公开(公告)号：US4438481A

公开(公告)日：1984-03-20

申请号：US429311

申请日：1982-09-30

申请人： Jeffrey Phillips ,  Hiroshi Takei

发明人： Jeffrey Phillips ,  Hiroshi Takei

IPC分类号： H01G9/00 ,  H01G9/155 ,  B01J21/02

CPC分类号： H01G9/155 ,  Y02E60/13

摘要： An electrical capacitor is described which comprises a housing, a pair of electrodes in said housing, one of said electrodes being composed of a mixture of carbon particles and an electrolyte and the other electrode being composed of a mixture of lead metal and the same electrolyte, and an ionically conductive separator means between and in contact with said pair of electrodes, electronically separating said electrodes from each other, wherein the electrolyte comprises an acidic solution of soluble sulfate salts.

摘要翻译： 描述了一种电容器，其包括壳体，所述壳体中的一对电极，所述电极中的一个由碳颗粒和电解质的混合物组成，另一个电极由铅金属和相同电解质的混合物组成， 并且离子导电分离器在所述一对电极之间接触并与之接触，将所述电极彼此电子分离，其中所述电解质包含可溶性硫酸盐的酸性溶液。

公开(公告)号：US20190115609A1

公开(公告)日：2019-04-18

申请号：US15787637

申请日：2017-10-18

申请人： Jeffrey Phillips

发明人： Jeffrey Phillips

IPC分类号： H01M8/18 ,  H01M4/52 ,  H01M4/60 ,  H01M8/0202 ,  H01M8/2455 ,  H01M8/04537 ,  H01M8/0444 ,  H01M4/36

摘要： A novel high cycle life, low cost hybrid redox flow battery that has application in the storage of energy generated by solar cells, windmills and other means is described. By combining a solid battery positive electrode with a redox flow negative electrode, the volumetric energy density of the system is maximized and footprint minimized for medium scaled installations of multi kilowatt-hour size as may be envisioned in domestic distributed power systems. The positive electrode is a high cycle life rechargeable nickel hydroxide electrode in alkaline solution. The negative active material is a low cost organic chemical such as a substituted anthroquinone dissolved in an alkaline electrolyte and stored external to the negative plate of the electrochemical device. The material of the negative plate is high surface area and capable of facilitating the oxidation and reduction reactions of the negative active material. The negative and positive electrodes are separated by an electronically insulating but ionically conducting separator material that allows ionic mobility and the generation of electric current when charging or discharging of the battery takes place. Ideally, an ion exchange membrane would separate the positive and negative active material in order to maximize service life and reduce intermingling of active material.

公开(公告)号：US08048566B2

公开(公告)日：2011-11-01

申请号：US12432639

申请日：2009-04-29

申请人： Mingming Geng ,  Jeffrey Phillips ,  Samaresh Mohanta

发明人： Mingming Geng ,  Jeffrey Phillips ,  Samaresh Mohanta

IPC分类号： H01M4/13 ,  H01M4/42 ,  H01M4/48 ,  H01M4/32 ,  H01M10/26

CPC分类号： C01G53/04 ,  B82Y30/00 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2004/84 ,  H01G11/30 ,  H01M4/26 ,  H01M4/32 ,  H01M4/362 ,  H01M4/52 ,  H01M4/624 ,  H01M10/30 ,  Y02E60/13 ,  Y02T10/7022

摘要： The nickel hydroxide particles for a nickel hydroxide electrode may be treated using an alkaline solution of a strong oxidizing agent such as sodium or potassium persulfate to modify the surface nickel hydroxide structure. The resulting modified surface structure has been found to impart various benefits to electrodes formed from the nickel hydroxide. It is believed that the oxidation of cobalt compounds at the surface of the nickel hydroxide particles results in a highly conductive cobalt compound that plays an important role in the high reliability, high stability and high capacity utilization of nickel electrodes as described herein.

