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    Anionic polymerization initiators containing adducts of cyclic secondary amines and conjugated dienes, and products therefrom
    21.
    发明授权
    Anionic polymerization initiators containing adducts of cyclic secondary amines and conjugated dienes, and products therefrom 失效
    含有环状仲胺和共轭二烯的加合物的阴离子聚合引发剂及其产物

    公开(公告)号：US5610228A

    公开(公告)日：1997-03-11

    申请号：US471276

    申请日：1995-06-06

    申请人： David F. Lawson ,  Thomas A. Antkowiak ,  James E. Hall ,  Mark L. Stayer, Jr.

    发明人： David F. Lawson ,  Thomas A. Antkowiak ,  James E. Hall ,  Mark L. Stayer, Jr.

    IPC分类号： C08F4/08 ,  C07F1/02 ,  C08F4/42 ,  C08F4/46 ,  C08F4/48 ,  C08F236/04 ,  C08F236/10 ,  C08K5/01

    CPC分类号： C07F1/02

    摘要： An anionic polymerization initiator includes a carbon-lithio salt of the adduct of a cyclic secondary amine with a conjugated diene. A method of preparing an anionic polymerization initiator includes reacting an excess of a cyclic secondary amine with a conjugated diene to form an adduct; and, reacting the adduct with an organolithium compound. A method of preparing a polymer includes forming a solution of one or more anionically polymerizable monomers in a hydrocarbon solvent; and, polymerizing the monomer with an anionic polymerization initiator comprising a carbon-lithio salt of the adduct of a cyclic secondary amine with a conjugated diene. A functionalized polymer includes the termination product of a living polymer having the general formula AYLi, wherein A is a functional group derived from an anionic polymerization initiator; and, Y is a divalent polymer radical; wherein the anionic polymerization initiator is a carbon-lithio salt of the adduct of a cyclic secondary amine with a conjugated diene.

    摘要翻译： 阴离子聚合引发剂包括环状仲胺与共轭二烯的加合物的碳 - 硫酸盐。 制备阴离子聚合引发剂的方法包括使过量的环状仲胺与共轭二烯反应形成加合物; 并使加合物与有机锂化合物反应。 制备聚合物的方法包括在烃溶剂中形成一种或多种阴离子聚合单体的溶液; 并且用包含环状仲胺加成物的碳 - 硫醇盐与共轭二烯的阴离子聚合引发剂聚合单体。 官能化聚合物包括具有通式AYLi的活性聚合物的终止产物，其中A是衍生自阴离子聚合引发剂的官能团; Y为二价聚合物基团; 其中所述阴离子聚合引发剂是环状仲胺与共轭二烯的加合物的碳 - 锂盐。

    Functionalized polymer of improved hysteresis properties prepared using amino-substituted aryllithium polymerization initiators
    22.
    发明授权
    Functionalized polymer of improved hysteresis properties prepared using amino-substituted aryllithium polymerization initiators 失效
    使用氨基取代的芳基锂聚合引发剂制备的具有改进的滞后性质的官能化聚合物

    公开(公告)号：US5523371A

    公开(公告)日：1996-06-04

    申请号：US418305

    申请日：1995-04-07

    申请人： David F. Lawson ,  Thomas A. Antkowiak ,  Mark L. Stayer, Jr. ,  John R. Schreffler ,  Hideki Komatsu

    发明人： David F. Lawson ,  Thomas A. Antkowiak ,  Mark L. Stayer, Jr. ,  John R. Schreffler ,  Hideki Komatsu

