公开(公告)号：US06884339B2

公开(公告)日：2005-04-26

申请号：US10018526

申请日：2001-04-20

申请人： Eric Benazzi ,  Pierre Marion ,  Alain Billon ,  Christophe Gueret ,  Jean-Claude Hipeaux ,  Jean Paul Gouzard

发明人： Eric Benazzi ,  Pierre Marion ,  Alain Billon ,  Christophe Gueret ,  Jean-Claude Hipeaux ,  Jean Paul Gouzard

IPC分类号： C10G45/08 ,  C10G45/50 ,  C10G45/52 ,  C10G45/62 ,  C10G45/64 ,  C10G47/20 ,  C10G65/08 ,  C10G65/12 ,  C10G67/04 ,  C10M101/02 ,  C10N70/00 ,  C10G69/02

CPC分类号： C10G65/12 ,  C10G2400/10

摘要： A process for the production of very high quality base oils optionally with simultaneous production of high quality middle distillates comprises the stages for hydrotreatment, preferably hydrocracking, on Y or beta zeolite, and atmospheric distillation. The effluent is subjected to a catalytic dewaxing on the ZSM-48 catalyst. The process then comprises a hydrofinishing stage for hydrogenating the aromatic compounds, preferably on a catalyst that comprises at least one noble metal of group VIII, chlorine and fluorine, and the stages of atmospheric and vacuum distillation. The hydrofinishing stage is conducted at a temperature lower by 20-200° C. than the catalytic dewaxing stage.

摘要翻译： 任选地同时生产高品质中间馏分的生产非常高质量的基础油的方法包括在Y或β沸石上进行加氢处理，优选加氢裂化的阶段和常压蒸馏。 流出物在ZSM-48催化剂上进行催化脱蜡。 该方法然后包括用于氢化芳族化合物的加氢精制阶段，优选在包含至少一种VIII族的贵金属，氯和氟的催化剂上，以及大气压和真空蒸馏阶段。 加氢精制阶段在比催化脱蜡阶段低20-200℃的温度下进行。

公开(公告)号：US20070108102A1

公开(公告)日：2007-05-17

申请号：US10584048

申请日：2004-12-13

申请人： Christophe Gueret ,  Raphael Huyghe ,  Hugues Dulot ,  Patrick Euzen

发明人： Christophe Gueret ,  Raphael Huyghe ,  Hugues Dulot ,  Patrick Euzen

IPC分类号： C10G7/00 ,  B01D3/00

CPC分类号： C10G21/14 ,  C10G47/00 ,  C10G67/049 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/301 ,  C10G2300/44

摘要： The invention relates to a process, including removal of resins, for the treatment of a hydrocarbon charge, at least 80% of the compounds of which have a boiling point which is above or equal to 340° C., in which process: the charge is sent to a fractionation stage during which the recovery takes place of at least one heavy fraction and at least one light fraction, at least some of the heavy fraction is sent to an extraction stage during which resins contained in said heavy fraction are extracted, and a purified fraction is recovered, a mixture is made which comprises at least part of the purified fraction which was obtained in the extraction stage and at least one light fraction which was obtained in the fractionation stage, and the mixture thus obtained is sent to a cracking stage. Drawing to be published.

摘要翻译： 本发明涉及一种方法，包括除去树脂，用于处理烃装料，其中至少80％的化合物具有高于或等于340℃的沸点，其中所述装料 送入分馏阶段，在此阶段，回收发生至少一个重馏分和至少一个轻馏分，至少部分重馏分被送至萃取阶段，在此阶段萃取所述重馏分中所含的树脂，以及 回收纯化的馏分，制备包含在萃取阶段获得的至少一部分纯化级分和在分馏阶段获得的至少一种轻馏分的混合物，将得到的混合物送入裂化 阶段。 绘图出版。

公开(公告)号：US20060289338A1

公开(公告)日：2006-12-28

申请号：US11449867

申请日：2006-06-09

申请人： Christophe Gueret ,  Thierry Chapus ,  Damien Hudebine

发明人： Christophe Gueret ,  Thierry Chapus ,  Damien Hudebine

IPC分类号： C10G57/00 ,  B01J8/18

CPC分类号： C10G69/04 ,  C10G11/18 ,  C10G47/00

摘要： The invention relates to a process for FCC pretreatment by mild hydrocracking of a hydrocarbon feedstock that comprises a vacuum distillate fraction or a deasphalted oil or else a mixture of these two fractions, said primary feedstock, to produce gas oil and an effluent having an initial boiling point of more than 320° C., said effluent (FCC feedstock) then being subjected to a catalytic cracking, process in which at least 85% by weight of said primary feedstock ends above 375° C. and at least 95% by weight of said primary feedstock ends below 650° C., whereby the mild hydrocracking is performed under an absolute pressure of 2 to 12 MPa and at a temperature of between 300 and 500° C., characterized in that the hydrocarbon feedstock also comprises a lighter hydrocarbon fraction, a so-called secondary feedstock, of which at least 50% by weight ends below 375° C. and at least 80% ends above 200° C.

