摘要:
A dielectric ceramic composition comprised of at least dielectric particles having barium titanate as its main ingredient, wherein the ratio of dielectric particles having a surface diffusion structure comprised of a main ingredient phase comprised of the main ingredient and a diffusion phase present around the main ingredient phase with respect to said dielectric particles is 60% or more and the ratio of dielectric particles having a domain in the main ingredient phase with respect to the dielectric particles having the surface diffusion structure is 20% or less. According to the present invention, a dielectric ceramic composition and electronic device realizing good high temperature accelerated life can be provided.
摘要:
A dielectric ceramic composition comprising a predetermined main component and a fifth subcomponent including an oxide of A (note that A is at least one king selected from a cation element group having an effective ionic radius of 0.065 nm to 0.085 nm at the time of 6 coordination); and the dielectric ceramic composition comprises a plurality of crystal grains including Ca elements and, when assuming that an average value of a concentration of entire Ca exiting in said respective crystal grains is grain Ca concentration, at least unevenness exists in said grain Ca concentration between said crystal grains and it is 5% or higher in a CV value.
摘要:
A dielectric ceramic composition, comprising a main component including barium titanate; a first subcomponent including at least one kind selected from MgO, CaO, BaO and SrO; a second subcomponent functioning as a sintering auxiliary agent; a third subcomponent including at least one kind selected from V2O5, MoO3 and WO3; a fourth subcomponent including an oxide of R1 (note that R1 is at least one kind selected from Sc, Er, Tm Yb and Lu); a fifth subcomponent including CaZrO3 or CaO+ZrO2; and an eighth subcomponent including an oxide of A (note that A is at least one kind selected from a cation element group having an effective ionic radius at the time of 6 coordination of 0.065 nm to 0.085 nm); wherein a ratio of the eighth subcomponent with respect to 100 moles of the main component is 0 to 4 moles (note that 0 mole and 4 moles are excluded, and the value is in terms of an A oxide).
摘要:
A multilayer ceramic capacitor comprising a capacitor element body: wherein dielectric layers composed of a dielectric ceramic composition and internal electrode layers are alternately stacked; the dielectric ceramic composition comprises a plurality of dielectric particles each having a shell, wherein subcomponents are dispersed in a main component, formed around a core substantially composed of the main component; and a difference of the maximum thickness and the minimum thickness of the shell in the dielectric particles having an average particle diameter is controlled to be 6 to 60% of a radius of the dielectric particles; wherein a high permittivity and preferable temperature characteristic are obtained and TC bias characteristics are improved, is provided.
摘要:
A ceramic electronic device including a dielectric layer, wherein the dielectric layer includes a main component expressed by a composition formula of Bam TiO2+m, wherein “m” satisfies 0.995≦m≦1.010 and a ratio of Ba and Ti satisfies 0.995≦Ba/Ti≦1.010, and a subcomponent (a sixth subcomponent) including an oxide of Al; and a content of the Al compound is 0 to 4.0 moles (note that 0 is not included) in terms of Al2O3 with respect to 100 moles of the main component; and preferably, the dielectric layer includes a segregation phase, and the segregation phase includes an oxide of Al.
摘要翻译:1.一种陶瓷电子器件,其特征在于,所述电介质层包括由组成式为Bam TiO 2 + m表示的主成分,其中,“m”满足0.995≤m≤1.010,Ba与Ti的比例满足0.995 < = Ba / Ti <= 1.010,以及包含Al的氧化物的副成分(第六副成分) Al化合物的含量相对于100摩尔主成分为0〜4.0摩尔(注意,不包括0)。 并且优选地,电介质层包括偏析相,并且偏析相包括Al的氧化物。
摘要:
A ceramic electronic device having a dielectric layer, wherein the dielectric layer includes a main component containing a (Ba, Ca (Ti, Zr)O3 based material and a subcomponent containing an oxide of Si; and a content of the Si oxide is 0 to 0.4 wt % (note that 0 is not included) with respect to the entire dielectric layer; and preferably the dielectric layer has a segregation phase; and the segregation phase contains an oxide of Si and substantially not containing an oxide of Li; by which it is possible to provide a ceramic electronic device, such as a multilayer ceramic capacitor, having a low IR defect rate (initial insulation resistance defect rate), excellent high temperature load lifetime and high reliability.
