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21.发明申请公开(公告)号：US20180179450A1
公开(公告)日：2018-06-28
申请号：US15783843
申请日：2017-10-13
Applicant: UOP LLC
Inventor： Avram M. Buchbinder , Stanley J. Frey , Karl Z. Steigleder
IPC: C10G11/05
CPC classification number: C10G11/05 , C10G2300/70 , C10G2400/20 , C10G2400/30
Abstract: The process for producing light olefins comprises the steps of contacting a feed stream comprising C4 to C11 hydrocarbons having at least 10 wt % paraffins and at least 15 wt % alkylaromatics with an acidic catalyst to form a cracked product comprising light olefins and aromatics. The catalyst comprises about 30 to about 80 wt-% of a crystalline zeolite and a low-acidic binder and may be regenerated.
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22.发明授权Method for recovering entrained ionic liquid from an ionic liquid immiscible phase 有权从离子液体不混溶相中回收夹带的离子液体的方法公开(公告)号：US09328296B2
公开(公告)日：2016-05-03
申请号：US14229462
申请日：2014-03-28
Applicant: UOP LLC
Inventor： Avram M. Buchbinder , Susie C. Martins , Sean Glennon Thomas Mueller , Kurt Detrick , Zhanping Xu
CPC classification number: C10G29/205 , B01D17/047 , C10G2300/70
Abstract: A method for recovering entrained ionic liquid from an immiscible phase containing droplets of ionic liquid is described. The method includes contacting the immiscible phase containing the droplets of ionic liquid with a scrubbing ionic liquid phase in a scrubbing zone. The immiscible phase containing the droplets of ionic liquid has a first level of droplets of ionic liquid. At least a portion of the droplets of ionic liquid are transferred to the scrubbing ionic liquid phase to form a recovered ionic liquid phase comprising the scrubbing ionic liquid and the transferred portion of the droplets of ionic liquid and a second immiscible phase having a second level of droplets of ionic liquid lower than the first level. The second immiscible phase is separated from the recovered ionic liquid phase.
Abstract translation: 描述了从含有离子液体的液滴的不混溶相中回收夹带的离子液体的方法。 该方法包括使含有离子液体的液滴的不混溶相与洗涤区中的洗涤离子液相接触。 含有离子液体液滴的不混溶相具有离子液体的第一级液滴。 离子液体的至少一部分液滴被转移到洗涤离子液相以形成回收的离子液相，其包含洗涤离子液体和离子液体的液滴的转移部分和具有第二水平的第二不混溶相 离子液滴小于第一级。 第二不混溶相与回收的离子液相分离。
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23.发明申请公开(公告)号：US20150273460A1
公开(公告)日：2015-10-01
申请号：US14229290
申请日：2014-03-28
Applicant: UOP LLC
Inventor： Avram M. Buchbinder , Susie C. Martins , John Q. Chen
CPC classification number: B01J31/4092 , B01J31/0225 , B01J31/0227 , B01J31/0277 , B01J31/40 , C10L1/16 , C10L2290/24
Abstract: Methods for regenerating deactivated acidic catalyst containing conjunct polymer are described. The deactivated acidic catalyst containing conjunct polymer is contacted with at least one aromatic compound in a regeneration zone under regeneration conditions. The conjunct polymer reacts with the at least one aromatic compound resulting in a regenerated acidic catalyst and at least one aromatic compound alkylated with conjunct polymer. The acidic catalyst is selected from the group consisting of sulfuric acid, hydrofluoric acid, trifluoromethanesulfonic acid, phosphoric acid, boron trifluoride, toluenesulfonic acid, trifluoroacetic acid, and acidic ionic liquids.
Abstract translation: 描述了用于再生失活的含酸性催化剂的结合聚合物的方法。 含有结合聚合物的失活酸性催化剂在再生条件下与再生区中的至少一种芳族化合物接触。 结合的聚合物与至少一种芳族化合物反应，产生再生的酸性催化剂和至少一种用结合聚合物烷基化的芳族化合物。 酸性催化剂选自硫酸，氢氟酸，三氟甲磺酸，磷酸，三氟化硼，甲苯磺酸，三氟乙酸和酸性离子液体。
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24.发明申请公开(公告)号：US20150094486A1
公开(公告)日：2015-04-02
申请号：US14039703
申请日：2013-09-27
Applicant: UOP LLC
Inventor： Avram M. Buchbinder , Alakananda Bhattacharyya , Praneeth D. Edirisinghe , Joel T. Walenga
IPC: C07C51/29
CPC classification number: C07C51/265 , B01J31/0284 , B01J2231/70 , Y02P20/542 , C07C63/26
Abstract: Ionic liquid compositions derived from imidazolium based ionic liquids that have been thermally treated or thermally and oxidatively treated are disclosed. These compositions can be utilized as the medium for oxidation of alkylaromatic compounds and their oxidized derivatives or as a medium for purification of aromatic carboxylic acids.
