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21.发明授权
公开(公告)号：US4131575A
公开(公告)日：1978-12-26
申请号：US769725
申请日：1977-02-17
CPC分类号： C08K5/103
摘要： The present invention is concerned with thermoplastic molding materials of high molecular weight, thermoplastic, aromatic polycarbonates based on aromatic dihydroxy compounds and containing from about 0.01 to 0.1% by weight of esters of saturated aliphatic carboxylic acids with 10 to 20 C atoms and 4-hydric to 6-hydric alcohols.
摘要翻译： 本发明涉及基于芳族二羟基化合物的高分子量，热塑性芳族聚碳酸酯的热塑性成型材料，并且含有约0.01至0.1重量％的具有10-20个碳原子的饱和脂族羧酸和4-羟基 至6-羟基醇。
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22.发明授权Thermoplastic polycarbonate moulding compositions with improved ease of mould release 失效具有提高脱模容易性的热塑性聚碳酸酯模塑组合物
公开(公告)号：US4065436A
公开(公告)日：1977-12-27
申请号：US710069
申请日：1976-07-30
摘要： The invention relates to a thermoplastic moulding composition comprising a thermoplastic aromatic polycarbonate based on an aromatic dihydroxy compound and containing 0.01 to 0.5% by weight of an ester of a saturated aliphatic carboxylic acid with 10 to 20 C atoms per molecule and an aromatic hydroxy compound with from 1 to 6 hydroxyl groups.
摘要翻译： 本发明涉及一种热塑性模塑组合物，其包含基于芳族二羟基化合物的热塑性芳族聚碳酸酯，并且含有0.01至0.5重量％的每分子具有10至20个C原子的饱和脂族羧酸酯和具有 1至6个羟基。
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公开(公告)号：US4012362A
公开(公告)日：1977-03-15
申请号：US573837
申请日：1975-05-02
IPC分类号： C07D215/26 , C08F20/34 , C08F20/60 , C08F22/22 , C08F22/36 , C08F26/06 , C08F120/60
CPC分类号： C08F22/36 , C07D215/26 , C08F20/34 , C08F20/60 , C08F22/22 , C08F26/06 , Y10S423/14
摘要： Homo- and copolymers of monomers obtained by acylation of 2-[4-hydroxy(or amino)phenyl]-2-[5-(8-hydroxyquinolyl)]-propane with .alpha.,.beta.-monoolefinically unsaturated carboxylic acid halides or - anhydrides. As comonomers can be employed compounds containing one or more .alpha.,.beta.-olefinically unsaturated groups such as olefines, diolefines, acrylic acid derivatives, vinyl monomers. The polymers having molecular weights between 5000 - 500,000 can be prepared by radical or ionic chain mechanisms, in continuous or discontinuous processes. They may be used for removing metal ions from their solution, for complexing of interfering metallic impurities in thermoplastic or thermosetting resins or in form of their metal complexes as stabilizers for plastics.
摘要翻译： 通过将2- [4-羟基（或氨基）苯基] -2- [5-（8-羟基喹啉基）] - 丙烷与α，β-单烯烃不饱和羧酸卤化物或 - 酸酐酰化获得的单体的均聚物和共聚物。 作为共聚单体，可以使用含有一个或多个α，β-烯属不饱和基团的化合物，例如烯烃，二烯，丙烯酸衍生物，乙烯基单体。 分子量在5000-500,000之间的聚合物可以通过自由基或离子链机制在连续或不连续过程中制备。 它们可用于从其溶液中除去金属离子，用于将干涉金属杂质与热塑性树脂或热固性树脂或其金属络合物的形式络合作为塑料稳定剂。
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24.发明授权
公开(公告)号：US6153788A
公开(公告)日：2000-11-28
申请号：US131026
申请日：1998-08-07
CPC分类号： C07C67/60
摘要： The present invention relates to a process for preparing unsaturated esters by azeo-tropically esterifyinga) monohydric or polyhydric alcohols orb) polyesters which contain at least two hydroxyl groups per molecule and are the reaction product of polyhydric alcohols with mono- or dibasis, saturated or aromatically unsaturated carboxylic acids,with ethylenically unsaturated carboxylic acids in the presence of an acid catalyst and subsequently reacting the acid catalyst and any unesterified carboxylic acid groups with ethylenically unsaturated monoepoxy compounds.
