公开(公告)号：US11319437B2

公开(公告)日：2022-05-03

申请号：US16492784

申请日：2018-04-02

Applicant: Toray Industries, Inc.

Inventor： Yusuke Tojo ,  Makito Yokoe ,  Hideyuki Umetsu

IPC: C08L67/02 ,  C08G63/183 ,  C08K5/00 ,  C08K5/3435 ,  C08K7/02 ,  C08L63/00

Abstract: A thermoplastic polyester resin composition includes 0.05 to 10 parts by weight of an epoxy compound (B) and 0.001 to 1 part by weight of a hindered amine compound (C) with respect to 100 parts by weight of a thermoplastic polyester resin (A) having an amount of carboxyl groups of 50 eq/t or less. The thermoplastic polyester resin composition is capable of producing a molded article which is excellent in mechanical properties and heat resistance, as well as in long-term hydrolysis resistance, and has a small decrease in mechanical properties and hydrolysis resistance even when melt-processed at a high temperature of 270° C. or more.

公开(公告)号：US09988521B2

公开(公告)日：2018-06-05

申请号：US14361482

申请日：2012-11-30

Applicant: Toray Industries, Inc. ,  Koito Manufacturing Co., Ltd.

Inventor： Naoya Ouchiyama ,  Kei Saitoh ,  Hideyuki Umetsu ,  Hideki Matsumoto ,  Hidetaka Anma ,  Daisuke Mochizuki ,  Hiroaki Hara ,  Masayuki Kobayashi

IPC: C08K3/34 ,  C08L81/04 ,  C08K5/5465 ,  C08K5/5435 ,  C08L79/08 ,  C08G73/10

CPC classification number: C08K5/5465 ,  C08G73/1046 ,  C08K3/34 ,  C08K3/346 ,  C08K5/5435 ,  C08K2201/016 ,  C08L79/08 ,  Y10T428/31533 ,  C08L81/04

Abstract: A polyphenylene sulfide resin composition has excellent heat resistance, flowability and lightweight property as well as surface smoothness and impact resistance. The polyphenylene sulfide resin composition includes 1 to 30 parts by weight of a mica (b) having an aspect ratio of not less than 80, relative to 100 parts by weight of a polyphenylene sulfide resin (a).

公开(公告)号：US20200071516A1

公开(公告)日：2020-03-05

申请号：US16492784

申请日：2018-04-02

Applicant: Toray Industries, Inc.

Inventor： Yusuke Tojo ,  Makito Yokoe ,  Hideyuki Umetsu

IPC: C08L67/02 ,  C08L63/00 ,  C08G63/183 ,  C08K5/3435 ,  C08K7/02 ,  C08K5/00

Abstract: A thermoplastic polyester resin composition includes 0.05 to 10 parts by weight of an epoxy compound (B) and 0.001 to 1 part by weight of a hindered amine compound (C) with respect to 100 parts by weight of a thermoplastic polyester resin (A) having an amount of carboxyl groups of 50 eq/t or less. The thermoplastic polyester resin composition is capable of producing a molded article which is excellent in mechanical properties and heat resistance, as well as in long-term hydrolysis resistance, and has a small decrease in mechanical properties and hydrolysis resistance even when melt-processed at a high temperature of 270° C. or more.

公开(公告)号：US20180312692A1

公开(公告)日：2018-11-01

申请号：US15770750

申请日：2016-07-06

Applicant: Toray Industries, Inc.

