公开(公告)号：US4085159A

公开(公告)日：1978-04-18

申请号：US681342

申请日：1976-04-28

申请人： Arthur Marsiat

发明人： Arthur Marsiat

IPC分类号： C09D5/03 ,  C08G63/00 ,  C08G63/12 ,  C08G63/88 ,  C08L67/00 ,  C08L67/08 ,  C09D5/25 ,  C09D5/46 ,  C09D163/00 ,  C09D167/00 ,  H01B3/40 ,  H01B3/42 ,  C08L63/00

CPC分类号： H01B3/422 ,  C08G63/12 ,  C09D163/00 ,  C09D167/00 ,  H01B3/40

摘要： Process for the preparation of powdered thermosetting coating composition suitable for application as paint or varnish on electricity-conducting articles by powder spray methods and fluidized bed coating processes, which comprises: in a first stage, preparing a branched-chain hydroxyl group-containing polyester from at least one dicarboxylic organic acid, at least one polycarboxylic aromatic acid and at least one dihydric organic compound; in a second stage, esterifying the hydroxyl group-containing polyester thus obtained with an aromatic or hydroaromatic dicarboxylic acid to give a carboxyl group-containing polyester having an acid number which is substantially equal to the hydroxyl number of the hydroxyl group-containing polyester obtained in the first stage; and in a third stage, homogenously mixing the carboxyl group-containing polyester obtained in the second stage with an epoxy compound containing at least two epoxy groups, and optionally adding auxiliary substances conventionally used in the manufacture of powdered paints and varnishes; and powdered thermosetting compositions suitable as paint or varnish obtained by this process.

摘要翻译： 用于制备粉末状热固性涂料组合物的方法，该组合物适用于通过粉末喷涂方法和流化床涂布方法在导电制品上作为涂料或清漆施用，其包括：在第一阶段中制备含支链羟基的聚酯， 至少一种二羧酸有机酸，至少一种多元羧酸芳族酸和至少一种二羟基有机化合物; 在第二阶段中，用芳族或芳族二芳族羧酸酯化由此获得的含羟基的聚酯，得到含羧基的聚酯，其酸值基本上等于含羟基的聚酯的羟基数 第一阶段 在第三阶段中，将第二阶段得到的含羧基的聚酯与含有至少两个环氧基的环氧化合物均匀混合，以及任选地添加常规用于制造粉末状涂料和清漆的辅助物质; 和适合作为通过该方法获得的油漆或清漆的粉末状热固性组合物。

公开(公告)号：US09934883B2

公开(公告)日：2018-04-03

申请号：US13910414

申请日：2013-06-05

申请人： E I DU PONT DE NEMOURS AND COMPANY

发明人： Eleni Karayianni ,  Judith Alison Peacock

IPC分类号： H01B3/42 ,  H01B7/295 ,  C08L67/02 ,  C08K5/523 ,  C08K5/5313 ,  C08L63/00

CPC分类号： H01B3/422 ,  C08K5/523 ,  C08K5/5313 ,  C08L63/00 ,  C08L67/025 ,  H01B3/427 ,  H01B7/295

摘要： Halogen-free flame retardant compositions comprising copolyetherester thermoplastic elastomers, melamine cyanurate and epoxy-containing compounds and cables and wires made from such flame retardant polymer composition provide good electrical insulation resistance during use.

公开(公告)号：US20150031794A1

公开(公告)日：2015-01-29

申请号：US14379677

申请日：2013-02-20

申请人： Commissariat A L'Energie Atomique Et Aux Energies Alternative

发明人： Chloé Schubert ,  Olivier Poncelet

IPC分类号： C08J3/215 ,  H01B3/40 ,  H01B3/30 ,  C08K7/26 ,  H01B3/42

CPC分类号： C08J3/215 ,  C08J2300/24 ,  C08J2367/02 ,  C08J2379/08 ,  C08K3/36 ,  C08K7/26 ,  H01B3/302 ,  H01B3/305 ,  H01B3/306 ,  H01B3/40 ,  H01B3/422

摘要： The invention relates to a method for in-situ synthesis of silicon nanoparticles in a thermosetting polymeric matrix, the thermosetting and thermoset matrices obtained in this way and a material including same. The method includes the following steps: a) forming an aqueous-phase/organic-phase inverse emulsion, wherein the aqueous phase includes at least a basic catalyst and the organic phase includes at least a non-cross-linked (co)polymer precursor chosen from an aliphatic, cycloaliphatic or aromatic epoxy resin precursor, a polyester-imide precursor, an unsaturated/epoxy polyester (co)polymer precursor, a polyether/epoxy (co)polymer precursor and a polyurethane precursor; b) introducing, into the inverse emulsion formed in step a), at least one silicon precursor forming a complete network whereof the rate of hydrolysis is greater than the cross-linking speed of the (co)polymer and c) stirring the mixture obtained in step b) and heating to a temperature between 20° C. and 70° C.

