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公开(公告)号：US4696703A
公开(公告)日：1987-09-29
申请号：US755247
申请日：1985-07-15
CPC分类号： C22C45/006
摘要： An amorphous metal alloy composition exhibiting corrosion resistance in acidic environments of the formula:Cr.sub.a M.sub.b B.sub.c C.sub.d R.sub.ewhereinM is at least one metal selected from the group consisting of Mo, W, Nb and Ta;R is at least one element selected from the group consisting of N, P, As, S and Se; andwhereina ranges from about greater than 0.4 to about 0.6;b ranges from about 0.15 to about less than 0.4; andc ranges from zero to about 0.16.d ranges from zero to about 0.2; ande ranges from zero to about 0.3;with the proviso that the sum of (c+d+e) ranges from about 0.04 to about 0.35.
摘要翻译： 一种在酸性环境中具有耐腐蚀性的无定形金属合金组合物，其结构式如下：CraMbBcCdRe其中M是选自Mo，W，Nb和Ta中的至少一种金属; R是选自N，P，As，S和Se中的至少一种元素; 并且其中a在约大于0.4至约0.6的范围内; b在约0.15至约小于0.4的范围内; c范围从零到大约0.16。 d范围从零到约0.2; e范围从0到约0.3; 条件是（c + d + e）的和为约0.04至约0.35。
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公开(公告)号：US4604244A
公开(公告)日：1986-08-05
申请号：US603257
申请日：1984-04-23
IPC分类号： C07C120/00 , C07C120/14 , C07C121/30
CPC分类号： C07C255/00
摘要： Disclosed is the reaction of propylene with acrylonitrile or acrylamide to make a cyano- or amidopentene and reacting that compound with NH.sub.3 and O.sub.2 to form mucononitrile or 5-cyano-2,4-pentadiene amide. Also disclosed is a process which comprises contacting a reactant of the formula H--(CH.sub.2).sub.a --(CH.dbd.CH)--(CH.sub.2).sub.b X with oxygen and ammonia to thereby form a product of the formula NC--CH.dbd.CH--CH.dbd.CH--X wherein X is --CN or --CONH.sub.2 and each of a and b are zero or an integer from 1 to 3 such that a+b=3.
摘要翻译： 公开了丙烯与丙烯腈或丙烯酰胺反应以制备氰基或酰胺基戊烯，并使该化合物与NH 3和O 2反应形成粘腈或5-氰基-2,4-戊二烯酰胺。 还公开了一种方法，其包括使式H-（CH 2）a - （CH = CH） - （CH 2）b X的反应物与氧和氨接触，从而形成式NC-CH = CH-CH = CH-X，其中X是-CN或-CONH 2，a和b各自为0或1至3的整数，使得+ b = 3。
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23.发明授权Amorphous metal alloy compositions and synthesis of same by solid state incorporation/reduction reactions 失效无定形金属合金组成及其通过固态掺入/还原反应的合成
公开(公告)号：US4585617A
公开(公告)日：1986-04-29
申请号：US751704
申请日：1985-07-03
摘要： Amorphous metal alloy compositions are synthesized by solid state incorporation/reduction reactions wherein a high-surface area support is brought in contact with a precursor metal-bearing compound in such a manner that the compound is incorporated into the support or caused to deposit metal onto the surface of the support. The composition obtained is an amorphous alloy composition or can be made so by heat treating at a temperature below the crystallization temperature of the amorphous metal alloy desired to be formed.
摘要翻译： 无定形金属合金组合物通过固态掺入/还原反应合成，其中高表面积载体与含前体金属的化合物接触，使得化合物被引入载体中或使金属沉积到 表面的支撑。 获得的组合物是非晶合金组合物，或者可以通过在低于期望形成的非晶态金属合金的结晶温度的温度下进行热处理而制成。
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公开(公告)号：US4503001A
公开(公告)日：1985-03-05
申请号：US373904
申请日：1982-05-03
IPC分类号： B01J23/887 , B01J27/186 , C07C120/14
CPC分类号： C07C253/26 , B01J23/8876 , B01J27/186 , Y02P20/52
摘要： Monoolefins such as propylene and isobutylene are converted to the corresponding unsaturated nitriles, acrylonitrile and methacrylonitrile, respectively, by reacting a mixture of the olefin, ammonia, and a molecular oxygen-containing gas in the presence of a catalyst containing the oxides of iron, bismuth, molybdenum, and cobalt or nickel or both, and optionally an oxide of at least one element selected from the group consisting of the alkali metals, rare earth metals, tantalum and niobium, and optionally one or more of the oxides of the elements selected from the group consisting of phosphorus and arsenic.
摘要翻译： 通过使烯烃，氨和含分子氧气体的混合物在含铁氧化物，铋的催化剂存在下，分别将丙烯和异丁烯等单烯烃转化为相应的不饱和腈，丙烯腈和甲基丙烯腈 ，钼和钴或镍或两者，以及任选的选自碱金属，稀土金属，钽和铌中的至少一种元素的氧化物，以及任选的一种或多种选自以下的元素的氧化物： 由磷和砷组成的组。
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公开(公告)号：US4473506A
公开(公告)日：1984-09-25
申请号：US434794
申请日：1982-10-18
IPC分类号： B01J27/057 , C07C120/14 , C07C5/32 , C07C51/21
CPC分类号： C07C253/26 , B01J27/0576 , B01J2523/00 , Y02P20/52 , Y02P20/582
摘要： Oxide complex catalysts of iron, selenium and tellurium provide good yields of acrylonitrile in the ammoxidation of propylene with high selectivities at low temperature.
