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    Production process of cyclohexenyl ketones
    21.
    发明授权
    Production process of cyclohexenyl ketones 失效
    环己烯酮的生产工艺

    公开(公告)号：US06822121B2

    公开(公告)日：2004-11-23

    申请号：US09875158

    申请日：2001-06-07

    申请人： Shinya Watanabe ,  Hideo Ujihara ,  Takeshi Yamamoto ,  Toshimitsu Hagiwara

    发明人： Shinya Watanabe ,  Hideo Ujihara ,  Takeshi Yamamoto ,  Toshimitsu Hagiwara

    IPC分类号： C07C4567

    CPC分类号： C07C403/16 ,  C07C45/67 ,  C07C45/69 ,  C07C2601/16 ,  C07C49/543

    摘要： An economical process for producing (2- and/or 1-)cyclohexenyl methyl ketones which are intermediates for the synthesis of &agr;- or &bgr;-damascone. In the presence of a catalyst, a 3-cyclohexenyl methyl ketone represented by the following formula (1a): wherein, R1, R2 and R3 each independently represents a hydrogen atom or a methyl group and at least two of R1, R2 and R3 are methyl groups, is isomerized.

    摘要翻译： 用于生产（2-和/或1-）环己烯基甲基酮的经济方法，其是用于合成α-大脑皮质或大黄酮的中间体。 在催化剂存在下，由下式（1a）表示的3-环己烯基甲基酮：其中，R 1，R 2和R 3各自独立地表示氢原子或甲基，R 1，R 2和R 3中的至少两个为 甲基，异构化。

    Aromatic bleaching agent composition
    23.
    发明授权
    Aromatic bleaching agent composition 失效
    芳香族漂白剂组合物

    公开(公告)号：US06645254B1

    公开(公告)日：2003-11-11

    申请号：US09816347

    申请日：2001-03-26

    申请人： Takashi Aida ,  Hiroyuki Matsuda ,  Tsunehide Yoneyama ,  Toshimitsu Hagiwara

    发明人： Takashi Aida ,  Hiroyuki Matsuda ,  Tsunehide Yoneyama ,  Toshimitsu Hagiwara

    IPC分类号： D06L300

    CPC分类号： C11D3/50 ,  C11D3/2072 ,  C11D3/3905 ,  C11D3/3947 ,  C11D3/3956

    摘要： One or more 1-substituted-2,2,4-trimethylpentane-3-one derivatives represented by the following general formula (1): wherein X represents a benzene ring or a cyclohexane ring; and R represents an arbitrary hydrogen atom on the benzene ring or cyclohexane ring or a methyl group which substitutes the hydrogen atom are incorporated in a bleaching agent composition containing a chlorine-based bleaching agent component such as sodium hypochlorite or oxygen-based bleaching agent component such as sodium perborate.

    摘要翻译： 一种或多种由以下通式（1）表示的1-取代-2,2,4-三甲基戊烷-3-酮衍生物：其中X表示苯环或环己烷环; R表示苯环或环己烷环上的任意的氢原子或取代氢原子的甲基，可以含有氯代漂白剂成分如次氯酸钠或氧基漂白剂成分的漂白剂组合物， 作为过硼酸钠。

    Process for producing optically active 3,7-dimethyl-6-octenol and process for producing intermediate therefor
    24.
    发明授权
    Process for producing optically active 3,7-dimethyl-6-octenol and process for producing intermediate therefor 失效
    光学活性3,7-二甲基-6-辛烯醇的制备方法及其制备方法

    公开(公告)号：US06489522B2

    公开(公告)日：2002-12-03

    申请号：US09827334

    申请日：2001-04-06

    申请人： Shinya Yamada ,  Yoshiki Okeda ,  Yoji Hori ,  Toshimitsu Hagiwara

    发明人： Shinya Yamada ,  Yoshiki Okeda ,  Yoji Hori ,  Toshimitsu Hagiwara

    IPC分类号： C07C3500

    CPC分类号： C07C209/68 ,  C07B2200/07 ,  C07C29/141 ,  C07C33/025 ,  C07C45/42 ,  C07C47/21 ,  C07C211/21

    摘要： Provided is citronellol, which has an elegant rosy fragrance and is extremely useful for fragrance impartation to aromatic articles. A mixture of an alkylamine and isoprene in a molar ratio of from 1:4 to 1:4.5 is subjected to telomerization at 80 to 100° C. for 2.5 to 3.5 hours in the presence of an alkyllithium catalyst and/or phenyllithium catalyst to obtain a nerylamine compound containing 2 to 10 wt % &agr;-nerylamine compound represented by general formula (4). From this nerylamine compound, citronellol containing 2 to 10 wt % optically active 3,7-dimethyl-7-octenol is produced through the reaction steps of asymmetric isomerization, hydrolysis, and hydrogenation.