Inventor： Kenichi Okunaga ,  Atsushi Masunaga ,  Shingo Nishida ,  Masaru Akita ,  Hideyuki Umetsu

IPC: C08L77/06 ,  C08L77/02 ,  C08G69/14 ,  C08G69/26 ,  C08K5/053 ,  C08K3/32

CPC classification number: C08J7/00 ,  C08K5/10 ,  C08K5/17 ,  C08K5/51 ,  C08L77/00

Abstract: A molded product made from a resin composition includes a polyamide resin and has a thickness of not less than 0.56 mm. A difference (Q−P) between Q and P is less than 0.06, where P (A1680/A1632) denotes an intensity ratio of a maximum value of absorbance A1680 at 1680 cm−1±8 cm−1 to a maximum value of absorbance A1632 at 1632 cm−1±8 cm−1 with an absorbance at 1800 cm−1 being set to 0 with regard to an infrared absorption spectrum of a cutting surface at a depth of 0.28 mm from a surface of the molded product, and Q (A′1680/A′1632) denotes an intensity ratio of a maximum value of absorbance A′1680 at 1680 cm−1±8 cm−1 to a maximum value of absorbance A′1632 at 1632 cm−1±8 cm−1 with an absorbance at 1800 cm−1 being set to 0.

公开(公告)号：US20160264778A1

公开(公告)日：2016-09-15

申请号：US15029366

申请日：2014-08-28

Applicant: TORAY INDUSTRIES, INC.

Inventor： Atsushi Masunaga ,  Hideyuki Umetsu

IPC: C08L77/06 ,  C08J3/00 ,  C08L77/02

CPC classification number: C08L77/06 ,  C08G69/48 ,  C08J3/005 ,  C08J2377/02 ,  C08J2377/06 ,  C08J2463/02 ,  C08J2463/04 ,  C08J2479/00 ,  C08K5/053 ,  C08K5/15 ,  C08K5/29 ,  C08L77/02 ,  C08L2201/08 ,  C08L79/00 ,  C08L63/00

Abstract: A polyamide resin composition has excellent heat aging resistance, surface appearance, retention stability, dimensional accuracy, chemical resistance and the like. One polyamide resin composition includes a specified amount of a compound and/or its condensate that includes a hydroxyl group and an epoxy group or a carbodiimide group and has a specific structure. Another polyamide resin composition includes specified amounts of an aliphatic compound having three or more amino groups or three or more hydroxyl groups per molecule and a compound having more than one functional group per molecule that is reactive with the amino group or the hydroxyl group, wherein, when an ASTM No. 1 dumbbell of 3.2 mm in thickness produced by injection molding of the polyamide resin composition is processed by heat treatment at 130° C. for 100 hours, an increase rate in concentration of a carboxyl group in the polyamide resin composition from a surface of the molded product to a depth of 0.2 mm after the heat treatment is lower than 70%.

Abstract translation: 聚酰胺树脂组合物具有优异的耐热老化性，表面外观，保持稳定性，尺寸精度，耐化学性等。 一种聚酰胺树脂组合物包含指定量的包含羟基和环氧基的化合物和/或其缩合物或碳二亚胺基并具有特定结构。 另外，聚酰胺树脂组合物含有规定量的每分子具有3个以上氨基或3个以上羟基的脂肪族化合物，每分子具有多于1个与氨基或羟基反应的官能团的化合物， 当通过聚酰胺树脂组合物的注射成型生产的厚度为3.2mm的ASTM No.1哑铃通过130℃热处理100小时，聚酰胺树脂组合物中羧基浓度的增加率从 热处理后的成型品的深度为0.2mm的面低于70％。

公开(公告)号：US11629243B2

公开(公告)日：2023-04-18

申请号：US17625188

申请日：2020-07-07

Applicant: Toray Industries, Inc.

Inventor： Nobuhiro Morioka ,  Akiyoshi Tamai ,  Hideyuki Umetsu

IPC: C08K13/02 ,  C08L77/02 ,  C08L77/04 ,  C08L77/06 ,  C08K3/32 ,  C08K5/09

Abstract: A polyamide resin composition makes it possible to obtain a molded article having excellent fluidity, excellent prying strength, and excellent adhesivity with metal. The polyamide resin composition includes 100 parts by mass of a polyamide resin (A) and 0.1 part by mass or more and 10 parts by mass or less of an ammonium salt (B) composed of a C6-12 aliphatic dicarboxylic acid and ammonia.

