LIQUID CRYSTALLINE POLYESTER RESIN COMPOSITION
    21.
    发明申请
    LIQUID CRYSTALLINE POLYESTER RESIN COMPOSITION 审中-公开
    液晶聚酯树脂组合物

    公开(公告)号:US20150038631A1

    公开(公告)日:2015-02-05

    申请号:US14381067

    申请日:2013-02-26

    Abstract: A liquid crystalline polyester resin composition has high strength and low warpage due to the reinforcement effects of a filler, high toughness to be resistant to pin press-fitting, good tribological property and good flexural fatigue characteristic. The liquid crystalline polyester resin composition includes 100 parts by weight of a liquid crystalline polyester (A) having a ratio (a)/[(a)+(b)] of an amount of terminal hydroxyl group (a) to a sum of the amount of terminal hydroxyl group (a) and an amount of terminal acetyl group (b) which is 0.70 to 1.00; and 10 to 100 parts by weight of a mica (B). The mica (B) included in the liquid crystalline polyester resin composition has a volume-average particle size of 10 to 50 μm. The mica (B) has an aspect ratio of 50 to 100.

    Abstract translation: 液晶聚酯树脂组合物由于填料的增强效果而具有高强度和低翘曲,具有高的韧性以抵抗针压配合,良好的摩擦学性能和良好的弯曲疲劳特性。 液晶聚酯树脂组合物包括100重量份具有末端羟基(a)的量的比率(a)/ [(a)+(b)]的液晶聚酯(A)与 末端羟基(a)的量和末端乙酰基(b)的量为0.70〜1.00; 和10〜100重量份的云母(B)。 液晶聚酯树脂组合物中所含的云母(B)的体积平均粒径为10〜50μm。 云母(B)的纵横比为50〜100。

    THERMOPLASTIC POLYESTER RESIN COMPOSITION AND MOLDED ARTICLE

    公开(公告)号:US20210032402A1

    公开(公告)日:2021-02-04

    申请号:US16608463

    申请日:2018-06-20

    Abstract: A thermoplastic polyester resin composition includes a thermoplastic polyester resin (A), an epoxy compound (B) having an epoxy equivalent of from 200 to 3,000 g/eq, and a hydroxy group-containing resin (C) having a number average molecular weight of from 2,000 to 500,000 and a halogen element content of 1,000 ppm or less, wherein the epoxy compound (B) is blended in an amount of from 0.05 to 10 parts by weight with respect to 100 parts by weight in total of 70 to 99.9 parts by weight of the thermoplastic polyester resin (A) and 0.1 to 30 parts by weight of the hydroxy group-containing resin (C). The thermoplastic resin composition and a molded article achieve both long-term hydrolysis resistance and heat aging resistance at a high level, and can further suppress bleed-out to the surface of the molded article during heat-dry and heat-moisture treatments.

    Method for producing liquid crystalline polyester, and liquid crystalline polyester

    公开(公告)号:US09850343B2

    公开(公告)日:2017-12-26

    申请号:US14900437

    申请日:2014-07-25

    CPC classification number: C08G63/605 C08G63/78 C09K19/3809

    Abstract: The present invention is a method for producing a liquid crystalline polyester, which comprises reacting an aromatic hydroxycarboxylic acid, a diol containing 70 mol % or more of an aromatic diol having a structural unit (I) as shown below and an aromatic dicarboxylic acid with one another in the presence of an acylating agent and an aliphatic sulfonic acid represented by formula (A) shown below. (wherein Ar represents a bivalent aromatic group which is an aromatic hydrocarbon group and has a molecular weight of less than 200) Formula (A) R—SO3H (wherein R represents an alkyl group having 1 to 12 carbon atoms) According to the present invention, a liquid crystalline polyester, which can be molded into an article having excellent tensile strength and excellent creep properties and from which a gas is generated in a reduced amount, can be produced with high efficiency.

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