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公开(公告)号：US4252922A
公开(公告)日：1981-02-24
申请号：US16457
申请日：1979-02-28
申请人： Siegfried Adelmann , Dieter Margotte , Werner Nouvertne , Manfred Schreckenberg , Frank Kleiner
发明人： Siegfried Adelmann , Dieter Margotte , Werner Nouvertne , Manfred Schreckenberg , Frank Kleiner
CPC分类号： C08L69/00 , C08G63/64 , C08G64/18 , C08G64/183
摘要： Thermoplastic molding compositions are provided comprising from about 80 to 98% by weight of a polycarbonate obtained from diphenols, having a mean weight-average molecular weight M.sub.w from about 10,000 to 200,000 and from about 20 to 2% by weight of a polyester-carbonate and/or polyether-carbonate with mean weight-average molecular weights M.sub.w of from about 50,000 to 300,000, which contain between about 50 and 70% by weight of soft polyester segments or soft polyether segments with mean number-average molecular weights M.sub.n of from about 10,000 to 20,000. The instant invention also relates to a process for the production of said thermoplastic molding compositions. These thermoplastic molding compositions show markedly improved resilience properties compared with known polycarbonates and can be employed as films and shaped articles in all cases where, on the one hand, high notched impact strength at low temperatures, high toughness properties at relatively high wall thicknesses, and transparency are required.
摘要翻译： 提供了热塑性模塑组合物，其包含约80至98重量％的由二酚获得的聚碳酸酯，其平均重均分子量Mw为约10,000至200,000和约20至2重量％的聚酯碳酸酯， /或聚醚 - 碳酸酯，其平均重均分子量Mw为约50,000至300,000，其含有约50至70重量％的平均数均分子量Mn为约10,000的软聚酯链段或软聚醚链段 至20,000。 本发明还涉及一种生产所述热塑性模塑组合物的方法。 这些热塑性成型组合物与已知的聚碳酸酯相比显示出显着改善的回弹性能，并且可以在所有情况下用作膜和成型制品，一方面，在低温下的高缺口冲击强度，较高的壁厚度下的高韧性，以及 需要透明度。
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2.发明授权
公开(公告)号：US4367186A
公开(公告)日：1983-01-04
申请号：US319532
申请日：1981-11-09
CPC分类号： C08J3/28 , C08G63/64 , C08G64/40 , C08L69/00 , C08J2369/00
摘要： This development is concerned with an improved process of preparing polycarbonate molding compositions and molded articles having superior hydrolysis resistance, stress crack resistance and flame retardancy, by thermoplastically processing a partially crosslinked aromatic polycarbonate. A crosslinkable aromatic thermoplastic polycarbonate is subject to irradiation to cause crosslinking on its surface such that between about 5 and 50 wt. % of the polymer is crosslinked and it is then thermoplastically processed. This partially crosslinked polycarbonate may be blended with uncrosslinked thermoplastic aromatic polycarbonate or known flame retardant agents. This development is also concerned with the compositions or articles so produced.
摘要翻译： 本发明涉及通过热塑性加工部分交联的芳族聚碳酸酯制备具有优异的耐水解性，抗应力开裂性和阻燃性的聚碳酸酯模塑组合物和模塑制品的改进方法。 可交联的芳族热塑性聚碳酸酯经受照射使其表面发生交联，使得约5至50重量％ 聚合物的％交联，然后进行热塑性加工。 该部分交联的聚碳酸酯可以与未交联的热塑性芳族聚碳酸酯或已知的阻燃剂共混。 这种发展也涉及如此生产的组合物或制品。
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3.发明授权Polycarbonates with alkylphenyl end groups, their preparation and their use 失效具有烷基苯基端基的聚碳酸酯，其制备及其用途
公开(公告)号：US4269964A
公开(公告)日：1981-05-26
申请号：US75439
申请日：1979-09-14
CPC分类号： C08G64/14
摘要： This development is concerned with aromatic thermoplastic polycarbonates with special chain terminators which give the polymers enhanced hydrolysis resistance and impact toughness. These chain terminators are alkyl substituted monohydroxy phenyls in which each phenyl is substituted by one alkyl group having 8 or 9 carbon atoms and about 47 to 89% of its hydrogen atoms trisubstituted on carbon atoms with up to about 20% of the substituents in the ortho position and the balance at the para position. This development is also concerned with a process for synthesizing such polymers by using such chain terminators as reactants in generically known synthesis methods for polycarbonates.
