摘要:
A polarizing electrode for an electric double layer capacitor has good moldability and is capable of achieving higher density of electrode and higher capacity. An electric double layer capacitor employs the same. The polarizing electrode for an electric double layer capacitor is made of an activated carbon obtained by activating a hard-to-graphitize material (for example, phenol resin) with water vapor, and the activated carbon has a median particle size within a range from 4 μm to 8 μm in the particle size distribution as measured by a laser diffraction method and a benzene adsorption ratio of not less than 47.0% and not more than 60% by weight of activated carbon.
摘要:
A polarizable electrode for an electric double layer capacitor includes an activated carbon powder, and a binder material mixed with the activated carbon. The amount of water contained in the polarizable electrode is 1500 ppm or less with respect to the weight of the polarizable electrode.
摘要:
A metal collector foil for an electric double layer capacitor is an etched metal collector foil having an oxide film in an amount of not greater than 300 mg/m2, and a capacitance per unit surface area of not less than 150 μF/cm2. The etched metal collector foil is free from a dielectric layer formed by an anodic formation process on a surface of the etched metal collector foil. A method of producing the metal collector foil and an electric double layer capacitor incorporating therein the metal collector foil are also disclosed.
摘要翻译:用于双电层电容器的金属集电体箔是具有不大于300mg / m 2的氧化膜的蚀刻金属集电箔,每单位表面积的电容不小于150μF/ cm <2>。 蚀刻后的金属集电箔不含有在蚀刻后的金属集电箔的表面上由阳极形成工艺形成的电介质层。 还公开了一种制造金属集电箔的方法和其中包含金属集电箔的双电层电容器。
摘要:
An electrode sheet for an electric double-layer capacitor is provided. The electrode sheet is molded from granules which are produced from ingredients including an electrochemically active material, an electrically conductive filler and a binder. A contact angle is equal to or less than 100 degrees when the contact angle is defined as (180-ALPHA) degrees, where ALPHA represents an apex angle of a droplet of an electrolytic solution for the electric double-layer capacitor, and when the droplet lies on the electrode sheet.
摘要:
A method is provided for optimizing the physical characteristics of a coating solution for a polarizable electrode layer formed on a collector. A first step is carried out to prepare a coating solution that includes porous particles, a fluorine-based binder, a good solvent that dissolves said fluorine-based binder, and a poor solvent that does not dissolve said fluorine-based binder. A second step is carried out to coat a collector with said coating solution to form the polarizable electrode layer on the collector. The viscosity of said coating solution for the polarizable electrode layer is set to between 0.5 to 3.5 Pa·s and a weight ratio (GS/PS) of said good solvent (GS) and said poor solvent (PS) is set to between 60/40 to 80/20. The occurrence of cracks in the polarizable electrode layer and large nonuniformities in the thickness of the polarizable electrode layer can thus be prevented.
摘要:
A method is provided for optimizing the physical characteristics of a coating solution for an undercoat layer formed between a polarizable electrode layer and surface-roughened collector. A first step is carried out to form an undercoat layer on a collector whose surface has been roughened, and a second step is carried out to form a polarizable electrode layer on the undercoat layer. The first step is performed by coating the collector with a coating solution for the undercoat layer that includes electroconductive particles, a binder, and a solvent; the viscosity of the coating solution for the undercoat layer is set to from 0.15 to 0.75 Pa·s, and the weight ratio (P/B) of the electroconductive particles (P) and binder (B) is set to from 20/80 to 40/60. The coating area of the undercoat layer can thereby be adjusted with high precision, and the resistance of the undercoat layer can be reduced.
摘要:
By using the polarized electrode for electric double layer capacitor of the present invention, which is produced by mixing powdery activated carbon with a binder, and is characterized by the concentration of an organic compound being not more than 300 (ppm), the amount of organic compounds which remain in the pore of the powdery activated carbon decrease, and a possibility of forming the electric double layer by adsorption of electrolytic ion can be prevented. Thereby, an electric double layer is sufficiently formed inside the pore of the powdery activated carbon, and the diffusion resistance between the powdery activated carbon and the electrolyte becomes low. By constituting as such, an electric double layer capacitor with a large electrostatic capacity and a little internal resistance can be obtained.
