公开(公告)号：US12241205B2

公开(公告)日：2025-03-04

申请号：US18713463

申请日：2022-12-06

Applicant: Rohm and Haas Company

Inventor： Brian R. Einsla ,  Andrew Hejl ,  Ethan C. Glor ,  Junsi Gu

IPC: D21H19/12 ,  B41M5/333 ,  B41M5/41 ,  B41M5/44 ,  D21H19/82

Abstract: The present invention relates to a coated paper article with an intermediate basecoat layer comprising high void fraction porous hollow sphere polymer particles (HISPs). HSPs with very small pore area density and high void fraction result in increased optical density at a given print energy in thermal printing applications.

公开(公告)号：US20240425695A1

公开(公告)日：2024-12-26

申请号：US18687159

申请日：2022-08-19

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Yanxiang Li ,  Ray E. Drumright ,  Zhenwen Fu ,  Andrew Hejl ,  Denise Lindenmuth

IPC: C08L63/00 ,  C08K5/1515

Abstract: The present invention relates to a composition comprising an aqueous dispersion of a thermosettable compound and polymer particles functionalized with aminoalkyl ester groups. The composition is useful as a two-component waterborne curing system and is effective in providing corrosion and blister resistance in industrial coatings applications.

公开(公告)号：US20240287743A1

公开(公告)日：2024-08-29

申请号：US18567147

申请日：2022-06-21

Applicant: Rohm and Haas Company ,  Dow Global Technologies LLC

Inventor： Xiangyi Zhang ,  John A. Roper, III ,  Andrew Hejl ,  Brian R. Einsla ,  Matthew Carter

IPC: D21H19/12 ,  C08F218/08 ,  C09D5/02 ,  C09D131/04 ,  D21H23/52

CPC classification number: D21H19/12 ,  C08F218/08 ,  C09D5/022 ,  C09D131/04 ,  D21H23/52 ,  C08F2800/20

Abstract: The present invention relates to a method comprising the steps of applying to a paper or paperboard substrate an aqueous dispersion of polymer particles which comprise structural units of a vinyl ester, vinyl alcohol, and an acrylate monomer, then drying the composition. The method provides a coating that has oil and grease resistance, mineral oil barrier performance, and beat scalability.

公开(公告)号：US11097307B2

公开(公告)日：2021-08-24

申请号：US16432096

申请日：2019-06-05

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Eric C. Greyson ,  Charles R. Hegedus ,  Andrew Hejl ,  Rebecca L. Ladewski ,  Erin B. Vogel ,  Wenqin Wang

IPC: C08F20/32 ,  C08F2/38 ,  C08F2/48 ,  B05D3/06

Abstract: The present invention relates to a method comprising the steps of: a) contacting an acrylate monomer, a carboxylic acid monomer, and a chain transfer agent under free radical polymerization conditions to form a solution of a polymer having an Mn in the range of from 5,000 to 50,000 Daltons; b) contacting the solution with a base and an ethylenically unsaturated glycidyl functionalized monomer to form a solution of an ethylenically unsaturated acrylate polymer; c) contacting the solution of the ethylenically unsaturated functionalized acrylate polymer with water to form an aqueous dispersion of ethylenically unsaturated functionalized acrylate polymers; and d) removing the organic solvent. The method of the present invention provides a composition suitable for use as a UV curable coating that achieves an excellent balance of hardness, flexibility, and warmth with less reliance on costly MFAs.

公开(公告)号：US20180320007A1

公开(公告)日：2018-11-08

申请号：US15968939

申请日：2018-05-02

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： James Keith Bardman ,  Jonathan DeRocher ,  Andrew Hejl ,  Antony K. Van Dyk ,  Lin Wang ,  Kimy Yeung

IPC: C09D7/40 ,  C09D133/06 ,  C09D7/65

CPC classification number: C09D7/70 ,  C08F2/26 ,  C08F265/02 ,  C08F265/06 ,  C08L2201/50 ,  C08L2201/52 ,  C08L2207/53 ,  C09D7/65 ,  C09D7/68 ,  C09D133/06 ,  C09D133/10 ,  C09D133/12 ,  C08F2220/1825 ,  C08F220/06 ,  C08F220/14 ,  C08L51/003