公开(公告)号：US20230065239A1

公开(公告)日：2023-03-02

申请号：US17789588

申请日：2020-12-21

Applicant: Toray Industries, Inc.

Inventor： Akito Konishi ,  Hiroshi Nakagawa ,  Junki Tanabe ,  Hideyuki Umetsu

IPC: C08G63/60 ,  C08J5/18

Abstract: A liquid crystal polyester resin comprising 42 to 80 mol % of structural unit (I) relative to 100 mol % of the total structural unit of the liquid crystal polyester resin, and ΔS (entropy of melting) defined by equation [1] is 0.01×10−3 to 2.7×10−3 J/g·K: ΔS(J/g·K)=ΔHm(J/g)/Tm(K)  [1] wherein Tm is an endothermic peak temperature determined by: after observation of an endothermic peak temperature (Tm1) observed when heating a liquid crystal polyester under temperature rising conditions of 20° C./minute from room temperature in differential scanning calorimetry, the liquid crystal polyester was maintained at a temperature of Tm1+20° C. for 5 minutes, followed by observation of the endothermic peak temperature observed when the temperature has fallen to room temperature under temperature falling conditions of 20° C./minute and then raised under temperature rising conditions of 20° C./minute, and ΔHm is an endothermic peak area of Tm:

公开(公告)号：US20220204729A1

公开(公告)日：2022-06-30

申请号：US17625188

申请日：2020-07-07

Applicant: Toray Industries, Inc.

Inventor： Nobuhiro Morioka ,  Akiyoshi Tamai ,  Hideyuki Umetsu

IPC: C08K13/02

Abstract: A polyamide resin composition makes it possible to obtain a molded article having excellent fluidity, excellent prying strength, and excellent adhesivity with metal. The polyamide resin composition includes 100 parts by mass of a polyamide resin (A) and 0.1 part by mass or more and 10 parts by mass or less of an ammonium salt (B) composed of a C6-12 aliphatic dicarboxylic acid and ammonia.

公开(公告)号：US11136447B2

公开(公告)日：2021-10-05

申请号：US16346986

申请日：2017-11-10

Applicant: Toray Industries, Inc.

Inventor： Akiyoshi Tamai ,  Hiroshi Nakagawa ,  Masaru Akita ,  Hideyuki Umetsu

IPC: C08K5/3492 ,  C08J3/20 ,  C08K3/16 ,  C08K5/378 ,  C08K5/47 ,  C08L77/06

Abstract: A polyamide resin composition includes 100 parts by weight of a polyamide resin (A), 0.1 to 50 parts by weight of a fire retardant (B), 0.001 to 1 part by weight of a metal and/or salt thereof (C), and 0.001 to 1 part by weight of a compound (D) as represented by formula [I]: QX [I] wherein in formula [I], Q represents an aromatic hydrocarbon group or an alicyclic hydrocarbon group and X represents a 5-membered heterocyclic ring group, Q and X forming a covalent bond or a fused ring.

公开(公告)号：US20190055398A1

公开(公告)日：2019-02-21

申请号：US16074482

申请日：2017-01-19

Applicant: Toray Industries, Inc.

Inventor： Yusuke Tojo ,  Makito Yokoe ,  Hideyuki Umetsu

IPC: C08L67/02

Abstract: A thermoplastic polyester resin composition is obtained by blending, per 100 parts by weight of (A) a thermoplastic polyester resin, 0.1 to 5 parts by weight of (B) a novolac type epoxy resin having a specific structure, and 0.05 to 10 parts by weight of (C) an epoxy compound having two epoxy functional groups per molecule. Thus, a molded article that exhibits superior melt stability with respect to a wide range of processing temperatures, has excellent mechanical properties and heat resistance, and exhibits superior long-term hydrolysis resistance, chemical resistance, and oxidative deterioration resistance can be obtained.