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31.发明授权公开(公告)号：US06660431B1
公开(公告)日：2003-12-09
申请号：US09913013
申请日：2001-08-08
申请人： Sou Kuranaka , Akihiro Maeda , Yoshio Moriwaki
发明人： Sou Kuranaka , Akihiro Maeda , Yoshio Moriwaki
IPC分类号： H01M458
CPC分类号： H01M4/242 , H01M4/383 , H01M10/345 , Y02E60/124 , Y10S420/90
摘要： The present invention relates to a hydrogen storage alloy electrode composed of a hydrogen storage alloy having a CaCu5 region and a Ce2Ni7 region in the crystal structure and satisfies the relational formula: p:q=1:(4+a), where p is the sum of the mole fraction of an element occupying the Ca site of the CaCu5 region and the mole fraction of an element occupying the Ce site of the Ce2Ni7 region, q is the sum of the mole fraction of an element occupying the Cu site of the CaCu5 region and the mole fraction of an element occupying the Ni site of the Ce2Ni7 region, and −0.2≦a≦0.4. Accordingly, although the hydrogen storage alloy electrode contains a little or no Co, it is possible to obtain an electrode having little deterioration due to pulverization of the alloy and a high capacity.
摘要翻译： 本发明涉及一种储氢合金电极，其由在晶体结构中具有CaCu5区域和Ce2Ni7区域的储氢合金构成，并且满足关系式：p = q = 1：（4 + a），其中p为 占据CaCu5区域的Ca位置的元素的摩尔分数和占Ce2Ni7区域的Ce位点的元素的摩尔分数之和，q是占据CaCu5的Cu位点的元素的摩尔分数之和 区域和占据Ce2Ni7区域的Ni位点的元素的摩尔分数，以及-0.2 <= a <= 0.4。 因此，虽然储氢合金电极含有很少或不含Co，但是可以获得由于合金粉碎和高容量而导致的劣化很小的电极。
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公开(公告)号：US06333124B1
公开(公告)日：2001-12-25
申请号：US09254365
申请日：1999-03-04
申请人： Yoshio Moriwaki , Akira Iwase , Susumu Kitaoka , Isao Matsumoto
发明人： Yoshio Moriwaki , Akira Iwase , Susumu Kitaoka , Isao Matsumoto
IPC分类号： H01M202
CPC分类号： H01M2/0272 , B21D22/28 , H01M2/0202 , H01M2/0217 , H01M2/0225 , H01M2/027 , H01M2/0275 , H01M2/0287 , Y10T29/49108
摘要： A battery has elements for electromotive-force accommodated in a metal outer can which has a bottom having a cylindrical, prismatic or similar shape. The ratio of the bottom thickness (TA) the side thickness (TB) is 1.5-7.0. The metal outer can contains primarily iron and a layer of nickel is provided on at least the inner face of the battery. Shallow grooves are formed on the nickel layer perpendicular to the bottom face. An iron-based metallic sheet formed with a nickel layer on at least one face is subjected to drawing forming into a tubular shape having a bottom, continuous ironing processing being performed such that the side of the can formed in the tubular shape has an ironing ratio in the range of 20% to 90% and a metal outer can is thereby manufactured having a ratio of a bottom thickness to its side thickness from 1.5 to 7.0, having a cylindrical shape, prismatic shape or shape similar thereto, and with shallow longitudinal grooves formed in a nickel layer provided on the battery inside face.
