4-Mercaptophenyl ester of acetic acid and process for producing the same
    21.
    发明申请
    4-Mercaptophenyl ester of acetic acid and process for producing the same 审中-公开
    乙酸4-巯基苯酯及其制备方法

    公开(公告)号:US20090082590A1

    公开(公告)日:2009-03-26

    申请号:US11918618

    申请日:2006-04-26

    IPC分类号: C07C321/26 C07C319/02

    摘要: The present invention provides a 4-mercaptophenyl ester of acetic acid, which is useful as a raw material for synthesizing a developer, etc., and a process for producing the same. The present invention provides a 4-mercaptophenyl ester of acetic acid represented by Formula (1); wherein Ac is an acetyl group, and R is a C1-4 alkyl group, and a process for producing the 4-mercaptophenyl ester of acetic acid having a step of reducing a 4-halosulfonylphenyl ester of acetic acid represented by Formula (2); wherein Ac is an acetyl group, R is a C1-4 alkyl group, and X is a halogen atom.

    摘要翻译: 本发明提供了可用作合成显影剂等的原料的乙酸4-巯基苯酯及其制备方法。 本发明提供由式(1)表示的乙酸4-巯基苯酯; 其中Ac是乙酰基,R是C1-4烷基,以及制备具有还原由式(2)表示的乙酸的4-卤代磺酰基苯基酯的步骤的乙酸4-巯基苯酯的方法; 其中Ac是乙酰基,R是C 1-4烷基,X是卤素原子。

    Sulphonation of phenols
    23.
    发明授权

    公开(公告)号:US06936732B2

    公开(公告)日:2005-08-30

    申请号:US10490361

    申请日:2002-09-18

    摘要: A process for the preparation of sulphonated phenols of general formula (I) where R1 is hydrogen, a C1-C20 alkyl group which is unsubstituted or substituted by halogen, cyano, hydroxyl, C1-C20 alkoxy, C2-C20 alkoxycarbonyl, acyloxy and/or phenyl which is unsubstituted or substituted by C1-C4 alkyl, C1-C4 alkoxy and/or halogen, R2 is hydrogen, C1-C20 alkyl or benzoyl of general formula (II) where R3 and R4 independently of one another are each hydrogen, halogen, C1-C12 alkyl, C1-C12 alkoxy, C1-C4 haloalkyl, C3-C8 cycloalkyl, C4-C12 cycloalkylalkyl, cyano, hydroxyl, or hydroxyethyl or are each phenoxy, C7-C10 phenylalkyl or phenyl which is unsubstituted or substituted by C1-C4 alkyl, C1-C4 alkoxy and/or halogen, and R5 is hydrogen or the group SO3X where X can be hydrogen, a monovalent metal or a group —N(R6)3, where each of the three radicals R6 can be independently of one another hydrogen, C1-C6 alkyl or C1-C6 hydroxy alkyl, which process comprises reacting a phenol of general formula (III) where R1 and R2 are as defined above, with a halosulphonic acid in a solvent which is a mixture of a C5-C10 aliphatic or cycloaliphatic hydrocarbon and a dialkyl carbonate of general formula (IV) R7—O—CO—O—R8 where R7 and R8 each represent independently a C1-C4 alkyl group

    Process for preparing acyloxybenzenesulfonates
    26.
    发明申请
    Process for preparing acyloxybenzenesulfonates 失效
    酰氧基苯磺酸盐的制备方法

    公开(公告)号:US20040198995A1

    公开(公告)日:2004-10-07

    申请号:US10755950

    申请日:2004-01-13

    申请人: Clariant GmbH

    IPC分类号: C07C39/28

    摘要: A process for preparing acyloxybenzenesulfonates by reacting a carboxylic acid derivative with a salt of a phenolsulfonic acid in the presence of an antioxidant, preferably 2,6-di-tert-butyl-4-methylphenol. The addition of such antioxidants gives a product having a high color quality.

    摘要翻译: 一种通过使羧酸衍生物与苯酚磺酸的盐在抗氧化剂,优选2,6-二叔丁基-4-甲基苯酚的存在下反应来制备酰氧基苯磺酸盐的方法。 添加这样的抗氧化剂可以提供具有高颜色品质的产品。

    Surface coating agents
    27.
    发明授权
    Surface coating agents 有权
    表面涂层剂

    公开(公告)号:US06603040B1

    公开(公告)日:2003-08-05

    申请号:US09888709

    申请日:2001-06-25

    申请人: Dale G. Swan

    发明人: Dale G. Swan

    IPC分类号: C07C30928

    摘要: Compounds useful as surface coating agents, including compounds of the formula: wherein X1 comprises a first photoreactive species; X2 comprises a second photoreactive species; Y comprises a nonpolymeric core molecule comprising an aromatic group; and Z comprises at least one charged group. The Y core can include an aromatic group such as a benzene radical, the charged groups Z can be independently selected from the organic acids that include sulfonic acid, carboxylic acid, and phosphoric acid, and the photoreactive species of X1 and X2 can independently be aryl ketones, such as those selected from the group acetophenone, benzophenone, anthraquinone, anthrone, and anthrone-like heterocycles, and their substituted derivatives. Examples of such coating agents include 4,5-bis(4-benzoylphenylmethyleneoxy) benzene-1,3-disulfonic acid di(potassium and/or sodium) salt, 2,5-bis(4-benzoylphenylmethyleneoxy) benzene-1,4-disulfonic acid di(potassium and/or sodium) salt (Compound II), and 2,5-bis(4-benzoylphenylmethyleneoxy) benzene-1-sulfonic acid monopotassium and/or monosodium salt.

