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    Control of CO2 emissions from a fischer-tropsch facility by use of dual functional syngas conversion
    31.
    发明授权
    Control of CO2 emissions from a fischer-tropsch facility by use of dual functional syngas conversion 失效
    通过双功能合成气转化控制费托设施的二氧化碳排放

    公开(公告)号：US06992113B2

    公开(公告)日：2006-01-31

    申请号：US10720673

    申请日：2003-11-25

    申请人： Dennis J. O'Rear ,  Charles L. Kibby

    发明人： Dennis J. O'Rear ,  Charles L. Kibby

    IPC分类号： C07C27/00

    CPC分类号： C10G2/32 ,  C10G2/50 ,  Y02P20/132 ,  Y02P20/582

    摘要： CO2 emissions from syngas conversion processes are reduced by use of a multi-stage Fischer-Tropsch reaction system. A process for the conversion of syngas using a Fischer-Tropsch reactor comprises forming a first syngas and reacting at least a portion of the first syngas in a Fischer-Tropsch reactor to form a first hydrocarbonaceous product and a second syngas. The second syngas is mixed with a hydrogen-containing stream to provide an adjusted syngas, at least a portion of which is reacted in a dual functional syngas conversion reactor to form a second hydrocarbonaceous product and a third syngas comprising a reduced amount of CO2 than was present in the adjusted syngas.

    摘要翻译： 通过使用多级费 - 托反应系统来减少来自合成气转化过程的CO 2 CO 2排放。 使用费 - 托反应器转化合成气的方法包括形成第一合成气并在费 - 托反应器中使至少一部分第一合成气反应以形成第一烃类产物和第二合成气。 将第二合成气与含氢物流混合以提供调节的合成气，其中至少一部分在双官能合成气转化反应器中反应以形成第二烃产物和包含减少量的CO 2 比在调节合成气中存在。

    Production of stable olefinic fischer tropsch fuels with minimum hydrogen consumption
    32.
    发明授权
    Production of stable olefinic fischer tropsch fuels with minimum hydrogen consumption 失效
    生产稳定的烯烃费 - 托燃料，具有最低的氢消耗

    公开(公告)号：US06933323B2

    公开(公告)日：2005-08-23

    申请号：US10354956

    申请日：2003-01-31

    申请人： Dennis J. O'Rear ,  Guan Dao Lei

    发明人： Dennis J. O'Rear ,  Guan Dao Lei

    IPC分类号： C07C20060101 ,  C07C1/04 ,  C07C7/20 ,  C07C27/00 ,  C07C27/06 ,  C10G20060101 ,  C10G2/00 ,  C10G15/00 ,  C10G29/22 ,  C10G45/00 ,  C10G45/04 ,  C10G47/04 ,  C10L1/04 ,  C10L1/10 ,  F02M20060101

    CPC分类号： C10G2/30 ,  C10G2/32 ,  C10G45/04 ,  C10G47/04 ,  C10L1/04 ,  Y10S208/95

    摘要： The present invention relates to a stable, low sulfur, olefinic distillate fuel blend component derived from a Fischer-Tropsch process and a process for producing this stable, low sulfur, olefinic distillate fuel blend component. The stable, low sulfur, olefinic distillate fuel comprises olefins in an amount of 2 to 80 weight percent, non-olefins in an amount of 20 to 98 weight percent wherein the non-olefins are predominantly paraffins, oxygenates in an amount of less than 1 weight percent, and sulfur in an amount of less than 10 ppm by weight. A distillate fuel comprising the above blend component forms less than 5 ppm peroxides after storage at 60° C. for four weeks.

    摘要翻译： 本发明涉及一种衍生自费 - 托法的稳定的低硫烯烃馏出物燃料混合物组分和用于生产该稳定的低硫烯烃馏出物燃料混合物组分的方法。 稳定的低硫烯烃馏出物燃料包含2-80重量％的烯烃，其量为20-98重量％的非烯烃，其中非烯烃主要是链烷烃，含氧化合物的量小于1 重量百分比以及小于10ppm重量的硫。 包含上述共混组分的馏出物燃料在60℃下储存四周后形成小于5ppm的过氧化物。

    Upgrading fischer-Tropsch and petroleum-derived naphthas and distillates
    34.
    发明授权
    Upgrading fischer-Tropsch and petroleum-derived naphthas and distillates 失效
    升级费 - 托和石油衍生的石脑油和馏出物

    公开(公告)号：US06863802B2

    公开(公告)日：2005-03-08

    申请号：US10059382

    申请日：2002-01-31

    申请人： Dennis J. O'Rear ,  Lawrence W. Jossens

    发明人： Dennis J. O'Rear ,  Lawrence W. Jossens

    IPC分类号： C10G65/00 ,  C10G69/08 ,  C10G69/14 ,  C10G35/04 ,  C10G35/06

    CPC分类号： C10G69/08 ,  C10G45/02 ,  C10G65/00 ,  C10G2300/1022 ,  C10G2400/02 ,  C10G2400/06 ,  C10G2400/10

    摘要： A process for upgrading at least one of a Fischer-Tropsch naphtha and a Fischer-Tropsch distillate to produce at least one of a gasoline component, a distillate fuel or a lube base feedstock component. The process includes reforming a Fischer-Tropsch naphtha to produce hydrogen by-product and a gasoline component with a research octane rating of at least about 80. The process further includes upgrading a Fischer-Tropsch distillate using the hydrogen by-product to produce a distillate fuel and/or a lube base feedstock component.

