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    Process for preparing a modified alkylaryl
    21.
    发明授权
    Process for preparing a modified alkylaryl 失效
    通过吸附分离制备表面活性剂的方法及其制备方法

    公开(公告)号：US06525233B1

    公开(公告)日：2003-02-25

    申请号：US09479364

    申请日：2000-01-07

    申请人： Daniel Stedman Connor ,  Jeffrey John Scheibel ,  James Charles Theophile Roger Burkett-St. Laurent ,  Thomas Anthony Cripe ,  Kevin Lee Kott ,  Phillip Kyle Vinson

    发明人： Daniel Stedman Connor ,  Jeffrey John Scheibel ,  James Charles Theophile Roger Burkett-St. Laurent ,  Thomas Anthony Cripe ,  Kevin Lee Kott ,  Phillip Kyle Vinson

    IPC分类号： C07C264

    CPC分类号： C07C303/06 ,  C07C7/13 ,  C07C15/02 ,  C07C9/00 ,  C07C309/31

    摘要： Processes for making particularly branched, especially monomethyl-branched or nongeminal dimethyl-branched surfactants used in cleaning products; preferred processes comprising particular combinations of two or more adsorptive separation steps and, more preferably, particular alkylation steps; products of such processes, including certain modified alkylbenzenes, modified alkylbenzenesulfonate surfactants, and consumer cleaning products, especially laundry detergents, containing them. Preferred processes herein more specifically use specific, unconventional sequences of sorptive separation steps to secure certain branched hydrocarbon fractions which are used in further process steps as alkylating agents for arenes or for other useful surfactant-making purposes. Surprisingly, such fractions can even be derived from effluents from current linear alkylbenzene manufacture.

    摘要翻译： 用于制造特别是支链的，特别是用于清洁产品中的单甲基支链或非农业二甲基支链表面活性剂的方法; 优选的方法包括两个或多个吸附分离步骤的特定组合，更优选特定的烷基化步骤; 这些方法的产物，包括某些改性烷基苯，改性烷基苯磺酸盐表面活性剂，以及含有它们的消费者清洁产品，特别是衣物洗涤剂。 本文优选的方法更具体地使用吸附分离步骤的特定的非常规序列，以确保在进一步的工艺步骤中使用的某些支链烃馏分作为芳烃的烷基化剂或其它有用的表面活性剂制备目的。 令人惊讶的是，这些馏分甚至可以从目前的直链烷基苯生产的流出物得到。

    Alkylaromatic hydrocarbon compositions
    22.
    发明授权
    Alkylaromatic hydrocarbon compositions 失效
    烷基芳烃组合物

    公开(公告)号：US06908894B2

    公开(公告)日：2005-06-21

    申请号：US10038170

    申请日：2001-10-22

    申请人： Kevin Lee Kott ,  Jeffrey John Scheibel ,  Thomas Anthony Cripe ,  Daniel Stedman Connor ,  Phillip Kyle Vinson

    发明人： Kevin Lee Kott ,  Jeffrey John Scheibel ,  Thomas Anthony Cripe ,  Daniel Stedman Connor ,  Phillip Kyle Vinson

    IPC分类号： C07C309/31 ,  C07C309/37 ,  C11D1/22 ,  C11D17/00

    CPC分类号： C11D1/22

    摘要： A surfactant composition comprising:alkylarylsulfonate surfactant system comprising at least two isomers of the alkylarylsulfonate surfactant of the formula: wherein: L is an acyclic aliphatic hydrocarbyl of from 6 to 18 carbon atoms in total; M is a cation or cation mixture and q is the valence thereof; a and b are numbers selected such that said composition is electroneutral; R′ is selected from H and C1 to C3 alkyl; R″ is selected from H and C1 to C3 alkyl; R′″ is selected from H and C1 to C3 alkyl; any of R′ and R″ is nonterminally attached to L and at least one of R′ and R″ is C1 to C3 alkyl; and A is aryl; and wherein: said alkylarylsulfonate surfactant system comprises two or more isomers with respect to positions of attachment of R′, R″ and A to L; in at least about 60% of said composition, A is attached to L in the position which is selected from positions alpha- and beta- to either of the two terminal carbon atoms thereof; and wherein further said alkylarylsulfonate surfactant system has at least one (preferably both) of the following properties: said alkylarylsulfonate surfactant system has a ratio of nonquaternary to quaternary carbon atoms in L of at least about 10:1 by weight, when said quaternary carbon atoms are present; and there is no more than 40% by weight loss as measured by Hardness Tolerance Test.

