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    MULTILAYER IMAGEABLE ELEMENT CONTAINING SULFONAMIDO RESIN
    22.
    发明申请
    MULTILAYER IMAGEABLE ELEMENT CONTAINING SULFONAMIDO RESIN 有权
    含有磺酰胺树脂的多层成像元素

    公开(公告)号：US20070172764A1

    公开(公告)日：2007-07-26

    申请号：US11551753

    申请日：2006-10-23

    申请人： Shashikant Saraiya ,  Anthony P. Kitson ,  Frederic E. Mikell ,  Larisa Novoselova

    发明人： Shashikant Saraiya ,  Anthony P. Kitson ,  Frederic E. Mikell ,  Larisa Novoselova

    IPC分类号： G03C1/00

    CPC分类号： B41C1/1016 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/14 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/262 ,  B41M2205/14 ,  Y10S430/106 ,  Y10S430/111 ,  Y10S430/165

    摘要： A positive-working imageable element comprises inner and outer layers and a radiation absorbing compound such as an IR absorbing dye. The inner layer includes a first polymeric material. The ink receptive outer layer includes a second polymeric binder comprising a polymer backbone and an —X—C(=T)-NR—S(═O)2— moiety that is attached to the polymer backbone, wherein —X— is an oxy or —NR′— group, T is O or S, R and R′ are independently hydrogen, halo, or an alkyl group having 1 to 6 carbon atoms. After thermal imaging, the element can be developed using an alkaline developer. Use of the particular second polymeric binder reduces sludging in the developer. Its dissolution rate in the developer is slow enough to resist developer attack in the non-imaged areas of the outer layer but rapid enough for the second polymeric binder to be quickly loosened from imaged areas and kept suspended or dissolved for a considerable time.

    摘要翻译： 正面工作的可成像元件包括内层和外层以及辐射吸收化合物，例如IR吸收染料。 内层包括第一聚合物材料。 油墨接收外层包括第二聚合物粘合剂，其包含聚合物主链和连接到聚合物主链上的-XC（= T）-NR-S（-O）2 - - 部分，其中 - X是氧基或-NR'-基，T是O或S，R和R'独立地是氢，卤素或具有1至6个碳原子的烷基。 热成像后，可以使用碱性显影剂显影元件。 使用特定的第二聚合物粘合剂减少了显影剂中的污泥。 其在显影剂中的溶解速率足够慢以抵抗在外层的非成像区域中的显影剂侵袭，但足够快以使第二聚合物粘合剂从成像区域快速松开并保持悬浮或溶解相当长的时间。

    Electrostatically imaged printing plate and method of preparation
    25.
    发明授权
    Electrostatically imaged printing plate and method of preparation 失效
    静电成像印版及其制备方法

    公开(公告)号：US06376140B1

    公开(公告)日：2002-04-23

    申请号：US09706521

    申请日：2000-11-03

    申请人： Patrick R. Friedman ,  Jian Bing Huang ,  Ken Shimazu ,  Shashikant Saraiya

    发明人： Patrick R. Friedman ,  Jian Bing Huang ,  Ken Shimazu ,  Shashikant Saraiya

    IPC分类号： G03G1326

    CPC分类号： G03G13/28 ,  G03G13/26 ,  G03G13/283 ,  G03G13/286

    摘要： A printing plate useful in lithographic printing is prepared by the process comprising: (a) applying an alkali soluble composition comprising at least one polymer composition to a hydrophilic surface on a substrate to provide the surface face with at least one layer which is alkali soluble at a pH in the range of about 6.0 to 14.0; (b) imaging the coated substrate electrostatically with a toner composition; (c) heating the imaged substrate a first time to a temperature greater than the glass transition temperature of the toner composition; (d) contacting the imaged substrate with an aqueous alkaline solution having a pH in the range of about 6.0 to about 14.0; and (e) heating the imaged substrate a second time to a temperature greater than the glass transition temperature of the toner composition. This printing plate is capable of long runs on press with good image quality and advantageously minimizes the occurrence of undesirable background toner “specking” on press. Accordingly, the printing plate is satisfactory for demanding printing tasks such as four-color newspaper printing, financial printing and the like.

