公开(公告)号：US07803462B2

公开(公告)日：2010-09-28

申请号：US10498746

申请日：2003-10-14

申请人： Takehiro Takahashi ,  Michio Kaneko ,  Hiroshi Osawa ,  Hiroshi Kanai

发明人： Takehiro Takahashi ,  Michio Kaneko ,  Hiroshi Osawa ,  Hiroshi Kanai

IPC分类号： B32B9/00

CPC分类号： C23C26/00 ,  B32B17/061 ,  B32B17/10036 ,  B32B17/10788 ,  C03C27/00 ,  C03C27/08 ,  C23C8/80 ,  C23C28/00 ,  Y10T428/26

摘要： The titanium materials of the present invention have an oxide film on the surface and an interference color of the oxide film. In forming a transparent coating layer on the surface of the titanium materials, provisions are made so that the oxide film has an thickness of 150 nm to 600 nm, or the interference color due to the anodic oxide film is developed by the actions of both wavelengths strengthened and weakened by interference and the color phases of the color developed by the wavelength strengthened by interference and that of complementary colors of the color developed by the wavelength weakened by interference are as close to each as not more than 90 degrees apart on the color wheel, or the L* value on the L*a*b* calorimetric system is not less than 33. The laminated glasses of the present invention having excellent ornamentality comprise at least said titanium sheet interposed between multiple sheet glasses layered together by means of adhesive layers.

摘要翻译： 本发明的钛材料的表面具有氧化膜和氧化膜的干涉色。 在钛材料的表面上形成透明涂层时，要规定氧化膜的厚度为150nm〜600nm，或由于阳极氧化膜的干涉色由两波长的作用而发展 被干扰强化和削弱，由被干扰强化的波长所产生的颜色的颜色相和由被干涉减弱的波长产生的颜色的互补色的颜色相位在色轮上分别接近不超过90度 ，或L * a * b *量热系统的L *值不小于33.本发明具有优异装饰性的夹层玻璃至少包括介于通过粘合剂层层叠在一起的多片玻璃之间的钛片 。

公开(公告)号：US07613788B2

公开(公告)日：2009-11-03

申请号：US11102870

申请日：2005-04-11

申请人： Michio Kaneko

发明人： Michio Kaneko

IPC分类号： G06F15/173

CPC分类号： H04L49/60 ,  H04L12/5601 ,  H04L2012/5649 ,  H04L2012/565 ,  H04L2012/5679

摘要： A network device is provided. The network device includes a controller configured to identify a head portion of a data packet received by the network device, and inhibit a transmission of the head portions of two received data packets from consecutive slots in a transmission cycle.

摘要翻译： 提供网络设备。 网络设备包括：控制器，被配置为识别由网络设备接收的数据分组的头部，并且禁止在传输周期中来自连续时隙的两个接收的数据分组的头部的传输。

公开(公告)号：US20090226785A1

公开(公告)日：2009-09-10

申请号：US11922302

申请日：2006-06-22

申请人： Hiroshi Kihira ,  Michio Kaneko ,  Mitsuharu Yamagata ,  Koki Tanaka ,  Yoichi Ikematsu ,  Yoichi Matsuzaki ,  Kazuoto Kawakami ,  Wataru Hisada ,  Suguru Suzuki

发明人： Hiroshi Kihira ,  Michio Kaneko ,  Mitsuharu Yamagata ,  Koki Tanaka ,  Yoichi Ikematsu ,  Yoichi Matsuzaki ,  Kazuoto Kawakami ,  Wataru Hisada ,  Suguru Suzuki

IPC分类号： H01M8/10 ,  H01M2/16 ,  H01M2/00 ,  B05D5/12 ,  G01B11/14

CPC分类号： H01M8/0206 ,  B22F1/02 ,  B22F2998/00 ,  C22C29/08 ,  H01M8/021 ,  H01M8/0213 ,  H01M8/0223 ,  H01M2008/1095 ,  Y02P70/56 ,  B22F3/10

摘要： The present invention releases a method of producing a metal separator for a solid polymer fuel cell by stainless steel, titanium, or titanium alloy during which securing lower cost and mass producibility by using a material having a high workability to form a complicated shape by a high productivity, then using an inexpensive blast process to drive a conductive substance into the surface of the metal separator member, that is, provides a stainless steel, titanium, or titanium alloy solid polymer fuel cell separator comprised of stainless steel, titanium, or titanium alloy in the surface of which a low ion release conductive substance is buried, having an arithmetic mean roughness (Ra) of the separator surface of 0.5 to 5.0 μm, having a 10-point mean roughness (Rz) of 3 to 20 μm, having an average spacing of surface relief shapes (Sm) of 300 μm or less, having values of a warp rate and twist rate of a separator of 0.1 or less, and having a contact resistance value with respect to carbon paper of 15 mΩcm2 or less at a surface pressure of 1 MPa.