    摘要翻译： 一种表面活性剂组合物，其包含：烷基芳基磺酸盐表面活性剂体系，其包含下式的烷基芳基磺酸盐表面活性剂的至少两种异构体：其中：L是总共6至18个碳原子的无环脂族烃基; M是阳离子或阳离子混合物，q是其化合价; a和b是选择的数字，使得所述组合物是电中性的; R'选自H和C 1至C 3烷基; R“选自H和C 1至C 3烷基; R“选自H和C 1至C 3烷基; R'和R“中的任一个与L非极性连接，R'和R”中的至少一个是C 1至C 3烷基; 和A是芳基; 并且其中：所述烷基芳基磺酸盐表面活性剂体系包含关于R'，R“和A至L的连接位置的两个或多个异构体; 在所述组合物的至少约60％中，A在选自其两个末端碳原子的α-和β-位置的位置处连接到L; 并且其中所述烷基芳基磺酸盐表面活性剂体系具有至少一种（优选两种）以下性质：所述烷基芳基磺酸盐表面活性剂体系在L中的非季铵化合物与季碳原子的重量比为至少约10:1，当所述季碳原子 存在; 并且通过耐硬度测试测量不超过40重量％的损失。

    Alkylbenzenesulfonate surfactants
    23.
    发明授权
    Alkylbenzenesulfonate surfactants 失效
    烷基苯磺酸盐表面活性剂

    公开(公告)号：US06593285B1

    公开(公告)日：2003-07-15

    申请号：US09478908

    申请日：2000-01-07

    申请人： Jeffrey John Scheibel ,  Thomas Anthony Cripe ,  Kevin Lee Kott ,  Daniel Stedman Connor ,  Phillip Kyle Vinson

    发明人： Jeffrey John Scheibel ,  Thomas Anthony Cripe ,  Kevin Lee Kott ,  Daniel Stedman Connor ,  Phillip Kyle Vinson

    IPC分类号： C11D1750

    CPC分类号： C11D1/37 ,  C11D1/22

    摘要： A surfactant composition comprising: alkylarylsulfonate surfactant system comprising at least two isomers of the alkylarylsulfonate surfactant of the formula:  wherein: L is an acyclic aliphatic hydrocarbyl of from 6 to 18 carbon atoms in total; M is a cation or cation mixture and q is the valence thereof; a and b are numbers selected such that said alkylarylsulfonate surfactant is electroneutral; R′, R″ and R′″ are independently selected from H and C1 to C3 alkyl; both of R′ and R″ are nonterminally attached to L and at least one of R′ and R″ is C1 to C3 alkyl; and A is aryl;  wherein: said alkylarylsulfonate surfactant system comprises two or more isomers with respect to positions of attachment of R′, R″ and A to L; in at least about 40% of said composition, A is attached to L in the position which is selected from positions alpha- and beta- to either of the two terminal carbon atoms of L; and  wherein further said alkylarylsulfonate surfactant system has at least one of the following properties: said alkylarylsulfonate surfactant system has a ratio of nonquaternary to quaternary carbon atoms in L of at least about 5:1 by weight, when said quaternary carbon atoms are present; or percentage biodegradation, as measured by the modified SCAS test, that exceeds tetrapropylene benzene sulfonate.

