公开(公告)号：US20180237714A1

公开(公告)日：2018-08-23

申请号：US15753377

申请日：2016-08-17

Applicant: Dow Global Technologies LLC

Inventor： Martin R. Greaves ,  Ronald Van Voorst ,  Marinus Meertens

IPC: C10M105/72 ,  C10M169/04 ,  C10M133/12 ,  C10M135/36

Abstract: A fluid contains a base oil and an antioxidant, the base oil consisting of sulfur-containing polyalkylene glycol where greater than 80 weight-percent of the fluid is a sulfur-containing polyalkylene glycol and less than one weight-percent of the fluid is water, with weight percent based on total fluid weight an wherein the sulfur-containing polyalkylene glycol is free of oxygen bound directly to sulfur.

公开(公告)号：US09963648B2

公开(公告)日：2018-05-08

申请号：US14901059

申请日：2014-06-18

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Paul R. Elowe ,  Wanglin Yu ,  Brad C. Bailey ,  Daniel J. Arriola ,  Jerzy J. Klosin ,  Suh Joon Han ,  Zenon Lysenko ,  Martin R. Greaves

IPC: C10G69/12 ,  B01J31/22 ,  C10M107/04 ,  C10G50/02 ,  C10M177/00 ,  C10M107/08 ,  C10M107/10 ,  C10M105/04

CPC classification number: C10G69/126 ,  B01J31/2239 ,  B01J2231/20 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  C10G50/02 ,  C10G2300/1088 ,  C10G2400/10 ,  C10M105/04 ,  C10M107/04 ,  C10M107/08 ,  C10M107/10 ,  C10M177/00 ,  C10M2205/0225 ,  C10M2205/0265 ,  C10M2205/0285 ,  C10N2220/022 ,  C10N2220/028 ,  C10N2230/02 ,  C10N2230/08 ,  C10N2260/02

Abstract: Processes to prepare branched polyolefins for lubricant applications comprise combining at least one olefin and a coordination-insertion catalyst under conditions such that at least one oligomer product is formed. Low molecular weight by-products are fractionated out and the oligomer product is converted to a saturated hydrocarbon via hydrogenation.

公开(公告)号：US20140303053A1

公开(公告)日：2014-10-09

申请号：US14353538

申请日：2012-10-25

Applicant: Dow Global Technologies LLC

Inventor： Martin R. Greaves

IPC: C10M141/10

CPC classification number: C10M141/10 ,  C10M107/34 ,  C10M133/44 ,  C10M137/04 ,  C10M137/08 ,  C10M169/04 ,  C10M2207/026 ,  C10M2209/1065 ,  C10M2209/1075 ,  C10M2209/1085 ,  C10M2215/065 ,  C10M2215/223 ,  C10M2219/066 ,  C10M2223/04 ,  C10M2223/043 ,  C10M2223/045 ,  C10M2223/047 ,  C10M2223/049 ,  C10N2230/00 ,  C10N2230/02 ,  C10N2230/06 ,  C10N2240/08 ,  C10N2240/10 ,  C10N2240/30 ,  C10M2209/1055

Abstract: A lubricant composition comprising at least 90 wt % of at least one oil soluble polyalkylene glycol (OSP), wherein the OSP comprises at least 40 wt % units derived from butylene oxide and at least 40 wt % units derived from propylene oxide, initiated by one or more initiators selected from monols, diols, and polyols; and at least 0.05 wt % of at least one anti-wear additive; wherein the lubricant composition exhibits a four ball anti-wear of less than or equal to 0.35 mm and an air release value at 50° C. of less than or equal to 1 minute is provided.

Abstract translation: 一种润滑剂组合物，其包含至少90重量％的至少一种油溶性聚亚烷基二醇（OSP），其中所述OSP包含至少40重量％的衍生自环氧丁烷的单元和至少40重量％衍生自环氧丙烷的单元，其由一个 或更多的选自单醇，二醇和多元醇的引发剂; 和至少0.05重量％的至少一种抗磨添加剂; 其中所述润滑剂组合物呈现小于或等于0.35mm的四球抗磨损，并且提供小于或等于1分钟的50℃下的空气释放值。