摘要翻译： 本发明涉及通过烃原料的轻度加氢裂化来进行FCC预处理的方法，所述烃原料包括真空蒸馏馏分或脱沥青油，或者所述主要原料的这两个馏分的混合物，以产生瓦斯油和具有初始沸点的流出物 所述流出物（FCC原料）然后进行催化裂化，其中至少85重量％的所述主要原料在375℃以上终止，并且至少95重量％ 所述主要原料终止于650℃以下，由此在2至12MPa的绝对压力和300至500℃的温度下进行轻度加氢裂化，其特征在于，烃原料还包含较轻的烃馏分 ，所谓的二次原料，其中至少50重量％终止于375℃以下且至少80％在200℃以上结束。

公开(公告)号：US5770154A

公开(公告)日：1998-06-23

申请号：US578223

申请日：1995-12-26

申请人： Pierre Bigeard ,  Stephane Kressmann ,  Christophe Gueret ,  Pierre Galtier ,  Julia Magne-Drisch

发明人： Pierre Bigeard ,  Stephane Kressmann ,  Christophe Gueret ,  Pierre Galtier ,  Julia Magne-Drisch

IPC分类号： B01J8/02 ,  G01N31/10 ,  G01N35/00

CPC分类号： B01J8/0285 ,  G01N31/10 ,  B01J2208/00415 ,  B01J2219/00135

摘要： A device for testing the development of processes or chemical reactions in the presence of solid catalysts comprising a reactor of cylindrical shape, of inside diameter D and of length L, such that 50

摘要翻译： 在固体催化剂存在下测试方法或化学反应的发展的装置，其包括内径为D且长度为L的圆柱形反应器，使得50

公开(公告)号：US08002970B2

公开(公告)日：2011-08-23

申请号：US11722610

申请日：2005-12-13

申请人： Patrick Euzen ,  Patrick Bourges ,  Christophe Gueret ,  Carole Bobin ,  Alexandra Chaumonnot ,  Hugues Dulot

发明人： Patrick Euzen ,  Patrick Bourges ,  Christophe Gueret ,  Carole Bobin ,  Alexandra Chaumonnot ,  Hugues Dulot

IPC分类号： C10G47/00

CPC分类号： B01J37/0009 ,  B01J21/12 ,  B01J29/146 ,  B01J29/166 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/108 ,  B01J2229/20 ,  B01J2229/42 ,  C10G47/14 ,  C10G47/20 ,  C10G65/12 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/4018

摘要： The present invention concerns doped catalysts on a mixed zeolite/alumino-silicate support with a low macropore content, and hydrocracking/hydroconversion and hydrotreatment processes employing them. The catalyst comprises at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and group VIII of the periodic table and a doping element in a controlled quantity selected from phosphorus, boron and silicon, and a support based on zeolite Y defined by a lattice parameter a of the unit cell in the range 24.40×10−10 m to 24.15×10−10 m and silica-alumina containing a quantity of more than 5% by weight and 95% by weight or less of silica (SiO2).

摘要翻译： 本发明涉及具有低大孔含量的混合沸石/铝硅酸盐载体上的掺杂催化剂，以及使用它们的加氢裂化/加氢转化和加氢处理方法。 该催化剂包含至少一种选自由元素周期表第ⅥB族和第Ⅷ族元素形成的基团和选自磷，硼和硅的受控量的掺杂元素和基于沸石Y的载体的脱氢元素， 在24.40×10-10 m至24.15×10-10m范围内的晶胞的晶格参数a和含有多于5重量％和95重量％以下的二氧化硅（SiO 2）的二氧化硅 - 氧化铝， 。

公开(公告)号：US07655136B2

公开(公告)日：2010-02-02

申请号：US11475259

申请日：2006-06-27

申请人： Patrick Euzen ,  Christophe Gueret ,  Vincenzo Calemma

发明人： Patrick Euzen ,  Christophe Gueret ,  Vincenzo Calemma

IPC分类号： C10G11/02

CPC分类号： B01J21/12 ,  B01J23/24 ,  B01J23/40 ,  B01J23/42 ,  B01J23/74 ,  B01J23/85 ,  B01J27/1856 ,  B01J35/0066 ,  B01J35/0093 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/108 ,  C10G47/18 ,  C10G65/12 ,  C10G65/14 ,  C10G2400/04 ,  C10G2400/06

摘要： The invention concerns a process for producing middle distillates from a paraffinic feed produced by Fischer-Tropsch synthesis, using a hydrocracking/hydroisomerization catalyst which comprises: at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and group VIII of the periodic table; 0.01% to 6% of phosphorus as a doping element; and a non-zeolitic support based on mesoporous alumina-silica.

