公开(公告)号：US09758603B2

公开(公告)日：2017-09-12

申请号：US15461064

申请日：2017-03-16

Applicant: Basell Polyolefine GmbH

Inventor： Dieter Littmann ,  Jürgen Peter Mohrbutter ,  Giulia Mei ,  Andre-Armand Finette ,  Sven Georg Wolfram ,  Michael Deuerling ,  Danir Khayrullin ,  Georg Groos ,  Christoph Wolf

IPC: C08F110/02 ,  C08F2/01 ,  C08J5/18 ,  B01J19/24 ,  C08F2/34 ,  C08F2/38

CPC classification number: C08F110/02 ,  B01J19/2415 ,  C08F2/01 ,  C08F2/34 ,  C08J5/18 ,  C08J2323/06 ,  C08F2/00 ,  C08F2500/12 ,  C08F2500/26

Abstract: The present technology relates to a process for polymerizing or copolymerizing ethylenically unsaturated monomers in the presence of free-radical polymerization initiators, wherein the polymerization is carried out in a continuously operated tubular reactor at temperatures from 100° C. to 350° C. and pressures from 180 MPa to 340 MPa, with a specific reactor surface area Asp of 2 m2/(t/h) to 5.5 m2/(t/h), and the tubular reactor has a specific ratio RDsp of 0.0050 MPa−1 to 0.0069 MPa−1 and an inner surface which has a surface roughness Ra of 2 μm or less.

公开(公告)号：US09738778B2

公开(公告)日：2017-08-22

申请号：US14407204

申请日：2013-06-19

Applicant: Basell Polyolefine GmbH

Inventor： Fabiana Fantinel ,  Bodo Richter ,  Shahram Mihan ,  Massimo Covezzi ,  Claudio Cavalieri ,  Michele Grazzi

IPC: C08L23/12 ,  C08F4/619 ,  C08F4/6592 ,  C08F4/70 ,  C08L23/08 ,  C08L23/10 ,  C08L23/16 ,  C08J5/18

CPC classification number: C08L23/12 ,  C08F4/61912 ,  C08F4/61916 ,  C08F4/65927 ,  C08F4/7042 ,  C08J5/18 ,  C08J2323/16 ,  C08J2423/06 ,  C08J2423/12 ,  C08L23/0815 ,  C08L23/10 ,  C08L23/16 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2314/06 ,  C08L2314/08 ,  Y10T428/139 ,  C08F210/16 ,  C08F2/001 ,  C08F4/61904 ,  C08L23/08 ,  C08L23/142 ,  C08F210/06 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/21 ,  C08L23/06

Abstract: A two steps polymerization process for obtaining a polyolefin composition comprising: a) from 25 wt % to 70 wt % of a propylene homopolymer or a propylene-ethylene copolymer containing from 0.1 wt % to 10 wt % of ethylene derived units; b) from 27 wt % to 70 wt % of a copolymer of ethylene and at least one C3-C20 alpha olefins, wherein the ethylene derived units content ranges from 15 wt % to 70 wt %; c) from 3 wt % to 20 wt % of polyethylene homopolymer or an ethylene and at least one C3-C20 alpha olefins copolymer; the sum a)+b)+c) being 100, wherein said process comprises: step a) contacting under polymerization conditions propylene, optionally ethylene and the catalyst system in order to obtain component a), step b) contacting under polymerization conditions ethylene and at least one C3-C20 alpha-olefins and the catalyst system in order to obtain components b) and c); wherein the catalyst system comprises a metallocene compound and an iron complex.

公开(公告)号：US20170121512A1

公开(公告)日：2017-05-04

申请号：US15408172

申请日：2017-01-17

Applicant: Basell Polyolefine GmbH

Inventor： Iakovos Vittorias ,  Jens Wiesecke ,  Bernd Lothar Marczinke ,  Gerhardus Meier ,  Ulf Schüller ,  Volker Dolle ,  Johannes-Friedrich Enderle ,  Dieter Lilge ,  Barbara Gall

IPC: C08L23/08 ,  B29B15/00 ,  B29C49/04 ,  C08J5/00 ,  B29C49/00

CPC classification number: C08L23/0815 ,  B29B15/00 ,  B29C47/0004 ,  B29C47/92 ,  B29C49/0005 ,  B29C49/04 ,  B29K2023/06 ,  B29L2031/7154 ,  B29L2031/7172 ,  C08F210/16 ,  C08J5/00 ,  C08J2323/06 ,  C08J2323/08 ,  C08J2423/06 ,  C08J2423/08 ,  C08L23/06 ,  C08L2205/025 ,  C08L2207/07 ,  C08L2308/00 ,  C08L2314/02

Abstract: The present disclosure relates to a polyethylene composition with improved swell ratio and mechanical properties for use in preparing blow-moulded articles and having the following features: 1) a density from 0.945 to less than 0.952 g/cm3; 2) an MIF/MIP ratio from 15 to 30; 3) a Shear-Induced Crystallization Index (SIC) from 2.5 to 5.5.

