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    Copper beryllium-containing catalysts for the production of alcohols
    1.
    发明授权
    Copper beryllium-containing catalysts for the production of alcohols 失效
    用于生产醇的含铜铍催化剂

    公开(公告)号：US4616000A

    公开(公告)日：1986-10-07

    申请号：US763868

    申请日：1985-08-09

    申请人： Terry J. Mazanec ,  John G. Frye, Jr. ,  Harley F. Hardman

    发明人： Terry J. Mazanec ,  John G. Frye, Jr. ,  Harley F. Hardman

    IPC分类号： B01J23/76 ,  B01J23/78 ,  B01J23/89 ,  C07C29/154 ,  B01J23/02 ,  B01J23/72

    CPC分类号： C07C29/154 ,  B01J23/76 ,  B01J23/78 ,  B01J23/8946 ,  Y02P20/52

    摘要： A ruthenium-free catalyst suitable for the conversion of carbon monoxide and hydrogen to alcohols, particularly methanol, comprises a mixture of metal oxides of the metals copper and beryllium where the atomic ratio of copper to beryllium is from about 0.01 to 1 to 20.0 to 1. A further metal M such as Th or Al may also be present, the atomic ratio of the metal M to beryllium being from about 0.1 to 1 to 7.5 to 1.The catalyst can be employed as convert carbon monoxide and hydrogen at elevated temperature and pressure, for example 100.degree. to 500.degree. C. and 150 to 4000 psig, to a product rich in alcohols and low in acids and hydrocarbons.

    摘要翻译： 适用于将一氧化碳和氢转化为醇，特别是甲醇的无钌催化剂包括金属铜和铍的金属氧化物的混合物，其中铜与铍的原子比为约0.01至1至20.0至1 还可以存在另外的金属M，例如Th或Al，金属M与铍的原子比为约0.1至1至7.5:1。该催化剂可用作在升高的温度下转化一氧化碳和氢气， 压力，例如100至500℃和150至4000磅/平方英寸，富含醇的产物和酸和碳氢化合物低。

    Continuous process for the extraction and esterification of carboxylic acid
    4.
    发明授权
    Continuous process for the extraction and esterification of carboxylic acid 失效
    连续提取和酯化羧酸的方法

    公开(公告)号：US4458088A

    公开(公告)日：1984-07-03

    申请号：US364387

    申请日：1982-04-01

    申请人： Harley F. Hardman ,  John G. Frye, Jr. ,  Terry J. Mazanec

    发明人： Harley F. Hardman ,  John G. Frye, Jr. ,  Terry J. Mazanec

    IPC分类号： C07C67/10

    CPC分类号： C07C67/08 ,  C07C67/10 ,  Y02P20/582

    摘要： A continuous process for the production of alkyl esters from carboxylic acids wherein an aqueous stream containing a first carboxylic acid, RCO.sub.2 H, is contacted with an organic stream comprising a carboxylic acid ester, R"CO.sub.2 R', so that the organic stream is enriched with RCO.sub.2 H. The RCO.sub.2 H enriched organic stream is separated from the aqueous stream and is contacted with a catalyst to obtain a second carboxylic acid, R"CO.sub.2 H, and a product carboxylic acid ester, RCO.sub.2 R'. The product ester, RCO.sub.2 R', is separated from the second acid, R"CO.sub.2 H, the reactant ester, R"CO.sub.2 R', and the first acid, RCO.sub.2 H, and the second acid, R"CO.sub.2 H, is esterified to obtain the reactant ester, R"CO.sub.2 R', which is recycled to the initial part of the process. In this process R is aliphatic or aromatic, R' is alkyl and R" is aliphatic with at least about 4 carbon atoms. When the reactant ester is a bifunctional polymer having both sulfonic acid and R' carboxylic acid ester pendant functional groups, this process may be performed in the absence of a catalyst.