摘要翻译： 本发明涉及一种通过将a）一元或多元醇或b）每分子含有至少两个羟基的聚酯并且是多元醇与单 - 或二 - 二饱和的多元醇的反应产物 - 或芳族不饱和羧酸与烯键式不饱和羧酸在酸催化剂的存在下反应，随后使酸催化剂和任何未酯化的羧酸基团与烯属不饱和单环氧化合物反应。
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25.发明授权
公开(公告)号：US5308912A
公开(公告)日：1994-05-03
申请号：US971449
申请日：1992-11-04
申请人： Dieter Margotte , Werner Kubitza
发明人： Dieter Margotte , Werner Kubitza
IPC分类号： C08G18/08 , C08G18/40 , C08G18/70 , C09D175/04 , C09D175/08 , C08L75/06
CPC分类号： C08G18/706 , C08G18/0819 , C08G18/4063 , C09D175/04
摘要： The present invention relates to an aqueous coating composition containinga) an aqueous solution or dispersion of a polyol component containing at least one water-dilutable polyacrylate resin having hydroxyl groups and a molecular weight (M.sub.n) above 500,b) a polyisocyanate component which has a viscosity of 50 to 10,000 mPa.s at 23.degree. C. and is emulsified in component a), andc) 0.5 to 6% by weight, based on the weight of component a), of a water-soluble polyether polyol having a molecular weight of 300 to 1000,wherein the coating composition has an NCO/OH equivalent ratio of 0.5:1 to 5:1, based on the isocyanate groups of component b) and the alcoholic hydroxyl groups of components a) and c).
摘要翻译： 本发明涉及一种水性涂料组合物，其含有a）多元醇组分的水溶液或分散体，其含有至少一种具有羟基并且分子量（Mn）在500以上的水可稀释的聚丙烯酸酯树脂，b）多异氰酸酯组分，其具有 在23℃下的粘度为50至10,000mPa.s，并在组分a）中乳化，c）基于组分a）的重量计为0.5至6重量％的水溶性聚醚多元醇，其具有 分子量为300〜1000，其中涂料组合物的NCO / OH当量比为0.5:1至5:1，基于组分b）的异氰酸酯基和组分a）和c）的醇羟基。
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26.发明授权Solutions of isocyanurate polyisocyanates in coatings solvents and a process for their production 失效异氰脲酸酯多异氰酸酯在涂料溶剂中的溶液及其制备方法
公开(公告)号：US5064960A
公开(公告)日：1991-11-12
申请号：US571465
申请日：1990-08-22
申请人： Josef Pedain , Dieter Margotte
发明人： Josef Pedain , Dieter Margotte
IPC分类号： C08G18/02 , C07D251/34 , C08G18/79 , C08G18/80 , C09D175/00
CPC分类号： C08G18/794 , C07D251/34 , C08G18/8064
摘要： The present invention relates to a process for the preparation of a composition containing an isocyanurate polyisocyanate dissolved in a solvent inert to isocyanate groups bya) reacting 2.5 to 7% of the isocyanate groups of a starting diisocyanate based on 2,4-diisocyanatotoluene or a mixture of 2,4-diisocyanatotoluene and 2,6-diisocyanatotoluene with a monohydric alcohol corresponding to the formula ##STR1## wherein R.sub.1 is an aliphatic or cycloaliphatic C.sub.6-18 hydrocarbon radical which may be olefinically unsaturated,R.sub.2 is hydrogen or a methyl group, andn is 0 or an integer from 1 to 3,b) adding a sufficient amount of an organic solvent which is inert to isocyanate groups to form a 30 to 70% solution of the urethanized diisocyanate either before, during or after step a),c) subsequently partially trimerizing the remaining isocyanate groups of said urethanized diisocyanate in the presence of a catalyst which accelerates the trimerization of isocyanate groups andd) terminating the trimerization reaction when the content of unreacted diisocyanotoluene is less than 0.5% by weight by the addition of a catalyst poison.The present invention also relates to the solutions of isocyanurate polyisocyanates obtained by this process.
摘要翻译： 本发明涉及一种制备含有异氰脲酸酯多异氰酸酯的组合物的方法，所述组合物溶解在对异氰酸酯基团惰性的溶剂中，通过以下步骤：a）使2.5至7％的起始二异氰酸酯基于2,4-二异氰酸根合甲苯或 2,4-二异氰酸根合甲苯和2,6-二异氰酸基甲苯与一种对应于式R 1的一元醇的混合物，其中R 1是可以是烯属不饱和的脂族或脂环族C 6-18烃基，R 2是氢或甲基 ，n为0或1〜3的整数，b）在步骤a）之前，期间或之后，加入足够量的异氰酸酯基惰性的有机溶剂，形成氨基甲酸酯化二异氰酸酯的30〜70％ c）随后在催化剂存在下将所述氨基甲酸酯化二异氰酸酯的剩余异氰酸酯基部分三聚化，催化剂加速异氰酸酯基团的三聚化，和d）终止 当未反应的二异氰酰甲苯的含量通过加入催化剂毒物小于0.5重量％时，三聚反应。 本发明还涉及通过该方法获得的异氰脲酸酯多异氰酸酯的溶液。
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27.发明授权
公开(公告)号：US4748269A
公开(公告)日：1988-05-31
申请号：US851742
申请日：1986-04-14
申请人： Jurgen Meixner , Josef Pedain , Peter Hohlein , Dieter Margotte
发明人： Jurgen Meixner , Josef Pedain , Peter Hohlein , Dieter Margotte
IPC分类号： C07C69/54 , C08F2/46 , C08F220/36 , C07C69/52
摘要： (Meth)acrylic acid esters can be prepared by acid-catalyzed reaction of (meth)acrylic acid with alcohols in a water-immiscible solvent. After the esterification, the reaction mixture is washed with aqueous solutions having an alkaline reaction and then reacted at elevated temperature with carbodiimides. Acid numbers below 0.5 (mg of KOH/g of substance) are obtained in this way. (Meth)acrylic acid esters are used, for example, as reactive diluents or as comonomers.