公开(公告)号：US20170022303A1

公开(公告)日：2017-01-26

申请号：US15240084

申请日：2016-08-18

Applicant: Basell Polyolefine GmbH

Inventor： Dieter Littmann ,  Jurgen Peter Mohrbutter ,  Giulia Mei ,  Andre-Armand Finette ,  Sven Georg Wolfram ,  Michael Deuerling ,  Danir Khayrullin ,  Georg Groos ,  Christoph Wolf

IPC: C08F110/02 ,  B01J19/24

CPC classification number: C08F110/02 ,  B01J19/2415 ,  C08F2/01 ,  C08F2/34 ,  C08J5/18 ,  C08J2323/06 ,  C08F2/00 ,  C08F2500/12 ,  C08F2500/26

Abstract: The present technology relates to a process for polymerizing or copolymerizing ethylenically unsaturated monomers in the presence of free-radical polymerization initiators, wherein the polymerization is carried out in a continuously operated tubular reactor at temperatures from 100° C. to 350° C. and pressures from 180 MPa to 340 MPa, with a specific reactor surface area Asp of 2 m2/(t/h) to 5.5 m2/(t/h), and the tubular reactor has a specific ratio RDsp of 0.0050 MPa−1 to 0.0069 MPa−1 and an inner surface which has a surface roughness Ra of 2 μm or less.

Abstract translation: 本技术涉及在自由基聚合引发剂存在下聚合或共聚烯键式不饱和单体的方法，其中聚合在连续操作的管式反应器中在100℃至350℃的温度下进行，压力 从180MPa到340MPa，比表面积Asp为2m 2 /（t / h）至5.5m 2 /（t / h），并且管式反应器的比值RDsp为0.0050MPa-1至0.0069MPa -1，表面粗糙度Ra为2μm以下的内表面。

公开(公告)号：US20160280896A1

公开(公告)日：2016-09-29

申请号：US15029744

申请日：2014-09-24

Applicant: BASELL POLYOLEFINE GMBH

Inventor： Bernd Hoecker ,  Thomas Lindner ,  Peter Bisson ,  Gerd Mannebach

IPC: C08L23/08 ,  C08F210/16

CPC classification number: C08L23/0815 ,  C08F210/16 ,  C08F2410/04 ,  C08F2500/05 ,  C08F2500/12 ,  C08F2500/13 ,  C08L2201/08 ,  C08L2205/025 ,  C08L2205/06 ,  C08L2314/06 ,  C08L2314/08

Abstract: The present disclosure relates to a polyethylene composition comprising copolymers of ethylene with 1-alkenes, or mixtures of ethylene homopolymers and said copolymers of ethylene with 1-alkenes, wherein the polyethylene composition has a molar mass distribution width (MWD) Mw/Mn of from 7 to 15, a density of from 0.942 to 0.954 g/cm3, a weight average molar mass Mw of from 20,000 g/mol to 500,000 g/mol, a MIE of from 1.0 to 3.0 g/10 min, a MIF of from 100 to 200 g/10 min, and a ratio MIF/MIE of from 40 to 50.

Abstract translation: 本公开内容涉及包含乙烯与1-烯烃的共聚物或乙烯均聚物和所述乙烯与1-烯烃的所述共聚物的共聚物的聚乙烯组合物，其中所述聚乙烯组合物的摩尔质量分布宽度（MWD）Mw / Mn为 7至15，密度为0.942至0.954g / cm3，重量平均摩尔质量Mw为20,000g / mol至500,000g / mol，MIE为1.0至3.0g / 10min，MIF为100 至200g / 10min，MIF / MIE为40〜50。

公开(公告)号：US20160251504A1

公开(公告)日：2016-09-01

申请号：US15154800

申请日：2016-05-13

Applicant: Basell Polyolefine GmbH

Inventor： Joachim Berthold ,  Lutz-Gerd Heinicke ,  Gerhardus Meier

IPC: C08L23/06 ,  C08J5/18

CPC classification number: C08L23/06 ,  C08J5/18 ,  C08J2323/04 ,  C08J2323/06 ,  C08J2423/08 ,  C08L23/04 ,  C08L23/08 ,  C08L23/0807 ,  C08L23/0815 ,  C08L2203/16 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2666/06

Abstract: The invention relates to a polyethylene molding composition having a multimodal molar mass distribution particularly suitable for blow molding films having a thickness in the range from 8 to 200 μm. The molding composition has a density at a temperature of 23° C. in the range from 0.953 to 0.960 g/cm3 and an MFR190/5 of the final product after extrusion in the range from 0.10 to 0.50 dg/min. The composition comprises from 30 to 60% by weight of a first ethylene polymer fraction made of a homopolymer A having a first molecular weight, from 22 to 40% by weight of a second ethylene polymer fraction made of a further homopolymer or first copolymer B of ethylene and at least one first comonomer from the group of olefins having from 4 to 8 carbon atoms, the first copolymer B having a second molecular weight higher than the first molecular weight, and from 10 to 30% by weight of a third ethylene polymer fraction made of a second copolymer C having a third molecular weight higher than the second molecular weight. The molding composition of the invention allows to produce thin films having improved processability without impairing the mechanical properties.

