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21.发明申请公开(公告)号：US20120305836A1
公开(公告)日：2012-12-06
申请号：US13150844
申请日：2011-06-01
IPC分类号： B01J23/889 , C09K3/00
CPC分类号： B01J23/883 , C10G3/46 , C10G65/04 , C10G2300/1011 , Y02P30/20
摘要： Embodiments of methods and catalysts for deoxygenating a biomass-derived pyrolysis oil are provided. The method comprises the step of contacting the biomass-derived pyrolysis oil with a first deoxygenating catalyst in the presence of hydrogen at first predetermined hydroprocessing conditions to form a first low-oxygen biomass-derived pyrolysis oil effluent. The first deoxygenating catalyst comprises a neutral catalyst support, nickel, cobalt, and molybdenum. The first deoxygenating catalyst comprises nickel in an amount calculated as an oxide of from about 0.1 to about 1.5 wt. %.
摘要翻译： 提供了用于脱氧生物质衍生的热解油的方法和催化剂的实施方案。 该方法包括在第一预定加氢处理条件下，在氢存在下使生物质衍生的热解油与第一脱氧催化剂接触的步骤，以形成第一低氧生物质衍生的热解油流出物。 第一脱氧催化剂包括中性催化剂载体，镍，钴和钼。 第一脱氧催化剂包括以约0.1至约1.5重量％的氧化物计算的量的镍。 ％。
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22.发明授权Production of blended gasoline and blended aviation fuel from renewable feedstocks 有权从可再生原料生产混合汽油和混合航空燃料公开(公告)号：US08324438B2
公开(公告)日：2012-12-04
申请号：US12418994
申请日：2009-04-06
CPC分类号： C10G3/52 , C10G3/46 , C10G3/47 , C10G3/49 , C10G69/00 , C10G69/02 , C10G69/14 , C10G2300/1014 , C10G2300/1018 , C10G2300/1022 , C10G2300/1037 , C10G2300/4081 , C10G2300/80 , C10G2400/02 , C10G2400/04 , C10G2400/08 , Y02P30/20
摘要： A process for producing at least one blended fuel from a paraffin rich component and a cyclic rich component, where each of the components are generated from a renewable feedstock, is presented. The paraffin rich component is generated from glycerides and free fatty acids in feedstocks such as plant and animal oils. The cyclic rich component is generated from biomass derived pyrolysis oil. The source of the animal or plant oil and the biomass may be the same renewable source.
摘要翻译： 提出了一种从富含链烷烃的组分和富含氟的组分制备至少一种混合燃料的方法，其中每种组分由可再生原料生成。 富含石蜡的组分由原料如植物油和动物油中的甘油酯和游离脂肪酸产生。 循环富成分由生物质衍生的热解油产生。 动物或植物油和生物质的来源可能是相同的可再生能源。
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23.发明申请METHODS FOR PRODUCING BIOMASS-DERIVED PYROLYSIS OILS HAVING INCREASED PHASE STABILITY 有权用于生产具有增加的相稳定性的生物质衍生的热解油的方法公开(公告)号：US20110120909A1
公开(公告)日：2011-05-26
申请号：US12949077
申请日：2010-11-18
申请人： Timothy A. Brandvold
发明人： Timothy A. Brandvold
IPC分类号： C10L1/02
摘要： A process for stabilizing pyrolysis oil has been developed. The process involves heating the pyrolysis oil at a temperature of about 40° C. to about 85° C. under a reducing atmosphere for a time to stabilize the oil. The reducing atmosphere or gas is preferably hydrogen.
摘要翻译： 已经开发了用于稳定热解油的方法。 该方法包括在还原气氛下在约40℃至约85℃的温度下加热热解油一段时间以稳定油。 还原性气体或气体优选为氢。
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24.发明申请Process for the Production of Methanol from Methane using a Supported Transition Metal Catalyst 审中-公开使用支持的过渡金属催化剂从甲烷生产甲醇的方法公开(公告)号：US20080249197A1
公开(公告)日：2008-10-09
申请号：US11697774
申请日：2007-04-09
IPC分类号： C07C27/06
CPC分类号： C07C29/095 , C07C67/035 , C07C31/04 , C07C69/63
摘要： A process for the selective oxidation of methane to methanol using a supported transition metal catalyst has been developed. Examples of the transition metals which can be used are copper and palladium, while an example of a support is silica. Optionally, the catalyst can contain a modifier component such as cesium. Generally the process involves contacting a gas stream, comprising methane, a solvent such as trifluoroacetic acid and an oxidizing agent such as air or hydrogen peroxide with the catalyst, at oxidation conditions to produce a methyl ester, e.g. methyl trifluoroacetate. Finally, the methyl ester is hydrolyzed to yield a methanol product stream.