    摘要翻译： 提供香茅醇，其具有优雅的玫瑰香，并且对芳香物品的芳香赋予非常有用。 摩尔比为1:4〜1:4.5的烷基胺和异戊二烯的混合物在烷基锂催化剂和/或苯基锂催化剂存在下，在80〜100℃下进行2.5〜3.5小时的调聚，得到 含有通式（4）表示的2-10重量％α-椰子胺化合物的橙花胺化合物。由该橙花胺化合物，通过反应步骤产生含有2至10重量％光学活性的3,7-二甲基-7-辛烯醇的香茅醇 的不对称异构化，水解和氢化。

    Process for producing 3-1-menthoxypropane-1,2-diol
    25.
    发明授权
    Process for producing 3-1-menthoxypropane-1,2-diol 有权
    制备3-1-薄荷氧基丙-1,2-二醇的方法

    公开(公告)号：US06407293B1

    公开(公告)日：2002-06-18

    申请号：US09962122

    申请日：2001-09-26

    申请人： Akira Amano ,  Teruyoshi Akiyama ,  Takashi Miura ,  Toshimitsu Hagiwara

    发明人： Akira Amano ,  Teruyoshi Akiyama ,  Takashi Miura ,  Toshimitsu Hagiwara

    IPC分类号： C07C3512

    CPC分类号： C07C43/196 ,  C07C41/03

    摘要： A process for producing highly pure 3-1-menthoxypropane-1,2-diol safely and efficiently, and an intermediate to be used in the process. 3-1-menthoxypropane-1,2-diol represented by the chemical formula (IV) is produced by adding 1-menthol to a 1,2-epoxy-3-halogenopropane represented by the following general formula (I) (wherein X represents a halogen atom) in an organic solvent in the presence of a Lewis acid to produce a novel 1-halogeno-3-1-menthoxypropan-2-ol represented by the following general formula (II), then, epoxidating it with a base in the presence of a phase transfer catalyst to produce a 1,2-epoxy-3-1-menthoxypropane represented by the chemical formula (III), and further hydrolyzing it.

    摘要翻译： 安全有效地生产高纯度3-1-薄荷氧基丙二醇-1,2-二醇的方法，以及该方法中使用的中间体。 由化学式（IV）表示的3-1-薄荷氧基丙烷-1,2-二醇通过将1-薄荷醇加入到由下列通式（I）表示的1,2-环氧-3-氯代丙烷中（其中X表示 卤素原子）在有机溶剂中在路易斯酸存在下反应，得到由以下通式（II）表示的新型1-卤代-3-三氟甲氧基丙-2-醇，然后用碱进行环氧化 存在相转移催化剂以制备由化学式（III）表示的1,2-环氧-3-丁氧基丙烷，并进一步水解。

    Ruthenium-optically active phosphine complex, process for the preparation thereof and process for the preparation of optically active 4-methyl-2-oxetanone using same
    26.
    发明授权
    Ruthenium-optically active phosphine complex, process for the preparation thereof and process for the preparation of optically active 4-methyl-2-oxetanone using same 失效
    钌光学活性膦络合物，其制备方法和使用其制备光学活性4-甲基-2-氧杂环丁酮的方法

    公开(公告)号：US5981782A

    公开(公告)日：1999-11-09

    申请号：US963619

    申请日：1997-11-04

    申请人： Yoshiki Okeda ,  Yoji Hori ,  Toshimitsu Hagiwara

    发明人： Yoshiki Okeda ,  Yoji Hori ,  Toshimitsu Hagiwara

    IPC分类号： C07D305/12 ,  B01J31/24 ,  C07B53/00 ,  C07B61/00 ,  C07D315/00 ,  C07F15/00

    CPC分类号： B01J31/2452 ,  C07D315/00 ,  C07F15/0053 ,  B01J2231/645 ,  B01J2531/0266 ,  B01J2531/821 ,  B01J31/2208 ,  B01J31/2295 ,  C07B2200/07

    摘要： The present invention provides a catalyst which exhibits a high catalytic activity and allows asymmetric reaction in a high asymmetric yield to obtain a reaction product having a high optical purity. The present invention also provides a process for the preparation of an optically active 4-methyl-2-oxetanone having a high optical purity useful as starting material of polymer in a high yield in a short period in the presence of the foregoing catalyst. A novel ruthenium-iodo-optically active phosphine complex is provided, represented by the following general formula (1):Ru--I.sub.2 --(R.sup.1 -BINAP) (1)wherein R.sup.1 -BINAP represents an optically active tertiary phosphine represented by the following general formula (2): ##STR1## wherein R.sup.1 represents an aryl group which may have a substituent selected from the group consisting of a C.sub.1-4 lower alkyl group, a C.sub.1-4 lower alkoxy group, a C.sub.1-4 lower alkylamino group, and a halogen atom or a C.sub.3-8 cycloalkyl group.