摘要翻译： 电池具有容纳在金属外罐中的电动势的元件，其具有圆柱形，棱柱形或类似形状的底部。 底部厚度（TA）与侧面厚度（TB）之比为1.5-7.0。 金属外壳主要包含铁，并且至少在电池的内表面上设置一层镍。 在垂直于底面的镍层上形成浅槽。 在至少一个面上形成有镍层的铁基金属片被拉伸成形为具有底部连续熨烫加工的管状，使得形成为管状的罐的侧面具有熨烫比 在20％至90％的范围内，并且由此制造具有底部厚度与其侧面厚度的比率为1.5至7.0的金属外罐，其具有圆柱形形状，棱柱形状或类似形状，并且具有浅纵向凹槽 形成在设置在电池内侧的镍层中。
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公开(公告)号：US06258480B1
公开(公告)日：2001-07-10
申请号：US09284304
申请日：1999-04-09
申请人： Yoshio Moriwaki , Akira Iwase , Susumu Kitaoka , Mamoru Iida , Isao Matsumoto
发明人： Yoshio Moriwaki , Akira Iwase , Susumu Kitaoka , Mamoru Iida , Isao Matsumoto
IPC分类号： H01M0204
CPC分类号： H01M2/0275 , H01M2/0217 , H01M2/023 , H01M2/0237 , H01M2/0272 , H01M6/10 , H01M10/0525 , Y10T29/49108 , Y10T29/53135
摘要： A battery accommodates elements for electromotive-force within a metal case. This metal case is a metal case having a bottom wherein the bottom thickness/side thickness ratio has a value of 1.2-4.0 and has a cylindrical, prismatic or similar shape. The metal case is constructed of a metal material whose chief constituent is aluminum. Furthermore, it is desirable that a multiplicity of shallow grooves perpendicular to a bottom face are formed in at least a battery inside face of the metal case and moreover that a nickel layer is provided on the battery inside face. The metal case is made by DI processing involving drawing and ironing, to have a value of bottom thickness/side thickness ratio which was hitherto unavailable,i.e., 1.2-4.0 can be obtained.
摘要翻译： 电池容纳金属外壳内的电动元件。 该金属壳体是具有底部的金属壳体，其中底部厚度/侧壁厚度比值为1.2-4.0，并且具有圆柱形，棱柱形或类似形状。 金属外壳由主要成分为铝的金属材料构成。 此外，在金属壳体的至少一个电池内表面中形成垂直于底面的多个浅槽，并且还在电池内侧设置有镍层。 金属外壳由涉及拉丝和熨烫的DI加工制成，具有迄今为止不能得到的底部厚度/厚度比的值，即可得到1.2-4.0。
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公开(公告)号：US5468309A
公开(公告)日：1995-11-21
申请号：US120244
申请日：1993-09-13
CPC分类号： C01B3/0031 , H01M4/383 , Y02E60/327 , Y10S420/90
摘要： A hydrogen storage alloy electrode comprising a hydrogen storage alloy having a major phase of C15 (MgCu.sub.2) type Laves phase with a composition expressed as ZrMn.sub.w M.sub.x Cr.sub.y Ni.sub.z (where M is one or more elements selected from V and Mo), or its hydride. In this formula, one composition range is 0.6.ltoreq.w.ltoreq.0.8, 0.1.ltoreq.x.ltoreq.0.3, 0
摘要翻译： 一种储氢合金电极，其包含具有表现为ZrMnwMxCryNiz（其中M为选自V和Mo中的一种或多种元素）的组成的C15（MgCu2）型Laves相的主相的储氢合金或其氢化物。 在该公式中，一个组成范围是0.6≤x≤0.8,0.1≤x≤0.3,0≤y≤0.2,0.2≤z≤5.5，另一个 组成范围为0.6≤0.08,0.1≤x≤0.3,0≤y≤0.2,0.8≤z≤2.2。
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公开(公告)号：US07481853B2
公开(公告)日：2009-01-27
申请号：US11383228
申请日：2006-05-15
申请人： Sumihito Ishida , Keisuke Tanaka , Yoshio Moriwaki , Hideo Kaiya
发明人： Sumihito Ishida , Keisuke Tanaka , Yoshio Moriwaki , Hideo Kaiya
CPC分类号： H01M10/052 , H01M2/0212 , H01M2/20 , H01M4/04 , H01M6/42 , H01M10/0565 , Y10T29/4911 , Y10T29/49114
摘要： A non-aqueous electrolyte secondary battery comprising: a positive electrode plate including an outer jacket comprising a sheet-shaped positive electrode current collector and a positive electrode active material layer formed on an inner surface of the outer jacket except for a peripheral portion thereof; a negative electrode plate including an outer jacket comprising a sheet-shaped negative electrode current collector and a negative electrode active material layer formed on an inner surface of the outer jacket except for a peripheral portion thereof; a separator layer comprising a polymer electrolyte interposed between the positive electrode active material layer and the negative electrode active material layer, wherein the peripheral portion of the positive electrode current collector and the peripheral portion of the negative electrode current collector are bonded together, with an insulating material interposed therebetween.
