摘要:
A use of ansa-metallocene complexes for the polymerisation of cyclic esters and cyclic amides is disclosed. The ansa-metallocene complexes are particularly active as initiators/catalysts in the polymerisation of lactides, with the resulting polymeric material demonstrating low polydispersity.
摘要:
Titanium dioxide is used as an emissivity enhancer in high emissivity coating compositions. The titanium dioxide increases the emissivity of the high emissivity coating compositions. In certain embodiments, titanium dioxide is recovered from industrial waste sources such as catalyst containing waste streams from olefin polymerization processes or re-based sources. Titanium dioxide emissivity enhancers recovered from industrial waste sources contribute favorably to the cost of manufacturing high emissivity coating compositions containing such enhancers.
摘要:
Layered double hydroxides having a high surface area (at least 125 m2/g) and the formula (I) [Mz+1-xM′y+x(OH)2]a+(Xn-)a/n+bH2O.c(AMO-solvent) (I) wherein M and M′ are different and each is a charged metal cation (and must be present), z=1 or 2; y=3 or 4, 0
摘要:
The invention relates to a catalyst for olefin polymerization represented by the general formula (1): wherein; M is a transition metal; X1 and X2 are independently selected from the group consisting of halide, alkyl group, aryl group, alkyl amine group, or alkyl aryl group, and are directly bond to M, R1 and R2 are independently selected from the group consisting of hydrogen, alkyl group or aryl group; and Cp is a cyclopentadienyl group. R1R2C═N—OMCPX1X2 (I)
摘要翻译:本发明涉及由通式(I)表示的烯烃聚合催化剂:ƒ€ƒ€ƒ€ƒ€ƒR 1 R 2 C = N-OMC P X 1 X 2其中; M是过渡金属; X 1和X 2独立地选自卤素,烷基,芳基,烷基胺基或烷基芳基,并且直接与M键合,R 1和R 2独立地选自 氢,烷基或芳基; Cp是环戊二烯基。
摘要:
New layered double hydroxide materials useful as intermediates in the formation of catalysts are described, as well as methods of preparing the layered double hydroxides. Also described are catalysts suitable for catalysing the hydrogenation of CO2 to methanol, as well as methods for preparing the catalysts. The LDH-derived catalysts of the invention are active in the hydrogenation of CO2 to methanol, and show improved activity with respect to Cu/ZnO catalysts derived from copper-zinc hydroxycarbonate precursors.
摘要:
The present invention relates to a process for producing a multimodal polyethylene composition in the reactor system according to the invention, comprising; (a) polymerizing ethylene in an inert hydrocarbon medium in the first reactor in the presence of a catalyst system, selected from Ziegler-Natta catalyst or metallocene, and hydrogen in an amount of 0.1-95% by mol with respect to the total gas present in the vapor phase in the first reactor to obtain a low molecular weight polyethylene or a medium molecular weight polyethylene; (b) removing in the hydrogen removal unit 98.0 to 99.8% by weight of the hydrogen comprised in a slurry mixture obtained from the first reactor at a pressure in the range of 103-145 kPa (abs) and transferring the obtained residual mixture to the second reactor; (c) polymerizing ethylene and optionally C4 to C12 α-olefin comonomer in the second reactor in the presence of a catalyst system, selected from Ziegler-Natta catalyst or metallocene, and in the presence of hydrogen in an amount obtained in step (b) to obtain a first high molecular weight polyethylene or a first ultra high molecular weight polyethylene in the form of a homopolymer or a copolymer and transferring a resultant mixture to the third reactor; and (d) polymerizing ethylene, and optionally α-olefin comonomer in the third reactor in the presence of a catalyst system, selected from Ziegler-Natta catalyst or metallocene, and hydrogen, wherein the amount of hydrogen in the third reactor is in a range of 1-70% by mol, preferably 1-60% by mol with respect to the total gas present in the vapor phase in the third reactor or optionally substantial absence of hydrogen to obtain a second high molecular weight polyethylene or a second ultra high molecular weight polyethylene homopolymer or copolymer; and a multimodal polyethylene composition obtainable this way.
摘要:
A floating arrangement may include at least one support-floatation-unit for supporting a solar panel, the at least one support-floatation-unit has a main body having a flat base and at least one connection portion; and at least one connecting-floatation-unit having a flat base and at least one connection portion. The respective corner-connection-portions may be coupled together to form a connection joint connecting the support-floatation-unit and the connecting-floatation-unit in a side-by-side arrangement. A height from the base of the support-floatation-unit to the connection joint may be larger than a height from the base of the connecting-floatation-unit to the connection joint such that the base of the support-floatation-unit may extend downwards from the base of the connecting-floatation-unit by a depth which defines an additional displacement volume of the support-floatation-unit configured to provide additional buoyancy to support the solar panel.
摘要:
The present invention relates to polymer composition comprising 100 parts by weight of halogen containing polymer, 10 to 70 parts by weight of plasticizer, 2 to 10 parts by weight of stabilizer, 1-15 parts by weight of a layered double hydroxide (LDH) having the formula (I) wherein M and M′ are different and each is at least one metal cation, z=1 or 2; y=3 or 4, 0
摘要:
Unsymmetrical metallocene compounds based on cyclopentadienyl ligands are disclosed, as well as catalytic compositions comprising the compounds supported on solid support materials. The compounds and compositions are useful as catalysts in the polymerisation of olefins. In particular, the compounds and compositions are useful catalysts in the preparation of low molecular weight polyethylene (e.g. polyethylene wax) and copolymers formed from the polymerisation of ethylene and other α-olefins.