摘要翻译： 本发明涉及一种使用加氢裂化/加氢异构化催化剂由费 - 托合成生产的链烷烃进料生产中间馏分的方法，所述加氢裂化/加氢异构化催化剂包括：至少一种选自由周期性的VIB族和VIII族的元素形成的加氢元素 表; 0.01〜6％的磷作为掺杂元素; 和基于介孔氧化铝 - 二氧化硅的非沸石载体。

公开(公告)号：US07220349B2

公开(公告)日：2007-05-22

申请号：US10189759

申请日：2002-07-08

申请人： Eric Benazzi ,  Christophe Gueret

发明人： Eric Benazzi ,  Christophe Gueret

IPC分类号： C10G65/12

CPC分类号： C10G65/12 ,  C10G2300/1022 ,  C10G2300/301 ,  C10G2300/4081 ,  C10G2400/06 ,  C10G2400/08

摘要： The invention concerns a process for producing middle distillates from an effluent produced by a Fischer-Tropsch unit, comprising optional fractionation to obtain at least one heavy fraction with an initial boiling point in the range 120-200° C., said heavy fraction or said effluent optionally being hydrotreated, then bringing it into contact with a first amorphous hydrocracking/hydroisomerization catalyst that contains at least one noble group VIII metal, the effluent obtained is distilled, then the residual fraction boiling above the middle distillates and/or a portion of the middle distillates is brought into contact with a second amorphous hydrocracking/hydroisomerization catalyst containing at least one noble group VIII metal. The invention also concerns a unit.

摘要翻译： 本发明涉及从由费 - 托单元产生的流出物中生产中间馏分的方法，该方法包括任选的分馏以获得至少一种初馏点在120-200℃范围内的重馏分，所述重馏分或所述 流出物任选地进行加氢处理，然后使其与含有至少一种贵金属VIII族金属的第一无定形加氢裂化/加氢异构化催化剂接触，将所得流出物蒸馏，然后在中间馏分沸腾的残余馏分和/或部分 使中间馏分与含有至少一种贵金属VIII族金属的第二无定形加氢裂化/加氢异构化催化剂接触。 本发明还涉及一个单元。

公开(公告)号：US07156978B2

公开(公告)日：2007-01-02

申请号：US10189793

申请日：2002-07-08

申请人： Eric Benazzi ,  Christophe Gueret

发明人： Eric Benazzi ,  Christophe Gueret

IPC分类号： C10G49/02 ,  C10G47/02 ,  C10G69/14

CPC分类号： C10G65/00 ,  C10G45/62 ,  C10G47/14 ,  C10G65/14 ,  C10G69/14 ,  C10G2300/1022 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2300/4081 ,  C10G2400/04 ,  C10G2400/06 ,  C10G2400/08 ,  Y10S208/95

摘要： A system comprising: a paraffin feed produced by the Fischer-Tropsch process is fractionable into at least three fractions: an intermediate fraction boiling between T1 and T2, T1 being in the range 120–200° C. and T2 being more than 300° C. and less than 410° C., a light fraction boiling below it and a heavy fraction boiling above it; at least a portion of the intermediate fraction is hydrotreated then at least a portion thereof is passed over an amorphous hydroisomerisation/hydrocracking catalyst; the heavy fraction is passed over an amorphous hydroisomerisation/hydrocracking catalyst with a conversion of 370° C.+ products into 370° C.− products of more than 80% by weight; the hydrocracked/hydroisomerised fractions are distilled to obtain middle distillates (kerosine, gas oil).

