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21.发明申请COATED METAL OXIDE PARTICLES WITH LOW DISSOLUTION RATE, METHODS FOR PREPARING SAME AND USE THEREOF IN ELECTROCHEMICAL SYSTEMS 审中-公开具有低溶解速率的涂覆金属氧化物颗粒，其制备方法及其在电化学体系中的应用公开(公告)号：US20090017378A1
公开(公告)日：2009-01-15
申请号：US12162095
申请日：2007-01-24
申请人： Patrick Charest , Michel Perrier , Martin Dontigny , Michel Petitclerc , Abdelbast Guerfi , Karim Zaghib
发明人： Patrick Charest , Michel Perrier , Martin Dontigny , Michel Petitclerc , Abdelbast Guerfi , Karim Zaghib
CPC分类号： H01M4/621 , H01M4/131 , H01M4/136 , H01M4/139 , H01M4/366 , H01M4/485 , H01M4/5825 , H01M4/625 , H01M10/052 , H01M10/0565 , Y10T29/49108
摘要： Particles comprising a core and a coat covering at least part of the core surface. The core has more than 50% of an acidic metal oxide and the core coating is based on a polymer, preferably based on a soiled polymer with high electrochemical stability. The particle has a solubility rate (ts), in fixed time, of the metal oxide migrating towards the electrolyte, per cycle, which is less than 5 per 10000. The particles are obtained by mixing the polymer and a metal oxide, via dry process with addition of solvent. The electrodes constituting an electrode substrate at least partly coated with a mixture consisting of at least 40 of those particles have remarkable electrochemical properties, in particular regarding the lifetime of batteries in which they are incorporated.
摘要翻译： 颗粒包括芯和覆盖芯表面的至少一部分的涂层。 核心具有超过50％的酸性金属氧化物，核心涂层基于聚合物，优选基于具有高电化学稳定性的污染聚合物。 颗粒在固定时间内的溶解速率（ts）在金属氧化物向电解质迁移的循环中，每周期小于5。通过干法将该聚合物与金属氧化物混合得到颗粒 加入溶剂。 构成至少部分地涂覆有由这些颗粒中的至少40个的混合物组成的电极基底的电极具有显着的电化学特性，特别是关于它们掺入的电池的寿命。
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22.发明申请Electrode coated with a film obtained from an aqueous solution comprising a water-soluble binder, production method thereof and uses of same 有权用由包含水溶性粘合剂的水溶液获得的膜涂覆的电极，其制备方法和用途公开(公告)号：US20060166093A1
公开(公告)日：2006-07-27
申请号：US10534697
申请日：2003-11-13
申请人： Karim Zaghib , Michel Armand , Abdelbast Guerfi , Michel Perrier , Elisabeth Dupuis , Patrick Charest
发明人： Karim Zaghib , Michel Armand , Abdelbast Guerfi , Michel Perrier , Elisabeth Dupuis , Patrick Charest
CPC分类号： H01M4/0404 , H01G11/06 , H01G11/24 , H01G11/28 , H01G11/30 , H01G11/32 , H01G11/42 , H01G11/46 , H01G11/86 , H01M2/145 , H01M2/1653 , H01M4/04 , H01M4/0409 , H01M4/0471 , H01M4/133 , H01M4/136 , H01M4/139 , H01M4/1391 , H01M4/1393 , H01M4/1397 , H01M4/366 , H01M4/5825 , H01M4/587 , H01M4/621 , H01M4/622 , H01M4/623 , H01M4/625 , H01M4/66 , H01M4/661 , H01M10/0525 , H01M10/0565 , H01M10/0568 , H01M10/0569 , H01M2004/027 , H01M2004/028 , H01M2300/0028 , H01M2300/0037 , H01M2300/004 , H01M2300/0042 , H01M2300/0082 , Y02E60/122 , Y02E60/13 , Y02P70/54
摘要： The invention relates to a method of preparing an electrochemical electrode which is partially or totally covered with a film that is obtained by spreading an aqueous solution comprising a water-soluble binder over the electrode and subsequently drying same. The production cost of the electrodes thus obtained is reduced and the surface porosity thereof is associated with desirable resistance values.
