摘要:
The invention relates to a process for preparing crosslinkable polymers containing silane groups having at least one hydrolyzable radical by free-radical-initiated grafting of the base polymers with an olefinically unsaturated silane having at least one hydrolyzable radical, wherein the grafting is carried out in the presence of (a) an alkylsilane of the formula I, R1(SiR2nX3−n)m, (I) where R1 is a monovalent hydrocarbon radical having from 1 to 33 carbon atoms or a divalent hydrocarbon radical having from 4 to 24 carbon atoms, R2 is a hydrocarbon radical having from 1 to 10 carbon atoms, X are identical or different hydrolyzable radicals, n is 0, 1 or 2 and m is 1 or 2 and/or (b) a fluoroalkylsilane of the formula R3xSiR4yXz, (II) where R3 is a fluoroalkyl radical, R4 is an alkyl radical and X is a hydrolyzable radical, x is an integer from 1 to 3, y is 0, 1 or 2 and z is an integer from 1 to 3, with the proviso that the sum x+y+z=4.
摘要翻译:本发明涉及制备具有至少一个可水解基团的可交联聚合物的交联聚合物的方法,所述硅烷基团具有至少一个可水解基团的烯属不饱和硅烷通过自由基引发接枝基础聚合物,其中接枝在 存在(a)式I的烷基硅烷,其中R 1是具有1至33个碳原子的一价烃基或具有4至24个碳原子的二价烃基,R 2是具有1至10个碳原子的烃基 X为相同或不同的可水解基团,n为0,1或2,m为1或2,和/或(b)下式的氟代烷基硅烷,其中R 3为氟代烷基,R 4为烷基,X为可水解基团,x为 是1至3的整数,y是0,1或2,z是1至3的整数,条件是和x + y + z = 4。
摘要:
An aqueous organopolysiloxane-containing composition comprising organopolysiloxanes of formula I: HO [Si(A)(CH3)z(OH)1−zO]a[Si(B)(R2)y(OH)1−yO]b[Si(C)(CH3)O]c[Si(D)(OH)O]dH.(HX)e (I), wherein A is an aminoalkyl group of formula II: H2N (CH2)f(NH)g(CH2)hSi(OR)3−z(CH3)z (II), in which 0≦f≦6, g=0 if f=0 and g=1 if f>0, 0≦h≦6 and 0≦z≦1; B is a fluoroalkyl group of formula III: R1—Y—(CH2)2Si(R2)Y(OR)3−y (III) wherein R1 is a mono-, oligo- or perfluorinated alkyl group having 1-9 C atoms, or a mono-, oligo- or perfluorinated aryl group, Y is a CH2, O or S group, R2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0≦y≦1; C is an alkyl group of formula IV: R3—Si(CH3)(OR)2 (IV), and D is an alkyl group of formula V: R3—Si(OR)3 (V) wherein R3, in each case is identical or different, and is a linear, branched or cyclic alkyl group having 1-8 C atoms, and R, in each case is identical or different, and is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group; and HX is an acid, in which X is an inorganic or organic acid radical, and 0≦y≦1, 0≦z≦1, a>0, b>0, c≧0, d≧0, e≧0 and (a+b+c+d)≧2, the composition being essentially free from organic solvents, having a flash point of more than 70° C. and liberating essentially no alcohols by hydrolysis on dilution with water.
摘要翻译:含有机聚硅氧烷的组合物包含式I的有机聚硅氧烷:其中A是式II的氨基烷基:其中0≤f≤6,如果f = 0,则g = 0,如果f> 0,则g = = h <= 6且0 <= z <= 1; B是式III的氟烷基:其中R1是具有1-9个C原子的单,低聚或全氟化烷基,或单 - 或全氟化芳基,Y为CH 2,O或S基团,R 2为具有1-8个碳原子或芳基且0 <= y <1的直链,支链或环状烷基; C为 式Ⅳ:和D是式Ⅴ的烷基:其中R 3在每种情况下是相同或不同的,并且是具有1-8个C原子的直链,支链或环状的烷基,R在每种情况下是相同的或 不同的是具有1-8个碳原子或芳基的直链,支链或环状的烷基; HX是酸,其中X是无机或有机酸基,0 <= y <= 1,0 <= z <= 1,a> 0,b> 0,c> = 0,d> = 0,e> = 0,(a + b + c + d)> = 2, 有机溶剂,闪点高于70℃,在用水稀释时通过水解基本上不释放醇。
摘要:
A mixture of oligomers of alkylalkoxysilanes condensed in the chain and/or cyclic form, said mixture of oligomers containing less than 2% by weight of free alcohols and the condensed alkoxysilanes satisfying formula I: ##STR1## wherein R is an alkyl group having 3 to 18 carbon atoms, and each R' is a member (i) selected from the group consisting of methyl, ethyl or hydrogen, or is (ii) methyl or hydrogen, or is (iii) ethyl or hydrogen, the degree of oligomerization being in the range 2.ltoreq.x.ltoreq.20 and the quotient of the molar ratio �Si/alkoxy group!.gtoreq.1; and/orsatisfying formula II: ##STR2## in which R is an alkyl group having 3 to 18 carbon atoms, and each R' is a member (i) selected from the group consisting of methyl, ethyl or hydrogen, or is (ii) methyl or hydrogen or is (iii) ethyl or hydrogen, the degree of oligomerization being x.gtoreq.3 and the quotient of the molar ratio �Si/alkoxy group!.gtoreq.1.