    摘要翻译： 一种用于升级费 - 托石脑油和费 - 托馏出物中的至少一种以产生汽油组分，馏出燃料或润滑油基料原料组分中的至少一种的方法。 该方法包括重整费 - 托石脑油以产生氢副产物和研究辛烷值为至少约80的汽油组分。该方法还包括使用氢副产物升级费 - 托馏出物以产生馏出物 燃料和/或润滑油基料原料组分。

    Process for preparing lubes with high viscosity index values
    36.
    发明授权
    Process for preparing lubes with high viscosity index values 失效
    制备具有高粘度指数值的润滑剂的方法

    公开(公告)号：US06773578B1

    公开(公告)日：2004-08-10

    申请号：US09729215

    申请日：2000-12-05

    申请人： Dennis J. O'Rear ,  Joseph A. Biscardi

    发明人： Dennis J. O'Rear ,  Joseph A. Biscardi

    IPC分类号： C10G7000

    CPC分类号： C10G73/12 ,  C10G73/06 ,  C10G2400/10

    摘要： Lube base stocks and lube stock compositions, as well as a process for preparing lube base stocks and lube stock compositions, are disclosed. The lube oils preferably have a viscosity index above about 115. The process involves obtaining feedstocks that have a 95% point below 1150° F. and feedstocks that have 95% point above 1150° F. The feedstocks that have a 95% point below 1150° F. are catalytically dewaxed, and the feedstocks that have 95% point above 1150° F. are solvent dewaxed. The resulting products can optionally be blended, and the base stocks can be combined with various additives to form lube oil compositions. Hydrotreatment can optionally be performed on the lube base stocks to remove olefins, oxygenates and other impurities. In one embodiment, one or more of the fractions are obtained from Fischer-Tropsch synthesis. One or more of the fractions can also be obtained from other sources, for example, via distillation of crude oil, provided that the fractions do not include appreciable amounts (i.e., amounts which would adversely affect the catalyst used for catalytic isodewaxing) of thiols or amines. The individual fractions can also include combinations of feedstocks, from Fischer-Tropsch and other sources.

    摘要翻译： 公开了润滑油基础油和润滑油组合物，以及润滑油基础油和润滑油料组合物的制备方法。 润滑油优选具有高于约115的粘度指数。该方法包括获得具有低于1150°F的95％点的原料和具有高于1150°F的95％点的原料。具有低于1150°F的95％点的原料 °F被催化脱蜡，并且具有高于1150°F的95％点的原料是溶剂脱蜡的。 可以任意地混合所得产物，并且可以将基础油料与各种添加剂组合以形成润滑油组合物。 可以任选地在润滑油基础油上进行加氢处理以除去烯烃，含氧化合物和其它杂质。 在一个实施方案中，一种或多种级分由费 - 托合成得到。 一些或多个级分也可以从其他来源获得，例如通过蒸馏原油，条件是馏分不包括可信量（即不利地影响用于催化异构脱蜡的催化剂的量）硫醇或 胺类 单独的馏分还可以包括来自费托和其他来源的原料的组合。

    Condensation of olefins in fischer tropsch tail gas
    37.
    发明授权
    Condensation of olefins in fischer tropsch tail gas 失效
    烯烃在费托尾气中的缩合

    公开(公告)号：US06713657B2

    公开(公告)日：2004-03-30

    申请号：US10115129

    申请日：2002-04-04

    申请人： Dennis J. O'Rear ,  Stephen J. Miller

    发明人： Dennis J. O'Rear ,  Stephen J. Miller

    IPC分类号： C07C100

    CPC分类号： C10G2/32 ,  C07C1/04 ,  C07C2/12 ,  C07C2529/40 ,  C10G50/00

    摘要： Light olefins including LPG contained in unreacted tail gas from a Fischer-Tropsch process are catalytically condensed using an acidic oligomerization/aromatization catalyst to form higher molecular weight C5+ products. Thus, C3-C4 olefins are readily separated from the tail gas and upgraded to more valuable products. In one embodiment, the condensation is conducted on a mixed gas stream of fresh synthesis gas and tail gas from a Fischer-Tropsch process. In another embodiment, the condensation is conducted on a syngas feed to a Fischer-Tropsch reactor and removes a significant portion of catalytically poisonous nitrogen compounds.