摘要翻译： 本发明涉及一种制备电化学电极的方法，其部分或全部被膜覆盖，所述膜通过在电极上铺展包含水溶性粘合剂的水溶液并随后干燥而获得。 由此获得的电极的生产成本降低，并且其表面孔隙率与期望的电阻值相关联。
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公开(公告)号：US09972865B2
公开(公告)日：2018-05-15
申请号：US10543885
申请日：2004-01-29
IPC分类号： H01M10/00 , H01M10/0566 , H01M6/16 , H01M10/04 , H01M10/0567 , H01M10/42 , H01M2/16 , H01M4/134 , H01M10/052
CPC分类号： H01M10/0566 , H01M2/1653 , H01M4/134 , H01M6/168 , H01M10/0436 , H01M10/052 , H01M10/0567 , H01M10/4235 , H01M2300/0037 , H01M2300/0042 , H01M2300/0085 , Y02E60/122 , Y02P70/54
摘要： The invention relates to a metallic lithium rechargeable electrochemical accumulator, comprising at least one lithium metal electrode and at least one polymeric electrolyte gel. Said accumulator is capable of operating at temperatures from −20 to 60° C., essentially without formation of lithium dendrites on the whole surface of the metallic lithium electrode. The above is also wherein a particularly long life, even with intensive use at low temperature. Said inventive rechargeable accumulator can be produced by use of a production method with particular application of temperature control during the specific production stages. As a result of the extremely high electrochemical performance of said accumulator, in particular the remarkable stability thereof, said accumulator can be used in new application fields such as hybrid vehicles, electric vehicles and emergency supply systems such as those of the UPS type.
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公开(公告)号：US09240596B2
公开(公告)日：2016-01-19
申请号：US13003851
申请日：2009-07-24
CPC分类号： H01M4/625 , C01D15/02 , H01M4/0404 , H01M4/0471 , H01M4/1397 , H01M4/362 , H01M4/366 , H01M4/5825 , H01M4/623 , Y02E60/122 , Y10T428/292
摘要： The invention relates to a composite material comprising carbon fibers and complex oxide particles, wherein the carbon fibers and the complex oxide particles have a carbon coating on at least part of their surface, said carbon coating being a non powdery coating The material is prepared by a method comprising mixing a complex oxide or precursors thereof, an organic carbon precursor and carbon fibers, and subjecting the mixture to a heat treatment in an inert or reducing atmosphere for the decomposition of the precursors The material is useful as the cathode material in a battery.
摘要翻译： 本发明涉及包含碳纤维和复合氧化物颗粒的复合材料，其中碳纤维和复合氧化物颗粒在其表面的至少一部分上具有碳涂层，所述碳涂层是非粉末涂层。该材料由 方法包括混合复合氧化物或其前体，有机碳前体和碳纤维，以及使混合物在惰性或还原气氛中进行热处理以分解前体。该材料可用作电池中的阴极材料。
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25.发明授权Method for preparing ceramic powders in the presence of a carbon source, powders obtained and use thereof 有权在碳源存在下制备陶瓷粉末的方法，获得的粉末及其用途公开(公告)号：US08425976B2
公开(公告)日：2013-04-23
申请号：US12728991
申请日：2010-03-22
申请人： Karim Zaghib , Abdelbast Guerfi , Michel Armand , Patrick Charest
发明人： Karim Zaghib , Abdelbast Guerfi , Michel Armand , Patrick Charest
IPC分类号： B32B5/16
CPC分类号： C04B35/62821 , B82Y30/00 , C01G23/005 , C01G25/00 , C01P2004/51 , C01P2004/60 , C01P2004/64 , C04B35/462 , C04B35/505 , C04B35/62204 , C04B35/6265 , C04B35/628 , C04B35/62823 , C04B35/62839 , C04B35/63488 , C04B35/63496 , C04B2235/3203 , C04B2235/3225 , C04B2235/3232 , C04B2235/3234 , C04B2235/3237 , C04B2235/3244 , C04B2235/424 , C04B2235/48 , C04B2235/5409 , C04B2235/5436 , C04B2235/5445 , C04B2235/5454 , F02F3/0084 , H01M4/1391 , H01M4/485 , H01M4/9025 , H01M8/1246 , H01M10/052 , Y02E60/122 , Y02E60/525 , Y02P70/54 , Y02P70/56 , Y10T428/2982 , Y10T428/2991 , Y10T428/2993
摘要： A method for preparing ceramic powders in the presence of a carbon powder comprising a step of homogenizing a mixture of particles capable of resulting in a ceramic by heat treatment. Said method can be carried out in the presence of an accelerated solvent and provides, at reduced energy consumption, carbon-coated ceramic powders and then ceramics.