摘要翻译： 一种系统，包括：通过费 - 托法生产的链烷烃进料可分馏成至少三个馏分：在T 1和T 2之间沸腾的中间馏分，T 1在120-200℃范围内，T 2更多 低于300℃，低于410℃，在其下方沸腾的轻馏分和在其上沸腾的重馏分; 将至少一部分中间馏分进行加氢处理，然后将其至少一部分通过无定形加氢异构化/加氢裂化催化剂; 将重馏分通过无定形加氢异构化/加氢裂化催化剂，转化率为370℃+产物至370℃，产率大于80％; 将加氢裂化/加氢异构化馏分蒸馏得到中间馏分（煤油，瓦斯油）。

公开(公告)号：US20060070915A1

公开(公告)日：2006-04-06

申请号：US11221416

申请日：2005-09-08

申请人： Patrick Euzen ,  Alexandra Chaumonnot ,  Carole Bobin ,  Patrick Bourges ,  Christophe Gueret ,  Hugues Dulot

发明人： Patrick Euzen ,  Alexandra Chaumonnot ,  Carole Bobin ,  Patrick Bourges ,  Christophe Gueret ,  Hugues Dulot

IPC分类号： B01J21/12 ,  B01J27/187 ,  B01J21/02 ,  B01J27/182 ,  C10G47/02

CPC分类号： B01J37/28 ,  B01J21/02 ,  B01J21/12 ,  B01J23/74 ,  B01J23/85 ,  B01J23/883 ,  B01J23/8877 ,  B01J23/888 ,  B01J23/8885 ,  B01J23/8993 ,  B01J27/188 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0201 ,  B01J37/03 ,  B01J37/10 ,  B01J37/20 ,  B01J37/30 ,  C10G49/04 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  C10G2300/4018

摘要： This invention relates to doped catalysts on an aluminosilicate substrate with a low content of macropores and the hydrocracking/hydroconversion and hydrotreatment processes that use them. The catalyst comprises at least one hydro-dehydrogenating element that is selected from the group that is formed by the elements of group VIB and group VIII of the periodic table and a dopant in a controlled quantity that is selected from among phosphorus, boron, and silicon and a non-zeolitic substrate with a silica-alumina base that contains a quantity of more than 15% by weight and of less than or equal to 95% by weight of silica (SiO2).

摘要翻译： 本发明涉及具有低含量大孔的铝硅酸盐底物上的掺杂催化剂和使用它们的加氢裂化/加氢转化和加氢处理方法。 催化剂包含至少一种选自由元素周期表VIB族和VIII族的元素形成的基团和选自磷，硼和硅中的受控量的掺杂剂的氢脱氢元素 以及含有大于15重量％且小于或等于95重量％的二氧化硅（SiO 2）的量的二氧化硅 - 氧化铝基底的非沸石基材。

公开(公告)号：US20100065475A1

公开(公告)日：2010-03-18

申请号：US12558968

申请日：2009-09-14

申请人： Christophe Gueret ,  Vincent Mayeur

发明人： Christophe Gueret ,  Vincent Mayeur

IPC分类号： C10G69/04 ,  B01J8/18

CPC分类号： C10G47/02 ,  C10G3/46 ,  C10G3/50 ,  C10G69/04 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1074 ,  C10G2300/202 ,  C10G2300/301 ,  C10G2300/4081 ,  C10G2400/04 ,  Y02E50/13 ,  Y02P30/20

摘要： Process for FCC pretreatment by mild hydrocracking including diluting the feedstock with a feedstock of biological origin The invention relates to a process which comprises the stages consisting in carrying out a mild hydrocracking, implemented under a pressure of 20 to 120 bar and at a temperature of between 300 and 500° C., on a hydrocarbon feedstock comprising or consisting of a feedstock of petroleum origin, comprising or consisting of a vacuum distillate fraction and/or a deasphalted oil, at least 85% by weight of which boils above 370° C., and a feedstock of biological origin comprising components of vegetable oil and/or animal fat type, in order to produce gas oil and an effluent having an initial boiling point of greater than 330° C. within the meaning of the simulated distillation according to standard ASTM D2287, and carrying out a catalytic cracking (FCC) of a composition comprising or consisting of said effluent, and to a plant which makes it possible to carry out this process.

摘要翻译： 通过轻度加氢裂化进行FCC预处理的方法，包括用原料原料稀释原料本发明涉及一种方法，其包括在20至120巴的压力下和在20至120巴之间的温度下进行的温和加氢裂化 300和500℃，包含或由石油来源的原料组成的烃原料，其包含或由其中至少85重量％沸腾至370℃以上的真空馏分馏分和/或脱沥青油组成。 ，以及包含植物油和/或动物脂肪型成分的生物来源的原料，以便产生瓦斯油和根据标准的模拟蒸馏含义的初始沸点大于330℃的流出物 ASTM D2287，并且进行包含或由所述流出物组成的组合物的催化裂化（FCC），以及使得可以执行该p 加油