    摘要翻译： 一种表面活性剂组合物，其包含：烷基芳基磺酸盐表面活性剂体系，其包含下式的烷基芳基磺酸盐表面活性剂的至少两种异构体：其中：L是总共6至18个碳原子的无环脂族烃基; M是阳离子或阳离子混合物，q是 a和b是选择的数字，使得所述烷基芳基磺酸盐表面活性剂是电中性的; R'，R“和R”'独立地选自H和C 1至C 3烷基; R'和R“都非永久地连接 至L，R'和R“中的至少一个为C 1至C 3烷基; A是芳基; 其中：所述烷基芳基磺酸盐表面活性剂体系包含两个或多个相对于R'，R“和A至L的连接位置的异构体;在至少约40％的所述组合物中，A在选定的位置附着于L 从位于L的两个末端碳原子的α-和β-位置; 并且其中所述烷基芳基磺酸盐表面活性剂体系具有以下性质中的至少一种：当存在所述季碳原子时，所述烷基芳基磺酸盐表面活性剂体系具有至少约5:1重量比的至少约5:1重量比的L中的非季铵碳原子与季碳原子的比例; 如通过改进的SCAS测试所测得的百分比生物降解超过四苯基苯磺酸盐。

    Dishwashing compositions containing alkylbenzenesulfonate surfactants
    24.
    发明授权
    Dishwashing compositions containing alkylbenzenesulfonate surfactants 失效
    含有烷基苯磺酸盐表面活性剂的洗碗组合物

    公开(公告)号：US06498134B1

    公开(公告)日：2002-12-24

    申请号：US09889634

    申请日：2001-07-19

    申请人： Jeffrey John Scheibel ,  Thomas Anthony Cripe ,  Kevin Lee Kott ,  Daniel Stedman Connor ,  Phillip Kyle Vinson ,  William Michael Scheper ,  Chandrika Kasturi

    发明人： Jeffrey John Scheibel ,  Thomas Anthony Cripe ,  Kevin Lee Kott ,  Daniel Stedman Connor ,  Phillip Kyle Vinson ,  William Michael Scheper ,  Chandrika Kasturi

    IPC分类号： C11D1700

    CPC分类号： C11D3/046 ,  C11D1/22 ,  C11D1/72 ,  C11D1/83

    摘要： A hand dishwashing composition comprising: i) from about 0.01% to about 99.99% by weight of composition of a surfactant mixture, said surfactant mixture comprising: an alkylarylsulfonate surfactant system comprising at least two alkylarylsulfonate surfactants of the formula (I) wherein L is an acyclic aliphatic hydrocarbyl of from 6 to 18 carbon atoms in total; M is a cation or cation mixture and q is the valence thereof; a and b are numbers selected such that said alkylarylsulfonate surfactant is electroneutral; R′ is selected from H and C1 to C3 alkyl; R″ is selected from H and C1 to C3 alkyl; R′″ is selected from H and C1 to C3 alkyl; both of R′ and R″ are nonterminally attached to L and at least one of R′and R″ is C1 to C3 alkyl; and A is aryl; wherein said alkylarylsulfonate surfactant system comprises two or more isomers with respect to positions of attachment of R′, R″ and A to L; in at least about 60% of said alkylarylsulfonate surfactant system, A is attached to L in the position which is selected from positions alpha- and beta- to either of the two terminal carbon atoms of L; and wherein further said alkylarylsulfonate surfactant system has at least one of the following properties: said alkylarylsulfonate surfactant system has a ratio of nonquaternary to quaternary carbon atoms in L of at least about 5:1 by weight, when said quaternary carbon atoms are present; or percentage biodegradation, as measured by the modified SCAS test, that exceeds tetra propylene benzene sulphonate; ii) from about 0.0001% to about 99.99% by weight of composition of a conventional hand dishwashing adjunct; and iii) from about 0.01% to about 7% by weight of composition of a divalent ion selected from the group consisting of magnesium, calcium and mixtures thereof.

