公开(公告)号：US07355084B2

公开(公告)日：2008-04-08

申请号：US10480196

申请日：2002-06-07

申请人： Arnd Böttcher ,  Dominic Vanoppen ,  Jan-Dirk Arndt ,  Jochem Henkelmann ,  Konrad Knoll

发明人： Arnd Böttcher ,  Dominic Vanoppen ,  Jan-Dirk Arndt ,  Jochem Henkelmann ,  Konrad Knoll

IPC分类号： C07C5/00

CPC分类号： C07D295/023 ,  B01J21/08 ,  B01J23/462 ,  B01J37/18 ,  C07B2200/09 ,  C07C5/10 ,  C07C29/141 ,  C07C29/172 ,  C07C29/19 ,  C07C29/20 ,  C07C51/36 ,  C07C209/48 ,  C07C209/72 ,  C07C2523/46 ,  C07C2601/14 ,  C08F8/04 ,  C07C13/18 ,  C07C211/03 ,  C07C211/11 ,  C07C211/35 ,  C07C211/36 ,  C07C31/12 ,  C07C31/20 ,  C07C35/08 ,  C07C35/21 ,  C07C31/1355 ,  C07C29/175

摘要： In a process for hydrogenating at least one organic compound, the organic compound or compounds is/are brought into contact with a hydrogen-containing gas in the presence of a catalyst which comprises, as active metal, ruthenium either alone or together with at least one further metal of transition group I, VII or VIII of the Periodic Table applied to a support material based on amorphons silicon dioxide and is obtainable by: i) a single or multiple treatment of a support material based on amorphous silicon dioxide with a halogen-free aqueous solution of a low molecular weight ruthenium compound and subsequent drying of the treated support material at below 200° C., ii) reduction of the solid obtained in i) by means of hydrogen at from 100 to 350° C., with step ii) being carried out directly after step i).

摘要翻译： 在使至少一种有机化合物氢化的方法中，有机化合物与含氢气体在催化剂的存在下进行接触，所述催化剂单独或与至少一种作为活性金属包含钌 应用于基于无定形二氧化硅的载体材料的周期表的过渡组I，VII或VIII的进一步金属，可通过以下步骤获得：i）单独或多次处理基于无卤素的无定形二氧化硅的载体材料 低分子量钌化合物的水溶液，随后在低于200℃下干燥经处理的载体材料，ii）通过在100至350℃的氢气使i）中获得的固体还原，步骤ii ）在步骤i）之后直接进行。

公开(公告)号：US20050009990A1

公开(公告)日：2005-01-13

申请号：US10496080

申请日：2002-11-19

申请人： Konrad Knoll ,  Philippe Desbois ,  Hans-Michael Walter ,  Michael Ishaque ,  Till Gerlach ,  Friederike Osswald

发明人： Konrad Knoll ,  Philippe Desbois ,  Hans-Michael Walter ,  Michael Ishaque ,  Till Gerlach ,  Friederike Osswald

IPC分类号： C08F279/02 ,  C08F297/04 ,  C08L25/04 ,  C08L53/02 ,  C08L53/00

CPC分类号： C08L53/02 ,  C08F297/04 ,  C08L53/025 ,  C08L2666/24

摘要： Mixtures comprising linear block copolymers made from vinylaromatic monomers and from dienes of the structure (I) S1—B1—S2 and (II) S3—B2—S4, where S1 is a block made from vinylaromatic monomers with number-average molar mass Mn in the range from 40,000 to 100,000 g/mol, each of S2, S3 and S4 is a block made from vinylaromatic monomers with number-average molar mass Mn in the range from 5,000 to 20,000 g/mol, each of B1 and B2 is a block made from dienes or a copolymer block made from dienes and from vinylaromatic monomers with number-average molar mass Mn in the range from 15,000 to 40,000 g/mol, and the ratio of the block copolymers (I)/(II) is in the range from 0.6 to 2.

