Abstract:
An acrylic fiber for artificial hair includes an acrylic polymer, wherein the acrylic polymer includes 29.5 to 79.5% by mass of acrylonitrile, 20 to 70% by mass of vinyl chloride and/or vinylidene chloride, and 0.5 to 5% by mass of a vinyl monomer comprising a sulfonic acid group. The acrylic fiber for artificial hair includes 0.3 to 2% by mass of a good solvent for the acrylic polymer and 0.1 to 5% by mass of a compound comprising an epoxy group.
Abstract:
A one-fabric fire resistant (FR) solution having 2 or more layers of FR yarns knit together into one fabric, the at 2 or more layers including a face layer and a back layer, the back layer includes a silica yarn.
Abstract:
An object of the present invention is to provide an acrylic synthetic fiber having excellent stylability and heat resistance. The object may be attained by an acrylic synthetic fiber having a knot-like unevenness on a fiber surface thereof, a difference of distances between a depression and a projection of 5.0 micrometers to 15.0 micrometers, a distance between peaks of unevenness of 0.05 mm to 0.5 mm, a flexural rigidity value of the fiber of 7.0×10−7 N-m2/m to 10.0×10−7 N-m2/m, and a torsional rigidity value of the fiber of 5.0×10−9 N-m2 to 10.0×10−9 N-m2, and furthermore the object may be attained by an acrylic synthetic fiber comprising an acrylic copolymer having a content of acrylonitrile of not less than 60 mol %, a sulfur content originating in a vinyl based monomer including a sulfonic group of 0.15% by weight to 0.50% by weight, and a specific viscosity of 0.20 to 0.50.
Abstract:
A new, pulp-like, acrylic short fiber having excellent heat- and chemical-resistance is provided. The fiber has a thickness distribution of 0.1 .mu.m to 50 .mu.m, a length distribution of 1 mm to 20 mm, and a thermal transition temperature (Tg) of above 200.degree. C. The fiber is produced by heating a mixture of polyacrylonitrile and water of about 5% to 100% by weight to temperatures above hydration-melting temperature under seal to an amorphous melt; cooling the resulting amorphous melt to temperatures between the melting and the solidifying temperatures of the melt to form a supercooled melt; extruding the resulting supercooled melt to give extrudates; heat-stabilizing the resulting extrudates at temperatures between 180.degree. C. and 300.degree. C. for 1 minute to 4 hours after drying and drawing; and cutting and beating the resulting heat-stabilized extrudates into an appropriate size.
Abstract:
Disclosed is an acrylic fiber composed of an acrylonitrile homopolymer or copolymer whose surface consists of particulate and/or microfibrillar structures having a width of 0.01 to 0.5 .mu.m and a length of 0.05 to 10 .mu.m and fibrillar structures formed by aggregation of the particulate and/or microfibrillar structures and having a width of 0.1 to 10 .mu.m and a length of at least 50 .mu.m. The fiber is prepared by spinning a dope of an acrylonitrile homopolymer or copolymer in a solvent at a draft ratio of at least 5 into a coagulating bath comprising a solvent and a coagulant and having a composition such that a skin layer is not formed on the coagulated fiber; taking up the coagulated fiber from the coagulating bath so that the retention time in the coagulating bath is within 60 seconds; and then drawing the fiber in a drawing bath comprising a solvent and a coagulant and having a coagulating property to the dope and a composition such that a skin layer is not formed on the fiber.
Abstract:
The invention provides a polyacrylonitrile fiber having a tensile strength above 13 g/d and a modulus of elasticity above 2.4.times.10.sup.11 dyne/cm.sup.2, which is useful for tire cords, fiber-reinforced composite materials, precursors for producing carbon fiber, etc. The fiber is produced by integrally combining technical means which comprise using a polymer composed mainly of acrylonitrile whose weight average molecular weight is more than 400,000 and Mw/Mn ratio is less than 7.0; preparing a spinning solution from the polymer; spinning the solution into filaments; subjecting the resulting filaments to multistage stretching; and drying the filaments, all these steps being conducted under particular conditions.
Abstract:
The present invention discloses a flame-retardant acrylic synthetic fiber comprising acrylonitrile and a vinyl monomer copolymerizable therewith and containing a finely divided inorganic tin compound. The fiber has high flame retardancy, outstanding gloss and transparency, and satisfactory whiteness and dyeability.
Abstract:
A color stabilized modacrylic dye site containing copolymer composition containing from 20 to 80 percent by weight of acrylonitrile with the remainder being vinyl chloride. The color stabilizing agent is selected from inorganic zinc salts and ranges from 0.01 to 5.0 percent by weight of the copolymer.
Abstract:
One or more embodiments of the present invention relate to antibacterial acrylic artificial hair fibers containing chitosan and a nonionic surfactant, in which a content of the chitosan extracted with diluted acetic acid is 0.005% by weight to 0.4% by weight, or the content of the chitosan extracted with concentrated hydrochloric acid is 0.014% by weight to 1.2% by weight, a content of the nonionic surfactant is 0.10% by weight to 0.90% by weight, the nonionic surfactant is one or more selected from the group consisting of a polyoxyethylene sorbitan fatty acid ester, a polyoxyethylene fatty acid monoester, and a polyoxyethylene alkyl ether, and the nonionic surfactant has a hydrophilic-lipophilic balance (HLB) of 13.0 or more.
Abstract:
The present invention relates to an acrylic fiber for artificial hair containing an acrylic copolymer. The dry-heat shrinkage ratio of the acrylic fiber after dry-heat treatment at 90 to 180° C. for 30 minutes is 30 to 70%, and the torsional rigidity thereof is 0.3 to 2.0 mg·cm2. Also, one or more embodiments of the present invention relate to a crimped acrylic fiber for artificial hair containing an acrylic copolymer. In the crimped acrylic fiber, the number of crimps is 10 or more crimps per 10 cm, and the crimp height is 1.5 mm or more. In addition, in ten continuous crimps, at least two crimps differ in crimp width and at least two crimps differ in crimp height, while the crimps are formed in two or more different crimp directions.