    IPC分类号： B60C1/00 ,  C08F4/42 ,  C08F4/48 ,  C08F36/04 ,  C08F297/04 ,  C08F36/06 ,  C08F236/10

    CPC分类号： C08F4/48 ,  B60C1/0016 ,  C08F36/04 ,  C08F4/484

    摘要： A vulcanizable elastomeric compound and products such as pneumatic tires and the like, are formed from a functionalized polymer having a functional group derived from an anionic polymerization initiator. The anionic polymerization initiator comprises the general formula ##STR1## where R.sup.1 -R.sup.5 are the same or different and are selected from the group consisting of hydrogen; alkyls having from alkyls having from 1 to about 12 carbon atoms; aralkyls having from 7 to about 20 carbon atoms; dialkylaminos having from 2 to about 20 carbon atoms; and, dialkylaminoalkyls having from 3 to about 20 carbon atoms. At least one of R.sup.1 -R.sup.5 is selected from the group consisting of the dialkylaminos and the dialkylaminoalkyls. Methods of the present invention include preparing functionalized polymers and reducing the hysteresis of vulcanizable elastomeric compounds.

    摘要翻译： 可硫化的弹性体化合物和充气轮胎等产品由具有衍生自阴离子聚合引发剂的官能团的官能化聚合物形成。 阴离子聚合引发剂包括通式“IMAGE”，其中R 1 -R 5相同或不同，并且选自氢; 具有1至约12个碳原子的烷基的烷基; 具有7至约20个碳原子的芳烷基; 具有2至约20个碳原子的二烷基氨基; 和具有3至约20个碳原子的二烷基氨基烷基。 R1-R5中的至少一个选自二烷基氨基和二烷基氨基烷基。 本发明的方法包括制备官能化聚合物并降低可硫化弹性体化合物的滞后。

    Anionic polymerization initiators containing adducts of cyclic secondary amines and conjugated dienes, and products therefrom
    23.
    发明授权
    Anionic polymerization initiators containing adducts of cyclic secondary amines and conjugated dienes, and products therefrom 失效
    含有环状仲胺和共轭二烯的加合物的阴离子聚合引发剂及其产物

    公开(公告)号：US5502130A

    公开(公告)日：1996-03-26

    申请号：US469131

    申请日：1995-06-06

    申请人： David F. Lawson ,  Thomas A. Antkowiak ,  James E. Hall ,  Mark L. Stayer, Jr.

    发明人： David F. Lawson ,  Thomas A. Antkowiak ,  James E. Hall ,  Mark L. Stayer, Jr.

    IPC分类号： C08F4/08 ,  C07F1/02 ,  C08F4/42 ,  C08F4/46 ,  C08F4/48 ,  C08F236/04 ,  C08F236/10

    CPC分类号： C07F1/02

    摘要： An anionic polymerization initiator includes a carbon-lithio salt of the adduct of a cyclic secondary amine with a conjugated diene. A method of preparing an anionic polymerization initiator includes reacting an excess of a cyclic secondary amine with a conjugated diene to form an adduct; and, reacting the adduct with an organolithium compound. A method of preparing a polymer includes forming a solution of one or more anionically polymerizable monomers in a hydrocarbon solvent; and, polymerizing the monomer with an anionic polymerization initiator comprising a carbon-lithio salt of the adduct of a cyclic secondary amine with a conjugated diene. A functionalized polymer includes the termination product of a living polymer having the general formula AYLi, Wherein A is a functional group derived from an anionic polymerization initiator; and, Y is a divalent polymer radical; wherein the anionic polymerization initiator is a carbon-lithio salt of the adduct of a cyclic secondary amine with a conjugated diene.

    摘要翻译： 阴离子聚合引发剂包括环状仲胺与共轭二烯的加合物的碳 - 硫酸盐。 制备阴离子聚合引发剂的方法包括使过量的环状仲胺与共轭二烯反应形成加合物; 并使加合物与有机锂化合物反应。 制备聚合物的方法包括在烃溶剂中形成一种或多种阴离子聚合单体的溶液; 并且用包含环状仲胺加成物的碳 - 硫醇盐与共轭二烯的阴离子聚合引发剂聚合单体。 官能化聚合物包括具有通式AYLi的活性聚合物的终止产物，其中A是衍生自阴离子聚合引发剂的官能团; Y为二价聚合物基团; 其中所述阴离子聚合引发剂是环状仲胺与共轭二烯的加合物的碳 - 锂盐。