摘要翻译： 包括由乙烯基芳族单体和结构（I）S1-B1-S2和（II）S3-B2-S4的二烯制备的线性嵌段共聚物的混合物，其中S1是由具有数均摩尔质量Mn的乙烯基芳族单体制成的嵌段 40,000至100,000g / mol的范围，S2，S3和S4中的每一个是由数均摩尔质量Mn在5,000至20,000g / mol范围内的乙烯基芳族单体制成的嵌段，B1和B2各自为嵌段 由二烯制得的共聚物嵌段和数均摩尔质量Mn为15,000至40,000g / mol的乙烯基芳族单体，并且嵌段共聚物（I）/（II）的比例在 从0.6到2。

公开(公告)号：US06762218B2

公开(公告)日：2004-07-13

申请号：US10240681

申请日：2002-10-03

申请人： Michael Geprägs ,  Konrad Knoll

发明人： Michael Geprägs ,  Konrad Knoll

IPC分类号： C08L5300

CPC分类号： C08L25/06 ,  C08L51/08 ,  C08L53/02 ,  C08L71/12 ,  C08L2666/02 ,  C08L2666/24

摘要： Thermoplastic molding compositions comprising, as substantive constituents, A) from 5 to 96% by weight of a vinylaromatic polymer with a syndiotactic structure, B) from 2 to 50% by weight of an inorganic filler, C) from 1 to 15% by weight of a thermoplastic elastomer based on copolymers made from vinylaromatic monomers, dienes and, where appropriate, 1,1-diphenylethylene, D) from 1 to 10% by weight of a compatibilizer, and, where appropriate, E) from 1 to 15% by weight of an elastomeric particulate styrene-diene block copolymer whose diene content may have been completely or to some extent hydrogenated, and, where appropriate, F) additives, where the total of the percentages by weight of A) to F) is 100.

摘要翻译： 作为实质成分的热塑性成型组合物包含A）5至96重量％的具有间同立构结构的乙烯基芳族聚合物，B）2至50重量％的无机填料，C）1至15重量％ 基于由乙烯基芳族单体，二烯和适当的1,1-二苯基乙烯制成的共聚物的热塑性弹性体，D）1至10重量％的增容剂，以及在适当的情况下，E）1至15重量％ 其二烯含量可能已经完全或一定程度氢化的弹性体颗粒状苯乙烯 - 二烯嵌段共聚物的重量，以及适当的F）添加剂，其中A）至F）的总重量百分数为100。

公开(公告)号：US06348166B1

公开(公告)日：2002-02-19

申请号：US09555593

申请日：2000-05-31

申请人： Konrad Knoll ,  Hans-Herbert Brintzinger ,  Armin Weeber

发明人： Konrad Knoll ,  Hans-Herbert Brintzinger ,  Armin Weeber

IPC分类号： C07F300

CPC分类号： C07F3/02 ,  C07F3/00 ,  C08F12/04 ,  C08F4/50

摘要： A process for the preparation of bisorganoalkaline earth metal compounds comprises reacting an organometallic compound RnM2 with an alkaline earth metal salt M1Xm.

摘要翻译： 制备双有机碱土金属化合物的方法包括使有机金属化合物RnM2与碱土金属盐M1Xm反应。

公开(公告)号：US5625008A

公开(公告)日：1997-04-29

申请号：US314954

申请日：1994-09-29

申请人： Klaus Bronstert ,  Konrad Knoll

发明人： Klaus Bronstert ,  Konrad Knoll

IPC分类号： B01J19/18 ,  C08C19/44 ,  C08F2/38 ,  C08F8/00 ,  C08C19/00

CPC分类号： C08C19/44 ,  B01J19/18 ,  C08F8/00 ,  B01J2219/00094 ,  B01J2219/185

摘要： Telecheles are prepared by reacting, preferably, polyfunctional, living polymers obtained by anionic polymerization with a functionalizing agent by a process in which the reaction is carried out while stirring with a stirrer having knife-like blades as stirring elements, the latter being inclined relative to their plane of movement and passing over essentially the complete space occupied by the reaction mixture.