摘要翻译： 本发明涉及一种在热固性聚合物基质中原位合成硅纳米颗粒的方法，以这种方式获得的热固性和热固性基体以及包含它们的材料。 该方法包括以下步骤：a）形成水相/有机相反相乳液，其中所述水相至少包含碱性催化剂，并且所述有机相包含至少选自非交联（共）聚合物前体 来自脂肪族，脂环族或芳族环氧树脂前体，聚酯 - 酰亚胺前体，不饱和/环氧聚酯（共）聚合物前体，聚醚/环氧（共）聚合物前体和聚氨酯前体; b）将至少一种硅前体引入到步骤a）中形成的反相乳液中，形成一个完整的网络，其中水解速率大于（共）聚合物的交联速度，和c）搅拌得到的混合物 步骤b）并加热至20℃至70℃之间的温度。

公开(公告)号：US20120293374A1

公开(公告)日：2012-11-22

申请号：US13558444

申请日：2012-07-26

申请人： Masanori Kasai

发明人： Masanori Kasai

IPC分类号： H01Q1/38 ,  C09K19/54

CPC分类号： H01Q9/0421 ,  C08K3/013 ,  C08K5/02 ,  C09K19/38 ,  C09K2019/521 ,  C09K2019/523 ,  H01B3/422 ,  H01B3/445 ,  H01Q1/243 ,  H01Q1/38 ,  H01Q9/0442

摘要： A dielectric block provided in a dielectric antenna is formed with an organic polymer material containing a liquid crystal polymer and polytetrafluoroethylene. The added amount of polytetrafluoroethylene is 2 to 15% by volume based on the volume of the dielectric block. Preferably, the liquid crystal polymer has a flow beginning temperature of no lower than 310° C. and no higher than 335° C. The dielectric block may further contain a dielectric inorganic filler and in this case, the added amount of dielectric inorganic filler is 45% by volume or less based on the volume of the dielectric block.

摘要翻译： 设置在电介质天线中的介质块由含有液晶聚合物和聚四氟乙烯的有机聚合物材料形成。 相对于介质块的体积，聚四氟乙烯的添加量为2〜15体积％。 优选地，液晶聚合物的流动开始温度不低于310℃且不高于335℃。介电块还可以含有介电无机填料，在这种情况下，介电无机填料的添加量为 基于介电块的体积为45体积％以下。

公开(公告)号：US20120217040A1

公开(公告)日：2012-08-30

申请号：US13504778

申请日：2010-10-26

申请人： Tetsuo Yoshida

发明人： Tetsuo Yoshida

IPC分类号： H01B3/30 ,  H01B3/42

CPC分类号： H01G4/18 ,  B29C47/0021 ,  B29C47/36 ,  B32B15/08 ,  B32B15/09 ,  B32B27/08 ,  B32B27/18 ,  B32B27/20 ,  B32B27/30 ,  B32B27/302 ,  B32B27/36 ,  B32B2250/03 ,  B32B2255/10 ,  B32B2255/205 ,  B32B2255/26 ,  B32B2255/28 ,  B32B2307/20 ,  B32B2307/204 ,  B32B2367/00 ,  B32B2457/16 ,  C08J5/18 ,  C08J2367/02 ,  C08K3/045 ,  C08K5/005 ,  C08K5/16 ,  C08K5/20 ,  C08K7/16 ,  C08L25/06 ,  C08L67/02 ,  C08L67/03 ,  C08L83/04 ,  C08L2205/22 ,  C09D183/04 ,  C09D183/08 ,  H01B3/30 ,  H01B3/421 ,  H01B3/422 ,  H01B3/423 ,  H01B3/442 ,  H01B3/46 ,  H01G4/224 ,  Y10T428/254 ,  Y10T428/31786 ,  C08L2666/02

摘要： Disclosed is a biaxially oriented film for electrical insulation having even better withstand voltage characteristics than before together with excellent film-forming properties. The biaxially oriented film for electrical insulation of the invention is a film that includes a substrate layer containing a crystalline thermoplastic resin as a main component. The substrate layer contains a phenolic stabilizer in an amount of 0.001 wt % or more and 3 wt % or less based on the weight of the substrate layer. The phenolic stabilizer is an alkylenebisamide-type hindered phenol.

