Acrylic synthetic fiber improved in styleability
    23.
    发明申请
    Acrylic synthetic fiber improved in styleability 有权
    亚克力合成纤维的款式改善

    公开(公告)号:US20050287365A1

    公开(公告)日:2005-12-29

    申请号:US10522759

    申请日:2003-07-14

    CPC classification number: A41G3/0083 D01F6/40 Y10T428/2913 Y10T428/2967

    Abstract: An object of the present invention is to provide an acrylic synthetic fiber having excellent stylability and heat resistance. The object may be attained by an acrylic synthetic fiber having a knot-like unevenness on a fiber surface thereof, a difference of distances between a depression and a projection of 5.0 micrometers to 15.0 micrometers, a distance between peaks of unevenness of 0.05 mm to 0.5 mm, a flexural rigidity value of the fiber of 7.0×10−7 N-m2/m to 10.0×10−7 N-m2/m, and a torsional rigidity value of the fiber of 5.0×10−9 N-m2 to 10.0×10−9 N-m2, and furthermore the object may be attained by an acrylic synthetic fiber comprising an acrylic copolymer having a content of acrylonitrile of not less than 60 mol %, a sulfur content originating in a vinyl based monomer including a sulfonic group of 0.15% by weight to 0.50% by weight, and a specific viscosity of 0.20 to 0.50.

    Abstract translation: 本发明的目的是提供具有优良的造型性和耐热性的丙烯酸类合成纤维。 该目的可以通过在其纤维表面上具有结状凹凸的丙烯酸类合成纤维,凹陷和突起之间的距离差为5.0微米至15.0微米,不平坦峰之间的距离为0.05mm至0.5 mm,纤维的抗弯刚度值为7.0×10 -7 Nm 2 / m至10.0×10 -7 Nm 2, / SUP / m,纤维的扭转刚度值为5.0×10 -9 Nm 2至10.0×10 -9 Nm > 2,此外,目的可以通过丙烯酸类合成纤维来实现,所述丙烯酸类合成纤维包含丙烯腈含量不小于60mol%的丙烯酸共聚物,源自乙烯基类单体的硫含量,所述乙烯基类单体包括磺酸基 0.15重量%〜0.50重量%,比粘度为0.20〜0.50。

    Heat- and chemical-resistant acrylic short fibers without spinning
    24.
    发明授权
    Heat- and chemical-resistant acrylic short fibers without spinning 失效
    耐热耐化学品丙烯酸短纤维,不纺纱

    公开(公告)号:US5401576A

    公开(公告)日:1995-03-28

    申请号:US64345

    申请日:1993-05-20

    Abstract: A new, pulp-like, acrylic short fiber having excellent heat- and chemical-resistance is provided. The fiber has a thickness distribution of 0.1 .mu.m to 50 .mu.m, a length distribution of 1 mm to 20 mm, and a thermal transition temperature (Tg) of above 200.degree. C. The fiber is produced by heating a mixture of polyacrylonitrile and water of about 5% to 100% by weight to temperatures above hydration-melting temperature under seal to an amorphous melt; cooling the resulting amorphous melt to temperatures between the melting and the solidifying temperatures of the melt to form a supercooled melt; extruding the resulting supercooled melt to give extrudates; heat-stabilizing the resulting extrudates at temperatures between 180.degree. C. and 300.degree. C. for 1 minute to 4 hours after drying and drawing; and cutting and beating the resulting heat-stabilized extrudates into an appropriate size.