摘要翻译： 通过使通过阴离子聚合获得的多官能活性聚合物与官能化剂反应，通过使用具有刀状叶片作为搅拌元件的搅拌器一边搅拌一边进行反应的方法，将后者相对于 它们的运动平面基本上超过了反应混合物占据的完整空间。

公开(公告)号：US08759445B2

公开(公告)日：2014-06-24

申请号：US13000817

申请日：2009-06-23

申请人： Matthias Müller ,  Konrad Knoll ,  Christof Mehler ,  Helmut Steininger ,  Norbert Güntherberg ,  Daniel Wagner ,  Michael Schuster ,  Geert Verlinden ,  Florian Greger

发明人： Matthias Müller ,  Konrad Knoll ,  Christof Mehler ,  Helmut Steininger ,  Norbert Güntherberg ,  Daniel Wagner ,  Michael Schuster ,  Geert Verlinden ,  Florian Greger

IPC分类号： C08L53/02 ,  C08F297/04

CPC分类号： C08L53/02 ,  C08F297/04 ,  C08L2666/02 ,  C08L2666/24

摘要： A mixture which comprises a) from 5 to 95% by weight of a copolymer A which comprises one or more copolymer blocks (B/S)A each composed of from 65 to 95% by weight of vinylaromatic monomers and from 35 to 5% by weight of dienes and of a glass transition temperature TgA in the range from 40° to 90° C., b) from 95 to 5% by weight of a block copolymer B which comprises at least one hard block S composed of from 95 to 100% by weight of vinylaromatic monomers and of from 0 to 5 by weight of dienes, and comprises one or more copolymer blocks (B/S)A each composed of from 65 to 95% by weight of vinylaromatic monomers and of from 35 to 5% by weight of dienes and of a glass transition temperature TgA in the range from 40° to 90° C., and comprises one or more copolymer blocks (B/S)B each composed of from 20 to 60% by weight of vinylaromatic monomers and of from 80 to 40% by weight of dienes and of a glass transition temperature TgB in the range from −70° to 0° C., c) from 0 to 45% by weight of thermoplastic polymers C other than A and B, and d) from 0 to 6% by weight of processing aids D, where the entirety of A to D gives 100% by weight, and its use for the production of shrink films.

摘要翻译： 一种混合物，其包含a）5至95重量％的共聚物A，其包含一种或多种共聚物嵌段（B / S）A，每个共聚物嵌段（B / S）A由65至95重量％的乙烯基芳族单体和35至5重量％ 二烯的重量和玻璃化转变温度TgA在40℃至90℃的范围内，b）95至5重量％的嵌段共聚物B，其包含至少一种由95至100组成的硬质块S 重量百分比的乙烯基芳族单体和0至5重量份的二烯，并且包含一种或多种共聚物嵌段（B / S）A，各自由65至95重量％的乙烯基芳族单体和35至5重量％ 的二烯的玻璃化转变温度TgA和40〜90℃的玻璃化转变温度TgA，并且包含一种或多种共聚物嵌段（B / S）B，各自由20至60重量％的乙烯基芳族单体组成， 80〜40重量％的二烯，玻璃化转变温度TgB在-70℃〜0℃的范围内，c）0〜45％的重量 除了A和B之外的热塑性聚合物C，以及d）0至6重量％的加工助剂D，其中A至D的总量为100重量％，以及其用于生产收缩膜的用途。

公开(公告)号：US20120107540A1

公开(公告)日：2012-05-03

申请号：US13283275

申请日：2011-10-27

申请人： Konrad Knoll ,  Daniel Wagner ,  Andrea Colmbo ,  Geert Verlinden

发明人： Konrad Knoll ,  Daniel Wagner ,  Andrea Colmbo ,  Geert Verlinden

IPC分类号： B32B1/08 ,  C08F8/00 ,  C08F8/42 ,  C08F297/00

CPC分类号： B32B7/12 ,  C08F8/04 ,  C08F297/044 ,  Y10T428/139

摘要： Elastomeric block copolymers having star-shaped molecular architecture, where the star-shaped molecular architecture has at least two different arms of the star, a process for producing the elastomeric block copolymers, the use of the elastomeric block copolymers for producing moldings, or as adhesive layer in multilayer foils; as seal; as adhesion promoter or thermoplastic component in wood-plastics composites; as hot-melt adhesive component; for impact-modifying thermoplastics or elastomers, or for compatibilization, and to foils, foams, thermomoldings, injection moldings, flexible tubing, or profile extrudates composed of at least one elastomeric block copolymer.