摘要:
To provide a multilayer ceramic capacitor which has capacitance-temperature characteristics satisfying the X8R characteristic specified by the EIA standard and has capacitance with an excellent long-term stability.The object is achieved by a multilayer ceramic capacitor comprising a laminate including alternately stacked dielectric layers of a sintered compact composed of crystal particles of a dielectric porcelain composite and internal-electrode layers. The dielectric porcelain composite comprises a primary constituent containing barium titanate; a first accessory constituent composed of at least one of MgO, CaO, BaO, and SrO; a second accessory constituent containing silicon oxide as a major constituent; a third accessory constituent composed of at least one of V2O5, MoO3, and WO3; a fourth accessory constituent composed of an oxide of R1 (wherein R1 is at least one of Sc, Er, Tm, Yb, and Lu); a fifth accessory constituent composed of CaZrO3 or a combination of CaO and ZrO2; and a sixth accessory constituent composed of an oxide of R2 (wherein R2 is at least one of Y, Dy, Ho, Tb, Gd, and Eu). In the case of 100 moles of barium titanate, there are 0.1 to 3 moles of the first accessory constituent, 2 to 10 moles of the second accessory constituent, 0.01 to 0.5 moles of the third accessory constituent, 0.5 to 7 moles of the fourth accessory constituent (wherein the number of moles of the fourth accessory constituent is that of R1 alone), more than 0 but not more than 5 moles of the fifth accessory constituent, and more than 0 but not more than 9 moles of the sixth accessory constituent. The crystal particles constituting the dielectric layers have an average particle diameter of not less than 0.2 μm and less than or equal to 0.55 μm.
摘要:
A highly reliable ceramic electronic device having an excellent temperature characteristic of a capacitance and a low IR temperature dependency, comprising a dielectric layer: wherein the dielectric layer includes a main component expressed by a composition formula of BamTiO2+m, wherein “m” satisfies 0.995≦m≦1.010 and a ratio of Ba and Ti satisfies 0.995≦Ba/Ti≦1.010, and, as subcomponents, an oxide of Al and an oxide of Si or an oxide of R (note that R is at least one kind selected from Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu); and includes a secondary phase composed of at least a part of the oxide of Al and at least a part of the oxide of Si or the oxide of R and being different from a main phase mainly composed of the main component; and the production method are provided.
摘要翻译:一种具有优异的电容温度特性和低IR温度依赖性的高度可靠的陶瓷电子器件,包括电介质层:其中所述电介质层包括由组成式Ba≠TiO 2表示的主要成分 其中“m”满足0.995 <= m <= 1.010,Ba和Ti的比例满足0.995 <= Ba / Ti <= 1.010,作为次要成分的Al的氧化物 和Si的氧化物或R的氧化物(注意,R为选自Sc,Y,La,Ce,Pr,Nd,Pm,Sm,Eu,Gd,Tb,Dy,Ho,Er,Tm中的至少一种 ,Yb和Lu); 并且包括由Al的氧化物的至少一部分和Si的氧化物的至少一部分或R的氧化物组成的第二相,并且与主要由主要成分构成的主相不同; 并提供制造方法。
摘要:
An electronic device having an element body, wherein dielectric layers and internal electrode layers are alternately stacked, wherein a hetero phase is formed in the dielectric layers and/or the internal electrode layers; and the hetero phase includes a Mg element and a Mn element. Preferably, the hetero phase is formed at least at a part near boundaries of the dielectric layers and the internal electrode layers.
摘要:
A dielectric ceramic composition comprising a main component including barium titanate and an oxide of Al, wherein the dielectric ceramic composition includes a plurality of dielectric particles, concentration of Al in each of the dielectric particles becomes lower from a particle surface to inside thereof, and each of the dielectric particles has an Al non-dispersed region substantially not including Al at least at a center portion of the particle.