摘要翻译： 可以使用强氧化剂如过硫酸钠或过硫酸钾的碱溶液处理氢氧化镍电极用氢氧化镍颗粒，以改性表面氢氧化镍结构。 已经发现所得的改性表面结构对由氢氧化镍形成的电极赋予各种益处。 相信在氢氧化镍颗粒表面的钴化合物的氧化导致高度导电的钴化合物，其在如本文所述的镍电极的高可靠性，高稳定性和高容量利用中起重要作用。

公开(公告)号：US08043748B2

公开(公告)日：2011-10-25

申请号：US12365658

申请日：2009-02-04

申请人： Mingming Geng ,  Samaresh Mohanta ,  Jeffrey Phillips ,  Zeiad M. Muntasser ,  Jeff Barton

发明人： Mingming Geng ,  Samaresh Mohanta ,  Jeffrey Phillips ,  Zeiad M. Muntasser ,  Jeff Barton

IPC分类号： H01M10/26 ,  H01M4/13 ,  H01M10/24

CPC分类号： H01M4/26 ,  C01G51/04 ,  C01G53/04 ,  C01P2004/84 ,  H01M4/32 ,  H01M4/362 ,  H01M4/52 ,  H01M4/624 ,  H01M10/30

摘要： Active material for a positive electrode of a rechargeable alkaline electrochemical cell is made with nickel hydroxide particles or cobalt-coated nickel hydroxide particles treated with strongly oxidizing reagents such as alkali metal persulfate in alkaline solution. The active material also may be made with cobalt-coated nickel hydroxide particles having a high percentage of cobalt(III) on a surface or an average cobalt oxidation state of about 3 measured across the particles. The treated nickel hydroxide or cobalt-coated nickel hydroxide decreases the cobalt solubility in the alkaline electrolyte and increases the high-rate charge and discharge capability. The lower cobalt solubility decreases cobalt migration that can increase self discharge and lead to premature failure.

摘要翻译： 可充电碱性电化学电池的正极的活性材料由氢氧化镍颗粒或用强氧化剂如碱金属过硫酸盐在碱性溶液中处理的钴包覆的氢氧化镍颗粒制成。 活性材料也可以由在表面上具有高百分比的钴（III）的钴涂覆的氢氧化镍颗粒或在整个颗粒上测量的约3的平均钴氧化态约3制成。 经处理的氢氧化镍或钴包覆的氢氧化镍降低了在碱性电解液中的钴溶解度，并提高了高速率的充放电能力。 较低的钴溶解度降低了钴迁移，可以增加自放电并导致过早的失效。

公开(公告)号：US20110168565A1

公开(公告)日：2011-07-14

申请号：US13069879

申请日：2011-03-23

申请人： Feng Feng ,  Jeffrey Phillips ,  Sam Mohanta ,  Jeff Barton ,  Zeiad M. Muntasser

发明人： Feng Feng ,  Jeffrey Phillips ,  Sam Mohanta ,  Jeff Barton ,  Zeiad M. Muntasser

IPC分类号： C23C28/00

CPC分类号： H01M4/661 ,  C25D3/30 ,  C25D3/60 ,  C25D5/34 ,  C25D5/48 ,  C25D5/50 ,  C25D7/0614 ,  H01M4/244 ,  H01M4/26 ,  H01M4/32 ,  H01M4/667 ,  H01M10/24 ,  H01M10/30

摘要： An improved Ni—Zn cell with a negative electrode substrate plated with tin or tin and zinc during manufacturing has a reduced gassing rate. The copper or brass substrate is electrolytic cleaned, activated, electroplated with a matte surface to a defined thickness range, pasted with zinc oxide electrochemically active material, and baked. The defined plating thickness range of 40-80 μIn maximizes formation of an intermetallic compound Cu3Sn that helps to suppress the copper diffusion from under plating layer to the surface and eliminates formation of an intermetallic compound Cu6Sn5 during baking to provide adequate corrosion resistance during battery operation.