摘要翻译： 本发明公开了一种通过不锈钢，钛或钛合金制造固体高分子型燃料电池用金属隔板的方法，其中通过使用具有高加工性的材料来确保较低的成本和大量的生产率，以形成高的复杂形状 然后使用廉价的喷射方法将导电物质驱入金属分隔件的表面，即提供由不锈钢，钛或钛合金组成的不锈钢，钛或钛合金固体聚合物燃料电池隔板 在其表面埋有低离子释放导电物质，具有0.5〜5.0μm的隔膜表面的算术平均粗糙度（Ra），10点平均粗糙度（Rz）为3〜20μm，具有 表面浮雕形状（Sm）的平均间隔为300μm以下，隔膜的翘曲率和捻度的值为0.1以下，并且具有相对于ca的接触电阻值 15mOmegacm2以下的纸，表面压力为1MPa。

公开(公告)号：US20050148481A1

公开(公告)日：2005-07-07

申请号：US10509814

申请日：2003-09-24

申请人： Michio Kaneko ,  Kiyonori Tokuno ,  Hiroshi Shimizu ,  Takateru Dekura

发明人： Michio Kaneko ,  Kiyonori Tokuno ,  Hiroshi Shimizu ,  Takateru Dekura

IPC分类号： B08B1/00 ,  B08B3/08 ,  B08B7/04 ,  C09G1/02 ,  C11D3/02 ,  C11D3/04 ,  C11D3/14 ,  C11D3/20 ,  C11D3/28 ,  C11D3/33 ,  C11D3/34 ,  C11D3/36 ,  C11D3/37 ,  C11D3/43 ,  C11D11/00 ,  C11D17/00 ,  C23G1/06 ,  C23G1/10 ,  B08B3/00 ,  C11D1/00

CPC分类号： C11D3/364 ,  C09G1/02 ,  C11D3/042 ,  C11D3/046 ,  C11D3/14 ,  C11D3/2044 ,  C11D3/2075 ,  C11D3/28 ,  C11D3/33 ,  C11D3/3481 ,  C11D3/361 ,  C11D3/43 ,  C11D11/0029 ,  C11D17/0013 ,  C23G1/065 ,  C23G1/106

摘要： A removal cleaning agent for discolored sections of titanium building materials which comprises at least a water-soluble inorganic acid salt, an organic acid or organic acid salt, a surfactant and a hydrophilic oxygen-containing hydrocarbon solvent, and optionally an discoloration inhibitor, fluoracarbon resin and polishing material. In the cleaning method for discolored sections of titanium building materials, coating is carried out with a bristle brush and a sponge roller, the coated film sections are polished with a nonwoven fabric or foam resin, optionally after aging, and then the discolored sections are removed by washing with water.

摘要翻译： 含有至少水溶性无机酸盐，有机酸或有机酸盐，表面活性剂和亲水性含氧烃溶剂的钛建筑材料变色部分的去除清洁剂，以及任选的变色抑制剂，氟碳树脂 和抛光材料。 在钛建筑材料的变色部分的清洁方法中，用刷毛和海绵辊进行涂布，任选地在老化后用无纺织物或泡沫树脂抛光涂膜部分，然后除去变色部分 用水洗。

公开(公告)号：US06863987B2

公开(公告)日：2005-03-08

申请号：US10220030

申请日：2001-02-23

申请人： Michio Kaneko ,  Teruhiko Hayashi ,  Kazuhiro Takahashi ,  Kiyonori Tokuno ,  Junichi Tamenari ,  Kinichi Kimura ,  Hiroshi Shimizu ,  Shoichi Maruyama

发明人： Michio Kaneko ,  Teruhiko Hayashi ,  Kazuhiro Takahashi ,  Kiyonori Tokuno ,  Junichi Tamenari ,  Kinichi Kimura ,  Hiroshi Shimizu ,  Shoichi Maruyama