Abstract translation: 公开了衍生自经过热处理或热氧化处理的基于咪唑鎓的离子液体的离子液体组合物。 这些组合物可用作烷基芳族化合物及其氧化衍生物或芳族羧酸纯化介质的氧化介质。
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公开(公告)号：US12102986B2
公开(公告)日：2024-10-01
申请号：US17838063
申请日：2022-06-10
Applicant: UOP LLC
Inventor： Xi Zhao , Avram M. Buchbinder , J. W. Adriaan Sachtler , Wei Pan , John A. Karch
CPC classification number: B01J23/62 , B01J35/613 , B01J37/0209 , C10G29/04 , B01J2523/32 , B01J2523/828 , C10G2300/1081 , C10G2300/1096
Abstract: A de-hydrogenation catalyst and its use in dehydrogenation of hydrocarbons. The catalyst has low cracking activity and comprises gallium or gallium and platinum on an essentially non-acidic and amorphous alumina-phosphate or silica-alumina-phosphate support with an empirical chemical composition of [Al2O3][SiO2]Y[P2O5]Z, wherein Y is between 0 and 0.2 and Z is between 0.01 and 1.1, with a BET surface area above 50 m2/g, as measured by N2 adsorption experiment.
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Patent Agency Ranking
公开(公告)号：US11926800B2
公开(公告)日：2024-03-12
申请号：US17574439
申请日：2022-01-12
Applicant: UOP LLC
Inventor： Avram M. Buchbinder , John J. Senetar , Wei Pan , Wolfgang A Spieker , Richard A. Johnson, II
CPC classification number: C10G35/09 , B01J23/96 , B01J38/02 , C10G2300/1085 , C10G2400/20
Abstract: A fluidized catalytic reactor system cycles from 0.05-5% of catalyst at a time through a rejuvenation unit to be heated in the presence of oxygen to maintain catalyst activity. The use of the rejuvenation unit that may be 2% of the size of the main catalyst regeneration unit allows for reduction in equipment size and in catalyst inventory. The catalyst that is sent to the rejuvenation unit may be spent catalyst but may be partially or fully regenerated catalyst. The rejuvenation unit may be heated by combusting fuel or by hot flue gas.
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公开(公告)号：US20220135887A1
公开(公告)日：2022-05-05
申请号：US17574439
申请日：2022-01-12
Applicant: UOP LLC
Inventor： Avram M. Buchbinder , John J. Senetar , Wei Pan , Wolfgang A. Spieker , Richard A. Johnson, II
Abstract: A fluidized catalytic reactor system cycles from 0.05-5% of catalyst at a time through a rejuvenation unit to be heated in the presence of oxygen to maintain catalyst activity. The use of the rejuvenation unit that may be 2% of the size of the main catalyst regeneration unit allows for reduction in equipment size and in catalyst inventory. The catalyst that is sent to the rejuvenation unit may be spent catalyst but may be partially or fully regenerated catalyst. The rejuvenation unit may be heated by combusting fuel or by hot flue gas.
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公开(公告)号：US10814317B2
公开(公告)日：2020-10-27
申请号：US16128151
申请日：2018-09-11
Applicant: UOP LLC
Inventor： Avram M. Buchbinder , Hayim Abrevaya , Gavin P. Towler
Abstract: A process utilizing a micro-emulsion is described. The micro-emulsion formed by contacting an ionic liquid, a co-solvent, a hydrocarbon, an optional surfactant, and an optional catalyst promoter to form the micro-emulsion. The micro-emulsion comprises a hydrocarbon component comprising the hydrocarbon and an ionic liquid component comprising the ionic liquid. The ionic liquid comprises a halometallate anion and a cation. The co-solvent has a polarity greater than a polarity of the hydrocarbon. The ionic liquid is present in an amount of 0.05 wt % to 40 wt % of the micro-emulsion. A product mixture comprising a product is produced in a process zone containing the micro-emulsion.
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公开(公告)号：US10596561B2
公开(公告)日：2020-03-24
申请号：US15713017
申请日：2017-09-22
Applicant: UOP LLC
Inventor： Avram M. Buchbinder , Hayim Abrevaya , Gavin P. Towler
Abstract: A micro-emulsion and a method of making the micro-emulsion are described. The micro-emulsion includes a hydrocarbon component, an ionic liquid component, and a co-solvent. The ionic liquid comprises a halometallate anion and a cation. The micro-emulsion can optionally include a surfactant, and a catalyst promoter. The co-solvent has a polarity greater than the polarity of the hydrocarbon. The ionic liquid is present in an amount of about 0.05 wt % to about 40 wt % of the micro-emulsion.
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30.发明申请公开(公告)号：US20190105644A1
公开(公告)日：2019-04-11
申请号：US16209738
申请日：2018-12-04
Applicant: UOP LLC
Inventor： Avram M. Buchbinder , Susie C. Martins , Douglas A. Nafis , Donato Nucciarone
Abstract: A trialkylphosphonium haloaluminate compound having a formula: where R1, R2, and R3 are the same or different and each is independently selected from C1 to C8 hydrocarbyl; and X is selected from F, Cl, Br, I, or combinations thereof is described. An ionic liquid catalyst composition incorporating the trialkylphosphonium haloaluminate compound, methods of making the trialkylphosphonium haloaluminate compound, and alkylation processes incorporating the trialkylphosphonium haloaluminate compound are also described.
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