摘要翻译： 在制造期间镀有锡或锡和锌的负极基板的改进的Ni-Zn电池具有降低的放气率。 将铜或黄铜衬底电解清洗，活化，用无光泽表面电镀至规定的厚度范围，用氧化锌电化学活性材料粘贴并烘烤。 限定的电镀厚度范围为40-80μIn，使金属间化合物Cu3Sn的形成最大化，有助于抑制铜从电镀层扩散到表面，并消除了在烘烤过程中形成金属间化合物Cu6Sn5，以在电池工作期间提供足够的耐腐蚀性。

公开(公告)号：US20110086252A1

公开(公告)日：2011-04-14

申请号：US12903004

申请日：2010-10-12

申请人： Jeffrey Phillips

发明人： Jeffrey Phillips

IPC分类号： H01M2/12 ,  H01M10/04

CPC分类号： H01M2/1264 ,  H01M2/022 ,  H01M2/027 ,  H01M2/0275 ,  H01M2/0287 ,  H01M2/1229 ,  H01M10/0431 ,  H01M10/286 ,  H01M10/30 ,  H01M10/345 ,  Y10T29/4911

摘要： Rechargeable nickel zinc cells, and methods of manufacture, of a configuration that utilizes a positive can with a vent cap at the positive pole of the battery are described.

摘要翻译： 对可充电的镍锌电池及其制造方法进行说明，该电池的正极具有利用正的罐与通气盖的结构。

公开(公告)号：US07829221B2

公开(公告)日：2010-11-09

申请号：US10899593

申请日：2004-07-26

申请人： Jeffrey Phillips

发明人： Jeffrey Phillips

IPC分类号： H01M4/00 ,  H01M4/48 ,  H01M4/58

CPC分类号： H01M4/244 ,  H01M4/32 ,  H01M10/30

摘要： A nickel-zinc galvanic cell is provided, having a zinc oxide negative electrode, a nickel oxide positive electrode, and an alkaline electrolyte. Chemical additives are placed in each of the negative and positive electrodes. The positive nickel hydroxide electrode contains a mixture of cobalt oxide contained within a nickel oxide matrix in the range of about 1% to 10%, and cobalt metal in the range of about 1% to 10%, by weight. The negative zinc oxide electrode may contain oxides other than the oxide of zinc, which have redox potentials which are negative of −0.73 volts. Also, the metal oxide additives to the negative zinc oxide electrode are such as to inhibit release of soluble cobalt from the nickel oxide negative electrode prior to a formation charge being applied to the electrochemical cell.

摘要翻译： 提供了具有氧化锌负极，氧化镍正极和碱性电解质的镍锌原电池。 化学添加剂被放置在负极和正极中的每一个中。 正极氢氧化镍电极含有氧化镍基质中含有约1％至10％范围内的钴氧化物和约1％至10％重量的钴金属的混合物。 负极氧化锌电极可以含有除氧化锌以外的氧化物，其氧化还原电位为-0.73伏负。 此外，负电荷氧化锌电极的金属氧化物添加剂在施加到电化学电池之前，可以抑制可溶性钴从氧化镍负极的释放。

公开(公告)号：USRE40727E1

公开(公告)日：2009-06-09

申请号：US11598153

申请日：2006-11-09

申请人： Jeffrey Phillips

发明人： Jeffrey Phillips

IPC分类号： H01M4/48

CPC分类号： H01M4/244 ,  H01M4/32 ,  H01M4/48 ,  H01M4/62 ,  H01M4/626 ,  H01M10/24 ,  H01M10/26 ,  H01M10/30

摘要： A nickel zinc alkaline cell has a zinc oxide negative electrode supported on a conductive substrate, an alkaline electrolyte, and a positive electrode having nickel hydroxide paste supported on a conductive substrate. The negative zinc oxide electrode comprises 85% to 95% zinc oxide powder, 1% to 10% bismuth oxide, 1% to 2% of a binder, and 0.05% to 5% by weight of a fluoride salt chosen from the group consisting of: sodium, potassium, rubidium, caesium, lithium, and mixtures thereof. Typically, the fluoride salt is potassium fluoride, in the amount of 0.5% by weight of the zinc oxide.