IPC分类号： G01N23/207 ,  C22F1/00 ,  C22F1/02 ,  C22F1/18 ,  C23C8/08 ,  C23C8/16 ,  C23C30/00 ,  C25D11/26 ,  C25F1/08 ,  G01N23/227 ,  B32B15/04

CPC分类号： C25D11/26 ,  Y10S428/926

摘要： Titanium resistant to discoloration in an atmospheric environment characterized by having an average carbon concentration of 14 at % or less in a range to a depth of 100 nm from the surface and having an oxide film of a thickness of 12 to 40 nm at its surface. Titanium resistant to discoloration in an atmospheric environment characterized in that, in X-ray diffraction of its surface, a ratio (X1/X2) of a (200) peak intensity X1 of TiC to a (110) peak intensity X2 of titanium is not more than 0.18 and by having an oxide film of a thickness of 12 to 40 nm at its surface.

摘要翻译： 在大气环境中耐变色的钛，其特征在于在表面上具有厚度为12〜40nm的氧化膜的距表面100nm的深度的平均碳浓度为14at％以下。 在大气环境中耐变色的钛，其特征在于，在其表面的X射线衍射中，TiC的（200）峰强度X1与钛的（110）峰强度X2的比（X1 / X2）不是 大于0.18并且在其表面具有厚度为12至40nm的氧化物膜。

公开(公告)号：US09885102B2

公开(公告)日：2018-02-06

申请号：US11920486

申请日：2006-05-25

申请人： Michio Kaneko ,  Kiyonori Tokuno ,  Takao Wada ,  Mitsuyuki Hasegawa ,  Kazuo Yamagishi

发明人： Michio Kaneko ,  Kiyonori Tokuno ,  Takao Wada ,  Mitsuyuki Hasegawa ,  Kazuo Yamagishi

IPC分类号： C23C8/10 ,  C22C14/00 ,  C23C30/00 ,  C25D11/26 ,  C23C28/04

CPC分类号： C23C8/10 ,  C22C14/00 ,  C23C28/042 ,  C23C30/00 ,  C25D11/26

摘要： The present invention provides colored pure titanium or titanium alloy having low susceptibility to discoloration in an atmospheric environment exhibiting a superior resistance to discoloration even when the titanium is used in an environment of harsh acid rain such as a roof or wall material and free from deterioration of the aesthetic appearance over a long period of time, that is, colored pure titanium obtained by the anodic oxidation method, that is, colored pure titanium or titanium alloy having low susceptibility to discoloration in an atmospheric environment characterized by having an average phosphorus content in a range of 40 nm from a surface of a titanium oxide layer formed on the titanium surface of 5.5 atomic % or less and by having an average carbon concentration in a range of a depth of 100 nm from the titanium surface of 3 to 15 atomic %.

公开(公告)号：US08865612B2

公开(公告)日：2014-10-21

申请号：US13261058

申请日：2010-06-01

申请人： Michio Kaneko ,  Kiyonori Tokuno ,  Hiroshi Shimizu ,  Kazuo Yamagishi ,  Asami Shimomura ,  Mituyuki Hasegawa ,  Ruriko Yokoyama

发明人： Michio Kaneko ,  Kiyonori Tokuno ,  Hiroshi Shimizu ,  Kazuo Yamagishi ,  Asami Shimomura ,  Mituyuki Hasegawa ,  Ruriko Yokoyama

IPC分类号： B01J21/18 ,  B01J27/24 ,  B01J23/00 ,  B32B15/04 ,  B32B9/00 ,  B01J21/06 ,  B01J35/06 ,  B01J35/00 ,  B01J27/22 ,  C25D11/26

CPC分类号： B01J21/063 ,  B01J27/22 ,  B01J27/24 ,  B01J35/004 ,  B01J35/065 ,  C25D11/26 ,  Y10T428/31678

摘要： The provision of beautiful colored titanium which is excellent in adhesion of the pure titanium or a titanium alloy with the base material, is excellent in photocatalytic activity, and further is excellent in design properties and a method of production of the same which is excellent in productivity and uses an anodic oxidation process is made the object. A titanium-based material having visible light response and excellent in photocatalytic activity characterized in that the material has pure titanium or titanium alloy as a base material, a thickness of a titanium oxide layer which is present on its surface is 0.1 μm to 5.0 μm in range, said titanium oxide layer contains anatase-type titanium dioxide and titanium bonded with hydroxy groups, and further said titanium oxide layer contains nitrogen and carbon respectively in 0.5 to 30 mass %.

