摘要:
A polybutadiene brominating method uses a quaternary ammonium tribromide as the brominating agent. The brominating is performed in solution, and dual extractions recover the spent brominating agent and recombine it with fresh bromine to regenerate an active tribromide. Solvent and aqueous extraction streams can be purified and recycled as needed.
摘要:
Aliphatic bromine-containing polymers are stabilized using a mixture of an alkyl phosphite and an epoxy compound. This stabilizer package is very effective at preventing cross-linking reactions from occurring when the aliphatic bromine-containing polymer is subjected to high temperatures as are seen in melt processing operations. The stabilized aliphatic bromine-containing polymer is useful as a flame retardant for other polymers, notably polystyrene foam.
摘要:
Extruded polystyrene foams are made with an added brominated styrene-butadiene polymer as a flame retardant. The blowing agent is a mixture of carbon dioxide, ethanol and water, which may also contain a C4-C5 hydrocarbon. The blowing agent mixture overcomes a tendency of the brominated styrene-butadiene to form very small cells. This allows the foam to expand fully to form good quality, low density extruded foam.
摘要:
Aliphatic bromine-containing polymers are stabilized using a mixture of an alkyl phosphite and an epoxy compound. This stabilizer package is very effective at preventing cross-linking reactions from occurring when the aliphatic bromine-containing polymer is subjected to high temperatures as are seen in melt processing operations. The stabilized aliphatic bromine-containing polymer is useful as a flame retardant for other polymers, notably polystyrene foam.
摘要:
Cured resins having excellent thermal and abrasion resistance and improved processability are provided by the addition polymerization of a compound having isocyanurate moieties, imide and/or amic acid moieties and ethylenically unsaturated moieties. An example of such a compound is the reaction product of an unsaturated cyclic anhydride such as maleic anhydride, an organic polyisocyanate such as a polymeric methylene phenyl polyisocyanate and water.
摘要:
A polybutadiene brominating method uses a quaternary ammonium tribromide as the brominating agent. The brominating is performed in solution, and dual extractions recover the spent brominating agent and recombine it with fresh bromine to regenerate an active tribromide. Solvent and aqueous extraction streams can be purified and recycled as needed.
摘要:
Prepare an extruded polystyrene foam article by extruding a foamable polymer composition containing polystyrene homopolymer, a blowing agent containing 0.5 to three weight-parts water and 0.1 to five weight parts halloysite clay particles, with weight-parts relative to 100 weight-parts total polymer.
摘要:
Extruded polymer foams are prepared using brominated fatty acids, an ester, amide or ester-amide of a brominated fatty acid, a glyceride of one or more brominated fatty acids, or a polymerized brominated fatty acid as an FR additive. The brominated FR additives unexpectedly are stable at the extrusion temperatures, and provide excellent flame retardancy to the foams.
摘要:
Prepare an extruded thermoplastic polymer foam having less 1000 parts per million, based on total polymer weight, of cations from water soluble salts that exist or form into a solid or glassy state that is less malleable than the thermoplastic polymer as the foamable composition exits an extrusion die during foam manufacturing using a brominated flame retardant, an innocuous stabilizer and a blowing agent containing water.