    摘要翻译： 用于从羧酸生产烷基酯的连续方法，其中含有第一羧酸RCO 2 H的水流与包含羧酸酯R'CO 2 R'的有机物流接触，使得有机物流富含 RCO2H。 将富含RCO 2 H的有机物流与水流分离，并与催化剂接触，得到第二种羧酸R'CO 2 H和产物羧酸酯RCO 2 R'。 将产物酯RCO 2 R'与第二酸R'CO 2 H，反应物酯R'CO 2 R'和第一酸RCO 2 H和第二酸R'CO 2 H分离，得到 反应物酯R'CO 2 R'，其被再循环到该方法的初始部分。 在该方法中，R为脂族或芳族，R'为烷基，R“为具有至少约4个碳原子的脂族基。 当反应物酯是具有磺酸和R'羧酸酯侧链官能团的双功能聚合物时，该方法可以在不存在催化剂的情况下进行。

    Alcohol compositions for blending with gasoline
    9.
    发明授权
    Alcohol compositions for blending with gasoline 失效
    用于与汽油混合的酒精组合物

    公开(公告)号：US4705532A

    公开(公告)日：1987-11-10

    申请号：US9105

    申请日：1987-01-30

    申请人： Terry J. Mazanec ,  John G. Frye, Jr. ,  Harley F. Hardman

    发明人： Terry J. Mazanec ,  John G. Frye, Jr. ,  Harley F. Hardman

    IPC分类号： C07C29/154 ,  C10L1/02

    CPC分类号： C10L1/023 ,  C07C29/154

    摘要： An alcohol composition suitable for mixing with gasoline comprises at least 30 percent by weight of methanol, the remainder of said composition comprising higher alcohols the distribution of which on a methanol-free basis isC.sub.2 --about 10 to 90 weight percent,C.sub.3 --about 15 to 60 weight percent,C.sub.4 --about 0.5 to 35 weight percent,C.sub.5 --about 0 to 15 weight percent,C.sub.6 --about 0 to 15 weight percent,and wherein the percent of C.sub.3 is equal to or greater than 1.25 times the percent of C.sub.4.The alcohol composition can be prepared from hydrogen and carbon monoxide under alcohol forming conditions in the presence of a catalyst containing copper and uranium and alkali or alkaline earth metal.

    摘要翻译： 适用于与汽油混合的醇组合物包含至少30重量％的甲醇，所述组合物的其余部分包含高级醇，其在无甲醇的基础上的分布为约2-约10-90重量％，约C3-约15 至60重量％，C 4约0.5至35重量％，C 5约0至15重量％，C 6约0至15重量％，并且其中C 3的百分比等于或大于C 4的百分比的1.25倍 。 醇组合物可以在含有铜和铀和碱金属或碱土金属的催化剂存在下，在醇形成条件下由氢气和一氧化碳制备。

    Process for the manufacture of acrylonitrile and methacrylonitrile
    10.
    发明授权
    Process for the manufacture of acrylonitrile and methacrylonitrile 失效
    制备丙烯腈和甲基丙烯腈的方法

    公开(公告)号：US4503001A

    公开(公告)日：1985-03-05

    申请号：US373904

    申请日：1982-05-03

    申请人： Robert K. Grasselli ,  Arthur F. Miller ,  Harley F. Hardman

    发明人： Robert K. Grasselli ,  Arthur F. Miller ,  Harley F. Hardman

    IPC分类号： B01J23/887 ,  B01J27/186 ,  C07C120/14

    CPC分类号： C07C253/26 ,  B01J23/8876 ,  B01J27/186 ,  Y02P20/52

    摘要： Monoolefins such as propylene and isobutylene are converted to the corresponding unsaturated nitriles, acrylonitrile and methacrylonitrile, respectively, by reacting a mixture of the olefin, ammonia, and a molecular oxygen-containing gas in the presence of a catalyst containing the oxides of iron, bismuth, molybdenum, and cobalt or nickel or both, and optionally an oxide of at least one element selected from the group consisting of the alkali metals, rare earth metals, tantalum and niobium, and optionally one or more of the oxides of the elements selected from the group consisting of phosphorus and arsenic.

    摘要翻译： 通过使烯烃，氨和含分子氧气体的混合物在含铁氧化物，铋的催化剂存在下，分别将丙烯和异丁烯等单烯烃转化为相应的不饱和腈，丙烯腈和甲基丙烯腈 ，钼和钴或镍或两者，以及任选的选自碱金属，稀土金属，钽和铌中的至少一种元素的氧化物，以及任选的一种或多种选自以下的元素的氧化物： 由磷和砷组成的组。