摘要翻译： 铁，硒和碲的氧化物复合催化剂在低温下具有高选择性的丙烯的氨氧化作用提供了良好的丙烯腈收率。
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公开(公告)号：US4377534A
公开(公告)日：1983-03-22
申请号：US293822
申请日：1981-08-17
IPC分类号： B01J23/88 , B01J23/887 , B01J23/89 , C07C120/14
CPC分类号： B01J23/8873 , B01J23/8871 , B01J23/8872 , B01J23/8876 , B01J23/8993 , C07C253/26 , Y02P20/52
摘要： Catalysts containing iron, molybdenum, bismuth and nickel, cobalt, magnesium, zinc, cadmium, calcium or beryllium have been found to give especially large volumes of acrylonitrile or methacrylonitrile in a given time when manganese, antimony, thorium, zirconium, yttrium or mixtures thereof are incorporated into the catalyst.
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公开(公告)号：US4342698A
公开(公告)日：1982-08-03
申请号：US53607
申请日：1979-06-29
IPC分类号： B01J23/00 , B01J23/16 , B01J23/18 , B01J23/68 , B01J23/76 , B01J23/89 , B01J27/00 , B01J27/057 , B01J27/18 , B01J27/186 , C07B61/00 , C07D307/36 , C07D307/46 , C07D307/48 , C07D307/54
CPC分类号： B01J27/186 , B01J23/18 , B01J23/68 , B01J23/76 , B01J23/8933 , B01J27/0573 , B01J27/0576 , C07D307/36
摘要： Oxole compounds, e.g. furan, are produced by contacting alkenes and/or alkadienes with molecular oxygen in the presence of an antimony catalyst.
摘要翻译： 氧化物化合物，例如 呋喃通过在锑催化剂存在下使烯烃和/或链烯二烯与分子氧接触来制备。
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公开(公告)号：US4309361A
公开(公告)日：1982-01-05
申请号：US108324
申请日：1979-12-28
IPC分类号： B01J23/84 , B01J27/057 , B01J27/186 , C07C45/34 , C07C120/14
CPC分类号： C07C253/26 , B01J23/84 , B01J27/0576 , B01J27/186 , C07C45/34 , B01J2523/00 , Y02P20/52
摘要： Oxide complex catalysts comprising Fe-Sb-Bi-O.sub.x promoted with a wide variety of different elements have been found to be especially useful in the ammoxidation of olefins to nitriles such as acrylonitrile and methacrylonitrile. Not only are the desired nitriles obtained with high yields when these catalysts are used, but also the production of unwanted liquid byproducts such as acrolein, acrylic acid and acetonitrile is significantly reduced.
摘要翻译： 已经发现含有各种不同元素促进的包含Fe-Sb-Bi-Ox的氧化物复合催化剂特别可用于将烯烃氧化成腈类，如丙烯腈和甲基丙烯腈。 当使用这些催化剂时，不仅以高产率获得所需的腈，而且显着降低了不需要的液体副产物如丙烯醛，丙烯酸和乙腈的产生。
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公开(公告)号：US4176234A
公开(公告)日：1979-11-27
申请号：US800980
申请日：1977-05-26
IPC分类号： B01J23/887 , B01J27/192 , C07C51/25 , C07C45/04 , C07C51/32 , C07C57/04
CPC分类号： C07C45/35 , B01J23/8876 , B01J27/192 , C07C51/252 , B01J2523/00
摘要： The process comprises the vapor phase oxidation of lower molecular weight olefins to the corresponding unsaturated aldehydes and unsaturated carboxylic acids in the presence of a catalyst comprising the oxides of iron, bismuth, molybdenum and at least one element of the Group II elements as essential components, and optionally the oxides of phosphorus, arsenic and an alkali metal.
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公开(公告)号：US4065468A
公开(公告)日：1977-12-27
申请号：US685879
申请日：1976-05-12
IPC分类号： B01J23/24 , B01J23/88 , B01J27/057 , B01J27/186 , C07C51/215 , C07D307/60
CPC分类号： B01J23/8876 , B01J23/24 , B01J23/8877 , B01J23/8878 , B01J27/0576 , B01J27/186 , C07C51/215 , B01J2523/00
摘要： Maleic anhydride is produced by the reaction of n-butane with a molecular oxygen-containing gas at an elevated temperature in the presence of a catalyst composed of the combined oxides of the elements antimony, molybdenum and at least one member selected from the group consisting of iron and vanadium and optionally one or more oxides of aluminum, boron, tellurium, chromium, cobalt, nickel, copper, bismuth, phosphorus titanium and tungsten.
摘要翻译： 马来酸酐通过正丁烷与含分子氧的气体在升高的温度下在催化剂存在下反应生成，所述催化剂由元素锑，钼和至少一种选自以下的组分的组成的催化剂组成： 铁和钒以及任选的一种或多种铝，硼，碲，铬，钴，镍，铜，铋，磷钛和钨的氧化物。
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