Abstract: The present invention relates to a process for preparing a coatings composition with an open time additive comprising the steps of a) contacting an aqueous dispersion of alkali swellable polymer particles with a rheology modifier and a binder to form a coatings composition with a VOC of less than 50 g/L; and b) neutralizing the alkali swellable particles with a non-volatile base after or upon contact with the rheology modifier and the binder to form swelled multi-staged polymer particles; wherein the alkali swellable polymer particles comprise a shell having a Tg of not greater than 25° C. and an acid functionalized core; and wherein the core-to-shell ratio is in the range of from 1:3.2 to 1:10. The composition arising from the process of the present invention is useful for improving open time, especially for low VOC coatings applications.In another aspect the present invention relates to the preparation of the coatings composition with an open time additive comprising the steps of a) contacting the open time additive with a rheology modifier and a binder to form a coatings composition with a VOC of less than 50 g/L, then b) neutralizing the open time additive to form swelled multi-staged polymer particles, wherein the coatings composition with the open time additive exhibits less than a 50% increase in viscosity than the coating composition without the open time additive.

公开(公告)号：US10022995B2

公开(公告)日：2018-07-17

申请号：US15499999

申请日：2017-04-28

Applicant: Rohm and Haas Company ,  Dow Global Technologies LLC

Inventor： Andrew Hejl ,  Lanfang Li ,  Rebecca Smith ,  Jian Yang

IPC: B41M5/44 ,  B41M5/42 ,  D21H19/12 ,  D21H19/38 ,  D21H19/46 ,  D21H19/64 ,  D21H19/82

Abstract: The present invention relates to a thermally printable paper article with an elastomeric underlayer, which imparts improved printing performance.

公开(公告)号：US20170313116A1

公开(公告)日：2017-11-02

申请号：US15499999

申请日：2017-04-28

Applicant: Rohm and Haas Company ,  Dow Global Technologies LLC

Inventor： Andrew Hejl ,  Lanfang Li ,  Rebecca Smith ,  Jian Yang

IPC: B41M5/42 ,  D21H19/12 ,  D21H19/46 ,  D21H19/38 ,  D21H19/82 ,  D21H19/64

CPC classification number: B41M5/42 ,  B41M5/426 ,  B41M5/44 ,  B41M2205/04 ,  B41M2205/38 ,  D21H19/12 ,  D21H19/385 ,  D21H19/46 ,  D21H19/64 ,  D21H19/828

Abstract: The present invention relates to a thermally printable paper article with an elastomeric underlayer, which imparts improved printing performance.

公开(公告)号：US09000078B2

公开(公告)日：2015-04-07

申请号：US14052850

申请日：2013-10-14

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Andrew Hejl ,  Arkady L. Krasovskiy ,  Partha S. Majumdar ,  Mark R. Winkle

IPC: C09D7/12 ,  C09D5/02

CPC classification number: C09D7/1233 ,  C08K5/53 ,  C09D5/02 ,  C09D5/027 ,  C09D7/63

Abstract: The present invention is a composition comprising an aqueous dispersion of a binder and a salt of the following fluoroalkyl phosphonic acid: wherein n, q, and p are as described herein. The composition of the present invention is useful as a block additive in coating compositions.

Abstract translation: 本发明是一种组合物，其包含粘合剂的水性分散体和以下氟代烷基膦酸的盐：其中n，q和p如本文所述。 本发明的组合物可用作涂料组合物中的嵌段添加剂。

公开(公告)号：US20140179823A1

公开(公告)日：2014-06-26

申请号：US14107176

申请日：2013-12-16

Applicant: Rohm and Haas Company

Inventor： Andrew Hejl ,  Eric Greyson ,  Wenqin Wang

IPC: C09D133/08

CPC classification number: C09D133/08 ,  C09D4/06 ,  C09D5/00 ,  C08F220/14 ,  C08F220/06 ,  C08F2/38 ,  C08F222/1006

Abstract: The present invention provides low solvent or substantially solvent-free multi-ethylenically unsaturated acrylate composition imbibed particles of an acid functional group containing acrylic polymer for ultraviolet curing coating applications and methods of making the same wherein the acrylic polymer is formed by polymerizing in organic solvent, then neutralized and combined with a multi-ethylenically unsaturated acrylate composition prior to dispersing the mixture into water and, preferably, removing solvent.

Abstract translation: 本发明提供了低溶剂或基本上无溶剂的多烯属不饱和丙烯酸酯组合物，用于紫外线固化涂料的含酸官能团的丙烯酸聚合物的吸收颗粒及其制备方法，其中丙烯酸聚合物通过在有机溶剂中聚合形成， 然后在将混合物分散在水中之前中和并与多烯属不饱和丙烯酸酯组合物组合，并且优选除去溶剂。