摘要翻译： 公开了一种用于电绝缘的双轴取向膜，其具有比以前更好的耐电压特性以及优异的成膜性能。 本发明的电绝缘用双轴取向膜是包含以结晶性热塑性树脂为主要成分的基材层的膜。 基材层含有相对于基材层的重量为0.001重量％以上且3重量％以下的酚类稳定剂。 酚类稳定剂是亚烷基双酰胺型受阻酚。

公开(公告)号：US08008578B2

公开(公告)日：2011-08-30

申请号：US12225243

申请日：2007-03-29

申请人： Minoru Saito ,  Hideo Fukuda ,  Makoto Onodera ,  Tsuneo Aoi

发明人： Minoru Saito ,  Hideo Fukuda ,  Makoto Onodera ,  Tsuneo Aoi

IPC分类号： H01B7/00

CPC分类号： H01F27/323 ,  H01B3/305 ,  H01B3/422 ,  H01B3/441 ,  H01F27/2823

摘要： A multilayer insulated electric wire includes a conductor and three or more insulating layers covering the conductor. In the multilayer insulated electric wire, the outermost layer (A) of the insulating layers includes a coating layer formed of a resin composition of a polyamide resin containing copper iodide, and the innermost layer (B) of the insulating layers includes a coating layer formed of a resin composition of 100 parts by mass of a polyester-based resin (B1), all or a part of which is formed of an aliphatic alcohol component bonded with an acid component, and 5 to 40 parts by mass of an ethylene-based copolymer (B2) having side chains of a carboxylic acid or a metal salt of a carboxylic acid.

摘要翻译： 多层绝缘电线包括导体和覆盖导体的三个或更多个绝缘层。 在多层绝缘电线中，绝缘层的最外层（A）包括由含有碘化铜的聚酰胺树脂的树脂组合物形成的涂层，绝缘层的最内层（B）包括形成的涂层 的树脂组合物100质量份的全部或一部分由与酸成分结合的脂肪族醇成分形成的聚酯系树脂（B1）和乙烯系树脂5〜40质量份 具有羧酸侧链或羧酸金属盐的共聚物（B2）。

公开(公告)号：US5352534A

公开(公告)日：1994-10-04

申请号：US203923

申请日：1994-03-01

申请人： Hisashi Hamano ,  Masahiro Hosoi ,  Masanori Nishiyama ,  Yasuhiro Saeki

发明人： Hisashi Hamano ,  Masahiro Hosoi ,  Masanori Nishiyama ,  Yasuhiro Saeki

IPC分类号： C08G63/185 ,  C08G63/672 ,  C08J5/18 ,  H01B3/42 ,  B32B27/36

CPC分类号： C08J5/18 ,  C08G63/185 ,  C08G63/672 ,  H01B3/422 ,  C08J2367/02 ,  Y10T428/31786

摘要： An oriented polyester film (A) which comprises modified polyethylene-2,6-naphthalenedicarboxylate containing a 4,4'-diphenyldicarboxylic acid component and having a heat of crystallization of 16 to 25.5 Joule/g, and (B) which is biaxially oriented; and an oriented polyester film (A') which comprises modified polyethylene-2,6-naphthalenedicarboxylate containing of a glycol component derived from a compound represented by the following formula, ##STR1## wherein each of n and m is independently a positive number of 1 to 9 as an average, provided that m+n equals 2 to 9 as an average, and having a heat of crystallization of 6 to 20 Joule/g, and (B) which is biaxially oriented. These films are useful as a base film for a magnetic recording tape or as an electric insulation film.

摘要翻译： 一种定向聚酯膜（A），其包含含有4,4'-二苯基二羧酸组分的改性聚乙烯-2,6-萘二甲酸酯，结晶热为16-25.5焦耳/克，（B）为双轴取向; 和含有衍生自下式表示的化合物的二醇成分的改性聚乙烯-2,6-萘二甲酸酯的取向聚酯膜（A'），其中n和m各自独立地为1的正数 平均值为9，条件是m + n平均为2〜9，结晶热为6〜20焦耳/克，（B）为双轴取向。 这些膜可用作磁记录带或电绝缘膜的基膜。

公开(公告)号：US5021295A

公开(公告)日：1991-06-04

申请号：US321068

申请日：1989-03-09

申请人： Toshio Nakane ,  Michiro Naka ,  Hiroaki Konuma ,  Kenji Hijikata

发明人： Toshio Nakane ,  Michiro Naka ,  Hiroaki Konuma ,  Kenji Hijikata

IPC分类号： C08L67/00 ,  C08L67/02 ,  H01B3/42 ,  H01B7/295

CPC分类号： H01B3/422 ,  C08L67/02 ,  Y10T428/2933 ,  Y10T428/294

摘要： A flame-retarding polyester composition is useful for coating an electric wire, which comprises a melt-mixture of, (A) a copolyester having a halogen content of 0.5 to 30 wt. % and (B) a branched copolymer prepared by the condensation polymerization of monomers mainly comprising(a)' a component mainly comprising an aromatic dicarboxylic acid or an ester-forming derivative thereof,(b)' a component mainly comprising an aliphatic glycol or an ester-forming derivative thereof and(d) a branching compound, which contains 0.001 to 0.5 molar % (based on the total amount of the carbonyl groups of the copolyester) of said branching compound (d).

