摘要:
Fluoropolyethers having functional groups, consisting of randomly distributed sequences of perfluoropolyoxyalkylene units selected from: ##STR1## where X is F or CF.sub.3 T, T', T"=a perfluoroalkyl group containing from 1 to 3 carbon atoms and one or two atoms of Cl, Br or I;R, R'=halogen atoms;Y=a functional group;o, q=numbers, zero included, such that o+q=1-20;n=a number ranging from 1 to 15;m/n=a number ranging from 0.01 to 0.5;p=a number ranging from 1 to 20;s/p=a number ranging from 0.5 to 2; andz/o+p=a number ranging from 0.01 to 0.05.
摘要翻译:具有官能团的含氟聚醚,其由随机分布的全氟聚氧化烯单元序列组成,其选自:其中X为F或CF 3 T,T',T“=含有1至3个碳原子和1或2个Cl原子的全氟烷基,Br 或我; R,R'=卤素原子; Y =官能团; o,q =数字,包括零,使得o + q = 1-20; n = 1到15之间的数字; m / n = 0.01〜0.5的数; p = 1到20之间的数字; s / p =从0.5到2的数字; z + o + p = 0.01〜0.05的数。
摘要:
Method for the water removal from a surface, which comprises covering the surface with a composition having specific weight higher than that of the water, and subsequently removing water from the composition by skimming, such composition comprising a (per)fluoropolyether having molecular weight comprised between 300 and 1500 and a non ionic additive having a (per-fluoropolyethereal structure similar to that of the solvent, linked to an hydrogenated part of hydrophilic type, the molecular weight of the (per)fluorinated part is comprised between 400 and 1200 and the ratio by weight between (per)fluorinated part and hydrogenated part is comprised between 1.5 and 3.5.
摘要:
A method of protecting objects from graffiti using fluorinated polymers based on fluoropolyethers in a dry formulation wherein the fluorinated polymer includes a fluorinated part R.sub.F and optionally an hydrogenated part R.sub.H not containing groups capable of linking to basic acceptors by means of hydrogen bonds, the bonds linking the fluorinated part, derived from (per)fluoropolyethers, to the hydrogenated part being of simple C--O ether type, the T' terminal groups being such as to render the structure bi- or polyfunctional thus making possible the curing reaction, and subsequent curing of the fluorinated polymer.
摘要:
A fluorination catalyst based on of an amorphous Cr (III) compound and on a compound of another metal selected from Mg, Ca, Sr, Ba, Sc, Ti and Zr, wherein the atomic ratio of Cr/other metal is between 50:1 and 1:1, said compounds are supported on a AlF.sub.3 support and being prepared by impregnating the support with a concentrated aqueous solution containing a soluble Cr (III) salt and a soluble salt of the other metal. The catalyst can be used in gaseous phase reactions.
摘要:
Perfluoropolyethereal compounds having polycarbonate structure, and general formula: ##STR1## wherein c is an integer comprised between 0 and 10, preferably between 0 and 3,n is an integer from 2 to 1,000, extremes included,Rf is a poly-fluorooxyalkylenic chain, having number average molecular weight (Mn) comprised between 500 and 10,000.
摘要:
Use of amorphous perfluoropolymers based on homopolymers of the TTD dioxole or its amorphous copolymers to prepare solutions in fluoro-containing solvents, to obtain solutions for coatings, wherein TTD has the formula: ##STR1## wherein R.sub.F is a perfluoroalkylic radical with 1-5 carbon atoms, linear or branched when possible; X.sub.1 and X.sub.2 equal to or different from each other being F or CF.sub.3 ; the TTD amount ranges from 40 to 100% by moles.
摘要翻译:使用基于TTD二氧杂环戊烯或其无定形共聚物的均聚物的无定形全氟聚合物在含氟溶剂中制备溶液,以获得涂料溶液,其中TTD具有下式:其中RF是具有1-5个碳的全氟烷基 原子,可以是直链或支链的; X 1和X 2彼此相同或不同,是F或CF 3; TTD量为40-100摩尔%。
摘要:
Polytetrafluoroethylene (PTFE) dispersions in an organic solvent, comprising: (A) from 2 to 40% by weight of PTFE in powder form; (B) from 50 to 95% by weight of an organic solvent; (C) from 0.5 to 10% by weight of a dispersing agent of formula: (R.sub.H --L).sub.y --(R.sub.F --L).sub.x R.sub.H (I) wherein: x is an integer from 1 to 3; y is 0 or 1, with the proviso that x=1 when y=1; R.sub.H is a x-functional radical having an alkylic or polyoxyalkylenic structure; R.sub.F is (per)fluoropolyoxyalkylenic radical; L is a divalent organic group. Such dispersions are utilized for the surface treatment of metals, glass fibers, and the like, and in particular as mold release agents.
摘要:
Tetrafluoroethylene oxidation process at temperatures comprised between -80.degree. C. and -40.degree. C. in the presence of UV radiations and pentafluoropropane as solvent.
摘要:
Process for preparing perfluoropolyethers with bromo- or iodo- containing end groups, respectively, by subjecting a peroxidic perfluoropolyether to thermal treatment, in the absence of UV radiation, at temperatures from 120.degree. C. to 280.degree. C. in the presence of bromo- or iodo-containing compounds having, respectively, the following general formulas: T T' T" C Br wherein T, T', T" equal to or different from each other are selected from Br, F, H or R'.sub.f, wherein R'.sub.f is a perfluoroalkylic chain from 1 to 8 carbon atoms; R R' R" C I wherein R, R', R", equal to or different from each other can be I (iodine), H, F, or R'.sub.f, wherein R'.sub.f has the meaning indicated above.
摘要:
New phosphazene derivatives, fully substituted by aromatic groups and perfluoropolyethereal chains, are utilized as stabilizers for oils and greases based on perfluoropolyethers. Such derivatives inhibit the degradation process affecting the perfluoropolyethereal chains when these are subjected to high temperatures in an oxidizing atmosphere and in the presence of metals, such as for example aluminium, titanium, vanadium and their alloys, or steels.