    摘要翻译: 可用作表面包衣剂的化合物,包括下式的化合物:其中X1包含第一光反应性物质; X2包含第二光反应性物质; Y包含含有芳基的非聚合核心分子; Z包含至少一个带电基团。 Y芯可以包括苯基等芳基,带电基团Z可以独立地选自包括磺酸,羧酸和磷酸的有机酸,并且X1和X2的光反应性物质可以独立地为芳基 酮,例如选自苯乙酮,二苯甲酮,蒽醌,蒽酮和蒽酮类杂环的那些,及其取代的衍生物。 这种包衣剂的实例包括4,5-双(4-苯甲酰基苯基亚甲基氧基)苯-1,3-二磺酸二(钾和/或钠)盐,2,5-双(4-苯甲酰基苯基亚甲基氧基)苯-1,4- 盐(二盐酸盐)(化合物II)和2,5-双(4-苯甲酰基苯基亚甲基氧基)苯-1-磺酸单钾盐和/或单钠盐。

    Process for forming amido esters utilizing a spinning disc reactor
    29.
    发明授权
    Process for forming amido esters utilizing a spinning disc reactor 失效
    使用旋转盘式反应器形成酰胺酯的方法

    公开(公告)号:US06515153B2

    公开(公告)日:2003-02-04

    申请号:US09943453

    申请日:2001-08-30

    IPC分类号: C07C23100

    摘要: The present invention relates to the formation of an amido ester having the formula: R1—CO—NR3—R2—COL or R1—NR3—CO—R2—COL wherein R1 is C1-C12 linear or branched alkyl, C6-C14 aryl, C7-C14 alkyl substituted aryl unit; R2 is C1-C14 alkylene, C6-C14 arylene, C7-C14 alkyl substituted arylene; R3 is hydrogen, C1-C10 alkyl, C6-C10 aryl, C7-C10 alkyl substituted aryl, L is a aryl leaving group having the formula: R4 comprises one or more anionic or cationic units, wherein said compound is formed using a spinning disc reactor.

    摘要翻译: 本发明涉及具有下式的酰氨基酯的形成:其中R1是C1-C12直链或支链烷基,C6-C14芳基,C7-C14烷基取代的芳基单元; R2是C1-C14亚烷基,C6-C14亚芳基,C7-C14烷基取代的亚芳基; R3是氢,C1-C10烷基,C6-C10芳基,C7-C10烷基取代的芳基,L是具有下式的芳基离去基团:R4包含一个或多个阴离子或阳离子单元,其中所述化合物使用旋转盘 反应堆。

    Process for preparing and/or purifying amido acid phenyl ester sulfonates
    30.
    发明授权
    Process for preparing and/or purifying amido acid phenyl ester sulfonates 失效
    酰胺酸苯酯磺酸盐的制备和/或纯化方法

    公开(公告)号:US06369250B1

    公开(公告)日:2002-04-09

    申请号:US09485988

    申请日:2000-02-17

    IPC分类号: C07C23100

    摘要: The present invention relates to a process for the preparation of a purified salt of 4-sulfophenyl-[(1-oxyalkanoyl)amino]alkanoate. The process comprises the steps of: (a) providing a source of 4-sulfophenyl-[(1-oxyalkanoyl)amino]alkanoate; (b) admixing the source with a water-based purification system to form a purification mixture, the water-based purification system having water present at a ratio of 4-sulfophenyl-[(1-oxyalkanoyl)amino]alkanoate to water ranging from about 1:0.05 to about 1:50, preferably from about 1:0.1 to about 1:40; (c) separating a purified salt of 4-sulfophenyl-[(1-oxyalkanoyl)amino]alkanoate from the purification mixture; and (d) collecting said purified salt of 4-sulfophenyl-[(1-oxyalkanoyl)amino]alkanoate. In preferred embodiments, the purification mixture includes a processin aide such as ethyl alcohol, propyl alcohol, isopropyl alcohol, acetone and mixtures thereof.

    摘要翻译: 本发明涉及制备4-磺基苯基 - [(1-氧代烷酰基)氨基]链烷酸酯的纯化盐的方法。 该方法包括以下步骤:(a)提供4-磺基苯基 - [(1-氧代烷酰基)氨基]链烷酸酯的来源; (b)将来源与水基净化系统混合以形成纯化混合物,所述水基净化系统具有以4-磺基苯基 - [(1-氧代烷酰基)氨基]链烷酸酯的比例存在的水与约 1:0.05至约1:50,优选约1:0.1至约1:40; (c)从纯化混合物中分离纯化的4-磺基苯基 - [(1-氧代烷酰基)氨基]链烷酸盐; 和(d)收集所述纯化的4-磺基苯基 - [(1-氧代烷酰基)氨基]链烷酸盐。 在优选的实施方案中,纯化混合物包括处理物,例如乙醇,丙醇,异丙醇,丙酮及其混合物。