摘要翻译： 提供纯钛或钛合金与基材的附着性优异的美丽的有色钛，具有优异的光催化活性，并且还具有优异的设计性能及其制造方法，其生产率优异 并采用阳极氧化工艺制成的物体。 具有可见光响应且光催化活性优异的钛基材料，其特征在于，该材料具有纯钛或钛合金作为基材，其表面上存在的氧化钛层的厚度为0.1μm〜5.0μm 所述氧化钛层含有锐钛矿型二氧化钛和与羟基键合的钛，进一步，所述氧化钛层分别含有0.5〜30质量％的氮和碳。

公开(公告)号：US08785031B2

公开(公告)日：2014-07-22

申请号：US12304722

申请日：2007-06-15

申请人： Michio Kaneko ,  Kazuhiro Takahashi ,  Kiyonori Tokuno ,  Hiroshi Kihira ,  Wataru Hisada

发明人： Michio Kaneko ,  Kazuhiro Takahashi ,  Kiyonori Tokuno ,  Hiroshi Kihira ,  Wataru Hisada

IPC分类号： H01M2/14 ,  H01M2/16 ,  H01M8/10 ,  B05D5/12

CPC分类号： C23C24/04 ,  C23C28/00 ,  H01M8/0204 ,  H01M8/0206 ,  H01M8/0208 ,  H01M8/0215 ,  H01M8/0228 ,  H01M2008/1095 ,  Y02P70/56

摘要： The present invention provides a polymer electrolyte fuel cell separator made of pure titanium or a titanium alloy superior in contact resistance with carbon paper and a method of production of the same, that is, a separator having a surface layer part to which conductive compound particles are affixed, characterized in that the surface oxide has a thickness of 3 to 15 nm in range, an average carbon concentration in a range from an outermost surface, including the oxide layer, to a depth of 100 nm is 0.02 to 6 at %, and the conductive compound particles have an average particle size of 0.01 to 20 μm. Further, the method of production of the present invention is characterized by forming, blast treating a surface of the formed article by particles comprised of conductive compound particles of an average particle size of 0.01 to 20 μm covering a surface of superhard core particles, impregnating it by a nitric acid aqueous solution of a concentration of 15 to 71 mass % and a temperature of 40 to 100° C. for 30 seconds to 180 minutes by spraying or dipping, then washing it.

摘要翻译： 本发明提供一种由碳钛纸或其制造方法制成的纯钛或钛合金制成的高分子电解质型燃料电池隔板及其制造方法，即具有导电性化合物粒子的表层部的隔膜 其特征在于，表面氧化物的范围为3〜15nm的厚度，从包括氧化物层的最外表面到100nm的深度的范围内的平均碳浓度为0.02〜6原子％， 导电性化合物粒子的平均粒径为0.01〜20μm。 此外，本发明的制造方法的特征在于，通过由覆盖超硬核粒子的表面的平均粒径为0.01〜20μm的导电性化合物粒子构成的粒子对成形体的表面进行喷砂处理，浸渍 通过喷雾或浸渍，浓度为15〜71质量％，温度为40〜100℃的硝酸水溶液30秒〜180分钟，然后进行洗涤。

公开(公告)号：US20110032537A1

公开(公告)日：2011-02-10

申请号：US12806764

申请日：2010-08-20

申请人： Hiroshi Kihira ,  Michio Kaneko ,  Mitsuharu Yamagata ,  Koki Tanaka ,  Yoichi Ikematsu ,  Yoichi Matsuzaki ,  Kazuto Kawakami ,  Wataru Hisada ,  Suguru Suzuki

发明人： Hiroshi Kihira ,  Michio Kaneko ,  Mitsuharu Yamagata ,  Koki Tanaka ,  Yoichi Ikematsu ,  Yoichi Matsuzaki ,  Kazuto Kawakami ,  Wataru Hisada ,  Suguru Suzuki

IPC分类号： G01B11/24

CPC分类号： H01M8/0206 ,  B22F1/02 ,  B22F2998/00 ,  C22C29/08 ,  H01M8/021 ,  H01M8/0213 ,  H01M8/0223 ,  H01M2008/1095 ,  Y02P70/56 ,  B22F3/10

