摘要:
Disclosed herein is a method for regenerating a separator for a fuel cell in which the separator is composed of a substrate of Ti or Ti alloy and a conductive film formed thereon. The method includes a step of removing the conductive film from the separator for a fuel cell and also removing part of the surface of the substrate, thereby giving a regenerated substrate, and a step of forming a regenerated conductive film on the regenerated substrate. The conductive film and the regenerated conductive film are at least one species of noble metal or alloy thereof selected from the group of noble metals consisting of Au, Pt, and Pd, or an alloy composed of at least one species selected from the group of noble metals and one species selected from the group of metals consisting of Ti, Zr, Hf, Nb, Ta, and Si.
摘要:
Disclosed is a titanium fuel cell separator having excellent conductivity and durability. In the disclosed titanium fuel cell separator (10), a carbon layer (2) is formed on the surface of a substrate (1) formed from pure titanium or a titanium alloy. The carbon layer (2) comprises graphite which is orientated so as to be parallel to the (002) plane of the carbon layer (2). The deposition amount of the carbon layer (2) is at least 2 μg/cm2.
摘要翻译:公开了具有优异的导电性和耐久性的钛燃料电池隔板。 在所公开的钛燃料电池隔板(10)中,在由纯钛或钛合金形成的基板(1)的表面上形成碳层(2)。 碳层(2)包括石墨,其被定向成平行于碳层(2)的(002)面。 碳层(2)的沉积量为2μg/ cm 2以上。
摘要:
Disclosed is anode for use in a lithium ion secondary battery. The anode includes an anode current collector and an anode active material arranged thereon, in which the anode active material contains amorphous carbon and at least one metal dispersed in the amorphous carbon, and the at least one metal is selected from: 30 to 70 atomic percent of Si; and 1 to 40 atomic percent of Sn. The anode gives a lithium ion secondary battery that has a high charge/discharge capacity and is resistant to deterioration of its anode active material even after repetitive charge/discharge cycles.
摘要:
A method for manufacturing a fuel cell separator, including: forming by a PVD method a precious metal layer on a surface of a substrate, as a fuel cell separator, made of Ti or a Ti alloy, wherein the precious metal layer includes at least one precious metal selected from Ru, Rh, Pd, Os, Ir, Pt and Au and has a thickness of 2 nm or more, and a heat treatment wherein the substrate on which the precious metal layer was formed in the precious metal layer forming is subjected to a heat treatment at a predetermined heat treatment temperature and under a predetermined oxygen partial pressure. According to the method, a fuel cell separator made of Ti or a Ti alloy having excellent corrosion resistance, good adhesion of a precious metal layer, low contact resistance, and further excellent productivity can be produced.
摘要:
The present invention concerns an alloy film for a metal separator for a fuel cell characterized by containing at least one noble metal element selected from Au and Pt and at least one non-noble metal element selected from the group consisting of Ti, Zr, Nb, Hf, and Ta, at a content ratio of noble metal element/non-noble metal element of 35/65 to 95/5, and having a film thickness of 2 nm or more. The present invention also relates to a manufacturing method of an alloy film for the metal separator for the fuel cell and a target material for sputtering, as well as the metal separator and the fuel sell. The alloy film for the metal separator for the fuel cell according to the invention is excellent in the corrosion resistance, has low contact resistance, can maintain the low contact resistance for a long time even in a corrosive environment, and is excellent further in the productivity.
摘要:
Disclosed is a reflecting film comprising: an Ag or Ag-base alloy thin film of an Ag-base alloy containing at least one element among Au, Pt, Pd, Bi, and rare-earth elements as a first layer; a film of an oxide or oxynitride of at least one element among Si, Al and Ti having a thickness between 5 and 50 nm as a second layer deposited on the first layer; and a film having a thickness between 10 and 100 nm formed by a plasma polymerization process as a third layer deposited on the second layer.
摘要:
It is an object of the present invention to provide a titanium electrode material which is low in cost and is excellent in electric conductivity, corrosion resistance and hydrogen absorption resistance, and a surface treatment method of a titanium electrode material. A titanium electrode material includes: on the surface of a titanium material including pure titanium or a titanium alloy, a titanium oxide layer having a thickness of 3 nm or more and 75 nm or less, and having an atomic concentration ratio of oxygen and titanium (O/Ti) at a site having the maximum oxygen concentration in the layer of 0.3 or more and 1.7 or less; and an alloy layer including at least one noble metal selected from Au, Pt, and Pd, and at least one non-noble metal selected from Zr, Nb, Ta, and Hf, having a content ratio of the noble metal and the non-noble metal of 35:65 to 95:5 by atomic ratio, and having a thickness of 2 nm or more, on the titanium oxide layer. The surface treatment method of a titanium electrode material includes a titanium oxide layer formation step, an alloy layer formation step, and a heat treatment step.
摘要翻译:本发明的目的是提供一种成本低且导电性,耐腐蚀性和耐氢吸收性优异的钛电极材料以及钛电极材料的表面处理方法。 钛电极材料包括:在包括纯钛或钛合金的钛材料的表面上,具有3nm以上且75nm以下的氧化钛层,并且具有氧和钛的原子浓度比( O / Ti)在层中的最大氧浓度为0.3以上且1.7以下的部位; 以及包含选自Au,Pt和Pd中的至少一种贵金属和选自Zr,Nb,Ta和Hf中的至少一种非贵金属的合金层,其具有贵金属和非金属的含量比, 在氧化钛层上的原子比为35:65〜95:5的贵金属,厚度为2nm以上。 钛电极材料的表面处理方法包括氧化钛层形成步骤,合金层形成步骤和热处理步骤。
摘要:
A metal separator 1 for a fuel cell according to the invention is a metal separator for a fuel cell manufactured by using a metal substrate 2 with a flat surface, or with concave gas flow paths formed on at least a part of the surface. The metal separator 1 includes an acid-resistant metal film 3 formed over the surface of the metal substrate 2, and containing one or more kinds of non-noble metals selected from the group comprised of Zr, Nb, and Ta, and a conductive alloy film 4 formed over the acid-resistant metal film 3, and containing one or more kinds of noble metals selected from the group comprised of Au and Pt, and one or more kinds of non-noble metals selected from the group comprised of Zr, Nb, and Ta. A method for manufacturing the metal separator for a fuel cell according to the invention includes a step S1 of depositing an acid-resistant metal film, and a step S2 of depositing a conductive alloy film. With this structure, the invention provides the metal separator for a fuel cell with an excellent acid resistance and a low contact resistance, and a manufacturing method thereof.
摘要:
The present invention concerns an alloy film for a metal separator for a fuel cell characterized by containing at least one noble metal element selected from Au and Pt and at least one non-noble metal element selected from the group consisting of Ti, Zr, Nb, Hf, and Ta, at a content ratio of noble metal element/non-noble metal element of 35/65 to 95/5, and having a film thickness of 2 nm or more. The present invention also relates to a manufacturing method of an alloy film for the metal separator for the fuel cell and a target material for sputtering, as well as the metal separator and the fuel sell. The alloy film for the metal separator for the fuel cell according to the invention is excellent in the corrosion resistance, has low contact resistance, can maintain the low contact resistance for a long time even in a corrosive environment, and is excellent further in the productivity.
摘要:
A titanium substrate, for forming a separator for a fuel cell, is made of titanium or a titanium alloy and has surface layers containing carbon having binding energy in the range of to 284 eV as measured by x-ray photoelectron spectroscopy in a carbon content of 25% at. or below.