摘要:
A process for the manufacture of a functional (per)fluoropolyether derivative comprising at least one triazole group, such process comprising: (1) reacting a (per)fluoropolyether hydroxyl derivative having at least one hydroxyl group [derivative (PFPE-OH)] with an activating agent, to yield an activated (per)fluoropolyether hydroxyl derivative comprising at least one activated hydroxyl group [derivative (a-PFPE-OH)];(2) reacting said activated (per)fluoropolyether hydroxyl derivative [derivative (a-PFPE-OH)] with at least one azide salt to yield a functional (per)fluoropolyether derivative comprising at least one azido group [derivative (PFPE-N3)] ; and (3) reacting said functional (per)fluoropolyether derivative comprising at least one azido group [derivative (PFPE-N3)] with a hydrocarbon compound having a terminal alkyne group to yield a functional (per)fluoropolyether derivative comprising at least one triazole group [derivative (PFPE-azole)].
摘要:
The invention discloses a method for synthesizing hollow structured freestanding membrane having pore size of 2 to 200 nm which provides long-term stability that makes it viable for many practical applications such as protein separation and drug delivery.
摘要:
The invention discloses a method for synthesizing hollow structured freestanding membrane having pore size of 2 to 200 nm which provides long-term stability that makes it viable for many practical applications such as protein separation and drug delivery.
摘要:
The present invention relates to the development of hydrophobically modified polymers [HMPs], which have emerged as promising materials in diverse fields such as paints, cosmetics, oils, food and textiles. They are used as thickeners in these applications. In our study, the hydrophobic modification on PAA was performed using hydrophobic compounds obtained from naturally occurring materials such as Cashew Nut Shell Liquid, [CNSL]. The DCCI coupling method was chosen for the hydrophobic modification of PAA. A series of hydrophobically modified PAAs were synthesized with different degrees of hydrophobic contents and were characterized by solution rheology.
摘要:
A quaternary onium aromatic sulfonate represented by the formula: wherein each R1 independently comprises substituted or unsubstituted, aliphatic or aromatic, hydrocarbyl, carbocyclic or heterocyclic radicals, each X is selected from the group consisting of phosphorus and nitrogen; wherein “a” has a value of 0, 1 or 2, and “b” has a value of 0 or 1 with the proviso that (a+b) is equal to 1 or 2; G1 is an aromatic group; E comprises a bis(carbonyloxyalkyl) polydiorganosiloxane, a bis(carbonyloxyaryl) polydiorganosiloxane, and an ether linkage; each Y1 independently comprises hydrogen, a monovalent hydrocarbon group, alkenyl, allyl, halogen, bromine, chlorine; nitro; and OR, wherein R is a monovalent hydrocarbon group; “q” represents any integer from and including zero through the number of positions on G1 available for substitution; “t” represents an integer equal to at least one; “s” represents an integer equal to either zero or one; and “u” represents any integer including zero; with the proviso that when E is an ether linkage, then X is phosphorus.
摘要:
A process for the manufacture of a functional (per)fluoropolyether derivative comprising at least one triazole group, such process comprising: (1) reacting a (per)fluoropolyether hydroxyl derivative having at least one hydroxyl group [derivative (PFPE-OH)] with an activating agent, to yield an activated (per)fluoropolyether hydroxyl derivative comprising at least one activated hydroxyl group [derivative (a-PFPE-OH)]; (2) reacting said activated (per)fluoropolyether hydroxyl derivative [derivative (a-PFPE-OH)] with at least one azide salt to yield a functional (per)fluoropolyether derivative comprising at least one azido group [derivative (PFPE-N3)]; and (3) reacting said functional (per)fluoropolyether derivative comprising at least one azido group [derivative (PFPE-N3)] with a hydrocarbon compound having a terminal alkyne group to yield a functional (per)fluoropolyether derivative comprising at least one triazole group [derivative (PFPE-azole)].
摘要:
The present invention provides a novel bisphenol compound of formula (I). wherein R1 and R2 are the same or different and are independently either hydrogen or methyl at each occurrence. The present invention also provides a process for preparation of these bisphenol compounds starting from Cashew Nut Shell Liquid (CNSL); —a renewable resource material. The bisphenols prepared in the present invention can be utilized as difunctional monomers for the preparation of various polymers such as epoxy resins, polyesters, polyethersulfones, polyetherketones, polyetherimides, polyarylates, polycarbonates, etc.
摘要:
Compositions exhibiting water resistant anti-static properties prepared from a thermoplastic polymer and a polymeric anti-static salt is disclosed.
摘要:
A quaternary onium aromatic sulfonate represented by the formula: wherein each R1 independently comprises substituted or unsubstituted, aliphatic or aromatic, hydrocarbyl, carbocyclic or heterocyclic radicals, each X is selected from the group consisting of phosphorus and nitrogen; wherein “a” has a value of 0, 1 or 2, and “b” has a value of 0 or 1 with the proviso that (a+b) is equal to 1 or 2; G1 is an aromatic group; E comprises a bis(carbonyloxyalkyl) polydiorganosiloxane, a bis(carbonyloxyaryl) polydiorganosiloxane, and an ether linkage; each Y1 independently comprises hydrogen, a monovalent hydrocarbon group, alkenyl, allyl, halogen, bromine, chlorine; nitro; and OR, wherein R is a monovalent hydrocarbon group; “q” represents any integer from and including zero through the number of positions on G1 available for substitution; “t” represents an integer equal to at least one; “s” represents an integer equal to either zero or one; and “u” represents any integer including zero; with the proviso that when E is an ether linkage, then X is phosphorus.