公开(公告)号：US20080166632A1

公开(公告)日：2008-07-10

申请号：US11978209

申请日：2007-10-26

申请人： Jeffrey Phillips ,  Jason Zhao

发明人： Jeffrey Phillips ,  Jason Zhao

IPC分类号： H01M10/36

CPC分类号： H01M10/0431 ,  H01M4/38 ,  H01M10/30 ,  Y10T29/49115

摘要： Methods of manufacturing a rechargeable power cell are described. Methods include providing a slurry, paste, or dry mixture of negative electrode materials having low toxicity and including dispersants to prevent the agglomeration of particles that may adversely affect the performance of power cells. The methods utilize semi-permeable sheets to separate the electrodes and minimize formation of dendrites; and further provide electrode specific electrolyte to achieve efficient electrochemistry and to further discourage dendritic growth in the cell. The negative electrode materials may be comprised of zinc and zinc compounds. Zinc and zinc compounds are notably less toxic than the cadmium used in nickel cadmium batteries. The described methods may utilize some production techniques employed in existing NiCad production lines. Thus, the methods described will find particular use in an already well-defined and mature manufacturing base.

摘要翻译： 描述了可再充电电池的制造方法。 方法包括提供具有低毒性并包括分散剂的负极材料的浆料，糊剂或干混合物，以防止可能不利地影响动力单元性能的颗粒的聚集。 该方法利用半透膜分离电极并最小化枝晶的形成; 并进一步提供电极特异性电解质以实现有效的电化学和进一步阻止细胞中的树突生长。 负极材料可以由锌和锌化合物组成。 锌和锌化合物的毒性明显低于镍镉电池中使用的镉。 所描述的方法可以利用现有NiCad生产线中使用的一些生产技术。 因此，所描述的方法将在已经定义明确且成熟的制造基地中得到特别的应用。

公开(公告)号：US07255720B2

公开(公告)日：2007-08-14

申请号：US10471485

申请日：2002-03-15

申请人： Jeffrey Phillips

发明人： Jeffrey Phillips

IPC分类号： H01M4/48

CPC分类号： H01M4/244 ,  H01M4/04 ,  H01M4/26 ,  H01M4/364 ,  H01M4/62 ,  H01M4/622 ,  H01M10/24 ,  Y10T29/49115

摘要： A zinc electrode for use in alkaline batteries comprises a mixture of 0.425 to 1.55 volume parts of zinc oxide with a volume part of a metallic oxide chosen from the group consisting of: calcium oxide, barium oxide, and mixtures thereof, together with hydroxy-ethyl cellulose, an oxide dispersant chosen from the group consisting of: soap derivatives, anionic polyelectrolytes, anionic surfactants, and mixtures thereof, and a binder. The electrode is prepared by mixing zinc oxide with the chosen metallic oxide in an aqueous medium such as water or potassium hydroxide, stirring overnight, filtering and drying the mixture, optionally adding a further small amount of zinc oxide, optionally adding other metallic oxides, and adding hydroxy-ethyl cellulose, an oxide dispersant, and a binder. The aqueous paste os slurry thus formed is placed on a conductive substrate, drawn through a sizing gap, cut and dried, to form low cost pasted zinc oxide electrodes.

摘要翻译： 用于碱性电池的锌电极包括0.425至1.55体积份量的氧化锌与体积部分金属氧化物的混合物，其选自氧化钙，氧化钡及其混合物，以及羟基乙基 纤维素，选自以下的氧化物分散剂：皂衍生物，阴离子聚电解质，阴离子表面活性剂及其混合物，以及粘合剂。 电极通过在水性介质如水或氢氧化钾中混合氧化锌和选择的金属氧化物，搅拌过夜，过滤并干燥混合物，任选地加入少量氧化锌，任选地加入其它金属氧化物，以及 加入羟乙基纤维素，氧化物分散剂和粘合剂。 将如此形成的水性浆料浆料放置在导电基材上，通过筛分间隙拉伸，切割并干燥，形成低成本的糊化氧化锌电极。