摘要翻译： 这种发展涉及具有特殊链终止剂的芳族热塑性聚碳酸酯，其赋予聚合物增强的耐水解性和冲击韧性。 这些链终止剂是烷基取代的单羟基苯基，其中每个苯基被一个具有8或9个碳原子的烷基取代，并且其在碳原子上三取代的氢原子的约47-89％，在邻位上具有高达约20％的取代基。 位置和对位的余额。 这种发展也涉及通过使用这种链终止剂作为一般已知的聚碳酸酯合成方法中的反应物合成这种聚合物的方法。
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4.发明授权
公开(公告)号：US4366276A
公开(公告)日：1982-12-28
申请号：US274387
申请日：1981-06-07
申请人： Dieter Freitag , Werner Nouvertne , Klaus Reinking , Peter Tacke , Frank Kleiner , Manfred Schmidt
发明人： Dieter Freitag , Werner Nouvertne , Klaus Reinking , Peter Tacke , Frank Kleiner , Manfred Schmidt
IPC分类号： C08G63/195 , C08G63/64 , C08K5/00 , C08K5/098 , C08K5/3417 , C08K5/42 , C08L67/00 , C08L69/00 , C08K3/16 , C08K5/34
CPC分类号： C08L67/00 , C08G63/195 , C08G63/64 , C08K5/0066 , C08K5/098 , C08K5/3417 , C08K5/42 , C08L69/00 , C08L69/005 , C08L27/18
摘要： Aromatic polyesters and polyestercarbonates based on diphenols and iso- and/or terephthalic acids become flame-proof if admixed with small quantities of ammonium or alkali metal salts of inorganic or organic acids and optionally halophthalimides and optionally polytetrafluoroethylene. The mechanical and chemical properties of the polyester (carbonates) remain unchanged.
摘要翻译： 如果与少量的无机或有机酸的铵或碱金属盐和任选的卤代邻苯二甲酰亚胺和任选的聚四氟乙烯混合，则基于二酚和异 - 和/或对苯二甲酸的芳族聚酯和聚酯碳酸酯变成阻燃的。 聚酯（碳酸酯）的机械和化学性质保持不变。
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5.发明授权
公开(公告)号：US4081495A
公开(公告)日：1978-03-28
申请号：US710070
申请日：1976-07-30
申请人： Dieter Freitag , Werner Nouvertne , Frank Kleiner
发明人： Dieter Freitag , Werner Nouvertne , Frank Kleiner
CPC分类号： C08L69/00
摘要： The invention relates to a thermoplastic moulding composition comprising an aromatic high-molecular weight polycarbonate based on a diphenol, with a weight-average molecular weight (M.sub.w) of at least 10,000 and from 0.5 to 5% by weight, relative to the high molecular weight polycarbonate, of a polycarbonate which has an M.sub.w of from 1,200 to 9,000 and which corresponds to the formula (I): ##STR1## wherein "E" represents a radical of the formula (II): ##STR2## in which THE GROUPS R' are identical and denote H or halogenx is an integer of from 7 to 24"Z" is a divalent aromatic radical, and"n", the degree of polymerization, results from the M.sub.w between 1,200 and 9,000.
摘要翻译： 本发明涉及一种热塑性模塑组合物，其包含相对于高分子量的基于二酚的芳族高分子量聚碳酸酯，其重均分子量（Mw）为至少10,000和0.5至5重量％ 聚碳酸酯，其具有1,200至9,000的Mw并且对应于式（I）的聚碳酸酯：其中“E”表示式（II）的基团：其中（I） 其中基团R'相同并且表示H或卤素X为7至24的整数“Z”为二价芳族基，“N”为聚合度，结果为1,200至9,000之间的Mw。
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6.发明授权
公开(公告)号：US4158538A
公开(公告)日：1979-06-19
申请号：US715078
申请日：1976-08-17
申请人： Frank Kleiner , Karl H. Muller
发明人： Frank Kleiner , Karl H. Muller
IPC分类号： B29C35/06 , B29C44/00 , B29C44/28 , B29C44/56 , B29C47/00 , B29C47/34 , B29C47/88 , B29D1/00 , B29K23/00 , B29D27/00
CPC分类号： B29C44/28 , B29C44/5636 , Y10S264/18
摘要： The invention relates to an apparatus for the continuous production of continuous plastics foam webs from extruded polyolefin webs containing peroxide and blowing agent by cross-linking on a perforated conveyor belt with subsequent foaming, suspended freely in space into a continuous heating furnace.
