecting polyfunctional quaternary ammonium compound which is at least substantially insoluble and/or is fixed to a solid which is substantially insoluble in the wash bath to collect from the wash bath at least a portion of the soils loosened from the article.
摘要:
The process of regenerating a soil-laden detergent solution comprising contacting said solution with a soil collector comprising a polyfunctional quaternary ammonium compound which is at least substantially insoluble in the solution and/or immobilized on a solid correspondingly insoluble in the solution.
摘要:
The invention relates to a process for preparing tertiary ether amines corresponding to the following general formula: ##STR1## by reacting in the presence of a strong base a tertiary amine corresponding to the following formula: ##STR2## with a sulfuric acid semi-ester salt corresponding to the following formula:R.sup.1 --(OC.sub.n H.sub.2n).sub.x --OSO.sub.3 M. (III)Preferably, each mole of the tertiary amine corresponding to formula (II) is reacted under substantially anhydrous conditions at a temperature of 140.degree. to 230.degree. C. with from about 0.2 to 3.0 moles of the sulfuric acid semi-ester salt of formula (III) in the presence of from about 1 to 1.5 moles of a strong base preferably an alkali metal hydroxide or an alkali metal alcoholate.
摘要:
An improved process for the emulsion polymerization of ethylenically unsaturated monomers in an aqueous emulsion, using as the primary emulsifier an ethoxylated C.sub.8-25 aliphatic vicinal diol.
摘要:
Compositions containing an organic polyisocyanate and a fatty polyol are provided. The fatty polyols may be derived from an epoxidized fatty alcohol that has been reacted with a polyfunctional-hydroxy compound. The compositions are preferably salt-free and are useful in preparing a variety polyurethane materials.