    摘要翻译： 包含在费 - 托法的未反应尾气中的轻质烯烃包括LPG，使用酸性低聚/芳构化催化剂进行催化缩合以形成较高分子量的C5 +产物。 因此，C3-C4烯烃容易与尾气分离并升级为更有价值的产品。 在一个实施方案中，对来自费 - 托方法的新鲜合成气和尾气的混合气流进行冷凝。 在另一个实施方案中，在合成气进料到费 - 托反应器上进行冷凝，并除去大部分催化有毒的氮化合物。

    Process for making a lube base stock from a lower molecular weight feedstock using at least two oligomerization zones
    38.
    发明授权
    Process for making a lube base stock from a lower molecular weight feedstock using at least two oligomerization zones 失效
    使用至少两个低聚区从较低分子量原料制备润滑油基础油料的方法

    公开(公告)号：US06686511B2

    公开(公告)日：2004-02-03

    申请号：US09758897

    申请日：2001-01-11

    申请人： Stephen J. Miller ,  Dennis J. O'Rear ,  Thomas V. Harris ,  Russell R. Krug

    发明人： Stephen J. Miller ,  Dennis J. O'Rear ,  Thomas V. Harris ,  Russell R. Krug

    IPC分类号： C07C212

    CPC分类号： C10M177/00 ,  C10G50/02 ,  C10G57/02 ,  C10M107/10 ,  C10N2270/00 ,  Y10S208/95

    摘要： A process for making a lube base stock wherein an olefinic feedstock is separated into a light olefin fraction and a medium olefin fraction. The light olefin fraction is contacted with a first oligomerization catalyst in a first oligomerization zone to produce a first product. Both the medium olefin fraction and the first product are contacted with a second oligomerization catalyst in a second oligomerization zone to produce a second product. The second product is separated into a light byproduct fraction and a heavy product fraction that includes hydrocarbons in the lube base stock range.

    摘要翻译： 一种制备润滑油基料的方法，其中将烯烃原料分离成轻质烯烃馏分和中等烯烃馏分。 在第一低聚区中轻链烯烃部分与第一低聚催化剂接触以产生第一产物。 中间烯烃部分和第一产物都在第二低聚区中与第二低聚催化剂接触以产生第二产物。 将第二产物分离成轻质副产物馏分和在润滑油基料范围内包含烃的重质产物馏分。

    Protection of Fischer-Tropsch catalysts from traces of sulfur
    39.
    发明授权
    Protection of Fischer-Tropsch catalysts from traces of sulfur 失效
    保护费 - 托催化剂的痕量硫

    公开(公告)号：US06682711B2

    公开(公告)日：2004-01-27

    申请号：US09842673

    申请日：2001-04-27

    申请人： Robert J. Motal ,  Dennis J. O'Rear

    发明人： Robert J. Motal ,  Dennis J. O'Rear

    IPC分类号： C10K120

    CPC分类号： C10G2/32 ,  B01J8/008 ,  B01J8/04 ,  B01J35/0006 ,  B01J2208/00707 ,  B01J2208/00831 ,  C10G2/332 ,  C10G2/333 ,  C10G2/34

    摘要： Methods for removing sulfur from syngas in a Fischer-Tropsch reactor, and reactors including means for removing sulfur from syngas are disclosed. Sulfur-reactive metals can be used in the Fischer-Tropsch unit to sequester the sulfur. For example, the Fischer-Tropsch unit can be run in stages, using a sacrificial catalyst in a first stage to adsorb the sulfur. The Fischer-Tropsch reactor can include internal baffles that separate the reactor into zones, with a sacrificial catalyst in one or more of the zones, that can be easily sequestered and regenerated or replaced. Sulfur adsorbents can be placed in the inlet gas manifold. A portion of the Fischer-Tropsch catalyst can be converted into larger size pellets that do not fluidize with the finer grain Fischer-Tropsch catalyst and remain near the gas inlet where they adsorb and sequester the sulfur. These embodiments can be combined in any suitable manner to lower the sulfur concentration in the syngas feed. The resulting syngas feed preferably has a sulfur concentration less than 50 wppb, more preferably less than 15 wppb, and most preferably less than 1 wppb.

    摘要翻译： 公开了在费 - 托反应器中从合成气中除去硫的方法，以及包括从合成气中除去硫的装置的反应器。 硫反应性金属可用于费 - 托单元以螯合硫。 例如，费 - 托单元可以分阶段运行，在第一阶段使用牺牲催化剂吸附硫。 费 - 托反应器可以包括将反应器分离成区域的内部挡板，其中一个或多个区域中的牺牲催化剂可以容易地隔离和再生或更换。 硫吸附剂可以放置在进气歧管中。 费 - 托催化剂的一部分可以转化成更大尺寸的颗粒，其不会与更细晶粒费 - 托催化剂一起流化，并保持在气体入口附近，在那里它们吸附和螯合硫。 这些实施方案可以以任何合适的方式组合以降低合成气进料中的硫浓度。 所得合成气进料优选具有小于50wppb，更优选小于15wppb，最优选小于1wppb的硫浓度。