Abstract translation: 本发明涉及具有特别适用于厚度在8至200μm范围内的吹塑薄膜的多峰摩尔质量分布的聚乙烯模塑组合物。 模塑组合物的密度在23℃的温度范围为0.953至0.960g / cm3，挤出后的最终产品的MFR 190/5为0.10至0.50dg / min。 该组合物包含30至60重量％的由具有第一分子量的均聚物A制成的第一乙烯聚合物部分，22至40重量％的由其它均聚物或第一共聚物B制成的第二乙烯聚合物部分 乙烯和来自具有4至8个碳原子的烯烃基团的至少一种第一共聚单体，第一共聚物B具有高于第一分子量的第二分子量和10至30重量％的第三乙烯聚合物部分 由具有高于第二分子量的第三分子量的第二共聚物C制成。 本发明的模塑组合物允许制造具有改进加工性能的薄膜而不损害机械性能。

公开(公告)号：US20160237238A1

公开(公告)日：2016-08-18

申请号：US15029985

申请日：2014-09-24

Applicant: BASELL POLYOLEFINE GMBH

Inventor： Bernd Hoecker

IPC: C08K3/04 ,  B65D25/02

CPC classification number: C08K3/04 ,  B65D25/02 ,  C08F4/65916 ,  C08F4/65925 ,  C08F10/02 ,  C08F210/16 ,  C08K5/005 ,  C08L23/06 ,  C08L23/0815 ,  C08L2314/06 ,  C08F4/61904 ,  C08F4/7042 ,  C08L23/04

Abstract: A polyethylene composition having density from 0.943 to 1.1 g/cm3, comprising: A) carbon black, or a UV stabilizer, or a mixture of carbon black and a UV stabilizer; B) a polyethylene comprising copolymers of ethylene with 1-alkenes, or mixtures of ethylene homopolymers and said copolymers of ethylene with 1-alkenes, which polyethylene has molar mass distribution width (MWD) Mw/Mn of from 7 to 15, density of from 0.942 to 0.954 g/cm3, a weight average molar mass Mw of from 20,000 g/mol to 500,000 g/mol, a MIE of from 1.0 to 3.0 g/10 min, a MIF of from 100 to 200 g/10 min, and a ratio MIF/MIE of from 40 to 50.

Abstract translation: 一种密度为0.943〜1.1g / cm3的聚乙烯组合物，包括：A）炭黑或UV稳定剂，或炭黑和UV稳定剂的混合物; B）包含乙烯与1-烯烃的共聚物的聚乙烯，或乙烯均聚物和所述乙烯与1-烯烃的所述共聚物的混合物，该聚乙烯的摩尔质量分布宽度（MWD）Mw / Mn为7至15，密度为 0.942〜0.954g / cm3，重量平均摩尔质量Mw为20,000g / mol〜500,000g / mol，MIE为1.0〜3.0g / 10min，MIF为100〜200g / 10min， 比例MIF / MIE为40至50。

公开(公告)号：US09399688B2

公开(公告)日：2016-07-26

申请号：US14889794

申请日：2014-05-13

Applicant: Basell Polyolefine GmbH

Inventor： Giuseppe Penzo ,  Gabriele Mei ,  Gerhardus Meier ,  Ulf Schueller ,  Antonio Ciarrocchi

IPC: C08F2/00 ,  B01J19/18 ,  C08F110/02 ,  B01J19/24

CPC classification number: C08F110/02 ,  B01J8/0025 ,  B01J8/1863 ,  B01J8/1872 ,  B01J8/26 ,  B01J19/245 ,  B01J2208/00274 ,  B01J2208/00292 ,  B01J2208/00557 ,  B01J2208/00752 ,  B01J2208/00761 ,  B01J2208/00769 ,  B01J2208/00991 ,  B01J2219/24 ,  C08F10/00 ,  C08F2/001 ,  C08F2/34 ,  C08F2/01 ,  C08F2500/12 ,  C08F2500/07 ,  C08F2500/24 ,  C08F2500/18

Abstract: A process for polymerizing olefins at temperatures of from 30° C. to 140° C. and pressures of from 1.0 MPa to 10 MPa in the presence of a polymerization catalyst in a multistage polymerization of olefins in at least two serially connected gas-phase polymerization reactors, and apparatus for the multistage polymerization of olefins, comprising at least two serially connected gas-phase polymerization reactors and a device for transferring polyolefin particles from an up-stream gas-phase polymerization reactor to a downstream gas-phase polymerization reactor, the transferring device comprising—a gas/solid separation chamber placed downstream of the upstream gas-phase polymerization which gas/solid separation chamber is equipped at a lower part with an net for introducing a fluid, and—connected to the gas/solid separation chamber at least two lock hoppers, placed in a parallel arrangement, each connected to the downstream gas-phase polymerization reactor.