    摘要翻译： 一种手洗餐具组合物，其包含：i）组合物的约0.01％至约99.99％的表面活性剂混合物，所述表面活性剂混合物包含：烷基芳基磺酸盐表面活性剂体系，其包含至少两种式（I）的烷基芳基磺酸盐表面活性剂，其中L为 总共6至18个碳原子的无环脂族烃基; M是阳离子或阳离子混合物，q是其化合价; a和b是选择的数字，使得所述烷基芳基磺酸盐表面活性剂是电中性的; R'选自H和C 1至C 3烷基; R“选自H和C 1至C 3烷基; R“'选自H和C 1至C 3烷基; R'和R“都与L非极性相连，R 1和R 2中的至少一个是C 1至C 3烷基; 和A是芳基; 其中所述烷基芳基磺酸盐表面活性剂体系包含关于R'，R“和A至L的连接位置的两个或多个异构体; 在所述烷基芳基磺酸盐表面活性剂体系的至少约60％中，A在选自L的两个末端碳原子的α-和β-位置的位置处连接到L; 并且其中所述烷基芳基磺酸盐表面活性剂体系具有以下特性中的至少一种：当所述季碳原子存在时，所述烷基芳基磺酸盐表面活性剂体系具有至少约5:1重量比的至少约5:1重量比的L中的非季铵碳原子与季碳原子的比率; 或通过改进的SCAS试验测量的生物降解百分比超过四丙烯苯磺酸盐; ii）约0.0001％至约99.99重量％的常规手洗餐具辅料的组成; 和iii）约0.01重量％至约7重量％的组合物，选自镁，钙及其混合物的二价离子。

    Alkylbenzenesulfonate surfactants
    25.
    发明授权
    Alkylbenzenesulfonate surfactants 失效
    烷基苯磺酸盐表面活性剂

    公开(公告)号：US06306817B1

    公开(公告)日：2001-10-23

    申请号：US09479365

    申请日：2000-01-07

    申请人： Kevin Lee Kott ,  Jeffrey John Scheibel ,  Thomas Anthony Cripe ,  Daniel Stedman Connor ,  Phillip Kyle Vinson

    发明人： Kevin Lee Kott ,  Jeffrey John Scheibel ,  Thomas Anthony Cripe ,  Daniel Stedman Connor ,  Phillip Kyle Vinson

    IPC分类号： C11D1700

    CPC分类号： C11D1/22

    摘要： A surfactant composition comprising: alkylarylsulfonate surfactant system comprising at least two isomers of the alkylarylsulfonate surfactant of the formula:  wherein: L is an acyclic aliphatic hydrocarbyl of from 6 to 18 carbon atoms in total; M is a cation or cation mixture and q is the valence thereof; and b are numbers selected such that said composition is electroneutral; R′ is selected from H and C1 to C3 alkyl; R″ is selected from H and C1 to C3 alkyl; R′″ is selected from H and C1 to C3 alkyl; any of R′ and R″ is nonterminally attached to L and at least one of R′ and R″ is C1 to C3 alkyl; and A is aryl; and wherein: said alkylarylsulfonate surfactant system comprises two or more isomers with respect to positions of attachment of R′, R″ and A to L; in at least about 60% of said composition, A is attached to L in the position which is selected from positions alpha- and beta- to either of the two terminal carbon atoms thereof; and wherein further said alkylarylsulfonate surfactant system has at least one (preferably both) of the following properties: said alkylarylsulfonate surfactant system has a ratio of nonquatemary to quaternary carbon atoms in L of at least about 10:1 by weight, when said quaternary carbon atoms are present; and there is no more than 40% by weight loss as measured by Hardness Tolerance Test.

    摘要翻译： 一种表面活性剂组合物，其包含：烷基芳基磺酸盐表面活性剂体系，其包含下式的烷基芳基磺酸盐表面活性剂的至少两种异构体：其中：L是总共6至18个碳原子的无环脂族烃基; M是阳离子或阳离子混合物，q是 b为选择为所述组成为电中性的数字; R'选自H和C 1至C 3烷基; R“选自H和C 1至C 3烷基; R”'选自H和C 1 至C3烷基; R'和R“中的任一个非离子地连接到L，R'和R”中的至少一个是C 1至C 3烷基; A是芳基; 并且其中：所述烷基芳基磺酸盐表面活性剂体系包含两个或多个相对于R'，R“和A至L的连接位置的异构体;在所述组合物的至少约60％中，A在所选择的位置附着于L 从位于其两个末端碳原子的α-和β-位置; 并且其中所述烷基芳基磺酸盐表面活性剂体系具有至少一种（优选两者）以下性质：所述烷基芳基磺酸盐表面活性剂体系具有至少约10:1重量比的至少约10:1重量比的非季铵碳原子比，当所述季碳原子为 当下; 并且通过耐硬度测试测量不超过40重量％的损失。