CEMENT-REDUCED CONSTRUCTION COMPOSITION
    27.
    发明公开

    公开(公告)号:US20230303446A1

    公开(公告)日:2023-09-28

    申请号:US18023268

    申请日:2021-08-25

    摘要: A cement-reduced construction composition comprises a) a cementitious binder comprising one or more calcium silicate mineral phases and one or more calcium aluminate mineral phases, and having a Blaine surface area of at least 3800 cm2/g, in an amount of 180 to 400 kg per m3 of the freshly mixed construction composition; b) a fine material having a Dv90 of less than 200 μm, selected from alkali-activatable binders, rock powders and inorganic pigments, or mixtures thereof, in a total amount of 20 to 200 parts by weight, relative to 100 parts by weight of cementitious binder a); c) optionally, an extraneous aluminate source; d) a sulfate source; and e) a polyol in an amount of 0.3 to 2.5 wt.-%, relative to the amount of cementitious binder a). The composition contains available aluminate, calculated as Al(OH)4—, from the calcium aluminate mineral phases plus the optional extraneous aluminate source, per 100 g of cementitious binder a), in a total amount of at least 0.08 mol, if the amount of cementitious binder a) is in the range of 180 to less than 220 kg per m3 of the freshly mixed composition, at least 0.06 mol, if the amount of cementitious binder a) is in the range of 220 to less than 280 kg per m3 of the freshly mixed composition, and at least 0.05 mol, if the amount of cementitious binder a) is 280 kg or more per m3 of the freshly mixed composition; and the molar ratio of total available aluminate to sulfate is 0.4 to 2.0. The construction composition further comprises f) an ettringite formation controller comprising (i) glyoxylic acid, a glyoxylic acid salt and/or a glyoxylic acid derivative; and (ii) at least one of (ii-a) a borate source and (ii-b) a carbonate source, wherein the carbonate source is selected from inorganic carbonates having an aqueous solubility of 0.1 g·L−1 or more, organic carbonates, and mixtures thereof; and g) a co-retarder selected from (g-1) α-hydroxy monocarboxylic acids and salts thereof, (g-2) phosphonic acids and salts thereof, (g-3) polycarboxylic acids and salts thereof, and mixtures thereof. The cement-reduced construction composition is a reduced carbon footprint construction composition and exhibits high early strength, high final strength, sufficient open time, high durability, and reduced shrinkage compared to ordinary Portland cement based mixes. Ingredients of the construction composition are abundantly available.

    POLYVINYL ALCOHOL-BASED POLYMER
    28.
    发明公开

    公开(公告)号:US20230242687A1

    公开(公告)日:2023-08-03

    申请号:US17927523

    申请日:2021-07-15

    发明人: Akihiro YAMASHITA

    IPC分类号: C08F16/06 C04B24/26 C09K8/467

    摘要: A PVA is excellent in heat resistance and pressure resistance. A polyvinyl alcohol-based polymer, as a saponificated product of a homopolymer composed of a vinyl ester monomer; a copolymer of a vinyl ester monomer and a monofunctional monomer other than the vinyl ester; a copolymer of a vinyl ester monomer and a polyfunctional monomer; or a copolymer of a vinyl ester monomer, a monofunctional monomer other than vinyl ester, wherein the polyvinyl alcohol-based polymer has a slope of 1.2 or less in a double logarithmic plot of storage elastic modulus G′ (at 20° C.) in an angular frequency region of 1.0 to 10.0 rad/s, in measurement of an aqueous solution of the polyvinyl alcohol-based polymer filtered through a 100-mesh filter (opening: 0.154 mm) and then adjusted to a concentration of 10.0 mass %.

    POLYVINYL ALCOHOL-BASED POLYMER
    30.
    发明公开

    公开(公告)号:US20230212332A1

    公开(公告)日:2023-07-06

    申请号:US17927581

    申请日:2021-07-15

    发明人: Akihiro YAMASHITA

    IPC分类号: C08F16/06 C04B24/26 C09K8/487

    摘要: A PVA excellent in resistance to melting at high temperature is provided. The polyvinyl alcohol-based polymer is a saponificated product of a homopolymer composed of a vinyl ester monomer, a copolymer of a vinyl ester monomer and a monofunctional monomer other than the vinyl ester, a copolymer of a vinyl ester monomer and a polyfunctional monomer, or a copolymer of a vinyl ester monomer, a monofunctional monomer other than vinyl ester, and a polyfunctional monomer has a particle size of 50 nm or more at a cumulative frequency of 50% in particle size distribution by dynamic light scattering measurement of a 0.4 mass % aqueous solution of the polyvinyl alcohol-based polymer at 25° C.