摘要翻译： 一种在碳粉存在下制备陶瓷粉末的方法，包括通过热处理使能够产生陶瓷的颗粒的混合物均匀化的步骤。 所述方法可以在加速溶剂的存在下进行，并且以降低的能量消耗提供碳涂覆的陶瓷粉末，然后提供陶瓷。
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26.发明授权Co-crushed mixture of an active material and of a conductive material, preparation methods and uses thereof 有权活性材料和导电材料的共粉碎混合物，其制备方法和用途公开(公告)号：US08333911B2
公开(公告)日：2012-12-18
申请号：US12162098
申请日：2007-01-25
CPC分类号： G11B5/714 , C09D5/00 , H01B1/24 , H01M4/36 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/587 , Y10T428/2982
摘要： A mixture of particles having a carrier based on at least one active material M1 of average size T1 and of specific surface S1 on which are bonded, via physical and/or chemical bonds, particles of at least an electronically conductive material M2 of average size T2 and of specific surface S2. The mixture is characterized in that: the average size ratio T1/T2 ranges between 5 and 10000; the specific surface ratio S1/S2 ranges between 1/300 and 1/2; and the amount of active material present in the mixture preferably represents more than 80% of the amount of the conductive material. The incorporation of said mixtures into elements constituting electrochemical systems substantially improves the performances of the latter.
摘要翻译： 具有平均尺寸为T1的至少一种活性物质M1和比表面积S1的载体的颗粒的混合物通过物理和/或化学键接合至少一种平均尺寸为T2的电子导电材料M2的颗粒 和比表面S2。 混合物的特征在于：平均尺寸比T1 / T2在5和10000之间; 比表面比S1 / S2在1/300和1/2之间; 并且混合物中存在的活性物质的量优选占导电材料量的80％以上。 将所述混合物并入构成电化学系统的元素中大大改善了后者的性能。
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公开(公告)号：US20110068294A1
公开(公告)日：2011-03-24
申请号：US12867414
申请日：2009-02-24
IPC分类号： H01M4/583
CPC分类号： H01M4/131 , H01B1/20 , H01M4/02 , H01M4/136 , H01M4/1393 , H01M4/1397 , H01M4/366 , H01M4/485 , H01M4/5825 , H01M4/623 , H01M4/625 , H01M10/052 , H01M2004/021 , H01M2004/028
摘要： The invention relates to a composite electrode material consisting of a carbon coated complex oxide, fibrous carbon and a binder. Said material is prepared by a method which comprises co-grinding an active electrode material and fibrous carbon, and adding a binder to the co-grinded mixture to lower the viscosity of the mixture. The fibrous carbon is preferably vapor grown carbon fibers.
摘要翻译： 本发明涉及由碳涂复合氧化物，纤维状碳和粘结剂组成的复合电极材料。 所述材料通过包括共同研磨活性电极材料和纤维状碳的方法以及向共磨碎的混合物中加入粘合剂以降低混合物的粘度的方法制备。 纤维状碳优选为气相生长碳纤维。
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28.发明申请公开(公告)号：US20100047692A1
公开(公告)日：2010-02-25
申请号：US12533817
申请日：2009-07-31
摘要： Mixture of particles comprising a non-conducting or semi-conducting nucleus covered with a hybrid conductor coating and hybrid conductor chains located between the particles of the mixture to constitute a conductivity network, that is prepared by mechanical crushing. Due to a very good conductivity of the network, a low resistivity, a very good capacity under elevated current and/or a good density of energy, these mixtures of particles are advantageously incorporated in anodes and cathodes of electrochemical generators, resulting in highly performing electrochemical systems.