公开(公告)号：US20140249063A1

公开(公告)日：2014-09-04

申请号：US14350094

申请日：2012-09-14

Applicant: Dow Global Technologies LLC

Inventor： Martin R. Greaves ,  Ronald Van Voorst ,  Marinus Meertens

IPC: C10M169/04

CPC classification number: C10M169/04 ,  C10M111/04 ,  C10M169/041 ,  C10M2203/1006 ,  C10M2203/1025 ,  C10M2205/0285 ,  C10M2209/105 ,  C10M2209/1055 ,  C10N2220/021 ,  C10N2230/70 ,  C10N2270/00 ,  C10N2220/022 ,  C10M2209/106 ,  C10M2209/108 ,  C10M2209/1065 ,  C10M2209/1085

Abstract: A lubricant composition comprising a Group I, II, III or IV hydrocarbon oil and a polyalkylene glycol, the polyalkylene glycol having been prepared by reacting a C8-C20 alcohol and a mixed butylene oxide/propylene oxide feed using a double metal cyanide catalyst catalyzed oxyalkylation process, and wherein the lubricant composition remains clear and shows no phase separation at temperatures equal to and greater than the pour point of the hydrocarbon oil is provided. A method for making a lubricant composition is also provided.

Abstract translation: 包含I，II，III或IV族烃油和聚亚烷基二醇的润滑剂组合物，所述聚亚烷基二醇是通过使用双金属氰化物催化剂催化的烷氧基化使C8-C20醇和混合环氧丁烷/环氧丙烷进料反应制备的 并且其中润滑剂组合物保持透明并且在等于并且大于提供烃油的倾点的温度下不显示相分离。 还提供了制备润滑剂组合物的方法。

公开(公告)号：US20140107004A1

公开(公告)日：2014-04-17

申请号：US14118683

申请日：2012-06-08

Applicant: Dow Global Technologies LLC

Inventor： Nadjet Khelidj ,  Martin R. Greaves ,  Evelyn A. Zaugg-Hoozemans

IPC: C10M129/08

CPC classification number: C10M129/08 ,  C10M145/26 ,  C10M169/041 ,  C10M2207/2835 ,  C10M2207/301 ,  C10M2207/401 ,  C10M2209/10 ,  C10M2209/103 ,  C10M2209/104 ,  C10M2219/044 ,  C10M2223/043 ,  C10N2230/66 ,  C10N2240/08 ,  C10M2209/105

Abstract: A lubricant composition comprising (a) from 0.1 to 10 percent by weight of one or more polyalkylene glycols (PAG); and (2) one or more ester base oils selected from the group of natural esters, synthetic esters and combinations thereof; wherein the one or more PAG has a molecular weight in the range 1500 to 5000 g/mole, comprises from 10 to 40 percent by weight of units derived from ethylene oxide and from 90 to 60 percent by weight of units derived from propylene oxide; and wherein the one or more PAGs are in the form of block copolymer, reverse block copolymer or combinations thereof is provided. Also provided is a method of enhancing the hydrolytic stability of an ester base oil.

Abstract translation: 一种润滑剂组合物，其包含（a）0.1至10重量％的一种或多种聚亚烷基二醇（PAG）; 和（2）一种或多种选自天然酯，合成酯及其组合的酯基油; 其中所述一种或多种PAG的分子量为1500至5000g / mol，包含10至40重量％的衍生自环氧乙烷的单元和90至60重量％的源自环氧丙烷的单元; 并且其中所述一种或多种PAG为嵌段共聚物的形式，提供反向嵌段共聚物或其组合。 还提供了提高酯基油的水解稳定性的方法。

公开(公告)号：US11505762B2

公开(公告)日：2022-11-22

申请号：US17281651

申请日：2019-10-03

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Martin R. Greaves

IPC: C10M173/02 ,  C10N20/00 ,  C10N20/04 ,  C10N30/02 ,  C10N40/08

Abstract: A composition comprising water, a glycol, and a polyalkylene glycol which has a biodegradability of at least 60% as determined using OECD 301F wherein the composition has a kinematic viscosity of at least 25 mm2/sec at 40° C. is useful as a rheology modifier, particularly in subsea applications. In some instances, the composition comprises 10 to 65 weight % water, 20 to 60 weight % of a glycol selected from ethylene glycol, diethylene glycol, triethylene glycol and tetra ethylene glycol, 10 to 40 weight % of a polyalkylene glycol, and 0 to 10% of additives based on total weight of the composition wherein the polyalkylene glycol has a—molecular weight of no more than 4000 g/mol and is characterized in that it is an oxyethylene/oxypropylene block copolymer having a weight percent of oxyethylene of at least 20% based on total weight of the copolymer.