    摘要翻译： 本发明提供一种催化活性高的催化剂，能够以不对称产率进行不对称反应，得到光学纯度高的反应产物。 本发明还提供了在上述催化剂存在下，在短时间内以高收率制备具有高光学纯度的光学纯度高的光学活性4-甲基-2-氧杂环丁酮的方法。 提供了由以下通式（1）表示的新型钌 - 碘 - 光学活性膦配合物：Ru-I2-（R1-BINAP）（1）其中R1-BINAP表示由以下通式表示的光学活性叔膦 式（2）：其中R1表示可以具有选自C 1-4低级烷基，C 1-4低级烷氧基，C 1-4低级烷基氨基和卤素原子的取代基的芳基 或C 3-8环烷基。

    Optically active block polyester copolymer and method for production thereof
    27.
    发明授权
    Optically active block polyester copolymer and method for production thereof 失效
    光学活性嵌段聚酯共聚物及其制备方法

    公开(公告)号：US5840811A

    公开(公告)日：1998-11-24

    申请号：US786253

    申请日：1997-01-22

    申请人： Yoji Hori ,  Tohru Kobayashi ,  Hideyuki Hongo ,  Akio Yamaguchi ,  Yoko Takahashi ,  Takashi Imai ,  Toshimitsu Hagiwara

    发明人： Yoji Hori ,  Tohru Kobayashi ,  Hideyuki Hongo ,  Akio Yamaguchi ,  Yoko Takahashi ,  Takashi Imai ,  Toshimitsu Hagiwara

    IPC分类号： C08G63/06 ,  C08G63/08 ,  C08G63/82 ,  C08L101/16 ,  C08G63/85

    CPC分类号： C08G63/823 ,  C08G63/08

    摘要： An optically active block polyester copolymer formed of structural units represented by the following general formulas (I) and (II): ##STR1## wherein represents for an asymmetric carbon atom and m and n each represents a natural number in the range of from 300 to 5000 is obtained by subjecting an optically active butyrolactone and a species of lactone other than the optically active butyrolactone to sequential ringopening copolymerization in the presence of a catalyst. This optically active block polyester copolymer possesses a high molecular weight and a high melting point (not less than 130.degree. C.) and forms a biodegradable and hydrolyzable material of high strength capable of tolerating the impacts of actual use.

    摘要翻译： 由以下通式（I）和（II）表示的结构单元形成的光学活性嵌段聚酯共聚物：式（I）公制碳原子，m和n各自表示300-5000的自然数 是通过使光学活性丁内酯和除光学活性丁内酯以外的其他种类的内酯在催化剂存在下进行顺序环环化共聚获得的。 该光学活性嵌段聚酯共聚物具有高分子量和高熔点（不低于130℃），并形成能够耐受实际影响的高强度的可生物降解和可水解的材料。

    Biodegradable high molecular composition
    28.
    发明授权
    Biodegradable high molecular composition 失效
    可生物降解的高分子组成

    公开(公告)号：US5824751A

    公开(公告)日：1998-10-20

    申请号：US592518

    申请日：1996-01-26

    申请人： Yoji Hori ,  Yoko Takahashi ,  Hideyuki Hongo ,  Akio Yamaguchi ,  Toshimitsu Hagiwara

    发明人： Yoji Hori ,  Yoko Takahashi ,  Hideyuki Hongo ,  Akio Yamaguchi ,  Toshimitsu Hagiwara

    IPC分类号： C08G63/06 ,  C08G63/08 ,  C08G63/64

    CPC分类号： C08G63/08 ,  C08G63/06 ,  C08G63/64

    摘要： The biodegradable composition comprises at least poly(beta-hydroxybutyric acid) or a biodegradable copolymer thereof and a stereospecifically regular block copolymer having the structure units of formula (I): ##STR1## where R1 is a hydrocarbon group having 1 to 14 carbon atoms, optionally including double bonds, oxygen atoms or both of them; and m and n are respectively an integer ranging from 300 to 5,000, or having the structure units of formula (II): ##STR2## where R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are either a hydrogen atom or a methyl group; and m and n are respectively an integer ranging from 300 to 5,000.

    摘要翻译： 可生物降解组合物至少包含聚（β-羟基丁酸）或其可生物降解的共聚物和具有式（I）结构单元的立体专一规则嵌段共聚物：其中R 1为具有1至14个碳原子的烃基 碳原子，任选地包括双键，氧原子或它们两者; m和n分别为300-5000的整数，或具有式（II）的结构单元：其中R 2，R 3，R 4和R 5为氢原子或甲基; m和n分别为300-5000的整数。