摘要:
The invention relates to an agent for providing substrates based on cellulose and/or starch with water-repellent and simultaneously antifungal, antibacterial, insect-repellent and antialgal properties, which contains water and, as active substance, at least one linear, cyclic, branched or crosslinked co-oligomer or mixtures of co-oligomers from the series consisting of the alkyl-/aminoalkyl-/alkoxy- or hydroxy-siloxanes, the use of such agents and a special treatment process using such agents.
摘要:
The present invention relates to composite materials based on (a) at least one cellulose- or lignocellulose-containing material and (b) at least one aminoalkylsilane of the formula (I) R1R2N(CHR4)aSi(R3)r(OR)3-r (I), in which groups R1 and R2 are identical or different and in each case are H or a linear, branched or cyclic C1- to C20-alkyl group or an aryl group or an aminocarbyl group, it being possible for groups R1 and R2 to be optionally substituted, groups R4 are identical or different and R is H or methyl, a is from 1 to 10, R3 is H or a linear or branched C1- to C8-alkyl group, groups R are identical or different and R is H or a linear or branched C1- to C8-alkyl group and r is 0 or 1 or 2, or at least one cocondensate of at least one aminoalkylsilane of the general formula (I) and at least one further functional silane of the general formula (II) R7(CHR6)bSi(R5)p(OR)3-p (II), in which R7 is H or a vinyl group or an amino group or a glycidyloxy group or an acryloyloxy group or a methacryloyloxy group or a mercapto group or a sulfane group or a linear or branched C1- to C20-alkyl group or an aryl group, it being possible for the group R7 to be optionally substituted, groups R6 are identical or different and R6 is H or methyl, b is from 0 to 18, R5 is H or a linear or branched C1- to C8-alkyl group, groups R are identical or different and R is H or a linear or branched C1- to C8-alkyl group and p is 0 or 1 or 2, it being possible for the amino functions in the cocondensate to be partly or completely neutralized with an inorganic or organic acid, or an aqueous solution which contains at least one aminoalkylsilane of the formula (I) or at least one cocondensate based on at least one aminoalkylsilane of the general formula (I) and at least one further functional silane of the general formula (II), as a binder, such composite materials being obtainable by—treating dried or moist cellulose- or lignocellulose-containing material with—a liquid which contains at least one aminosilane compound according to the formula (I) or at least one cocondensate based on at >least one aminoalkylsilane of the general formula (I) and at least one further functional silane of the general formula (II),—bringing the cellulose or lignocellulose material thus treated into a desired form and then hot-pressing it. The present invention furthermore relates to a corresponding process for the production of composite materials and the use of aminosilane compounds according to the formula (I) or at least one cocondensate based on at least one aminoalkylsilane of the general formula (I) and at least one further functional silane of the general formula (II) as a binder for producing wood-based materials.
摘要:
The present invention relates to a composite material based on (a) a cellulose- or lignocellulose-containing material and (b) a composite as a binder, the composite resulting from the reaction of at least the components (i) a glycidyloxypropylalkoxysilane, (ii) an aqueous silica sol having a solids content of >20% by weight, (iii) an organic acid as a hydrolysis catalyst and (iv) n-propyl zirconate, butyl titanate or titanium acetylacetonate as a crosslinking agent. The present invention furthermore relates to a process for the production of said composite materials and the use of a composite (b) as a binder for the production of wood-based materials.
摘要:
The present invention relates to a binder for composite materials comprising cellulose- or lignocellulose-containing materials, which is based on the components (i) at least one binder from the series consisting of organic resins, isocyanates, natural or near-natural binders and (ii) at least one composition based on an aminoalkylsilane. The invention furthermore relates to a composite material which is at least based on a cellulose- or lignocellulose-containing material and the abovementioned binder, a process for the production of such a composite material and the use of the binder system according to the invention for the production of wood-based materials.
摘要:
The present invention provides a composition based on the reaction at least of the following components: (i) a glycidyloxypropylalkoxysilane, (ii) an aqueous silica sol having an SiO2 content of >20% by weight, (iii) an organic acid hydrolysis catalyst, and (iv) n-propyl zirconate, butyl titanate or titanium acetylacetonate as crosslinker, a process for its preparation, and the use thereof, particularly as a composition for scratch resistant coatings, and also provides articles thus coated.
摘要:
A composition comprising at least one organofluorine-functional silane and/or siloxane, at least one mineral acid and at least one metal salt of aluminum(III), tin(II), tin(IV), iron(III) or titanium(III); a process for preparing said composition and to its use; and surface-modified substrates obtainable by coating with said composition.
摘要:
The present invention relates to a stable composition of water-soluble organosiloxanes obtained by reacting a) a water-soluble amino-functional alkoxysilane with at least one water-insoluble alkenyl-functional alkoxysilane b) by adding water to form a mixture, and c) removing the alcohol formed during step b) from the mixture, where the amino-functional alkoxysilane and the water are used in the reaction at least in amounts such that substantially all of the alkoxy groups of the water-insoluble silane can react and such that when a resulting composition is diluted with water, essentially no alcohol is liberated by hydrolysis, and the composition, during an/or after the reaction, has a pH of from 2 to 6, the pH being preferably adjusted by adding an organic or inorganic, optionally aqueous, acid. In addition, the present invention discloses a process for the preparation of such a composition and also its use.