摘要翻译： 具有星形分子结构的弹性嵌段共聚物，其中星形分子结构具有至少两个不同的星形臂，制备弹性体嵌段共聚物的方法，弹性体嵌段共聚物用于生产模制品或粘合剂 多层箔; 作为密封; 作为木塑复合材料中的粘合促进剂或热塑性组分; 作为热熔胶组件; 用于冲击改性热塑性塑料或弹性体，或用于增容，以及由至少一种弹性体嵌段共聚物组成的箔，泡沫，热塑性塑料，注射成形品，柔性管或型材挤出物。

公开(公告)号：US20110098401A1

公开(公告)日：2011-04-28

申请号：US13000817

申请日：2009-06-23

申请人： Matthias Müller ,  Konrad Knoll ,  Christof Mehler ,  Helmut Steininger ,  Norbert Güntherberg ,  Daniel Wagner ,  Michael Schuster ,  Geert Verlinden ,  Florian Greger

发明人： Matthias Müller ,  Konrad Knoll ,  Christof Mehler ,  Helmut Steininger ,  Norbert Güntherberg ,  Daniel Wagner ,  Michael Schuster ,  Geert Verlinden ,  Florian Greger

IPC分类号： C08L53/02

CPC分类号： C08L53/02 ,  C08F297/04 ,  C08L2666/02 ,  C08L2666/24

摘要： A mixture which comprisesa) from 5 to 95% by weight of a copolymer A which comprises one or more copolymer blocks (B/S)A each composed of from 65 to 95% by weight of vinylaromatic monomers and from 35 to 5% by weight of dienes and of a glass transition temperature TgA in the range from 40° to 90° C.,b) from 95 to 5% by weight of a block copolymer B which comprises at least one hard block S composed of from 95 to 100% by weight of vinylaromatic monomers and of from 0 to 5 by weight of dienes, and comprises one or more copolymer blocks (B/S)A each composed of from 65 to 95% by weight of vinylaromatic monomers and of from 35 to 5% by weight of dienes and of a glass transition temperature TgA in the range from 40° to 90° C., and comprises one or more copolymer blocks (B/S)B each composed of from 20 to 60% by weight of vinylaromatic monomers and of from 80 to 40% by weight of dienes and of a glass transition temperature TgB in the range from −70° to 0° C.,c) from 0 to 45% by weight of thermoplastic polymers C other than A and B, andd) from 0 to 6% by weight of processing aids D,where the entirety of A to D gives 100% by weight, and its use for the production of shrink films.

摘要翻译： 一种混合物，其包含a）5至95重量％的共聚物A，其包含一种或多种共聚物嵌段（B / S）A，每个共聚物嵌段（B / S）A由65至95重量％的乙烯基芳族单体和35至5重量％ 二烯的重量和玻璃化转变温度TgA在40℃至90℃的范围内，b）95至5重量％的嵌段共聚物B，其包含至少一种由95至100组成的硬质块S 重量百分比的乙烯基芳族单体和0至5重量份的二烯，并且包含一种或多种共聚物嵌段（B / S）A，各自由65至95重量％的乙烯基芳族单体和35至5重量％ 的二烯的玻璃化转变温度TgA和40〜90℃的玻璃化转变温度TgA，并且包含一种或多种共聚物嵌段（B / S）B，各自由20至60重量％的乙烯基芳族单体组成， 80〜40重量％的二烯，玻璃化转变温度TgB在-70℃〜0℃的范围内，c）0〜45％的重量 除了A和B之外的热塑性聚合物C，以及d）0至6重量％的加工助剂D，其中A至D的总量为100重量％，以及其用于生产收缩膜的用途。