摘要翻译： （甲基）丙烯酸酯可以通过（甲基）丙烯酸与醇在水不混溶溶剂中的酸催化反应来制备。 酯化后，反应混合物用碱性反应的水溶液洗涤，然后在高温下与碳二亚胺反应。 以这种方式获得酸值低于0.5（KOH / g的物质）。 （甲基）丙烯酸酯用作例如作为反应性稀释剂或共聚单体。
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28.发明授权Reacting polycarbonate resin with aryl chlorocarbonate to improve aging characteristics 失效用碳酸芳基酯反应聚碳酸酯树脂以改善老化特性
公开(公告)号：US4460752A
公开(公告)日：1984-07-17
申请号：US436473
申请日：1982-10-25
申请人： Dieter Neuray , Dieter Margotte , Erhard Tresper , Gunter Jacobs
发明人： Dieter Neuray , Dieter Margotte , Erhard Tresper , Gunter Jacobs
摘要： A process for the preparation of polycarbonates from diphenols and/or chlorocarbonic acid esters thereof and phosgene by the two-phase boundary process wherein said polycarbonate is reacted with aryl chlorocarbonate is disclosed; the reaction products are noted for their improved ageing and hydrolysis characteristics which render them useful as thermoplastic molding compositions.
摘要翻译： 公开了一种通过二相边界方法从二酚和/或其氯碳酸酯和光气制备聚碳酸酯的方法，其中所述聚碳酸酯与氯碳酸芳基反应; 注意到反应产物的改进的老化和水解特性，使其可用作热塑性模塑组合物。
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29.发明授权Process for the preparation of polycarbonates catalyzed by cyclic aza compounds 失效环状氮杂化合物催化聚碳酸酯的制备方法
公开(公告)号：US4346210A
公开(公告)日：1982-08-24
申请号：US88694
申请日：1979-10-26
CPC分类号： C08G64/24
摘要： The present invention relates to a process for the preparation of aromatic polycarbonates from diphenols by the phase boundary process, which is characterized in that cyclic, preferably monocyclic or bicyclic, aza compounds are used as catalysts. The present invention also relates to the polycarbonates obtainable according to the process, which are distinguished by high light transmission and a low tendency to yellowing, even after relatively severe exposure to heat.
摘要翻译： 本发明涉及通过相界法从二酚制备芳族聚碳酸酯的方法，其特征在于使用环状，优选单环或双环的氮杂化合物作为催化剂。 本发明还涉及根据该方法可获得的聚碳酸酯，即使在相对严重的暴露于热之后，其也被高透光性和低黄变的特性区分。
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公开(公告)号：US4252922A
公开(公告)日：1981-02-24
申请号：US16457
申请日：1979-02-28
申请人： Siegfried Adelmann , Dieter Margotte , Werner Nouvertne , Manfred Schreckenberg , Frank Kleiner
发明人： Siegfried Adelmann , Dieter Margotte , Werner Nouvertne , Manfred Schreckenberg , Frank Kleiner
CPC分类号： C08L69/00 , C08G63/64 , C08G64/18 , C08G64/183
摘要： Thermoplastic molding compositions are provided comprising from about 80 to 98% by weight of a polycarbonate obtained from diphenols, having a mean weight-average molecular weight M.sub.w from about 10,000 to 200,000 and from about 20 to 2% by weight of a polyester-carbonate and/or polyether-carbonate with mean weight-average molecular weights M.sub.w of from about 50,000 to 300,000, which contain between about 50 and 70% by weight of soft polyester segments or soft polyether segments with mean number-average molecular weights M.sub.n of from about 10,000 to 20,000. The instant invention also relates to a process for the production of said thermoplastic molding compositions. These thermoplastic molding compositions show markedly improved resilience properties compared with known polycarbonates and can be employed as films and shaped articles in all cases where, on the one hand, high notched impact strength at low temperatures, high toughness properties at relatively high wall thicknesses, and transparency are required.
摘要翻译： 提供了热塑性模塑组合物，其包含约80至98重量％的由二酚获得的聚碳酸酯，其平均重均分子量Mw为约10,000至200,000和约20至2重量％的聚酯碳酸酯， /或聚醚 - 碳酸酯，其平均重均分子量Mw为约50,000至300,000，其含有约50至70重量％的平均数均分子量Mn为约10,000的软聚酯链段或软聚醚链段 至20,000。 本发明还涉及一种生产所述热塑性模塑组合物的方法。 这些热塑性成型组合物与已知的聚碳酸酯相比显示出显着改善的回弹性能，并且可以在所有情况下用作膜和成型制品，一方面，在低温下的高缺口冲击强度，较高的壁厚度下的高韧性，以及 需要透明度。
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