摘要翻译： 阻燃聚酯组合物可用于涂覆电线，其包括（A）具有0.5至30重量％的卤素含量的共聚酯的熔体混合物。 ％和（B）通过主要包含（a）'主要包含芳族二羧酸或其成酯衍生物的组分的单体的缩聚制备的支化共聚物，（b）主要包含脂族二醇或 其成酯衍生物和（d）支链化合物，其含有所述支化化合物（d）的0.001至0.5摩尔％（基于共聚酯的羰基的总量）。

公开(公告)号：US4528358A

公开(公告)日：1985-07-09

申请号：US635423

申请日：1984-07-30

申请人： Wolfgang Kleeberg ,  Klaus-Robert Hauschildt ,  Heinz Hacker ,  Klaus Kretzschmar

发明人： Wolfgang Kleeberg ,  Klaus-Robert Hauschildt ,  Heinz Hacker ,  Klaus Kretzschmar

IPC分类号： B32B27/12 ,  B32B27/38 ,  C08G59/00 ,  C08G59/40 ,  C08G59/50 ,  C08G59/68 ,  C09D163/00 ,  H01B3/30 ,  H01B3/40 ,  H01B3/42

CPC分类号： H01B3/305 ,  C08G59/686 ,  H01B3/40 ,  H01B3/422

摘要： Molding materials, laminates, stratified material and cover or protective layers which are of high electrical and mechanical quality are formed from polymerisable epoxy compounds if the corss-linking of the epoxy resins is accomplished by anionic polymerisation, using mixed catalysts of tertiary amines of the formula: ##STR1## and an imidazoles of the formula: ##STR2## as a polymerisation catalysts.

摘要翻译： 如果通过阴离子聚合实现环氧树脂的连接，则可聚合的环氧化合物由具有高的电学和机械质量的成型材料，层压材料，分层材料和覆盖层或保护层形成，使用式 和下式的咪唑：作为聚合催化剂的。

公开(公告)号：US4421888A

公开(公告)日：1983-12-20

申请号：US363676

申请日：1982-03-30

申请人： Tsuneyoshi Okada

发明人： Tsuneyoshi Okada

IPC分类号： C08L67/00 ,  C08K3/34 ,  C08K7/14 ,  C08K9/00 ,  C08L1/00 ,  C08L27/00 ,  C08L67/02 ,  H01B3/42

CPC分类号： H01B3/422 ,  C08K3/34 ,  C08K7/14 ,  C08L67/02

摘要： In an article molded from a non-burning, non-dripping filled polyester composition having a high level of arc resistance and tracking resistance, decay in the arc resistance with time is substantially decreased or prevented by incorporating a minor but critical amount of polyethylene terephthalate. Typical compositions comprise (a) approximately 30 to 60 percent by weight, based on the composition, of a mixture of polyethylene terephthalate and polybutylene terephthalate wherein polyethylene terephthalate comprises approximately 3 to 20 percent by weight; (b) approximately 30 to 60 percent by weight of the composition of a mixture of fiber glass and talc wherein talc comprises approximately 15 to 35 percent by weight of the composition; and (c) an effective amount, up to 20 percent by weight of the composition of a flame retardant additive or a mixture thereof. Typical compositions possess superior electrical properties, comparable to those of thermosetting molding resins.

摘要翻译： 在由具有高水平的耐电弧性和耐追踪性的非燃烧型非滴加填充的聚酯组合物成型的制品中，通过加入少量但临界量的聚对苯二甲酸乙二醇酯，可以显着降低或防止电弧电阻随时间的衰减。 典型的组合物包含（a）基于组合物约30至60重量％的聚对苯二甲酸乙二醇酯和聚对苯二甲酸丁二醇酯的混合物，其中聚对苯二甲酸乙二醇酯包含约3至20重量％ （b）组合物的约30至60重量％的玻璃纤维和滑石的混合物，其中滑石占组合物的约15至35重量％; 和（c）有效量，至多20重量％的组合物的阻燃添加剂或其混合物。 典型的组合物具有优异的电性能，与热固性模塑树脂相当。