摘要翻译： 包含非导电或半导体核的混合物，其覆盖有混合导体涂层和位于混合物颗粒之间的混合导体链，以构成通过机械破碎制备的导电网络。 由于网络的非常好的导电性，低电阻率，在升高的电流和/或良好的能量密度下具有非常好的容量，这些颗粒混合物有利地结合到电化学发生器的阳极和阴极中，导致高度电化学 系统。
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29.发明申请CO-CRUSHED MIXTURE OF AN ACTIVE MATERIAL AND OF A CONDUCTIVE MATERIAL, PREPARATION METHODS AND USES THEREOF 有权活性材料和导电材料的混合混合物，其制备方法及其用途公开(公告)号：US20090087709A1
公开(公告)日：2009-04-02
申请号：US12162098
申请日：2007-01-25
CPC分类号： G11B5/714 , C09D5/00 , H01B1/24 , H01M4/36 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/587 , Y10T428/2982
摘要： A mixture of particles having a carrier based on at least one active material M1 of average size T1 and of specific surface S1 on which are bonded, via physical and/or chemical bonds, particles of at least an electronically conductive material M2 of average size T2 and of specific surface S2. The mixture is characterized in that: the average size ratio T1/T2 ranges between 5 and 10000; the specific surface ratio S1/S2 ranges between 1/300 and 1/2; and the amount of active material present in the mixture preferably represents more than 80% of the amount of the conductive material. The incorporation of said mixtures into elements constituting electrochemical systems substantially improves the performances of the latter.
摘要翻译： 具有平均尺寸为T1的至少一种活性物质M1和比表面积S1的载体的颗粒的混合物通过物理和/或化学键接合至少一种平均尺寸为T2的电子导电材料M2的颗粒 和比表面S2。 混合物的特征在于：平均尺寸比T1 / T2在5和10000之间; 比表面比S1 / S2在1/300和1/2之间; 并且混合物中存在的活性物质的量优选占导电材料量的80％以上。 将所述混合物并入构成电化学系统的元素中大大改善了后者的性能。
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公开(公告)号：US20070111105A1
公开(公告)日：2007-05-17
申请号：US10543885
申请日：2004-01-29
IPC分类号： H01M6/18
CPC分类号： H01M10/0566 , H01M2/1653 , H01M4/134 , H01M6/168 , H01M10/0436 , H01M10/052 , H01M10/0567 , H01M10/4235 , H01M2300/0037 , H01M2300/0042 , H01M2300/0085 , Y02E60/122 , Y02P70/54
摘要： The invention relates to a metallic lithium rechargeable electrochemical accumulator, comprising at least one lithium metal electrode and at least one polymeric electrolyte gel. Said accumulator is capable of operating at temperatures from −20 to 60° C., essentially without formation of lithium dendrites on the whole surface of the metallic lithium electrode. The above is also wherein a particularly long life, even with intensive use at low temperature. Said inventive rechargeable accumulator can be produced by use of a production method with particular application of temperature control during the specific production stages. As a result of the extremely high electrochemical performance of said accumulator, in particular the remarkable stability thereof, said accumulator can be used in new application fields such as hybrid vehicles, electric vehicles and emergency supply systems such as those of the UPS type.
摘要翻译： 本发明涉及一种金属锂可再充电电化学蓄电池，其包含至少一种锂金属电极和至少一种聚合物电解质凝胶。 所述蓄能器能够在-20至60℃的温度下操作，基本上在金属锂电极的整个表面上不形成锂枝晶。 上述还具有特别长的使用寿命，即使在低温下也是密集使用的。 所述本发明的可再充电蓄电池可以通过使用在特定生产阶段中特别应用温度控制的生产方法来生产。 由于所述蓄电池的电化学性能极高，特别是其显着的稳定性，所述蓄电池可用于诸如混合动力车辆，电动车辆和UPS型应急供电系统等新的应用领域。
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