    Abstract translation: 提供了具有优异的耐热和耐化学性的新的纸浆状丙烯酸类短纤维。 纤维的厚度分布为0.1μm〜50μm,长度分布为1mm〜20mm,热转变温度(Tg)为200℃以上。纤维通过加热聚丙烯腈和 约5%至100%重量的水至密封下的水合熔融温度至无定形熔体的温度; 将所得到的无定形熔体冷却至熔体的熔融温度和固化温度之间以形成过冷熔体; 挤出所得过冷熔体以得到挤出物; 在180℃至300℃的温度下,将所得挤出物在干燥和拉伸后热稳定1分钟至4小时; 并将所得热稳定的挤出物切割并打浆成适当的尺寸。

    Acrylic fiber having excellent durability and dyeability and process for
preparation thereof
    25.
    发明授权
    Acrylic fiber having excellent durability and dyeability and process for preparation thereof 失效
    丙烯酸纤维具有优异的耐久性和染色性及其制备方法

    公开(公告)号:US4663232A

    公开(公告)日:1987-05-05

    申请号:US728276

    申请日:1985-04-29

    CPC classification number: D01F6/18 Y10T428/2978 Y10T428/298

    Abstract: Disclosed is an acrylic fiber composed of an acrylonitrile homopolymer or copolymer whose surface consists of particulate and/or microfibrillar structures having a width of 0.01 to 0.5 .mu.m and a length of 0.05 to 10 .mu.m and fibrillar structures formed by aggregation of the particulate and/or microfibrillar structures and having a width of 0.1 to 10 .mu.m and a length of at least 50 .mu.m. The fiber is prepared by spinning a dope of an acrylonitrile homopolymer or copolymer in a solvent at a draft ratio of at least 5 into a coagulating bath comprising a solvent and a coagulant and having a composition such that a skin layer is not formed on the coagulated fiber; taking up the coagulated fiber from the coagulating bath so that the retention time in the coagulating bath is within 60 seconds; and then drawing the fiber in a drawing bath comprising a solvent and a coagulant and having a coagulating property to the dope and a composition such that a skin layer is not formed on the fiber.

    Abstract translation: 公开了由丙烯腈均聚物或共聚物组成的丙烯酸纤维,其表面由宽度为0.01至0.5μm和长度为0.05至10μm的颗粒和/或微原纤维结构组成,并且通过颗粒和 /或微原纤维结构,宽度为0.1〜10μm,长度为50μm以上。 纤维通过将丙烯腈均聚物或共聚物的涂料在溶剂中以至少5的牵伸比纺丝到包含溶剂和凝结剂的凝结浴中并具有使得在凝固物上不形成表皮层的组合物来制备 纤维; 从凝固浴中吸收凝固纤维,使得凝固浴中的停留时间在60秒以内; 然后在包含溶剂和凝结剂的拉伸浴中将纤维拉伸到涂料上并具有凝胶性的组合物,使得在纤维上不形成表皮层。

    Polyacrylonitrile fiber with high strength and high modulus of elasticity
    26.
    发明授权
    Polyacrylonitrile fiber with high strength and high modulus of elasticity 失效
    聚丙烯腈纤维具有高强度和高弹性模量

    公开(公告)号:US4658004A

    公开(公告)日:1987-04-14

    申请号:US781037

    申请日:1985-09-27

    CPC classification number: D01F6/18

    Abstract: The invention provides a polyacrylonitrile fiber having a tensile strength above 13 g/d and a modulus of elasticity above 2.4.times.10.sup.11 dyne/cm.sup.2, which is useful for tire cords, fiber-reinforced composite materials, precursors for producing carbon fiber, etc. The fiber is produced by integrally combining technical means which comprise using a polymer composed mainly of acrylonitrile whose weight average molecular weight is more than 400,000 and Mw/Mn ratio is less than 7.0; preparing a spinning solution from the polymer; spinning the solution into filaments; subjecting the resulting filaments to multistage stretching; and drying the filaments, all these steps being conducted under particular conditions.

    Abstract translation: 本发明提供拉伸强度高于13g / d,弹性模量高于2.4×10 11达因/ cm 2的聚丙烯腈纤维,其可用于轮胎帘线,纤维增强复合材料,用于生产碳纤维的前体等。纤维 通过整体地组合包括使用主要由重均分子量大于400,000的丙烯腈组成的聚合物和&lt ;bar> Mw /<上升&Mn比率小于7.0的技术方法来生产; 从聚合物制备纺丝溶液; 将溶液纺丝成长丝; 对所得长丝进行多段拉伸; 并干燥长丝,所有这些步骤都是在特定条件下进行的。

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