公开(公告)号：US20100152387A1

公开(公告)日：2010-06-17

申请号：US12601147

申请日：2008-05-07

申请人： Helmut Steininger ,  Konrad Knoll ,  Rolf Mülhaupt ,  Barbara Gall ,  Frédéric Pelascini

发明人： Helmut Steininger ,  Konrad Knoll ,  Rolf Mülhaupt ,  Barbara Gall ,  Frédéric Pelascini

IPC分类号： C08F8/08 ,  C08F212/08 ,  C08F4/76 ,  C08F226/02 ,  C08F230/08 ,  C08F214/00 ,  C08F4/80

CPC分类号： C08F236/20 ,  C08F8/08 ,  C08F8/20 ,  C08F8/30 ,  C08F8/42 ,  C08F10/00 ,  C08F12/08 ,  C08F257/02 ,  C08F290/04 ,  C08F290/06 ,  C08F293/005 ,  C08F2438/01 ,  C08F2810/40 ,  C08G61/04 ,  C08G61/08 ,  C08L51/003 ,  C08L53/00 ,  C08L53/02 ,  C08F212/08 ,  C08L2666/02 ,  C08L2666/04 ,  C08F4/64196 ,  C08F112/08

摘要： The present invention relates to a process for preparing functionalized isotactic polystyrene, functionalized isotactic polystyrene which can be prepared by the process of the invention, the use of the functionalized isotactic polystyrene of the invention as macromonomer, a process for preparing a macroinitiator, a macroinitiator which can be prepared by the abovementioned process, the use of the macroinitiator for controlled free-radical polymerization, the use of the functionalized isotactic polystyrene of the invention as macromonomer, preferably in copolymerization with olefins, ROMP with cycloolefins or for coupling with silicone segments, a process for epoxidizing the functionalized isotactic polystyrene of the invention, epoxidized isotactic polystyrene which can be prepared by the abovementioned process and a process for preparing soft thermoplastic elastomers (TPEs) by metathesis polymerization of the functionalized isotactic polystyrene of the invention with suitable polymers which have terminal double bonds and soft thermoplastic elastomers which can be prepared by the process of the invention.

摘要翻译： 本发明涉及一种制备官能化全同立构聚苯乙烯的方法，其可通过本发明方法制备的官能化全同立构聚苯乙烯，本发明的官能化全同立构聚苯乙烯作为大分子单体的用途，大分子引发剂的制备方法，大分子引发剂 可以通过上述方法制备，使用大分子引发剂进行受控的自由基聚合，使用本发明的官能化全同立构聚苯乙烯作为大分子单体，优选与烯烃共聚，ROMP与环烯烃或与硅氧烷链段偶联， 环氧化本发明的官能化全同立构聚苯乙烯的方法，可通过上述方法制备的环氧化全同立构聚苯乙烯和通过本发明的官能化全同立构聚苯乙烯与合适聚合物的复分解聚合制备软热塑性弹性体（TPE）的方法 其具有末端双键和可通过本发明的方法制备的软质热塑性弹性体。

公开(公告)号：US20080045640A1

公开(公告)日：2008-02-21

申请号：US11577565

申请日：2005-10-20

申请人： Volker Warzelhan ,  Thomas Breiner ,  Konrad Knoll ,  Chirag Tejuja

发明人： Volker Warzelhan ,  Thomas Breiner ,  Konrad Knoll ,  Chirag Tejuja

IPC分类号： C08K9/04

CPC分类号： C08L53/02 ,  C08F297/04 ,  C08F297/044 ,  C08L2666/28

摘要： The invention relates to a nanocomposite containing (I) a star-shaped, branched block copolymer made of vinylaromatic monomers and dienes and (II) a layer silicate. The invention also relates to a method for the production thereof.

摘要翻译： 本发明涉及含有（I）由乙烯基芳族单体和二烯制成的星形支链嵌段共聚物和（II）层状硅酸盐的纳米复合材料。 本发明还涉及其制备方法。