    摘要翻译： 通过该方法制备用于平版印刷的印版，其包括：（a）将包含至少一种聚合物组合物的碱溶性组合物施加到基材上的亲水表面上，以使表面具有至少一个碱溶于 pH在约6.0至14.0的范围内;（b）用调色剂组合物静电成像涂布的基材;（c）将成像的基材第一次加热至高于调色剂组合物的玻璃化转变温度的温度;（d ）使成像的底物与pH在约6.0至约14.0范围内的碱性水溶液接触; 和（e）第二次将成像的基材加热到大于调色剂组合物的玻璃化转变温度的温度。该印刷版能够在压制时长时间运行，具有良好的图像质量，并且有利地最小化不期望的背景调色剂“斑点”的出现 “在新闻界。 因此，印刷版对于诸如四色报纸印刷，金融印刷等的苛刻的打印任务是令人满意的。

    Thermal digital lithographic printing plate
    26.
    发明授权
    Thermal digital lithographic printing plate 有权
    热数码平版印刷版

    公开(公告)号：US06352812B1

    公开(公告)日：2002-03-05

    申请号：US09301866

    申请日：1999-04-29

    申请人： Ken-Ichi Shimazu ,  Jayanti Patel ,  Shashikant Saraiya ,  Nishith Merchant ,  Celin Savariar-Hauck ,  Hans-Joachim Timpe ,  Christopher D. McCullough

    发明人： Ken-Ichi Shimazu ,  Jayanti Patel ,  Shashikant Saraiya ,  Nishith Merchant ,  Celin Savariar-Hauck ,  Hans-Joachim Timpe ,  Christopher D. McCullough

    IPC分类号： G03F709

    CPC分类号： B41M5/42 ,  B41C1/1016 ,  B41C2201/04 ,  B41C2210/02 ,  B41C2210/06 ,  B41C2210/14 ,  B41C2210/24 ,  B41C2210/26 ,  B41C2210/262 ,  B41C2210/264 ,  B41C2210/266 ,  B41M5/368 ,  B41M5/44 ,  B41M5/465

    摘要： A thermal lithographic printing plate, which can be imaged by thermal energy typically by imagewise exposure with an infrared emitting laser, a thermal printing head, etc., is made up of a hydrophilic substrate, and a composite layer structure composed of two layer coatings. Preferably, the first layer of the composite is composed of an aqueous developable polymer mixture containing a photothermal conversion material which is contiguous to the hydrophilic substrate. The second layer of the composite is composed of one or more non-aqueous soluble polymers which are soluble or dispersible in a solvent which does not dissolve the first layer. The plate is exposed with an infrared laser or a thermal print head, and upon aqueous development of the imaged plate, the exposed portions are removed exposing hydrophilic substrate surfaces receptive to conventional aqueous fountain solutions. The unexposed portions contain the ink-receptive image areas. The second layer may also contain a photothermal conversion material. Alternatively, the composite layer may be free of photothermal conversion material when thermal imaging is carried out using a thermal printing head.

    摘要翻译： 可以通过热能成像通过用红外发射激光成像曝光，热打印头等来成像的热平版印刷版由亲水基材和由两层涂层组成的复合层结构构成。 优选地，复合材料的第一层由包含与亲水基底邻接的光热转换材料的水性可显影聚合物混合物组成。 复合材料的第二层由一种或多种可溶于或不溶于不溶于第一层的溶剂中的非水溶性聚合物组成。 该板用红外激光或热打印头曝光，并且在成像板的水性显影时，去除曝光部分，暴露接受常规水性喷泉溶液的亲水底物表面。 未曝光部分包含吸墨图像区域。 第二层也可以含有光热转换材料。 或者，当使用热敏打印头进行热成像时，复合层可以不含光热转换材料。

    Processless, laser imageable lithographic printing plate
    27.
    发明授权
    Processless, laser imageable lithographic printing plate 失效
    无源激光可成像平版印刷版

    公开(公告)号：US06261740B1

    公开(公告)日：2001-07-17

    申请号：US09244339

    申请日：1999-02-04

    申请人： My T. Nguyen ,  Shashikant Saraiya ,  Ken-Ichi Shimazu ,  S. Peter Pappas ,  Robert Hallman ,  Ajay Shah ,  Omkar J. Natu ,  Jayanti Patel

    发明人： My T. Nguyen ,  Shashikant Saraiya ,  Ken-Ichi Shimazu ,  S. Peter Pappas ,  Robert Hallman ,  Ajay Shah ,  Omkar J. Natu ,  Jayanti Patel

    IPC分类号： G03C176

    CPC分类号： B41C1/1033 ,  B41C1/1041 ,  B41M5/368 ,  B41N1/006

    摘要： A lithographic printing surface is prepared using a thermal lithographic printing plate which requires no chemical development to remove areas of the imaged plate. The processless thermal lithographic printing plate has a sheet substrate; a hydrophilic layer on the sheet substrate; and a thermally sensitive imaging layer on the hydrophilic layer. The hydrophilic layer contains about 30 weight % of an aluminosilicate or clay, and preferably has an exterior surface which is micro-porous. The imaging layer preferably is micro-porous. The imaging layer is exposed imagewise using infrared laser radiation to produce an imaged layer. The imaged layer is treated with a conditioner liquid to produce a lithographic printing surface. By this method, the printing plate can be digitally imaged by infrared laser radiation so that the exposed areas become ink receptive and the non-exposed areas repel ink after simple treatment with a conditioner such as an aqueous surfactant solution such as a fountain solution containing an amphoteric surfactant.