摘要翻译： 已经开发了使用负载型过渡金属催化剂将甲烷选择性氧化成甲醇的方法。 可以使用的过渡金属的实例是铜和钯，而载体的实例是二氧化硅。 任选地，催化剂可以含有改性剂组分如铯。 通常，该方法包括在氧化条件下使包含甲烷的气流，诸如三氟乙酸的溶剂和氧化剂（例如空气或过氧化氢）与催化剂接触，以产生甲酯，例如甲酯。 三氟乙酸甲酯。 最后，将甲酯水解，得到甲醇产物流。
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公开(公告)号：US07361792B2
公开(公告)日：2008-04-22
申请号：US11311037
申请日：2005-12-19
IPC分类号： C07C407/00
CPC分类号： C10L1/1811 , B01J23/002 , B01J23/34 , B01J2523/00 , C07B41/14 , B01J2523/22 , B01J2523/72 , B01J2523/11 , B01J2523/12 , B01J2523/51 , B01J2523/48
摘要： A process and catalyst for preparing organic hydroperoxides by oxidizing hydrocarbon compounds in the presence of an oxygen-containing gas and a catalyst containing a transition metal on a solid support.
摘要翻译： 一种通过在含氧气体和含有过渡金属的催化剂存在下在固体载体上氧化烃化合物来制备有机氢过氧化物的方法和催化剂。
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26.发明授权Process for separating chiral compounds using a unimodal large pore silica as the support 失效使用单峰大孔二氧化硅作为载体分离手性化合物的方法
公开(公告)号：US6106724A
公开(公告)日：2000-08-22
申请号：US281992
申请日：1999-03-29
申请人： Beth McCulloch , Timothy A. Brandvold , Peter K. Nickl , Jennifer S. Holmgren , Joseph J. Alcaraz
发明人： Beth McCulloch , Timothy A. Brandvold , Peter K. Nickl , Jennifer S. Holmgren , Joseph J. Alcaraz
IPC分类号： B01D15/38 , B01J20/286 , B01J20/29 , B01D15/08 , B01D15/00 , B01J49/00 , C02F1/28 , C02F1/42
CPC分类号： B01D15/3833 , B01J20/103 , B01J20/28057 , B01J20/2809 , B01J20/286 , B01J20/29 , B01J20/3204
摘要： A process for separating one chiral compound from a mixture of chiral compounds is disclosed. The separation process involves using a chiral stationary phase (CSP) which comprises a chiral organic material deposited on an amorphous silica support having a unimodal distribution of pore sizes in the range of about 300 .ANG. to about 25,000 .ANG. and a surface area of less than about 30 m.sup.2 /g.
摘要翻译： 公开了从手性化合物的混合物中分离一个手性化合物的方法。 分离方法包括使用手性固定相（CSP），其包含沉积在无定形二氧化硅载体上的手性有机材料，所述手性有机材料具有在约300安培至约25,000安培范围内的孔径的单峰分布，并且表面积小于约 30 m2 / g。
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公开(公告)号：US5889180A
公开(公告)日：1999-03-30
申请号：US966740
申请日：1997-11-10
CPC分类号： B01J20/286 , B01J20/28078 , B01J20/29 , B01J20/3204 , B01J20/3274 , B01J20/3293 , C07B57/00 , B01J2220/54
摘要： Small pore silicas serving as the inert core support in chiral stationary phases show a surprising increase in column capacity relative to conventional chiral stationary phases having large pore silicas as the inert core support. This affords increased productivity and lower overall costs for chiral resolutions using a chiral stationary phase as adsorbent and an achiral liquid as eluant.