    Liquid diene polymers and copolymers terminated by reaction with fused-ring polynuclear aromatic compounds
    24.
    发明授权
    Liquid diene polymers and copolymers terminated by reaction with fused-ring polynuclear aromatic compounds 失效
    通过与稠环多核芳族化合物反应终止的液体二烯聚合物和共聚物

    公开(公告)号：US5334665A

    公开(公告)日：1994-08-02

    申请号：US58340

    申请日：1993-05-06

    申请人： David F. Lawson ,  Mark L. Stayer, Jr. ,  Thomas A. Antkowiak

    发明人： David F. Lawson ,  Mark L. Stayer, Jr. ,  Thomas A. Antkowiak

    IPC分类号： C08C19/44 ,  C08F8/00 ,  C08F36/00 ,  C08F36/04 ,  C08F236/10 ,  C08K3/04 ,  C08L9/00 ,  C08L9/06

    CPC分类号： C08C19/44

    摘要： A terminally functionalized liquid polymer is prepared by reacting a low molecular weight living diene polymer or copolymer obtained by anionic polymerization of a diene monomer or mixture of a diene monomer and a vinyl aromatic hydrocarbon monomer with a fused-ring polynuclear aromatic compound. The resultant terminally functionalized liquid diene polymers or copolymers can be utilized as dispersants for particulates such as carbon black or graphite and may also be employed as viscosity modifiers for lubricating oils or in electrorheological devices or damping devices.

    摘要翻译： 通过二烯单体或二烯单体和乙烯基芳烃单体的混合物的阴离子聚合得到的低分子量活性二烯聚合物或共聚物与稠环多核芳族化合物反应来制备末端官能化液体聚合物。 得到的末端官能化液态二烯聚合物或共聚物可用作颗粒物如炭黑或石墨的分散剂，也可用作润滑油的粘度改进剂或电流变学装置或阻尼装置。

    Diene polymers and copolymers terminated with compounds having multiple-bonded nitrogen atoms and partially crosslinked with polyfunctional reagents
    25.
    发明授权
    Diene polymers and copolymers terminated with compounds having multiple-bonded nitrogen atoms and partially crosslinked with polyfunctional reagents 失效
    二烯聚合物和共聚物用具有多键氮原子并与多官能试剂部分交联的化合物封端

    公开(公告)号：US5310798A

    公开(公告)日：1994-05-10

    申请号：US106729

    申请日：1993-08-16

    申请人： David F. Lawson ,  Mark L. Stayer, Jr. ,  Thomas A. Antkowiak

    发明人： David F. Lawson ,  Mark L. Stayer, Jr. ,  Thomas A. Antkowiak

    IPC分类号： C08F8/30 ,  C08C19/44 ,  C08F236/04 ,  C08F236/10 ,  C08F8/40

    CPC分类号： C08C19/44

    摘要： Diene polymers or copolymers having improved raw polymer viscosity and reduced hysteresis in the cured and carbon black reinforced state are provided. These diene polymers or copolymers are prepared by a method which involves first terminating substantially all of the living diene polymer or copolymer chains obtained by anionic polymerization with a compound having multiple-bonded nitrogen atoms selected from the group consisting of aromatic nitriles and substituted imines having the formula ##STR1## and then coupling a portion of the resultant terminated polymer chains with a polyfunctional reagent selected from the groups consisting of silicon polyhalides, polyisocyanates, phosphoryl halides and polycarboxylic acid halides.

    摘要翻译： 提供了在固化和炭黑增强状态下具有改进的原料聚合物粘度和降低的滞后的二烯聚合物或共聚物。 这些二烯聚合物或共聚物是通过一种方法制备的，该方法包括首先使具有多键键氮原子的化合物基本上所有的通过阴离子聚合得到的活性二烯聚合物或共聚物链终止，所述化合物具有选自芳族腈和具有 然后将一部分所得的封端的聚合物链与选自多硅卤化物，多异氰酸酯，磷酰卤和多羧酸卤化物的多官能试剂偶联。