Abstract translation: 在烯烃的多段聚合中在聚合催化剂存在下，在至少两个串联连接的气相聚合中，在30℃至140℃的温度和1.0MPa至10MPa的温度下使烯烃聚合的方法 反应器和用于烯烃多段聚合的装置，包括至少两个串联连接的气相聚合反应器和用于将聚烯烃颗粒从上游气相聚合反应器转移到下游气相聚合反应器的装置，转移 装置包括：在上游气相聚合的下游设置的气/固分离室，气/固分离室在下部配备有用于引入流体的网，并至少与气/固分离室连接 两个锁定料斗，并排布置，每个连接到下游气相聚合反应器。

公开(公告)号：US20160152747A1

公开(公告)日：2016-06-02

申请号：US14900955

申请日：2014-06-19

Applicant: BASELL POLYOLEFINE GMBH

Inventor： GERHARDUS MEIER ,  ULF SCHULLER ,  DIANA DOTSCH ,  BERND LOTHAR MARCZINKE ,  JENS WIESECKE

IPC: C08F210/16

CPC classification number: C08F210/16 ,  B29C49/0005 ,  B29C2049/047 ,  B29K2023/06 ,  C08L23/06 ,  C08L23/0815 ,  C08L2205/025 ,  C08L2314/02

Abstract: The present technology relates to a polyethylene composition suitable for producing small articles such as flexible and collapsible tubes by blow molding comprising: 1) a density from 0.948 to 0.955 g/cm3; 2) a MIF/MIP ratio from 12 to 25; 3) a MIF from 25 to 40 g/10 min; 4) a Mz from 1000000 to 2000000 g/mol; and 5) a long-chain branching index, LCBI, equal to or greater than 0.55.

Abstract translation: 本技术涉及一种适用于通过吹塑成型生产小型制品如柔性和可折叠管的聚乙烯组合物，其包括：1）0.948至0.955g / cm3的密度; 2）MIF / MIP比率为12至25; 3）MIF为25〜40g / 10min; 4）Mz从1000000到2000000g / mol; 和5）长链支化指数LCBI等于或大于0.55。

公开(公告)号：US20160031193A1

公开(公告)日：2016-02-04

申请号：US14774265

申请日：2014-02-04

Applicant: BASELL POLYOLEFINE GMBH

Inventor： Gianni Perdomi ,  Johannes Gerhard Muller ,  Ankur Rastogi

IPC: B32B27/08 ,  D01F8/06 ,  B32B27/32

CPC classification number: B32B27/08 ,  B32B27/32 ,  B32B2250/03 ,  B32B2250/242 ,  B32B2250/40 ,  B32B2307/54 ,  B32B2307/72 ,  D01D5/32 ,  D01D5/426 ,  D01F8/06 ,  D10B2321/021

Abstract: A multilayer fiber ABA comprising: A) at least two top layers (layer A) comprising propylene copolymer with ethylene having an ethylene derived units content ranging from 3.5 wt % to 6.5 wt %; a melt flow rate according to ISO 1133 (230° C., 2.16 Kg) comprised between from 0.5 g/10 min to 5 g/10 min; a fraction of polymer soluble in xylene at 25° C. ranging from 10 wt % to 17 wt % based on the total weight of said copolymer: B) at least one core layer (layer B) comprising a high density polyethylene having a density ranging from 0.942 g/cm3 to 0.958 g/cm3; and having a melt flow rate (MFR measured at 190° C. 5.0 kg) ranging from 0.3 g/10 min to 5 g/10 min.

Abstract translation: 一种多层纤维ABA，包括：A）至少两层顶层（A层），其包含乙烯衍生单元含量为3.5重量％至6.5重量％的乙烯的丙烯共聚物; 根据ISO 1133（230℃，2.16Kg）的熔体流动速率为0.5g / 10min至5g / 10min; 基于所述共聚物的总重量，25℃下可溶于二甲苯的聚合物的分数为10重量％至17重量％; B）至少一个包含密度范围的高密度聚乙烯的芯层（B层） 从0.942g / cm 3到0.958g / cm 3; 并且具有范围为0.3g / 10min至5g / 10min的熔体流动速率（190℃，5.0kg下测得的MFR）。