公开(公告)号：US11193083B2

公开(公告)日：2021-12-07

申请号：US15500789

申请日：2015-07-21

Applicant: Dow Global Technologies LLC

Inventor： Nadjet Khelidj ,  Martin R. Greaves ,  Evelyn A. Zaugg-Hoozemans

IPC: C10M145/34 ,  C10M169/04 ,  C10N20/02 ,  C10N30/02 ,  C10N40/04 ,  C10N40/08 ,  C10N40/12 ,  C10N40/30 ,  C10N40/25

Abstract: An industrial base oil formulation comprising a base oil, preferably a hydrocarbon base oil, having a kinematic viscosity of more than 100 centiStokes, preferably 150 centiStokes or more, at 40 degrees Celsius and an AC-OSP where the AC-OSP has the structure of Formula I: R1[O(R2O)n(R3O)mR4]p (I) where R1 is an alkyl having from one to thirty carbons, R2 and R3 are independently selected from alkyl groups having three or four carbons and can be in block form or randomly combined, R4 is an alkyl having from one to 18 carbon atoms, n and m are independently numbers ranging from zero to 20 provided that n+m is greater than zero and p is a number within a range of one to three; wherein the industrial base oil formulation has a kinematic viscosity of greater than 100 centiStokes, preferably 150 centiStokes or more, at 40 degrees Celsius is useful in a lubricant for mechanical devices.

公开(公告)号：US10577557B2

公开(公告)日：2020-03-03

申请号：US15753448

申请日：2016-08-17

Applicant: Dow Global Technologies LLC

Inventor： Martin R. Greaves ,  Evelyn A. Zaugg-Hoozemans

IPC: C10M169/04 ,  C10M105/18 ,  C10M129/72 ,  C10M133/12 ,  C10M135/36

Abstract: A fluid contains a base oil consisting of an alcohol-initiated polyalkylene glycol where polyalkylene glycol component is selected from a homopolymer of 1,2-butylene oxide and copolymer of 1,2-butylene oxide and propylene oxide; a glycerol-initiated unsaturated ester that is free of tertiary carbon atoms and quaternary carbon atoms; and an antioxidant.

公开(公告)号：US10428293B2

公开(公告)日：2019-10-01

申请号：US15553666

申请日：2016-02-22

Applicant: Dow Global Technologies LLC

Inventor： Ashish Kotnis ,  Martin R. Greaves ,  Govindlal Khemchandani

IPC: C10M169/04 ,  C10M141/08 ,  C10M105/00 ,  C10M135/04 ,  C10M145/04 ,  C10M161/00

Abstract: A lubricant formulation contains: (a) at least 50 weight-percent hydrocarbon base oil; (b) five to 50 weight-percent of an oil soluble polyalkylene glycol selected from monol, diol and triol initiated 1,2-butylene oxide homopolymer and monol initiated copolymers of 1,2-butylene oxide and propylene oxide; and (c) 0.1 to five weight-percent or less of a sulfurized olefin; where weight-percent is based on total lubricant formulation weight.

公开(公告)号：US10113134B2

公开(公告)日：2018-10-30

申请号：US15500412

申请日：2015-07-21

Applicant: Dow Global Technologies LLC

Inventor： Nadjet Khelidj ,  Martin R. Greaves ,  Marinus Meertens ,  Ronald Van Voorst

IPC: C10M145/32 ,  C10M145/34 ,  C10M145/36 ,  C10M107/34

Abstract: A capped oil soluble polyalkylene glycol has the following structure: R1O-(AO)n—R2 where: R1 is a linear or branched alkyl or aryl with one to 18 carbon atoms; AO refers to residuals of monomers selected from 1,2-butylene oxide and 1,2-propylene oxide selected so that at least 50 weight-percent of the (AO)n component is 1,2-butylene oxide residuals; n is selected to provide a kinematic viscosity at 100 degrees Celsius of less than 5 centiStokes for the non-capped polyalkylene glycol; and R2 is a linear or branched alkyl or aryl having from 1-8 carbon atoms and wherein the capped oil soluble polyalkylene glycol is characterized by having a kinematic viscosity of less than 4.5 centiStokes at 100 degrees Celsius and a viscosity index of greater than 150.