摘要翻译： 一种非水电解质二次电池，包括：正极板，包括外护套，所述外护套包括片状正电极集电体和形成在所述外护套的除了其周边部分的内表面之外的正极活性物质层; 包括外护套的负极板，所述外护套包括形成在所述外护套的除了其周边部分的内表面之外的片状负极集电体和负极活性物质层; 隔离层，其包含插入正极活性物质层和负极活性物质层之间的聚合物电解质，其中正极集电体的周边部分和负极集电体的周边部分用绝缘体 介于其间的材料。
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公开(公告)号：US06338917B1
公开(公告)日：2002-01-15
申请号：US09201843
申请日：1998-12-01
IPC分类号： H01M432
CPC分类号： H01M10/345 , H01M4/52 , H01M10/26 , Y02E60/124
摘要： A nickel positive electrode including an active material mixture mainly composed of a nickel oxide and an electrically conductive support, a metal and/or an oxide thereof including elements effective for increasing oxygen overvoltage, preferably at least one element selected from Ca, Ti, Nb, Cr, Y and Yb is contained in a conducting agent such as metallic Co and/or Co oxide added to supplement the electrical conductivity of the active material. By virtue of this construction, the decrease of charging efficiency caused by increase of battery temperature and decrease of the oxygen overvoltage with charging of the battery can be inhibited and the charging efficiency can be improved in a wide temperature atmosphere. Thus, a nickel-metal hydride storage battery of high capacity can be provided.
摘要翻译： 包括主要由氧化镍和导电载体组成的活性物质混合物的镍正极，包含有效提高氧过电压的元素的金属和/或氧化物，优选选自Ca，Ti，Nb， Cr，Y和Yb包含在添加的金属Co和/或Co氧化物等导电剂中以补充活性物质的导电性。 通过这种结构，可以抑制由于电池温度升高引起的充电效率的降低和电池充电时的氧过电压的降低，并且可以在宽温度的气氛中提高充电效率。 因此，可以提供高容量的镍氢蓄电池。
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公开(公告)号：US6127064A
公开(公告)日：2000-10-03
申请号：US138754
申请日：1998-08-24
IPC分类号： H01M2/02
CPC分类号： H01M2/0257 , H01M2/0217
摘要： A jar can for a secondary battery is formed by deep-drawing a clad material prepared by bonding an aluminum sheet and an iron sheet to each other. A nickel layer is formed between the iron sheet and the aluminum sheet. Another nickel layer is formed on another surface of the iron sheet. Thus, a lightweight jar can for a secondary battery having high rigidity is obtained.
摘要翻译： 二次电池的罐可以通过将通过将铝板和铁板彼此粘合而制备的复合材料进行深冲压来形成。 在铁板和铝板之间形成镍层。 在铁板的另一个表面上形成另一个镍层。 因此，获得了具有高刚度的二次电池的轻质罐罐。
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38.发明授权
公开(公告)号：US5962156A
公开(公告)日：1999-10-05
申请号：US801340
申请日：1997-02-19
CPC分类号： C22C1/0441 , H01M4/383 , Y02E60/327 , Y10S420/90
摘要： A nickel-metal hydride storage battery having a high capacity and excellent cycle life is disclosed. The battery employs, as its material for the negative electrode, a hydrogen storage alloy powder having a composition represented by the general formula Zr.sub.1-x M3.sub.x Mn.sub.a Mo.sub.b Cr.sub.c M1.sub.d M2.sub.e Ni.sub.f, where M1 represents at least one element selected from the group consisting of V, Nb and rare earth elements, M2 represents at least one element selected from the group consisting of Fe, Co and Cu, and M3 represents at least one element selected from the group consisting of Ti and Hf, and where 0.ltoreq.x.ltoreq.0.3, 0.3.ltoreq.a.ltoreq.0.7, 0.01.ltoreq.b.ltoreq.0.2, 0.05.ltoreq.c.ltoreq.0.3, 0.ltoreq.d.ltoreq.0.1, 0.ltoreq.e.ltoreq.0.2, 0.8.ltoreq.f.ltoreq.1.3, and 1.6.ltoreq.a+b+c+d+e+f.ltoreq.2.2, and wherein said hydrogen storage alloy has at least one of a Laves phase having a crystal structure of the MgCu.sub.2 -type (C15) and a Laves phase having a crystal structure of the MgZn.sub.2 -type (C14), and wherein a sum of integrated intensities of diffraction peaks other than those attributed to the presence of said Laves phase is not more than 5% of a sum of integrated intensities of all diffraction peaks in a diffraction angle 2.theta. of 10.degree. to 80.degree. in a powder X-ray diffraction pattern by Cu K.alpha. radiation.