摘要翻译： 用作手性固定相中的惰性核心载体的小孔二氧化硅相对于具有大孔二氧化硅作为惰性核心载体的常规手性固定相，显示了柱容量惊人的增加。 这提供了增加的生产率和降低使用手性固定相作为吸附剂和非手性液体作为洗脱剂的手性拆分的总体成本。
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28.发明授权Process for separating linear and branched hydrocarbons using alkylene-bridged polysilsesquioxanes 失效使用亚烷基桥连聚倍半硅氧烷分离线性和支链烃的方法
公开(公告)号：US5476985A
公开(公告)日：1995-12-19
申请号：US357901
申请日：1994-12-16
IPC分类号： C07C7/12
CPC分类号： C07C7/12
摘要： An adsorptive process to separate the components of a solution of linear and branched hydrocarbons into a linear hydrocarbon portion and a branched hydrocarbon portion where the adsorbent is an alkylene-bridged polysilsesquioxane has been developed. The hydrocarbon components to be separated may be alkanes, alkenes, or alkynes, and the alkylene-bridging group of the adsorbent may contain from about 2 to about 14 carbon atoms. A specific embodiment of the invention is one where the process is operated in the simulated moving bed mode.
摘要翻译： 已经开发了将线性和支链烃溶液的组分分离成直链烃部分和支链烃部分的吸附方法，其中吸附剂是亚烷基桥连的聚倍半硅氧烷。 待分离的烃组分可以是烷烃，烯烃或炔烃，并且吸附剂的亚烷基桥连基团可以含有约2至约14个碳原子。 本发明的一个具体实施例是以模拟移动床模式操作该过程的实施例。
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29.发明授权Process for controlling the simultaneous production of diesel and jet fuel range paraffins by blending feedstocks 有权通过混合原料控制同时生产柴油和喷气燃料范围石蜡的方法公开(公告)号：US08927795B2
公开(公告)日：2015-01-06
申请号：US13475630
申请日：2012-05-18
CPC分类号： C10G45/58 , C10G3/42 , C10G3/50 , C10G3/60 , C10G2300/1014 , C10G2300/1018 , C10G2400/04 , C10G2400/08 , C10L1/08 , Y02E50/13 , Y02P30/20 , Y02T50/678
摘要： A process for controlling the simultaneous production of hydrocarbons with boiling points in both the diesel fuel range and the aviation fuel range from renewable feedstocks originating from plants or animals other than petroleum feedstocks is described. The hydrocarbon product can be adjusted by changing the feedstocks without requiring different process equipment.
摘要翻译： 描述了用于控制柴油燃料范围和航空燃料范围内沸点同时生产烃类的方法，该方法来自除石油原料以外的植物或动物的可再生原料。 可以通过改变原料而不需要不同的工艺设备来调节烃产物。
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30.发明授权公开(公告)号：US08927793B2
公开(公告)日：2015-01-06
申请号：US13194718
申请日：2011-07-29
IPC分类号： C07C1/00 , C10K1/00 , C10K1/34 , C10K3/02 , C10B49/22 , C10B53/02 , C10B57/06 , C10B57/18 , C10C5/00 , B01J23/00 , B01J23/02 , B01J29/08
CPC分类号： C10K1/00 , B01J23/007 , B01J23/02 , B01J29/082 , C10B49/22 , C10B53/02 , C10B57/06 , C10B57/18 , C10C5/00 , C10G2300/1014 , C10K1/34 , C10K3/026 , Y02E50/14 , Y02P30/20
摘要： Processes for producing reduced acid lignocellulosic-derived pyrolysis oil are provided. In a process, lignocellulosic material is fed to a heating zone. A basic solid catalyst is delivered to the heating zone. The lignocellulosic material is pyrolyzed in the presence of the basic solid catalyst in the heating zone to create pyrolysis gases. The oxygen in the pyrolysis gases is catalytically converted to separable species in the heating zone. The pyrolysis gases are removed from the heating zone and are liquefied to form the reduced acid lignocellulosic-derived pyrolysis oil.
摘要翻译： 提供了生产降低的酸性木素纤维素衍生的裂解油的方法。 在一个过程中，将木质纤维素材料送入加热区。 碱性固体催化剂被输送到加热区。 木质纤维素材料在碱性固体催化剂存在下在加热区中热解，以产生热解气体。 热解气体中的氧气在加热区域被催化转化为可分离的物质。 热解气体从加热区被去除，并被液化以形成还原酸木质纤维素衍生的裂解油。
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