    摘要翻译： 使用不需要化学显影去除成像板的区域的热平版印刷版制备平版印刷表面。 无机热平版印刷版具有片状基材; 在所述片基材上的亲水层; 和亲水层上的热敏成像层。 亲水层包含约30重量％的硅铝酸盐或粘土，并且优选具有微孔的外表面。 成像层优选是微孔的。 使用红外激光辐射使成像层成像曝光以产生成像层。 用调理液处理成像层以产生平版印刷表面。 通过这种方法，可以通过红外激光辐射对印版进行数字成像，使得曝光区域变为油墨接受，并且在用诸如表面活性剂水溶液的简单处理之后，非曝光区域排斥墨，所述表面活性剂水溶液例如含有 两性表面活性剂。

    Radiation sensitive diazo sulfo-acrylic adducts and method for producing a printing plate
    28.
    发明授权
    Radiation sensitive diazo sulfo-acrylic adducts and method for producing a printing plate 失效
    辐射敏感重氮磺基丙烯酸加合物及其印刷方法

    公开(公告)号：US5846685A

    公开(公告)日：1998-12-08

    申请号：US797675

    申请日：1997-01-31

    申请人： S. Peter Pappas ,  Jianbing Huang ,  Ajay Shah ,  Shashikant Saraiya

    发明人： S. Peter Pappas ,  Jianbing Huang ,  Ajay Shah ,  Shashikant Saraiya

    IPC分类号： G03F7/021 ,  G03F7/095

    CPC分类号： G03F7/021

    摘要： A radiation sensitive composition containing an adduct of a diazonium resin having pendant diazonium groups, with a sulfonated acrylic copolymer having pendant sulfonate groups. The sulfonated acrylic copolymer contains an acrylic moiety and a sulfonated styryl or acrylic moiety. The copolymer may optionally contain styryl moieties. The composition is useful as a radiation sensitive layer in imaging elements for graphic arts applications and is particularly useful in preparing durable, long-wear, printing plates.

    摘要翻译： 一种辐射敏感性组合物，其含有具有侧面重氮基团的重氮化合物的加合物和具有磺酸根基侧基的磺化丙烯酸共聚物。 磺化丙烯酸共聚物含有丙烯酸部分和磺化苯乙烯基或丙烯酸部分。 共聚物可以任选地含有苯乙烯基部分。 该组合物可用作用于图形艺术应用的成像元件中的辐射敏感层，并且在制备耐用的长寿命印刷版中特别有用。

    NEGATIVE-WORKING RADIATION-SENSITIVE COMPOSITIONS AND IMAGEABLE MATERIALS
    29.
    发明申请
    NEGATIVE-WORKING RADIATION-SENSITIVE COMPOSITIONS AND IMAGEABLE MATERIALS 有权
    负面工作辐射敏感组合物和成像材料

    公开(公告)号：US20080070152A1

    公开(公告)日：2008-03-20

    申请号：US11532647

    申请日：2006-09-18

    申请人： Jianfei Yu ,  Kevin B. Ray ,  Shashikant Saraiya ,  Thomas R. Jordan ,  Paul R. West

    发明人： Jianfei Yu ,  Kevin B. Ray ,  Shashikant Saraiya ,  Thomas R. Jordan ,  Paul R. West

    IPC分类号： G03C1/00

    CPC分类号： G03F7/035 ,  B41C1/1008 ,  B41C2210/04 ,  B41C2210/08 ,  B41C2210/20 ,  B41C2210/22 ,  B41C2210/24 ,  B41C2210/266 ,  B41M5/368 ,  G03F7/0388 ,  G03F7/40 ,  Y10S430/107 ,  Y10S430/111

    摘要： A radiation-sensitive composition and negative-working imageable element includes a free radically polymerizable component, an initiator composition capable of generating radicals sufficient to initiate polymerization of the free radically polymerizable component upon exposure to imaging radiation, a radiation absorbing compound, and particles of a poly(urethane-acrylic) hybrid that are distributed throughout the composition forming an imageable layer in the element. Imaging can be accomplished at a wide range of wavelengths from about 150 to about 1500 nm, and development can be accomplished using an organic solvent-based developer, warm water, plate cleaner, or on-press using a combination of a lithographic printing ink and a fountain solution.

    摘要翻译： 辐射敏感组合物和负性可成像元件包括可自由基聚合的组分，能够产生足以在暴露于成像辐射时引发可自由基聚合的组分聚合的自由基的引发剂组合物，辐射吸收化合物和 分布在整个组合物中的聚（氨基甲酸酯 - 丙烯酸）混合物，形成元件中的可成像层。 可以在约150至约1500nm的宽波长范围内实现成像，并且可以使用基于有机溶剂的显影剂，温水，板清洁剂或印刷机，使用平版印刷油墨和 一个喷泉的解决方案。