摘要翻译： 公开了一种具有高容量和优异的循环寿命的镍氢蓄电池。 作为负极材料，电池使用具有通式Zr1-xM3xMnaMobCrcM1dM2eNif表示的组成的储氢合金粉末，其中M1表示选自V，Nb和稀土元素中的至少一种元素， M2表示选自Fe，Co和Cu中的至少一种元素，M3表示选自Ti和Hf中的至少一种元素，并且其中0≤x≤0.3,0.3， = a = 0.2,0.8， = f
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公开(公告)号：US5879429A
公开(公告)日：1999-03-09
申请号：US827080
申请日：1997-03-26
CPC分类号： B22F1/025 , C01B3/0084 , H01M4/242 , H01M4/383 , Y02E60/327 , Y02P70/54 , Y10S420/90
摘要： A method for producing a hydrogen storage alloy electrode comprising the step of treating a hydrogen storage alloy by immersing it in an alkaline solution containing cobalt ion or copper ion at a high temperature at a stage wherein the alloy is in powder state before formed into an electrode and/or at a stage wherein the alloy has been formed into an electrode. By this treatment, a hydrogen storage alloy electrode having an excellent high-rate discharge performance at a low temperature is obtained.
摘要翻译： 一种储氢合金电极的制造方法，其特征在于，具有以下步骤：将所述储氢合金浸入含有钴离子或铜离子的碱性溶液中的高温下，在合金处于粉末状态之前，形成电极 和/或其中合金已经形成电极的阶段。 通过该处理，获得了在低温下具有优异的高倍率放电性能的储氢合金电极。
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公开(公告)号：US5837317A
公开(公告)日：1998-11-17
申请号：US813889
申请日：1997-03-07
申请人： Yoshio Moriwaki , Yoichi Izumi , Yasuharu Yamamura , Hideo Kaiya
发明人： Yoshio Moriwaki , Yoichi Izumi , Yasuharu Yamamura , Hideo Kaiya
IPC分类号： C22C1/00 , B22F1/02 , C22C1/04 , H01M4/26 , H01M4/38 , H01M10/30 , B05D7/00 , B05D3/02 , B05D3/12 , B05D5/12
CPC分类号： C22C1/0441 , B22F1/025 , H01M4/383 , Y02P70/54
摘要： The present invention provides a method of producing a hydrogen storage alloy low in cobalt content which can restrains a decrease in cycle life characteristic and preservation characteristic of an alkaline storage battery when the alloy is used as a negative electrode. The method includes the following steps. An Mm-Ni system hydrogen storage alloy which has a crystal structure of CaCu.sub.5 and contains 15 atom % or less of cobalt is powdered to have an average particle diameter of 10-100 .mu.m. Then, the powdered alloy is immersed in a treatment solution at 80.degree.-130.degree. C., the treatment solution comprising an alkaline aqueous solution containing 10 g/l or more of lithium hydroxide and having a specific gravity of 1.1 or higher, and cobalt ions which is contained in the alkaline aqueous solution, thereby forming a layer containing nickel and cobalt in higher concentration than in the bulk of the powdered alloy onto the alloy surface.
摘要翻译： 本发明提供一种低合金含量的储氢合金的制造方法，其能够抑制在将该合金用作负极时碱性蓄电池的循环寿命特性和保存特性的降低。 该方法包括以下步骤。 将具有CaCu 5的晶体结构并含有15原子％以下的钴的Mm-Ni体系的储氢合金粉碎成平均粒径为10〜100μm。 然后，将粉末状合金浸入80〜130℃的处理液中，处理液含有10g / l以上的氢氧化锂，比重为1.1以上的碱性水溶液，钴 离子，其包含在碱性水溶液中，从而在合金表面上形成含有比在粉末状合金中高的浓度的含有镍和钴的层。
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