摘要翻译： 本发明涉及一种用于连续生产连续塑料泡沫纤维网的装置，该连续塑料泡沫纤维网由含有过氧化物和发泡剂的挤出聚烯烃纤维网经多孔输送带交联连续地随后发泡，在空间中自由悬浮在连续加热炉中。
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公开(公告)号：US4301212A
公开(公告)日：1981-11-17
申请号：US911740
申请日：1978-06-02
申请人： Wolfgang Cohnen , Frank Kleiner , Gerhard Kranz
发明人： Wolfgang Cohnen , Frank Kleiner , Gerhard Kranz
CPC分类号： B32B27/36 , C08J7/042 , C08J2369/00 , C08J2427/12 , C08J2433/06 , Y10T428/31507 , Y10T428/3154
摘要： The present invention relates to a clear and transparent, scratch-resistant and weather-resistant laminate of high impact strength, consisting of a polycarbonate layer which, on at least one of its surfaces, carries a polyacrylate coating which, on its outer surface, is coated with a scratch-resistant and weather-resistant covering of a hydroxylated fluoropolymer which is cross-linked with methylmelamine and/or polysilicic acid. The present invention also relates to a process for the production of said scratch-resistant laminate.
摘要翻译： 本发明涉及一种具有高冲击强度的透明和透明，耐刮擦和耐候的层压材料，其由聚碳酸酯层组成，聚碳酸酯层在其至少一个表面上承载聚丙烯酸酯涂层，其外表面为 涂覆有与甲基蜜胺和/或聚硅酸交联的羟基化含氟聚合物的耐刮擦和耐候性覆盖物。 本发明还涉及生产所述防刮层压板的方法。
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公开(公告)号：US4208489A
公开(公告)日：1980-06-17
申请号：US868145
申请日：1978-01-09
CPC分类号： C08K5/3417 , C08K3/00 , C08K5/34
摘要： Thermoplastic aromatic polycarbonate molding compositions with improved flame retardancy which contain an alkali metal salt of an organic or inorganic acid and optionally a perfluoroethylene, characterized in that they contain a tetrahalogenophthalimide of the general formulae (I) or (II) or mixtures thereof ##STR1## wherein R denotes a hydrogen atom or a C.sub.1 to C.sub.4 l alkyl, C.sub.6 H.sub.5, C.sub.10 H.sub.7, C.sub.6 H.sub.4 X, C.sub.6 H.sub.3 X.sub.2 or C.sub.6 H.sub.2 X.sub.3 group, in which X denotes a fluorine, chlorine or bromine atom, R' denotes a single bond or a C.sub.2 to C.sub.4 alkylene, C.sub.6 H.sub.4 or p-diphenylene radical, and Z denotes a chlorine or bromine atom,are provided.
摘要翻译： 具有改进的阻燃性的热塑性芳族聚碳酸酯模塑组合物，其包含有机或无机酸的碱金属盐和任选的全氟乙烯，其特征在于它们含有通式（I）或（II）的四卤代邻苯二甲酰亚胺或其混合物。 其中R表示氢原子或C1至C4烷基，C6H5，C10H7，C6H4X，C6H3X2或C6H2X3基团，其中X表示氟，氯或溴原子，R'表示单键或C2至C4亚烷基， C6H4或对二亚苯基，Z表示氯或溴原子。
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公开(公告)号：US3965053A
公开(公告)日：1976-06-22
申请号：US539800
申请日：1975-01-09
CPC分类号： C08J9/0028 , C08J9/10 , C08J2323/00 , C08J2323/02 , Y10S264/05 , Y10S264/13
摘要： A process for the continuous production of a foamed foil from a polymer based on an .alpha.,.beta.-monolefinically unsaturated monomer wherein 0.05 to 0.2 % by weight of a diamide obtained by reacting an aliphatic diamine and at least one aliphatic monocarboxylic acid having at least 4 carbon atoms is added to the solid or molten polymer in addition to the chemical blowing agent before or while the polymer is processed.
摘要翻译： 一种从基于α，β-单烯属不饱和单体的聚合物连续生产泡沫箔的方法，其中通过使脂族二胺和至少一种具有至少4个的脂族二羧酸的脂肪族单羧酸反应得到0.05至0.2重量％的二酰胺 在处理聚合物之前或之后，除了化学发泡剂之外，还将碳原子加入到固体或熔融聚合物中。
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公开(公告)号：US4954604A
公开(公告)日：1990-09-04
申请号：US238406
申请日：1988-08-31
CPC分类号： C08G65/4012 , C08G65/38 , C08G65/4093
摘要： The invention relates to a process for the production of high molecular weight, crystalline, aromatic polyether ketones showing high temperature stability, high resistance to the effect of chemicals and good mechanical properties.
摘要翻译： 本发明涉及一种生产高分子量，结晶，芳香族聚醚酮的方法，显示出高温稳定性，对化学品的作用具有很高的抗性和良好的机械性能。
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