摘要:
The present invention provides a three-piece rectangular can which can overcome drawbacks (joint defect) of a can body joint portion of a three-piece can, and is of a new type which overcomes shortage of a can body strength which a two-piece can possesses, and exhibits excellent liquid leakage resistance, excellent can body strength and excellent heat radiation property or the like even when the can is used as a casing of a battery or electric equipment. For this end, the three-piece rectangular can of the present invention is formed such that a circular blank formed of an aluminum plate which forms an organic film on at least one surface thereof is formed into a bottomed circular can by deep drawing such that the organic film forms an inner side of the can, a cylindrical sleeve having no seam on a side surface thereof is formed by cutting a can bottom of the bottomed circular can, a rectangular can body portion having no seam on a side surface thereof is formed by deforming the cylindrical sleeve into a rectangular shape, a necking formed portion is formed by applying necking forming to opening portions at both ends of the rectangular can body, and a top lid and a bottom lid are mounted on the opening portions at both ends of the rectangular can body by double seaming by way of an organic compound.
摘要:
A method is provided for enhancing the bond between the polarizable electrode layer and the undercoat layer. The method includes a first step for forming an undercoat layer on a collector and a second step for forming a polarizable electrode layer on said undercoat layer. The first step is performed by coating said collector with a coating solution for the undercoat layer that includes electroconductive particles, a first binder, and a first solvent. The second step is performed by coating said undercoat layer with a coating solution for the polarizable electrode layer that includes porous particles, a second binder, and a second solvent. The first solvent can dissolve or disperse said first and second binders. The second solvent can dissolve or disperse said first and second binders. The fusion of the interface between the undercoat layer and the polarizable electrode layer enhances the bond therebetween.
摘要:
A storage battery which can further intensify the sealing properties of the electrode rod piercing portion thereof, a technique capable of increasing the area of the sealing surface at the sealed portion of the storage battery, a technique capable of certainly preventing the missing of mounting of a rubber-based sealing material corresponding to O-ring at the sealed portion of the storage battery, and an insulating material having an excellent corrosion resistance to highly corrosive battery content and a battery container including same are provided.An electrode rod 14 is allowed to extend upward through an annular member 15, a pressing member 18 is placed on the annular member 15, and a nut 22 is then threaded on a thread portion 21. This threading job is effected until the pressing member 18 is placed on and stopped by a collar portion 23. At the time when threading ends, a neck portion 25 is somewhat compressed to exhibit sealing properties. At the same time, a head portion 26 is drastically compressed and thus forms a first sealing portion at Point P1, a second sealing portion at Point P2 and a third sealing portion at Point P3. Further, while a disc sealing member 23 being properly compressed by the annular member 15 made of a resin and a current collecting plate 17, they are put in a vacuum heating furnace where they are then subjected to heat treatment at 160° C. in vacuo for 72 hours. This heat treatment allows PET film 25 to be heat-fused to the annular member 15 made of a resin and PET film 26 to be heat-fused to the current collecting plate 17. Moreover, a lid body 12 is formed integrally with an annular member 15 of rubber having a spindle-shaped section. And, this annular member 15 of rubber is bonded to PET film 32, 32 by the action of adhesive layer 33, 33. Since this bonding is firm, the annular member 15 of rubber cannot be detached from the lid body 12 during use.Further, an insulating material for electrode mounting to be used in a battery container which is made of a polyethylene terephthalate resin and a container having a lid member obtained by forming a polyester resin-coated aluminum sheet double-seamed attached to the opening of the body of a can are provided, and a polyethylene terephthalate resin insulating material for electrode mounting is attached to a through-hole provided piercing the central part of the lid member with an adhesive including (B) a hardener made of at least one of phenolic resin, amino resin and polyisocyanate resin incorporated in (A) a polyester resin including a dicarboxylic acid component mainly including terephthalic acid and a glycol component and having a glass transition temperature of from 30° C. to 110° C., whereby the battery content has an excellent corrosion resistance to the electrolyte including a highly corrosive propylene carbonate salt as a main component, etc. and an enhanced leakage resistance.