摘要： The present invention releases a method of producing a metal separator for a solid polymer fuel cell by stainless steel, titanium, or titanium alloy during which securing lower cost and mass producibility by using a material having a high workability to form a complicated shape by a high productivity, then using an inexpensive blast process to drive a conductive substance into the surface of the metal separator member, that is, provides a stainless steel, titanium, or titanium alloy solid polymer fuel cell separator comprised of stainless steel, titanium, or titanium alloy in the surface of which a low ion release conductive substance is buried, having an arithmetic mean roughness (Ra) of the separator surface of 0.5 to 5.0 μm, having a 10-point mean roughness (Rz) of 3 to 20 μm, having an average spacing of surface relief shapes (Sm) of 300 μm or less, having values of a warp rate and twist rate of a separator of 0.1 or less, and having a contact resistance value with respect to carbon paper of 15 mωcm2 or less at a surface pressure of 1 MPa.

摘要翻译： 本发明公开了一种通过不锈钢，钛或钛合金制造固体高分子型燃料电池用金属隔板的方法，其中通过使用具有高加工性的材料来确保较低的成本和大量的生产率，以形成高的复杂形状 然后使用廉价的喷射方法将导电物质驱入金属分隔件的表面，即提供由不锈钢，钛或钛合金组成的不锈钢，钛或钛合金固体聚合物燃料电池隔板 在其表面埋设有低离子释放导电物质，具有0.5〜5.0μm的隔膜表面的算术平均粗糙度（Ra），10点平均粗糙度（Rz）为3〜20μm，具有 平均间隔为300μm以下的表面浮雕形状（Sm），隔膜的翘曲率和扭曲率的值为0.1以下，并且具有相对于ca的接触电阻值 在1MPa的表面压力下为15mωcm2以下的纸。

公开(公告)号：US20090226787A1

公开(公告)日：2009-09-10

申请号：US12224429

申请日：2007-02-27

申请人： Koki Tanaka ,  Youichi Ikematsu ,  Hiroshi Kihira ,  Michio Kaneko ,  Wataru Hisada ,  Tamotsu Itoh

发明人： Koki Tanaka ,  Youichi Ikematsu ,  Hiroshi Kihira ,  Michio Kaneko ,  Wataru Hisada ,  Tamotsu Itoh

IPC分类号： H01M8/10 ,  H01M2/14

CPC分类号： H01M8/0228 ,  H01M8/0206 ,  H01M8/0208 ,  H01M8/021 ,  H01M8/0213 ,  H01M2008/1095 ,  Y02P70/56

摘要： The present invention provides a separator for a solid polymer type fuel cell superior in low contact resistance of the fuel cell separator surface with carbon paper and flatness and a method of production of the same, that is, a separator for a solid polymer type fuel cell comprising a substrate of stainless steel or titanium or a titanium alloy having a surface layer part on which conductive compound particles are fixed, wherein said conductive compound particles are comprised of one or more types of metal borides, metal carbides, and metal nitrides with an average particle size of 0.01 to 20 μm, said conductive compound particles are present in a region from said substrate surface to a depth of 10 μm, and a distribution of concentration of the metal element forming the conductive compound in said region satisfies relations between a concentration C of the metal element forming the conductive compound and a depth x from the substrate surface shown by equation (C=A·exp(−x/t)+B) and equation (10≦A≦90, −4.0≦B≦1.0, 0.5≦t≦4.0).

摘要翻译： 本发明提供了一种固体聚合物型燃料电池用隔膜，其特征在于，具有碳纸和平坦度的燃料电池隔板表面的低接触电阻优良的固体聚合物型燃料电池及其制造方法，即固体聚合物型燃料电池用隔板 包括不锈钢或钛的基板或具有固定有导电化合物颗粒的表面层部分的钛合金，其中所述导电化合物颗粒由一种或多种金属硼化物，金属碳化物和金属氮化物组成，平均 所述导电化合物颗粒存在于从所述衬底表面到10μm的深度的区域中，并且在所述区域中形成导电化合物的金属元素的浓度分布满足浓度C 的形成导电化合物的金属元素和由等式1（C = A.exp（-x / t）+ B）所示的衬底表面的深度x） 和等式<2>（10 <= A <= 90，-4.0 <= B <= 1.0,0.5 <= t <= 4.0）。